Meohole 2 Ale [phe zt My SEC Phenels , Hand book for Examination INV AVENE = 1 Elbe Covtd > egonpdy ¢ ec dy4. block Element - ip ODEL QUESTION PAPER- 1 Use Time: 3 how isan : Max Marks: 79 1) The question paper has four parts: A, B,C and D. All parts are compulsory, 2) Write balanced chemical equations and draw labeled diagrams whenever required: : 3) Use log table "Ss and simple calculator if necessary. (Use of Scientific calculators is not allowed) ~ | PARTA | I Answer ALL of the following. [Each question carries 1 mark] 10x1=10 (Answer each question in one wo rd or in one sentence) + What are isotonic solutions? « Soln What is the Van't Hoff factor for potassium sulphate in very dilute aqueous \ >> ~ solution? 7 ve Selo £C 3. Write the e battery. quation for the reaction occurring at the anode in the lead storage What is collision frequency? State Hardy ~ Schulze tule. : Which type of ore is concentrated by froth floatation? x Noble gases have very low boiling point, Why? Give the IUPAC name of CH; = CHC, What is the oxidizing agent used in Etard’s reaction? . Give an example for a -amino acid which is basic. 7 PART-B FIVE of the following. each question carries 2 marks} 5x2=10 Nl How ‘many tetrahedral and octahedral voids are possible if the mumber of close packed spheres in two layers is N? II Answer any Scanned with CamScannerdy | 23. a) Transition metals and their comps dt P+ 24. How is potassium permanganate prepared? Give equations, Cb) What is crystal field splitting? KOW glycol a7 80 Sega e KO What are P and Q? 17. What are analgesics? Give an example, 18. What are food preservatives? Give an example. PART-C TI Answer any FIVE of the following. i 19. What is the role of the following in the e ‘ch question carries 3 marks)” §x3=15 -xtraction of Iron. (i) Coke, (ii) Carbon monoxide, (iii) Lime stone. @) 20. Describe with equations the manufacture of nitric acid by Ostwald's Process. (3), 21. Mention three anomalous behavior of oxygen, @) 22. a) Complete the following equation: . 6NaOH + 3Cl, + + +3H,0 Hot & concentrated b) Interhalogen compounds are more reactive than halogens. Why? (+1) ounds are used as catalysts, Give two reasons, ~~ b) Write the outer electronic configuration of chromium (atomic no.=24) (241) @) 25. a) Mention any two applications of coordination compounds, @) Scanned with CamScanner‘Hand book for Examination 26. For [Co(en)s]Chs: CC i) — Give the UPAC name cc ii) Give the coordination number of the central metal ion Cc Ciii) What type of stereoisomerism does it exhibit? (3) PART -D TV . Answer any THREE of the following, [Each question carries § marks] 3x5"15 27. a) Calculate the packing efficiency in CCP unit cell. axk Sb) What is ferromagnetism? Give an example for ferromiagnetic substance, (342) _ “28. a) The vapour pressure of pure benzene at a certain temperature is 0.850 - Sle bar, When 0.5g of a non-volatile solute is added to 39.0g of benzene 54 [molar mass of benzene 78g mol], vapour pressure of the solution is 0.845 bar. What is the molar mass of a non-volatile solute? State Raoult's law for a solution of 2 volatile liquids. Give an example for liquid mixture that shows negative deviation from Raoult's law. (342) “~ The resistance of solution of a salt occupying a volume between two platinum electrodes 1.8cm apart and 5.4 cm? in area was found to be 32 ohms. Calculate the conductivity of the solution. ¥C b)_ Write the symbolic representation of standard hydrogen electrode and give its standard potential value. G42) , 30.a) Derive an integrated rate equation for the velocity constant for a first order reaction. : b) Draw a graph of concentration of R verstis time for a zero order reaction: R> products. What is the intercept of the line? (3+2) 31.a)Give any three -differences between physical adsorption and chemical adsorption. b) What is i) Tyndall effect ii) Peptisation? G+2) V Answer any FOUR of the following. [Each question carries 5 marks] 4x5=20 1) bw 320) Explain i) Wurtz-Fitting reaction. Scanned with CamScanner2) 2) 2) 20 Han ook fo Examination tion with’an example for ach HA <> i) Swartz rds SN? reaction? j/\-+ BY Which one ofthe folosing is move eactive towat cube, (CH,),,CHBr, (CH), CBF ay tt | ig a.) niin mechanism f dehydration of ethanol 9 STE inversi seb) How is salieylie asi converted {nto aspirin? Give equation. oH) and Sw So besa i eae wi consented NaOH: Wits chemical Elimin Rehm and name the reason 7 : statem 1) Comptete the ftlowing equations = Grit i) RCOONa SS +Na,CO, isa Sate 6 Haloa ip cli, coon uss y__+ HC! replac ssa Whats Hinbera’s reagent? How ie itsed 1 sioguish primary SS - Mom secondary ane? oy dey te mao rede nth WINE gm” Riel caHNH, +CHCOCI > . Ret i) me : Uses bean 180. : iodot Oo Peete UNI 46.2) Write the Haworth’ssiractre of Malte. Dass 1) Menton any two importance of molec aes reso 6) Name the horinone that contains iodine en) Prep 37. a) How are polymers: classified based on source? yar > rel eu ean OER 7 2) name tne denon acid used aoe ofthe monomer in he : Fhanaacturer of terylene ny sd rs eR RR a is . c « o Us Et wt Ph a Scanned with CamScanner20k for Examination q 0 MODEL QUESTION PAPER -2 } 1 3 hours 15 min, Max Marks: 70 ions: The question paper has four parts: A, B, C and D. All parts are compulsory. i Write bale “ rae lanced chemical equations and draw labeled diagrams whenever a Use log tables and simple. calcul calculators is not allowed) MMO" Hf necessary. (Use of Scientific PART-A swer ALL of the following. (Each question carries1 mark] 10x1=10 nswer each question in one word or in one sentence) % ate Henry's Law. Go) i % aqueous Ethanol cannot be concentrated by further distillation. Give, \ = i ason. . values of three metals A,B and C are +0.34V, +1.37V and -0.76V spectively. Arrange them in the i increasing order of their reducing power te unit of rate constant of a reaction is mol" L s'. What is the order of the action? rite the mathematical expression for Freundlich adsorption isotherm. erition the method used to refine the metals having low melting point. ow is Xe" PtFy prepared? . hy is boiling point of ethyl bromide higher than that of ethyl chloride? . anhydrous AICI; oO + CH;co-cl. ——~>X +Ha Trite the structure of X in the above reaction. ‘ame a vitamin that is stored in liver and adipose tissues. PART -B aswer any FIVE of the following. [Each question carries 2 marks] 5x2=10 sompound Ar Bjerystallises in a FCC lattice in which A occupies cach Ws and D anauniac the centre af each face of the cube. Scanned with CamScannerHand book for Exeminaig EC 12. Mention an; 'y two factors on which conductivity of an electrolytic Solution depends, : 13. Write any two differences between order and molecularity of a reaction, "14. What is lanthanoid contraction? contraction. “aed Write any one consequence of lanthanoig )\\CIS. Name the organic Compound formed when vapours of tertiary butyl ‘alcohol ig Passed over heated copper at 573K. Write the equation. 16. How is propanenitrile Converted into propanal? Write the equation. 17. What are transquilizers? Give,an example. 18. What are ngn-ionic detergents? Which class of synthetic detergents are Used in the preparation of tooth Pates, PART-C TH Answer any FIVE of the following. [each 19. Draw a labelled diagram for the extraction of aluminium from purified alumina by Hall-Heroult process. Write the overall reaction taking place in the cell. What is the role of NasAIF¢ in the above process? question carries 3 marks] 5x3=15, @) 20. For the manufacture of amtnonia by Haber's process, i) Draw the flow chart - : ii) Write the chemical equation for the reaction involved and iii) Name the catalyst used in the reaction. . @) 21.a) Explain charring action of concentrated sulphuric acid on carbohydrate. Give the equation. 7 b) Complete the equation: 2PLOyy—As (2+1) 22. Name the gas liberated when concentrated HCI is heated with MnO, Give the equation for the reaction. Name the reagent used to obtain bleaching powder from chlorine. @) 234) Cu +? (aq)‘is more stable than Cu* onisation enthalpy. increases along transition elements from left to right :) Zn has highest E” value (M?* / M*) among 3d series clements, (+141) ‘Scanned with CamScannerHand book for Examination 24. a) What is the gas liberated when dike ee Crystals of potassium permanganate is heated to 513K? Axde Un b- Acidified potassium permanganate is treated with oxalate ion at 333K. ade +b) Complete the following equation: 2MnO; + 3Mn**+2H,0—>___—+ 4H". (2+1) ¢.C 25. Using Valence bond theory account for the geometry and magnetic property ~ of complex ion [CoF¢]* (Given: At. Number of Co = 27) @B ¢¢ 26.8) What is coordination isomerism? Give an example. ¢. >) Write the IUPAC name of the complex: [Ag(NH3)2] [Ag(CN)2] Q+) PART-D IV_ Answer any THREE of the following [Each question carries 5 marks] 3x5=15 27. a) Calculate the packing efficiency in CCP / FCC arrangement. b) Mention one consequence of metal excess defect. (4+1) \-98, a) The boiling point of benzene is 353.23K. When 1.80g of a non-volatile | _— CALS solute was dissolved in 90g of benzene, the boiling point is raised:to So\4_ 354.11K. Calculate the molar mass of the solute. (Ky for benzene =2.53K — kg mol") S:\.\« b), What is reverse osmosis? Mention any one of its use? ~% yy G2) +-C 29. a) Calculate EMF of the cell represents below. " ‘Zn/Zn* (c= 0.1M)||Cu* (c= 1M) |Cu at 25°C Given: E%, =+0.34V and Ey, =-0.76V -C. b) Write the reaction taken place at anode and cathode during corrosion of iron. . : (3+2) 30. a) Derive an integrated rate’equation for the velocity constant of a zero order reaction. b) A reaction is 50% complete in 2 hours and 75% complete in 4 hours. What is the order of reaction? Give reason. (342) 31. a) What is i) multi molecular colloid and_ ii) Peptization? b) Name the type of adsorption which is highly specific in nature. , c) Write the equations for the two steps involved in enzyme catalysis. (2+1+2) ery Scanned with CamScanner—s Hand book for Examinaian V Answer any FOUR of the following. [Each question carries 5 marks} 4x5=29 Ade \+ 32. a) How do you convert a aryl halide to diphenyl? Write the equation and name the reaction, . dy Sb) Write Sy2 mechanism of the conversion of mehy! chloride to methyl alcohol. (342) PA c- 33. a) Explain the mechanism of acid catalysed dehydration of ethanol into . ethene, )\xc_ 6) How is phenol manufactured from cumene? (342) 34. a) Write the chemical equation for the following conversions, i) Ethanoic acid to ethanoic anhydride ii) Ethanoic acid to acetamide ~ _ iii) Benzoic acid to m-nitrobenzoic acid b) Explain diazotization reaction of aniline.» (342) 35. a) Compiete the following equations. i) R-CsN—!#4 ii) R-NH, +CHCI, +3KOH (alcoholic) *".......43KC143H,0 iii) C.HJNH, +3Br, Sy SHBr b) Explain Clemensen’s reduction with an example, 42) 36, a) Name i) the sugar moiety present in DNA ii) Nitrogenous base present only in DNA, but not in RNA. b) What is a peptide bond? How many peptide bonds are present in a pentapéptide? ¢) Name a hormone which regulates the blood sugar level in the body. (2+2+1) 37. a) What is thermoplastic? Name the monomer of nylon-6 and give the partial structure of nylon-6. 7 b) What is a biodegradable synthetic polymer? Give an example (342) BR oR oe ee Scanned with CamScannerwa «Hand book for Existing MODEL QUESTION PAPER - 3 Time: 3 hours 15 min. Max Marks:79 Instructions: 1) The question paper has four parts: A, B, C and D. All parts are compulsory. 2) Write balanced chemical equations and draw labeled diagrams Whenever required, : 3) Use log tables and simple calculator if necessary. (Use of Scientific calculator is not allowed) PART-A I Answer ALL of the following. [Each question carries 1 mark] 10x1=10 {Answer each question in one word or in one sentence] Ce\21. Name the Phenomenon involved when a raw mango / an egg placed in a concentrated salt solution loses water and shrinks. s- \2. State Raoult’s law of a solutions containing non volatile solute. S2{ ‘© 3. Two metals A and B have reduction Potential values -0.76V and +0.34V Tespectively. Which of these will liberate hydrogen gas from dilute HyS0,? 4. Give the SI unit of rate constant of Second order reaction. 5. -What is an emulsion? 6. Name the flux used to remove Iron impurity from molten copper matte. 7. What is the product formed when xenon reacts with Pte? Jib 8, What is racemisation? Give reason: “electron withdrawing group increases the acidic strength of carboxylic acid.” - 10. What is a glycosidic linkage? PART-B II Answer any FIVE of the following. [each question carries 2 marks] 5x2=10 11. In terms of Band theory, explain metalljc conductor and insulator. ‘¢ C 12. Write the reactions occur at anode and cathode in Lechlanche Cell. Scanned with CamScanner© Hand book fo mndnation 13. A first order reaction half life period of the is found to have a rate constant 5.5 X 10" S$". reaction, Ae 014. Give reason:va) Mn exhibits the higher oxidation state of +7 among 3d series trans \ Yb) Cut 15. Mention the major p on elements, i paramagnetic and Cu’ is diamagnetic. roduct formed in the following pbe a) C,H,OH —fms uso, aa yb) CH,CH,OH —See.ths0,_, 40K alte 16. Explain with equation the 1 addition reaction of acetaldehyde with Sodium bisulphite. 17. Give one example cach for a) Antifertility drugs. b) Artificial Sweetner 18. What are synthetic deterg. which type of detergents? ents? Liquid dishwashing detergents comes under PART-C III Answer any FIVE of the following. (each question carties 3 marks] 5x3=15 19. (a) Give the composition ot nee (b) write the reactions taking place in slag formation zone and reduction zone in the extraction of iron. @) 20. a) Give the reactions of white phosphorus with (i) oxygen (ii) Excess of dry chlorine gas ? b) How copper reacts with dil. HNO}. + 21. Write the chemical reactions in the manufacture of concentrated sulphuric acid by CONTACT process. . @) 22. a) Complete the following equations i) H,S+3Cl, —> 48d ii) 2NaOH + Cl, ——> NaCl +... (cota a) +H,0 . b) Give reason: “ BrF; is more reactive than Br.” (2+1) ‘Scanned with CamScannerHand book for Examination 23. Give reason: » i) Transition elements exhibit variable oxidation states. ~ ii) T; ** ion is colourless, \ iii) Cu’ ion is diamagnetic (4141) A we 24.%) In the titration of Fe?* ions with KMnOs in acidic medium, why dil. HS0, u is used as-acid not dil. HCI? Ay de ) Write the general electronic configuration of 3d series of transition oo elements, (2+1) CC 25. Using VBT, explain the geometry and magnetic property of [Nicl,]*-. Given atomic number of N; = 28. oe ~ ¢-©26. a) Write the IUPAC name of coordination compound [Pt(NH,),Cl]Br. c © >) Write any two postulates of Wemer’s theory of Coordination compounds, = (142) PART-D IV Answer any THREE of the following [Eact question carries five marks) 3x5=15 27. a) Calculate the packing efficiency in a simple cubic lattice, b) Define the terms i) Lattice point ii) unit cell ¢) Give an example for metal deficiency defect by cation vacancy. (2+2+1) \-28. a) If 1-71g of sugar (molar mass = 342) is dissolved in 500em? ofa solution SoD Sis at 300k. What will be its Osmotic pressure? [Given R = 0.083 L bar K™ mol") \>\-~ b) Point out the difference between ideal solution and non ideal solution. (342) Soft \-¢ 29 a) The molar conductances of sodium chloride, hydrochloride and Sodium F acetate at infinite dilution are 126.45, 426.16 and 91.0 ohm’! cm? mot lat 25°C respectively. Calculate the molar conductance of acetic acid infinite dilution. y. (>) What are the products formed at anode and cathode when aqueous solution * ~~ of Sodium Chloride is electrolysed? : (+2) Scanned with CamScannerHand book for Examination A iaet 30. a) ‘iacriain fitst order reaction is half completed in 46 min. Calculate the rate stant and also time taken for 75% completing of the reaction. b) Mention the factors affecting the rate of reaction. G42) 31. a) Explain electrodialysis for the purification of colloid. / (4141) b) Define shape selective catalysis. Give an example. Jil. H2SO, ¢) What happens to entropy when a gas is adsorbed on a solid ? (24241) 'V Answer any FOUR of the following questions. [Each questlon carries $ marks] 4x5=20 @ny Mw 32. a) (i) Identify the type of hybridisation of carbon atom bonded to halogen atom in the following: (CH, ), C- X, CH, =CH -X . - Giver ‘ " n + Mae Gi) Give reason; Racemic mixture is optically inactive. 7 {fe Ub) Write Sand Meyer's reaction. (+2) . {co \ 33: a) Arrange water, ethanol and phenol in increasing order of acidity and give pounds. ' reason for your answer. (142) ’ b) Complete the following reactions:~ | vi 3x5=15 7 } ters 7 ! k a (2+2+1) cH ution ¢>5) 2 ity coon on . (342) ion. (342) (5/4 . + (CHsCo:0—2_> . dium | aol at : 34. a) Explain the addition mechanism of HCN to Aldehydes or Ketones. Vinfinite b) Write the chemical equations for the following conversions. re (i) Benzamide to Benzoic acid. nm (3+2) (ii) Propanone to propane. (iii) Acetie acid to chloroacetic acid. (243) Scanned with CamScannerHand b00k for Examinarn, 35.a) How does Benzenamine reacts with Ethanoic anhydride? Give equation, »). Identify the major product in the following. i) + OH” Qe pans % Pyridine — NHa + (CHs CO;0——— iti) ¢)- Sn+HCl : (233) No, —=#Q 36.a) — What'are essential amino acids? Is glycine an essential amino acid. ») How is a dipeptide formed? Give equation. ©) Mention the disease caused by vitamin‘C. (242+1) 37. a) How are polymers classified based on structures? b) (i) Name the type of attractive forces present in Elastomers (i) What is the other name for condensation polymerisation, (+2) Ba Scanned with CamScannerHand book for Examination . = MODEL QUESTION PAPER - 4 i Time: 3 hours 15 min, ’ x Marks: 70 Instructions: 1) The questi x eommisonre Paper has four Parts: A, B, C and D. All parts are a 2) Write balz 2) eee ‘anced chemical equations and draw labeled diagrams whenever 9 Use log tables and simple cal f i calculators isnot alone ple Cacwator I necessary. (Use of Scien )PART-A I Answer ALL of the follo h wing. [Each question carries 1 mark] 10x1=10 (Answer each question in ot me word or in one sentence) + Define ebullioscopic constant. Sa) 2 - A solution of an ester in benzene freezes at 0.84 K temperature below the freezing point of the solution, What is the molality of the solution if Kr of © benzene is 5.12 K kg mol ~ - Write the cathodic reaction of lead storage battery is in use. . Express the rate of the reaction in terms of different reactants and products for 2N,,0,(g) > 4NO, +0, (g) 4 5. Name the enzyme which converts milk into curd. 6. Name the reducing agent used in the separation of gold from it’s complex. 7. Complete the following reaction. XeF, +2H,O— >... HE 3-8. Why is the solubility of haloalkanes ‘in water is very low although they are . polar in nature? : 9. Give reason; aldehydes are more reactive than ketones. 10. Mention the bonding helps in stabilising the .— helix structure of proteins. Scanned with CamScanner+ Hand book for Examination PART-B TL Answer any FIVE of the following, [each question carrles 2 marks} 5x2=19 11. Name the type of attractive force present in the following type of solids, (i) Non-polar molecular solids. (ii) lonic solids, \.C- 12. What is specific conductivity? Mention its SI unit. 13, Show that the rate of first order reaction is double when the concentration of the reactant is doubled, uty \14. Calculate the magnetic moment of Co” (Z=27). 16, Mention any two uses of carboxylic acids. {AC 15. Give the meaning of the following terms a) ractified spirit) Power alcohol. 17. Explain the terms a) erizyme inhibitors .b): What is the therapeutic use of iodoform. 18. Which among the following acts as antiseptic and disinfectant? i) 0.2% solution of phenol ii) 1% solution of phenol PART-C III Answer any FIVE of the following [Each question carries 3 marks] 5x3=15 19. How to extract copper from copper matte? (3) 20. For the manufacture of ammonia by Haber process. a) Write chemical reaction. ‘ b) Mention the catalyst used. ©) Whatis the temperature maintained? (4H) 21.) “Give reason: Fluorine exhibits -1 (only one) oxidation state only. b) Most of the reactions with Fluorine are exothermic. c) Complete the reaction. 2Fe* +SO, +2H,O—->.. 22.a) Explain the action of chlorine on slaked lime. Give the equation. b) Give reasor chlorine. (+141) : The electron gain enthalpy of fluorine is less than that of (241) Scanned with CamScannerHand book for Examination 23.8) Complete the following equations Je ) Give the IUPAC name of [co(wH,), (8, 0)clJc1, C76 Using VBT explain the electronic configuration, imagnetic property of [Ni(CN),]~ (+141) (241) geometry, hybridization and 6) PART-D IV Answer any THREE of the following. {each question carries $ marks] 3 x5=15, 27. a) Calculate the packing efficiency in cubic close packing (CCP) lattice. b). Silver forms CCP lattice and edge length of its unit cell is (atomic mass = 107.9 U). X-ray studies of its crystals show that the 408.6 pm. Calculate the density of silver GH) 28:4) How will you determine the molecular mass of solute from Relative lowering of vapour pressure b) Ethylene glycol (molar mass = 62 g/mol ) is a common automobile AS antifreeze. Calculate the depression in freezing point of a solution > 2! 2— containing 12.4g of this substance in 100g of water. (Given K; for water=1.86 K kg mot G2) The molar conductivity of 0.025 mol L""methanoic acid is 46.1 scm? mol". Calculate its degree of dissociation. A° (H’) = 349.6 Sem? mol! and A° (HCOO)= 54.6 S em? mot Cb) Define the terms; i) cell constant ii) Equivalent conductivity (3+2) Scanned with CamScannerHand book for Eran, 30. a) Derive an integrated rate equation for the velocity constant for 2 fire order reaction. b) i) Give an example for a second order reaction. ii) Define the term ‘rate constant’. (3+2) 31.a) Explain the preparation of gold sol by Bredig’s arc method or elecry disintegration method. b) Write the mathematical expression and Graphical Representation of Freundilich Adsorption isotherm. ¢) Name the theory used to explain mechanism of Heterogeneous catalysis. a 1) V_ Answer any FOUR of the following questions (Each question carries § marks} 4x5=20 32va) _ Define the following terms; (i) Retension of configuration Gi) Inversion of configuration (iii) Recemization. upe\ ©) Write the chemical reaction in which diazonfum group in diazonium salt replaced by iodide ion. (3+2) p.C33.a) Write the reactions taking place in the preparation of Ethanol from Molasses. . yb) Write Reimer-Tiemann reaction. es) 34, a) Explain the mechanism of addition of hydrogen cyanide to aldehydes and ketones. b) Give reason: i) Carboxylic acids are more acidic than phenols. ii) Fluoroacetic acid is stronger acid than chloroacetic acid. G2) 35.a) Give the structures of A, B and C in the following; "C,H, NO, Fa ATSB CHONG b). Arrange the following amines in the decreasing order of their Basic strength. CsHs NH2, C:HsNHp, (CHs): NH G+) 36.a) Give one example each for; | (i) ANon-Reducing Sugar (ii) An Aldohexose. b) (i Write the zwitter ion structure for Alanine. ~~ Scanned with CamScannerHand book for Examination (1) Mention the numberof peptide bonds in a tripeptide. ©) Name the base present only in RNA but not in DNA 4241) 37.) How to obtain PHBV? Write any one use of PHBV. ») Write the name of the monomers for the polymer i) Bakelite ii) Natural Rubber (342) oe See ed ‘Scanned with CamScannerHand book for Ea natin MODEL QUESTION PAPER - 5 Time: 3 hours 15 min. Max Marks:79 Instructions: 4) The: question ‘paper has four parts:'A, B, C and D. All paris ayy compulsory, 5) Write balanced chemical equations and draw labeled diagrams Whenever required. 6) Use log tables and simple calculator if necessary. (Use of Scientific calculator is not allowed) PART-A Answer ALL of the following. (Each question caries | mark] 10x1=19 [Answer each question in one word or in one sentence] 1. Define molality. ©2. Give an example for a solution of the type liquid in solid, How many coulombs of charge required for the oxidation of one mole of water to oxygen? : Draw the distribution curve showing energies among gaseous molecules. ~ Give an example for oil in water emulsion, 6. Name the refining method w here the metal is converted into its volatile compound. 7. Give reason majority of noble gas compounds are those of xenon, u be 8. In the following pair of compounds which will react faster in SN? reaction . with OH, (CH3)3CBr & CH3Br Pentan — 3 one does not undergo iodoform reaction, Give reason, 10. Name the vitamin responsible for coagulation of blood. 9. PART-B II _ Answer any FIVE of the following. {each question carries 2 marks] Sx2=10 aa? C14... Explain the term ferrimagnetism. Give an example, \- C 13¢ Mention any two methods to Prevent corrosion of metal. Scanned with CamScannerMN parts are ns whenever of Scientific 10x1=10 ne mole of cules. its volatile N2 reaction 5x2=10 13. Hand book for Examination From the graph givén beléw, what does the slope and intercept indicates? hk as ye 4, Give reasons “transition elements are known to form complex compounds. tee! “6° Give one example cach of the following. (@_ Dihydric alcohol Gii) Trihydric phenol 1& What happens when sodium acetate alone is heated strongly, Give the reaction. 18% What is a) Drug target b) Receptor 1% Mention ause of a) anionic detergents b) cationic detergents. PART -C” TIL Answer any FIVE of the following. {each question carries 3 marks] 5x3=15 49. Draw the Ellingham diagram for the formation of Feo from Fe, Co from C and CO; from CO, suggest a suitable reducing agent for the reduction of- Fe,03 below 1073K and above 1073K temperature. - GB) a) How is ammonia used to detect ‘Cu** ion? ‘Give the equation. +) b) Write the structure of orthophosphorus acid Write the reactions involved ini the manufacture of sulphuric acid by contact process: Mention the temperature and pressure used for the process. (3) a) Complete the following equation. . . (4141) 2KMnO, +16HCl —>. +. b) Arrange the following oxocids of halogens in the increasing order of acidic strength; HC1O4, HC1O2, HCIO;, HCO. c) Write structure of perchloric acid. Scanned with CamScannerHand book for Ex nayy fn 2%. Give reason: . : . (M4) ds J \ 8) Transition metal exhibits higher enthalpies of automisation. Axe Cr?" isa stronger reducing agent than Fe. : 4, 4 ©) The highest oxidation state is exhibited by oxoanions of the metal, ce 2&4) How to prepare potassium permanganate from MnO 9. Explain with 4A. reactions. (2+1) ¢¥ }-\B) Name the common oxidation state of Actinoids. C 26 a) Draw the Facial and Meridional isomers for [Co(NH,), (NO,),] (241) < © b) What is a spectrochemical series? ¢¢ 26 a) Write the TUPAC name for the following coordination compounds (i) K,[AI(cC,0,),]- (ii) [CoCl, (en), }* (2+1) ¢ © b) Mention a difference between a double salt and complex compound, PART-D IV _ Answer any THREE of the following. [Each question carries S marks] 3x5=15 2 a) In corundum, oxide ions are arranged in hep arrangement and Al’ ions occupy 2/3" of thé octahedral voids. What is the formula of the compound, b) Mention any two applications of the semiconductors. ¢) Which stoicheometric defect increases the density of the solid. (2+2+1) 2% \.a) The mole fraction of helium in a saturated solution at 20° is Gel 1.2 x 10°. Find the pressure of helium above the solution, G4 _ Given Henry’s constant at 20° ky = 144.97 k bar. . b) Give reason: i) NaCl dissolves in water but not in benzene. Sali. Cedi) Solution of chloroform and acetone shows negative >) deviation from Raoult’s law. : & pe —~ fii) Raisen Swell in size when kept ini water, ©?! (1+1+1) y ¢ AQ. a) Calculate the equilibrium constant of the reaction at 298 K, (342) Cu(s)+2Ag* (aq) —> Cu (aq)+2Ag(s), Given E° cell = 0.46V Scanned with CamScanner xHand book for Examination ¥.C. b) Write the reaction occurring at anode and cathod 30 a) Derive an integrated rate order gas phase reaction, mercury cell, equation fpr the velocity constant for a first b) Write the rate constant equation by combining energy factor and orientation factor, . ) What is an activated complex. GHI+t) 34. a) Mention any two differences between adsorption and absorption. b) Define the terms: i) Critical micelle concentra ion ) Electro Kinetic potential or Zeta potential. ©) What isa promoter? , (24241) V_ Answer any FOUR of the following questions (Each question carries § marks] 4x5=20 3228) Name.the type of isomerism shown by lactic acid, Write its isomers. pe & b) Identify A and B in the following reaction. a NaOH A irre} a 623K, (Pressure) a 300 atm, ©) How do polar solvents help in the first step of SN! mechanism. (2+2+1) j\.L-33. a) Explain hydration of propene in the presence of concentrated HzSOs. b) Give reason : (i) O - nitro phenol and P ~ nitro phenol can be separated by steam distillation. _ Ch (ii) There is a large difference in the Bp of alcohols and ethers. . 7 O— Ci ° (©) Give the IUPAC name for , Cc Gal) 34- a) Arrange the following carbonyl. compounds in the increasing order of their reactivity with nuélepluttic addition reactions and give reason; - Ethanal, Proponal, Propanoné, Butarione. ' os Scanned with CamScanner\ Hand book fo Exaniny b) Give two test to distinguish between propanal and propanone ©) Complete the following reaction. ‘COOH, A 38° a) What is Hoftimann’s bromamide reaction? Give an example, b) What are coupling reaction? Give an example. ©) Give reason: Primary amines have higher boiling point than tertiary amines, . (24241) 3@ a) Write the Haworth’s structure of B-D-ribose b) Write the reactions to show the presence of CHO group and 5-(OH) groups in Glucose. ©) Give an example for essential amino acid. 34 a) Give one example each for the following'polymers: i) Linear polymer ii) Branched chain polymer. iii) Cross linked or Network polymer. (24241) b) Which type of polymers are called chain growth polymers and step * growth polymers, y : (342) Scanned with CamScannery s g La a é > ' Ws a Hand book for Examination ' — PAPER - 6 MODEL QUESTION Max Marks: 79 __ Times UV hours LS win, Yastructions: : and D. All parts are 7 fon paper has four parts: AL B.C Ory : aw la diagrams whene ’ alanced chemical equations and draw labeled diag ver 2 log tables and simple calculator if necessary. (Use of Scientific aloulators is not allowed). PART-A . VL Anower ALL of the following, [Each question carries 1 mark] 10x1=19 ‘(Answer gach question in one Word or in one sentence) f s ium chloride (non-volatil \ UL The experimental value for the molar mass of sodium le 3 solute) is twice the theoretical value, What is the value of Vant Hoff factor 631 i) for the solute NaCl? 5 \ t2. Sea water fieezes a temperature lower than that of pure water. Why? Sor y CLA Whatis a secondary cell? . 14. By how many times does the ts; of zero onler reaction increase if the initial concentration of the reactant is doubled? AS. Name the biocatalyst used in the decomposition of glucose into ethanol. and Ps gl carbon dioxide, 16, Give the composition of ‘copper matte’, 17. NeE, +3H,0 + P+6HE. Whatis P? {S.A racemic misture is optically inactive, Why?) * ww gow | N01 COON, o “om... Give the IUPAC name of X 20. Name a nitrogen base present both in DNA and in RNA, h Scanned with CamScanner‘Hand book for Examinstion PART-B. I Answer any FIVE of the following, feach question carries? m: 39. Give two differences between Schottky tec 40. Name the gases liberated at anode and cathode respectively when an aqueous solution of sodium chloride is electrolysed. S| 5x and Frenkel defects in ionic solids. Al. Given 2NQ,) + Oy,)2NO;); rate= K{NO} [0,}' . By how many times docs the rate of the reaction el reduced to 1/3" of its ori of the reaction? ‘hange when the volume of the reaction vessel is al volume? Will there be any change in the order - Give reasons* i) actionoids show variable oxidation states. ‘4i) Zr and-Hf have almost identical radii . What is Lucas reagent? Between primary and tertiary alcohols, which one of these will react faster with Lucas reagent? Nc 44. A carboxylic acid is treated with alcohol in presence of conc. H2SOs. Name the reaction. Give its general equation, 45. (i) Give an example for a narcotic analgesic. Gi) To which class of drug does ranitidine belongs. 46. Explain saponification with chemical reaction. ene Wor 7 PART-C : III Answer any FIVE of the following. [each question carries 3 marks] 5x3=15, 20. Write the chemical reactions for the leaching of alumina from bauxite. 21. Explain the preparation of nitric acid by Ostwald’s process. Write equations, 22. Describe the preparation of ozonised oxygen with an equation. Name the oxidized product obtained when ozone reacts with lead sulphide. 23. Complete the following equations: c i) 2F, +2H,0O> ii) H,S+Cl, > iii) 8NH, (excess)+3Cl, > ‘24, Name the metal of the 1* row transition series that { i) has maximum number of unpaired electrons in its ground state, - | Scanned with CamScannerHand book for Fxamination il) Has zero spin only magnetic moment in its +2 oxidation state, $y °\C iii) Exhibits maximum number of oxidation states. of dichromate ions with \ 25. Write ionic equations for the reaction + ly hydroxyl ions ii) Fe"? ions in acidic medium. In which one of the above two reactions will the oxidation number of chromium remains unchanged. ¢ © 26, Using VBT account for the geometry and | magnetic property of [Ni (CN),J*, Given: Outer electronic configuration of Ni’ ; 3d"4s°. ¢ C27. Give the IUPAC name of [Co Clz (NH3)4JCI. Draw cis and trans isomer of [Co Cl2(NH3)4J" ion. PART - ae ce IV_ Answer any THREE of the following [Each question carries 5 marks) 3x5=15 27. a) Calculate the packing in a simple cubic lattice. b) Calculaté the number of particles present in FCC and draw the unit cell of FCC. © (+2) 28)a) Vapour pressure of liquids A and B at 298k is 300mm of Hg and © ¢° 450 mm of Hg, calculate the mole fraction of A in the mixture. Given © total vapour pressure of solution = 405 mm Hg. (,\e< b) What happens to the solubility of a gas ina liquid with i increase in temperature? Give reason. ‘ (+2) tet Sof 2 \ © 29.a) Calculate the equilibrium constant of the reaction at 298 K. Mg) + 2A8(.q) > Maia) +2ABq) 5 Boy = 43-16V % © b) How is molar conductivity related to the specific conductivity of a solution? Which one of these has higher molar condu: or 0.01 M KCI? 30. a) Derive.an integrated rate equation for the velocity constant for a first order reaction. b) Draw a graph of potential energy versus reaction coordinaté to show the’ effect of catalyst on activation energy. (+2) 31. a) What is coagulation of a sol? Name two methods by which a lyophobic sol can be coagulated? Scanned with CamScannerV Answer any FOUR of the following questions. tac queton We uh w chloride? {yy U->) Write the equations for the steps in Syt mechanism of the conversion of , tert-butyl bromide into tert-butyl alcohol GY) 33: a) Explain with equations: phe se phe pee 35. a) i) CgH,CONH, 2%" 9x, and tok for Beaminaion 1b) What is the change in enthal Wat ny and entropy daring adsorption of ga on QR) sarka} 445-20 32. a) Mention the major product formed in the following reactions. PART-A Answer ALL of the following. (Each question carries 1 mark] 10x1=19 [Answer each question in one word or in one sentence] Vant-Hoff’s factor ‘7 is greater than 1 for aqueous solution Containing Potassium chloride. Why? What is the SI unit of molal elevation constant (Ky) of a solvent? Define limiting molar conductivity. What is the effect of temperature.on the rate of reaction? Give reason: “activated cliarcoal is used in gas mask”. Name the method used to refine semiconducting metals, Mention the noble gas element used in cancer therapy. Which one of the following is more reactive towatds SN? Mechanism, (CH,), CBr, (CH,), CHBr, CH,Br Complete the following reaction: : #0: Cecoess = + CoHsOH ).. Write the Zwitter ion form of Alanine, a Scanned with CamScannerHand book for Examination PART-B TL Answer any FIVE of the following, each question earres? marks} 4 Sx2=10 { 11. What is Schottky defect? Give an example. i }-¢ © 12. Write the diagram of Deniel Cell and half cell reactions t 13. Show that half life period of first order reacti ut ' 1 rt action is independent concentration of the reactant. na on he ina ' Give reason: “transition metals generally form coloured compounds." - Explain Williamson's ether synthesis with an example. Mention two tests to distinguish aldehydes from Ketones. 17. Give one example each for 1 i a) Narrow Spectrum antibiotics. b) Analgesics | 18. What are food preservatives? Give an example. PART-C III “Answer any FIVE of the following. {Each question carries three marks] Sx3=15 19. a) How is zinc extracted from Zine oxide? 'b) What is the role of Cryolite in the extraction of aluminium? . — (2+1) 20. In the manufacture of ammonia by Habers process. i) Write the equation for the formation of ammonia. ii) Mention the promoter used. ii) What is temperature maintained in the process? (+14) 21. a) How is phosphine prepared in the laboratory? . b) Mention the allotropic form of sulphur which is more stable above 369 K. 22. a) Mention any two reasons for anomalous behaviour of Fluorine. b) What is aquaregia? @+H) ly 4-23. ta) Why VO%" has lesser oxidising power than Cr;0;7" 2 * b) What is the oxidation state of iron in Fe(CO);? Hy c) Among the first row transition metals whicli element have the greatest number of oxidation state, Ea) Scanned with CamScannerHand book f fOr Examy nay 24 Write the chemical reactions in the preparation of potassium dich, from chromite ore. mate — CG 25. Using VBT, explain the geometry and magnetic property of [Ni(cn) i le Given atomic number of Ni= 28. a CC 26. a) Mention the number of geometrical isomers for the compound With nae ‘ al formula Manco CL. ~b) Give an example for homoleptic coordination compound. sy © ~c) Explain bonding in metal carbonyls. PART -D IV Answer any THREE of the following. (Each question carries 5 marks] 3iSat5 27. a) Silver crystallises in FCC lattice. If the edge length of cell is 4.077 10%, calculate the density of Silver. Given the atomic mass of Ag = 108 amu, Na = 6.022 x 107? / mol. b) Give any two differences between n-type and p-type semiconductors, Gy «28. a) At 298 K, the vapour pressure of water is 23.75 mm of Hg. Calculate io"? vapour pressure at the same temperature over 5% aqueous solution of Urea, Given molar. mass of urea=60. * b) Mention any two applications of Henry’s law. 6 \.29. a) Write the Nernst equation and calculate the emf of the following cell at t 298K Mg(S)|Mg* (0.001M) || Cu*(0.0001M)|Cu(S) Given E° os. Met /me =—236V and Ef... =+0.34V yc ©b) Mention any two factors affecting electrode potential. (342) | 30.a) Derive an integrated rate equation for the velocity constant of zero order reaction. ‘ b) Define the terms i) Average rate _ ii) Instantaneous rate. (GH) 31. a) Mention any three methods of coagulation of Lyophobic sols. b) Give any two characteristic features of enzyme catalyst. (342) V Answer any FOUR of the following questions.(Each question carries 4 marks) 4x5-20 ‘(jf 32.. a) Explain Finkelstein reaction with an example. 4: f- \b) Write'the equations for the steps in SN! mechanism of the conversion of . t-butyl bromide into t-butyl alcohol; (+2) SS oe Scanned with CamScannerHand book for Examination Alc 33 ©#) Explain the mechanism of dehydration of ethanal to Ethene, ) On treating phe hydroxide at 340 k followed ( Write the name of the product. 34.) Explain the cadmium, by acid hydrolysis. gives the product Give the name of the reaction. (342) Preparation of Ketone from acid chloride and dialkyl ©). How to convert benzene to benzaldehyde by Gatterman-Koch reaction? . (243) 35.8) Give structures of thie products A, B and C in the following reaction” CH,COOH. A lets Bossman b) Give reas : (i) Methyl amine is soluble in water but not aniline. (i) Methyl amine is more basic than Ammonia. 36.a) (ji) What are Reducing Sugars? Give anexample (342) ii) Mention the number of peptide bonds in pentapeptide. ) Define denaturation. Mention its effect on structure of proteins. (32) 37.a) What ate polymers? How are they classified on the basis of synthesis? ) Write the partial structure of (i)Natural Rubber (ii) Nylon — 6,6. (342) : ae ak ok a Scanned with CamScanner