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bY
i AT
; BU aly OT
Y mola, i
: a) a
1 ‘ 7
| F
j Go, Wn
; ™~
feo
q Cur 2 olay heat Cepncity af cmetane
vels
Cy NR Con
| (Ob. Mone aT
[ave Senet)
Gum: Tk is the eat every Yeqpeived bo free
— Pomole of
nase. the te of boc by ('c ab ont vel.
Cy: Cheat cay aecky ab constant pressure)
=
PE US fhe Neot energy veqcred te tncveate the
temp of body by He at canst. pressure,ee aT
He U+rPVv
ons: Vel
gHodu + tdvtVdp
stant Sp dpse
ak — fonstant ma Ye Pyes > Payton
anode evenly pak
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ay 284 4 fewdvt 04 ——
s lane av few
—= ~ Hoek lavelved
. Fr ae) Vp eens F
> |
From 2 ©
nctant Ae
vels aaa
Ces DH
f° SF
DH Cp AT
~yw' moles ——Cp
cr
co free ( ew
t vol 1 CRD
2)
Ade the
fare
aCoin 2 olen Keak Crprety al cong pressure
TE is heat energy waquiived fo the temp d:
of a I mole of tedy by Pe at cons pressury
ape . > $
Specttic heat Copastty (ls) ae os the het ©
! ¢
energy Yeqyatverk te inc Lene ot | body by ° .
From 24, @ cz ¥
‘Bt
We gers q
\ 9
I \ .
\ c
4 ws
i & als
™
C2 Cex
: Cx? +
\4 “wine maT ig b> sar)
——— 3).
units Ge Cp Sk
Cony Cv = TET mol"! s
ts - Tate
Noi€'
Im physics, lm old Chemistry Com = fee Ye
Cy en 2 wy
5 Tsobante process, c atp—_—_—e......e.e,oakee==eee_eeeeeee_ee_ee_ee
. Tsochoric process Cohy
temp J sothernel . C20
R ‘ te
So presi Adiabatic %
i -6 2 R.
G> Show that doy fdeal gases Spm Sym R
he heal
5 (eb us considev He UtPV
2%! a 2 doe ALPY
for weal ye pve ner
dtr det atnar)
nferm FT 2» ACumste heat
dam 2 Cum AR
8) Show that Cyn = Fig where fa re of daqes
of freeclom
Gor ident gu)
ely Wee tre
NVe AKe EDRE-
fos tack wages 6 PE >?
Cp Wat 3
s a
Bo? OWE
¢ a
" ose
B te > Bneat oy pvr Lnrat
=
ESOTeens
3
NOTE
a ganis
Mm
At
at
i) Wre
= 7 x wey das
om Chins
- { ae ratio oF mctan Weak Copacckes (Win
4
(ren
wo Deqes of freedoms Cook): Te is tre me 2 -
qs o8 2 &
voays by hick & proiiche can have NOG
Sev
eo) Monostmie quae (etal_tof .
Fars bOF ~ 3 Rue OF O
ic) Dratomic Yet cy
Toor 2 3 Qiee iaet oe Nal a“
o\
(c) Triatomec ( Uneor ) (is
Tpop 7S Ree” 2 Voor » 39-8 a
a. ——$—$—$—$———$————
(A) Friokomce (mon- Linea) 1 eas Os
pee a Rroe > 3 Vose 2 39-6
= 83
wore:
Pe tev temperatures only — Tpor ~ signi fcant
At moderate tumprrtwe Toe, Rog - Syntetcant
Dc hah beperntinn Were —ahmibeiont”
At moderate temp.
~ 4s Cem +
ty Mono - 7 am .
otonte sk Ze 166
es ZS 2
it) Diatoniey Lk te M4
= z
qt) Trtatomic| gg We by
Cunemt) v
pacebies » (Wfrictomic | SR HR [33
(non -Unear) te
mes) _
mo. of “ ‘
g fhe Calculate 0 4 circy, gi G GOT
u
aa doy the Following molectes ck Bey temp
oem 4° @ © S°
ates GY He e¢ ,
C20 Bs Gare a i
Wi) Or 6 ae AR eS)
Pa i Gi) Coy i ae HR 133
— oe he Vr
ty) H-CEN 4 2
4 UR .
u (cheese 4 se Uae
; \
\ fe we we TABS
wid Apa ISS BRTn
8 & Value of He 1 always 3
MES SR bot S ve,
& uy ts FR ak Pow | bern | Seok ma
z mane
hemp asd more tan ER ak heh hemp. Caplan
ay
fax As He is monoatomi :
© there ave only Toor 3 3
| Cy vale ot temp is 8
} ¥ aye ZR
i As Sty’ Ue Motori", pom 26
ok Lens a) 2 Type FE eRY Sint Reamt
lus Ye: ;
| Poor
{ ak moderate temp, Figg, 18 Sy esigniticont
i Ove Sp,
: z
Fg ay The wrotan heat Cepactly of Hae ob ebtant
1 ‘i =
| progr. Cegm) 1s TO J kK mol | Suppose
i Lk Ketele Cleos ta/s) having Veg Ugo fs tuned
4
i on for too sec. what fs rice ty Etmp in tga,
WeeCpime TS x DR
Br
bo Be. Ke Came BT &
{ +
roa Moe YY TE BT .
= 5
M307. aT
a8
10} 30°. MWA TAK.
4s —t i
Sy Vigy | mole of Teal monoatomie gu & mined votth
weeded) sate of am Edeol Aictomte ges» The molen speci
Explain fic nent of mixture at const Vol ts hoe much:
23 e)
Ve Vit Ve
‘apa wnbave
4
ak crst Vol “Oy > av
anim 8t
M Cym OT =O Cums OT t Ma Sym OT
chant “nw |
se
= earned
a Ngo.
am + U-
3B) A monoatomic deal gos underqou a proces in vatth
dre totio of FEV ak any
what 5 the molar beak Capacity of
instant is constant anc
equals to t
the a
Gao (om cas py" eeae Pv constant Liso thermal)
py a Constant C Adiabatic)
put 2 Constant ( Poly tropte process) :
For poly Trophee proce
i ped
Cm > Molar Areal Capauily
v
(Cxrcmaee ee 6 ak const Vol
| be
Exehotgleg C8) ,
|
: oY Att Gorse vel catoy > Crt Ones)
a
i L4|
4 ‘ can | Hert involved > bo
1 AES ;
j oe Ue f
t 2 mWwo-t
| az oct >
| ate unant vol, heat toed Can be oltaned
q
From BUD
D> M ene \)
= a
enpesion
Coen ay Zs |
Yo cal for workgk consi) tobd bel iroolved 2 lrvecat
wr 2
4 A100
pe
purrwocal
G ot tomst p> bo determine heat javelued Ba
ge nok Sab Glente
ped fh vr | Cor any type oF system en) suystane)
his entaley
De takemol emargy of Agstem -
p - pressure of rysten
Vr Vebune 4, yeu
du- dut Arter)
[ae du ehh a vd j
doy Fintte — changes
put Pow t NF
Bw
ew)
nbtenel pas pur toy t vi ot
Bue S46 + OUR)
[ore pu + (Ove- FN
a
ak constant prone dpe
dy > tet yay
bis BOPP OY
we Kneo theb Meo Utevfor tdeal got Pvener
tf 2 U4net
Aa. Av edner>
au radar ned 4 &Tdy
(oH = be eneors a)
ak content” — Lunsp
AT>
1 Beh BU eDART aii)
Ans Unarge tn nos of wroles
NGR- NGR
AGP meclen whe Pro duvets ew) cx
NOR 2 ‘ Reottant v
Note »To — inddote hee of Ree eens re
No. of Goseert
pa is wed te &
bas To tndgenke ek of veote O ox Sv,
Buds vsed a
let us consider the tolloring cron ples
Gas Cl) Pele Pa ty
i) 0D (3)
pn V-031
&
Bu 2 BY 4 ener
keen
compe HO gy Ue LeRTSeren rere aU aeres TaD Stas TaESTEETEETEETEETS
Al) Nat Bh 7 TS
te lee
bw > DU eT RT
Dy > DA- PAT
Ba che Ck Bn fs ve)
Gi) My ten NO ES)
9)
¢
aye Roe ee
webs
ew) CAO 3.
= Ww) we)
Lop br + °
. Ba > dO
ay Gor tenetions —frvolutng sols ond Myce
“py 2 bY +P eV
DV x0
(ox ene r)
Vee noo |
&: a
a Caiameney > Cope)
at const 0
p> Ut POV
ok enst ‘Tt’
Bie BY SORT
NSA(8) For vem'c Hon DAL Boy enkheley Chang onlenter
| ok tonstant prmwe (S AsoT ok 300k iy is
(
Calealake the trtexnndk change we Yeatly ot Zook
i GH> DU + Pov 3
|
} AH = SU4 HnXT et
{ was
; Os ov — B-31UnK 300 a
i poe MA SUNT
: he di the PV graph wilt atve
nove: The aren woder the MY grep Hy in
the moan bade of work done
i Wo > [Pere dy
| «
| { ‘ bv ~
| eae |[ | > Pour’
Sa y's
|
; oe wey
2 foaeal . Low a
bed, Cc By
vesye Vg eee ,
Py eats ¥en be tw
Enttsal stare Finad strbe
eerange Ctertation of word done fm Bothrermal proces
Cy psamcneee
. Book Pew
vivir NE
gaa TS Ch pomdcd oooirst Pear 2 lowtm
z
oe
Wa J rene av 7
oe offen 4v iS
wo 2 to LY -Vi) “Wii
wvlexy pte be a a
L ote
By in toe Steps
eee! Jente = boat
ny, ES ey FESR
Wa > exe ov Ww, = Penk OV
2 ts wv slo OW
2 ist v-4) rota? rt Be
y .
aa vis YO
|
ln
VME
Gil) B Steps
wort rar Reaerte
Five > Py Pe
Wye AB xCy Ww, 2 Blu)
Wer WELL ty(ly 3 Steps
reel Cen 5
PV mM OV ONo a
Note. | bose coms J Jus a
wo, comp|
Coleutation Of wort involved in Asothermel reversrite
Process of am ideal gas
T = constant
Wedeerseer eee au
(as > Greed
Wa (-typade
a
PvanRT >) Pos = Po? —
2») Ts
t =
Los thermal — Pv= PRT in
TT pve PVE
- | We —2D30IRt lo ()]
a bu
Paeg > Tine ® at
Pent
Pent > Paes
ae
Fou Pyas — Cnpanston
Fost > pa = Compression ifor emp
a Rent € Pad
verst ite
ame Ponte 2 Pyaa “AP
Pow ome
Pent > Poste
Peat > & Pye tit
dae
~ | foe 7s |
invelved tm Ssotnewnal proces of an
Thermody namie change
Thermedgnarnte cierg
deck gos. Expression foy 4 19/2¥ 108
\ ) Tet hermeal Tr Constant
2 (3) arr
(vat)
fare} duce
aver
eee eat a
we
dur dyede
DU 5 DDT DneT 4 NAAT
ATroy BLP
OH > SORT
yom (ore)ccneeRnnN RAEN
(AY eversi lig preecess
for isothermal veversilte procers
toa omer In(ee)
Y>net Cassy)
DT 25 ; BU
ex
Bee Cit pnred ~
for Adi
(GE) Mreversite procen we bnc
ey Free Cxpansion »
beat
TF Rene 20 (8 Cate “Pree Crpangion
ws {te dv
isothermal — pteo
ante > BO ,
bee CIF pure)
mzonsie 7
constant extemel pressure
iy Intermediate
> AgaenseA eee eae A OE INT rr
7) OTeo , BU =e
=) BH? Cif Onz0)
tavolved in Adiabatic Process
enpressions for YD, bt
oo
far PAinbeke pros; 4 °°
pe tnas 18 law HO ayae
19 > Men Cah)
PVanel Coen “Cup ER
R
\ -\ ==
mR Ne
“ Cyn >
YA\
bu » 69 *DCnet)
Be SAR BT
| Bu > BO +n ROT
Se|e) 6120, Bus
pyro - Cif anz0)
i o>)
J) Thermodyeante Changes fewalved in atsale_process
oF an thea gos
expressions for Gov BA
—_—
for Bdla lak
wetnon I das BO ay 40
wr we know =| OU= 7 Comor, )
on
WIN Cum OT
2G m OT )
PV 2net Cy em
cies (a Ye
WR
bH > YU tAC HRT)
DUE NC AT
| Bu > bo +neot]
\____— =A) Reversitle process:
Yee
We Know dw 2 Par dv
toe Jota dy
Gut for veversitke proiess pian 2am
ws ftps dy i (-uree
poner
v boa-ne{Tdv, 0
To get the final tome
os to
VWevendt 2 fere dv
(
{
}
Pene F Fyas
Neyndya PAT
ve OKT
ay
NOymy IT 2 Rev
T v
Integrating % both she
vg Ve
wm |! _e(tdy
Gm |tar = es
vr
i
3
Cum Wile 2 seen |)
vw
Ue) ive
ci fr
bet— i
Ue) iveversitle
cee
lb) ie Ceca
fent ¥°
S00
ae?
pyze
pT?
bys DUTNRAT Bnet
pu = ORT [F onre
oHeo
OU) frtecmnedtote erpangio
_——_—— i
<4 tanstanE external premure
w—Sendv|
| 5
| 5
a 5
8) Caleutate the work vehi would be otained from
| an tothermal weverstbte enpanstor of tmole of CL 8)
| dyom de® to sodm at 273K € using (deol gas
Lehavior +
‘ 7 v
ane) toa 2) ALBO3
e ANE At
2 ea ees AAVE a)
ge Jy BMAK LAB RT BOB NET
2-8-8 ssa a
|
j 8) \ det of an tdeol gx ot o pressure of hogs ey,
| Man expands Teversilely and isorthermnally from HS
; iS
is inwebed ©?
ate) co de® . How muth of heat
and how murs of work fs done expainion co
tate the Value of dU and BH Oso.We — net ln (2)
= GeDloxt X 2°303%)
>
5 -2BORKIO™ [atm
wp —21303% ROT
we -b3 PP KS
qe URS
Duce bw 2 net
so) = 0
vite oh cl 8) 2 moles of an Sdeal gas expanded from LL ty SL
Seat gas isothermally and veersitty at a temp of Book, Colette
tw tiny Gi) Oe Uy) 48 7
t Babe
woe ~ 2x84 ¥B00 x [OVS *DIL Og ro
Ty ete
ee OR VRES 3B Ex U503 rea
as Yee
+ - 8B KT (8:04 by ) st
ts
Wy = +804 Avr. BK 2°
nf
6) a) S moles of an (det ge
isothermal from an
to a Ainak prere of 0-1 013 mn against
of © Moss m fa
intoal prenure
constant
W
of 10133 eyteynak premure Of 071013 mpa Cletake U-
Zromn its hoon
l ee
Sevolved —O) Coledake the corverpencling Values
Ces VS Cerrdek omte
anston? Cale Procems ° Pee
t Wo Fea BY co-eds Ve 01018x No
4 u
14% , ey
~BANS * on vee4v
Bul x
4 es 2 - oe x3 wt 23 gy
ae _ ic ay wih
ba* e se Sets Cor Fy 0 + 8&0 KT
| i ~ ts) ) wn 9 (atase:
(io
; Day? = -s90KT
(Few)
Types OF enthalpies of reactions:
@ standard enthalpy of comiurtion
+ Permation
* . Solutron
A neecbralcsati'on
7 . Artemis att on ete a)‘ T
fa) Standard enthalpy of Combustion
2
2) BW ter) Be A
sxe) i
at te we enthalpy range frvoled when tmole of
Lave wee Oasgger', Ue compo
stenderd stokes
Sy CLL
gq pulrbance & comple ety
aitaned ments ode Laker tn eet
2 Lomlwaon Is gros
eno thermic
a bBo = -ve
Ge (0) Cy) 7 ORL) 8 DOG. thIO KT
Cat ace)
ren When
a) He? = ~BIOKT
ore take *
(> or =) DHS of Cy = - 810 KT
Lad enthd wa Kae :
go Se
po pes
, 40 KT No Ne
(at asc) ae
i C4 On 2 OE 4$KT
OD GS ey £9) (oe ace)
geghite
2) bHye = PBR
a1 BUC of graphics 27S xs
a) rr tO 54 Dre ay 4% FAGKT
es >
ase)
Bue = -stets
BUS of Has ~ CET
mw . :
GH) Ccgeapniter * L029 Coen # HOH
bHyo x AL:
& DRE ot qragntte = -% ot Xx i
an anneabxc)
Sm OLS
bru
Ren When
ore bake
ard eathd
+ 890 KT
(ak ase)
1
[8) Standord _enthelpy of Combustion
2
oy) OWE er) be A
Te ws we enthalpy change
feantans 5 completely Coane wie OER Y
ener ea etal ea Stemcherd stakes
2 Lembo is genoly exo there
toled when Lmole of
=)
a
a Bn = -Ne
we 60, 420g FIO KT
ry =) '
Cat asec)
(0) Baggy 7 OF LSD
=) Hes -890KT
¥ oy wr 2) BHS of Chy = - 820 KF
wo hee
so Sr
po hes
Ne Ne
bh aO3,
din GS oS Cr fay 38h ax ace)
args)
2) DH? = OBES
wy BUS of grophice > HSE
avo we ton 57? Bre hy & FAG KT
a ese)
Bur = -steks
AWS of Hae ~ ERT
; n
GH) C coungniter * 202 Corey © s
bY? pK od
DUS of gape =r et X® Standard Frthalpy of formation ;
pean Es a ge
7 Sarees age (or bs We
ert came ewth ogy Chranne involved when tmole of g
! quistance ts formed fromm {ES Llemants 6 Substance *)
| taken fr Standad state and elements are tale,
| in weference State -)
| =) TE tan Ue mve GY) AVE
Exh Cerpaprttes * Oe coy 9 CPacay F343 KT eo
Cot rs°c9
=) AHO. 343 KT :
> ONO of graphite > -343 KF
a) DBP of Co, 2 ~3 kd
a)
= © Ha + dO, > Moy, FASGRT
oy aw ae Cat 26°C)
>) BRST 2 -Qee KT
| 2 BRS of Hy 2 ~ 186RT wo
2) ANB OF HO > —aeekD
| GY Coyrngrsty FAQ SHY gy t% ok bey
| ab Wg erect
; a BUSe of Crys ~ Herd Stand
i uv) Rot Ae PMA Qt YET
ae bes
2 Dag » TY RT bes
| anes
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oe
S0zta) t LOrts, $03 + A ed
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a Cegpapnttyy #% HL
Csatstance 2 Cepegrtey “> Cearegnteo F
o
yee cA
S Bre tale, .
“= bus?
o> BSS of geeprte 9°
—— Elaiqmend ) SOL
Ceqroghite
wes
Cot PCy =) Anes +8 col +
~~ puge
wit)
re) 2) Dy? oe
a Suge of Romie S20
« $e 4 Scmoncetintey
a) eRpoanicd
pug? ek monoetince S #0
*
ug® of clement = 0 C4 they ave formed in ve tevence
state
Standend enthalpy of mustralisatton
> Symbol SH ery BAe
deb: the enthalpy change involved when L geneyivatent
mow of an atd Compe bey nekralesed wy
Vam tqpivelent mats of the lrase” Cal there truer
{r gtand anal States) is Gded BUCOfry The enthely change Covelved hen mole
€
ot tt tons Combine with the Pmole oun fo —
alk vax to fo {mmole OF Bgo, ah are taken
fn Stondand State , is cated So
Ex: (iy Bd 4+ Ateon
En } t Maou — y Ala T-
oa Gag Hyocdy 4573 ky
o cay)
os
bat” = -ST3 Ky
(On#?P > seer) 7 Sette *f
diy at a a Mg AST Sep
one tay Sky ane
DMP a -sa seg | _
HNO 3 tKow-
y¥me, thar 4538 ep
cond fey) \
=
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2 SA } erate Seat ca
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on Syea le
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WAG
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2 a | Strang Aads SR CUgCOOM, HOH, Hg,
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