ASTOR Cec Ieee a Deebed URES WES PRE ‘two charged plates kept ata potential difference V esu. IF "e’and marecharge and mass ofan electron, respectively, then the value of hid. (where 2. is wavelength associated ‘with electron wave) is given by: 2016) (0) JineV ©) meV (6) mV (8) mv hg and i be threshold wavelength and wavelength of incident light, the velocity of photoelectron ejected ftom themetal surfaces: [Online April 11,2014] 3) mt ‘Theenergy required to break one mole ofC1 Cl bonds in (138242 kd mot, Thelongest wavelength of light pale ‘offbreaking a single Cl-Cl bond is ‘The shortest wavelength of H atom in the Lyman serisis, 2,.The longest wavelength in the Balmer series is Hes [Sep. 04,2020 1D} Brgy gy MH hy Soy oF of For the Balmer series in the spectrum of H atom, a wf j 3} the core wate anny (to Whar (Jan, 08, 2020 (DAs wavelength decreases, the lines in the series converge (The imteger n, is equal 102 {ill The ines of longest wavelength corresponds to n,=3 (QV) The ionization energy ofhydrogen can be calculated from wave number ofthese lines (@) @.qtb,av) () (.aD, «an © Manav @ h.a.avy @ol 2 13, 4 18, 17. ‘The radius of thesecond Bohr orbit, in terms ofthe Bohr radius, ay, in LPs: Wan, 08, 2020 (1) 20a 400 4a a> oF oF w Theratioof the shortest wavelength of to spectral series cofhydrogen spectrum i found to be about 9, The special series are Laprit 10,2019 4D) (@) Lyman and Paschen (b) Balmer and Bracket (Bracket and fund (€)Pasehen and Prund Forany given series of spectral lines of atomic hyrogen, let Ai ina ~ Fag be the difference in maximum and _ninrmam requncies nem The ratiOAT uF i (April, 2019 () @ 41 O94 | S:4 HIS ‘Which one ofthe following about an electron occupying the 1s orbital in a hydrogen atom is incorrect? (The Bohr radius is represented by a). [April 2019 11) (@) The probability density of finding the electron is ‘maximum atthe nucleus (6) The electron canbe found ata distance 2a from the mucus. (©) The magnitude ofthe potential energy is double that ofits kinetic energy.on an average. (@ Thetotal energyorthe electron is maximum when itis at adistance a, from the nucleus. Heat treatment of muscular pain involves radiation of ‘wavelength of about 900 nm. Which spectral line of H- atoms suitable for this purpose? Jam, 11, 2019 ()] [Ry~ 1108 em! h=6.6 x 10-6, 3 108m] (@) Paschen, c+ 3 (b) Paschen, S—>3 (©) Balmer,2-2—— (@) Lyman,>->1 ‘Which of the graphs shown below does not represent the relationship between incident light and the electron ejected from metal surface? Jan, 10,2019 (D] o | + Eeray oak + Frequency oftght 2. 2 > Froqency often Keo o | tes itt ‘The ground state energy of hydrogen atom is 13.6 eV. ‘The energy of second excited state of He" ion in eV is: Jan. 10, 2019 (1) (a) “S44 (0) 34) -604 (dy -272 Foremission line of stomic hydrogen from ,=8 ton, ) be (The Rydberg constant, Risin wave number unit) [an.9, 2019 (@) Linear with intercept —R,, (©) Non linear (©) Linear with slope R,, (@) Linear with slope~Ry, ‘Which of the following statements is fase? [Online April 16,2018} (a) Splitsing of spectral lines in electrical field is called Stark effect (©) Frequency of emitted radiation from ablack body goes froma lower wavelength to higher wavelength asthe temperature increases (©) Photon has momentum as well as wavelength (@) Rydberg constant has unit of energy Ejection of the photoelectron from metal in the photoelectric efeet experiment can be topped by applying 0.5V when the radiation of 250 nm is used. The work funetion ofthe metal is: [Online April 15,2018 (1)] (@) 4eV (SSE 45 SV ‘Theradius ofthe second Bohr orbit for hycrogen atom is, (Plank’s const. = 6.6262 » 10° Js; mass of electron =9.1091 « 10 kg; charge of electron €= 1.60210 « 10°C ; permitivty of vaccum = 8.854185 « 10° kg tm A) (2017) (@) 165A () 476A” (o) 529A (dy 2.124 If the shortest wavelength in Lyman series of hydrogen atom is, then the longest wavelength in Paschen series of He's: {Ontine April 8, 2017) SA DA SA) SHA OF OF OF OFRR] IIAAN__ cts mu 25, 6. 28, 2. 30, 31. 2. a ‘The electron in the hydrogen atom undergoes transition from higher onbitals to orbital of radius 211.6 pm. This transition is associated with : [Online April 9, 2017] (a) Lymanseries () Balmerseries (6) Paschen series (d) Brackett series ‘Which ofthe following is the energy of a possible excited state of hydrogen ? 2015] (a) -34eV 0) +68EV_ (©) +136eV ( ~68eV ‘The energy of an clectron in frst Boh orbit of H-atom is— 13.6 eV. The energy value of electron in the excited state of Li? is: [Online Aprit 9, 2014), (a) -272eV(b)306eV (@) ~306eV—) 272eV Based on the equation {Online April 11,2014] (11) aah | the wavelength ofthe light that mast be absorbed toexcite AE Ihydrogen electron from level n= to level n=2 will be: (= 6.625 » 10s, C= 3108s) (@) 1.325% 107m (0) 1.325% 10% (©) 2.650% 107m (@) $300% 10m If mand earethe mass and chargeof the reelving electron indhe«rbitof radius fr hydrogen atom, the total energy ofthe revolving electron wll b:[Online April 12,2014] os oo © we Eacited hydrogen ln citi inthe lravilt region at247 » 10" Ha, With tis fequency, the energy of single photon i [Online April 12,2014 (h= 663 10°55) (a) 80n1~ 104) (@) 2680103 (0) 1640105 @ GLI x10 Fonization energy of gaseous Na atoms is 495.5 kJ mol". The lowest posible fraquencyof ight that ‘onizes a sodium atom is (= 6.626% 10 ,N,=6.022 » 10° mob!) {Online April 19,2014 (a) 7.50% 108s (©) 4.76 108 (6) 313108 §! (@) 124% 108s Energy of an electron is given by E = ~ 2.178 x (2 10 ey 2 A Wavelength of light required to excite an electron in an hydrogen atom ffom level x= ton=2 willbe: [2013] (= 6.62» 10Jsande= 3.0 108ms) (@) 1214107 (b) 2816* 10-7m (©) 6500 107m (@) 8500* 10m ‘The wave numberof the fist emission line in the Balmer setiesofH-Spectrum is: [Online April 22,2013] (R= Rydberg constant) 5 ° 2 a 2 we © ZR ® 36 ® 400 © 6 Theliitng tine in Balmer series will havea fequency of Ontine May 7,2012] 29% 10"Seycles/s) 3 wy aR 5 (Rydberg constant, R, 4 35. 36. 37. 38 2» 40. TOPIC (@) 8210s!) 329% 108s! () 365*10s! — @) 526x108! The equency of light mitted forthe transition n=4 ton 2 of the He is equal to the transition in H. atom corresponding to which ofthe following? [2011RS] @) a=2wn=! @) e=3t00 (© andion-3 (@) n-3ton-1 Tonisation energy of He* is 19.6 » 10-" ators. The energy ofthe fest stationary state (n= 1) af Li? is (2010) (@) 44110" Jato! (o) ~4.41*10-" Jaton! (© -22 «108 Jatom! (@) 882% 10-1 Jaton The ionization enthalpy ofhydrogen atom is 1.312 = 105 mmol! The energy required to excite the electron in the 12008) atom from n= Lton=2is, @) 851% 10'Imol! —(&) 6.56% 108J mot! (6) 756% 105Imol! — (@) 984% 10° mot! ‘According to Bohr’s theory, the angular momentum of an electron in $® orbit is 12006) (@) W0h/s 6) 25h/n (©) 25h/e @ 10h/n The wavelength of the radiation emitted, when in a hydrogen atom electron fills from infinity to stationary state 1, would be (Rydberg constant = 1.097%10 my) 2004) (@) 406m ©) 1920m (6) 91m (@) 9.240% am In Bohe series of lines of hydrogen spectrum, the third line fom the red end corresponds to which ane of the fallowing iner-orbit jumps ofthe electron for Bohr orbits in an atom, of hydrogen 12003] @ 552 ) 451 © 295 @ 342 In a hydrogen atom, if energy of an electron in ground states 13.6 eV, then that inthe 2% excited state is [2002] @) L5LeV () 34eV (©) OOFV (A) 1360v. Dual Behaviour of Matter and Heisenberg Uncertainty rinciple The gure that is nota direct manifestation of the quantum nature of atoms is {Sep. 02,2020 ()] @ _ Ineosiy ; ofblac body dition n ) Rb Na et Frequency of niet ‘dion16 2. 45. 46. 48. ® fa The work funtion of sodium metal is 4.41 * 10°” J. 1 photons of wavelength 300 nm are incident on the metal, the kinetic energy of the ected electrons will be (i= 6.63% 10 3,0=3> 108 mvs) 1071) INV, Sep.02,2020¢D} The de Broglie wavelength ofan eleetron in the 48 Boh oni is: [yan, 09, 2020 ()] @) 2m) 4a, © Gra, @) Ba, Ifp isthe momentum ofthe fastest electron ejected from 1 metal surface after the irradiation of light having wavelength », then for 1.Sp momentum of the photoclectron, the wavelength ofthe light should be: (Assume kinetic energy of ejected photoelectron to be very high in comparison to work function): {April8, 2019 (1) 1 2 OF OFF WF the de Broglie wavelength ofthe eletron in n® Bohr cxbit in a hydeogenic atom is equal to 1.5 xa (a is Bohr radius, then the value ofn/2 is: (Jan. 12,2019 (0 @ 0H ©) 19 © 10 @ 07 The de Broglie wavelength (2) associated with a photoclectron varies withthe frequency 1) of theincdent radiation as, [yi threshold frequency]: (an. 11,2019 (D) 3 @ > (by he 7 (vole 1 i @ @¥0) he © x (v0 (w-wh ‘The de-Broglie's wavelength of electron present in first Bohr orbitof'H atoms: JOnline April 15, 2018 UD) (a) 405208 (6) 2005294, 0.529 oF (@ 05294, At temperature T, the average kinetic energy of any patcleis 347. The de Broglie wavelength follows the order [Online April 11, 2015) (@)_ Visible photon > Thermal neutron Thermal eletron (b) Thermal proton > Thermal electron > Visible photon (¢) Thermal proton > Visible photon > Thermal electron (@) Visible photon > Thermal electron > Thermal neutron 49, The de-Broglie wavelength ofa particle of mass 6.63 g moving witha velocity of 100 mss [Oaline Apeit 12,2014) ©) 10m &) 10% m (1 'm |G 10m 50. Thede Broglic wavelength of car of mass 1000 kg and velocity 36 mir is {Online Aprit 23,2013] (@) 6626%10%m ——(&) 6.626% 10-%m (6) 6626%10%m ——@) 6626x10%m 1. Ifthe radius of frst obit oF H atom isa, the de-Broglie ‘wavelength ofan electron inthe third obit is {Online May 12,2012] @) 42a, 0) 8x4, (©) Gra, @) 2nay 152. Ifthe kineticeneray afan electeon is increased fou times, the wavelength ofthe de-Broglie wave associated with it ‘would become Online May 19,2012] (@) one fourth (halt (6) fourtimes (2 twotimes '53._Inan atom, an electron is moving with speed of 600 m/s with an accuracy of 0.008%, Certainity with which the sti ofthe electron ean be located is (= 6.6 10° kg ms! mas of electron, ¢, 9.1 « 107" kg): (2009) (@) S10%10%'m 1.92% 10-%m (©) 384% 103m (@) 132 10-4m ‘4. Uncertainty in the position of an electron (mass =9.1 10°" kg) moving witha velocity 300 ms" accurate upto 0.001% wil be 120061 (@) 192+ 102m (6) 384% 102m (@) 192% 107m (@) 376» 102m (= 6.63 10°45) 5S. The de Broglie wavelength ofa tenis ball of mass 60 g moving with a velocity of 10 metres per second is approximately £2003] (@) 107% motes (0) 10" metres (©) 10° metres (©) 10 metres Planck's constant = 6.63 « 107438 ‘36, Uncertintyin positon ofa minute partcleof mass25 gin spaces 10° m, What isthe uncertainty in its velocity (in ms")? (= 6.6 x 10911) 12002] (@ 21x10 (0) 05 x 10 (6) 24x 10 (@ 03 x 10% ‘opie PY Quantum Mechanical Model DB of Atom 57. Inthe sixth period, the orbitals that are filled are [Sep. 05, 2020 ()] (a) 66,46 5d,6p (0) 65,54, 569 (©) 65,56, 64,69 ©) 65,6, 64, 6F9 SI cr ‘58. The correc statement about probability density (except a infinite distance from nucleus) is: [Sep. 05, 2020 (1) {@) Tteanbe zero for Ly orbital (b) Itcan benegative for 2p orbital (6) Itean be zero for 3p orbital (@ Itcan never be zer0 for 2s orbital 59, Consider the hypothetical situation where the azimuthal quantum number, (takes values, 1,2, 10 1, where isthe principal quantum number, Thea, the element with atomic number [Sep. 03, 2020 1D] (a) 94s the ist alkali metal (b) 13hasa halffilled valence subshell (6) Sis the first noble gas (@) 6has a 2p-valence subshell 60, The number of subshells associated with m= 4 and m= —2quantumnumbersis:" [Sep. 02, 2020 (11), Oe @ ee 6 aa 61, Menumber ooritasassocte wth quantum numbers is INVsdan,07, 2020 1 @u Os © ws 62, Thecketronsare mor key tobe fond {Apt 12,2019) t ve) (© in theregion sande (b) in the region cand (@ onlyin theregion a (€) only in the region ¢ 63. The graph between |y/? and r (radial distance) is shown below. This represents [April 10, 2019 (1)] \vi| (b) 2sorbital (@) 2porbital 64, The isoelectronic set of ions is [April 10, 2019 (1) (9) NP,0%, Prand Na® (b)N°>, Li", Mg? and O (©) F,Li',Na* and Mg (d) Li’, Na‘, O* and F 65. The quantum number of four electrons are given below 1 () Bsorbital (©) Isoxbital ML n=4, Om, No n=3,0=1my= Lm== UF or. 68. n. n. ‘The correct order of their increasing energies willbe LAprit8, 2019 (0) @ Wemen<1 —— @ Iet (nD (0) ns—>(n~2)f-Mn-1)d—> mp (©) ns 9 mp > (a Id (n-2Yh (@) 15> (1d 9 (0-2) mp ‘The correct set of four quantum numbers forthe valence cloctrons of rubidium atom (2= 37) is [2014] 1 ay 50.0,+1 sh0.+4 @ o © . (©) Sib 1 (@) S045 In an atom how many orbitals) will have the quantum numbers: 2=3,/=2and m,=+2?{Online April, 2013], @s 3 ot a7 Given (Ay n=3.m +1 (8) 2=2,0-1,m,=-Am,= 12 ‘The maximum number of electron(s) in an atom that ean hhave the quantum numbers as given in (A) and (B) are respectively: [Online April 25,2013], (@) 2Sand1 (®) Sand (©) Zand (@ 4andt§€488| Pri nm ™ 15. 16. ‘The electrons identified by quantum numbers and & (Ayn=4i=1 @n=41=0 2012] © n-3.1-2 )n=3,I-1 can be placed in order of nezeasing energy’as @) ODO) &) O} (6) Li',Na'Mge,Co? (© KCC Se* — (d) Ba SK, CoP Of the following sets which one does NOT contain isoelectronic species? 12005} 2. 8. a4, 8s. (@) Bo},CO?, NOs (6) S08, CO, NOS © ON-NaC} POF, SO2,ClOF In amult-leceon atom, which ofthe following orbitals Geseribed by the thre quantum members will ave the same energyin he absence of magntic andclecrc feds? 12005] (A) n=1,/=0,n B) n=2,1=0,m=0 (Ow-2l-Lm=1 Dy n=3.1=2,m=1 ©) n=3,/=2, (a) (D)and(e) ©) C)anaD) (0) (ByandiC) (@) (A)and (B) Which ofthe following ets of quantum numbers is correct focan electron in orbital? 12004] (@) n=40=3, 4 (0) =4,1=4, % (0) med le3,mm hsm 44 (@ m=3.0 2s=+%4 Consider the ground state of Cr atorn (X= 24). The number of electrons with the azimuthal quantum numbers, [= | and 2are, respectively 2004) (@) 16and4 () Wands (©) ands (@) Wands Which one of the following sets of fons represents the collection of isoelectronic species? 12004) (@) K’CI.Mg™Se" — (b) Na’, Ca, Sc F (©) KC Ser (@) Na’, Me AP, Ct (Atomic nos. : F=9, C1=17,Na= 11, Mg=12, Al=13, K=19,Ca=20,Se=21) The number of d-eleetrons retained in Fe (At-no. of Fe=26) ion is @4 ys © 6 3 Which one of the following groupings represents a collection ofisoclectronic species MAL nos,: C3:55, Br:38) 12003] 12003) () BeAl*,Cr (@) Na’, Ca*, Mg (a) NP Nw (0) C#,Cs',Br[Structure of Aor) 1 n. nm 14. 15. ay Node Sq Wy Ba ¢——> (b) Number of orbitals ina shell = () According to Aufbau principle, the sequence of billing cleeteons in sixth period is 65 4f- Sd~6pi.e, (ns) (0-2) fr Id np (a) The cleetronie configuration of Rubidium (Rb=37) is 22s? 2p83s3 pad! as? apSsst ‘Since last electron entersin Ssoxbital Hence n=5,!=0,m=0, (©) 1=3,1=2 means 3 orbital a oH o 4 2 i.e, in an atom only one orbital can have the value @) (i) n=Smeans!=0,1,2,3,4 since m= +1 thence total no, of electrons will be = O(ftom.) + 2¢cm p)-+ 20m d+ 20m f)+ 20m 2) 0424242428 Gi) n=2,1= 1,m,=-1, m, = 1/2 represent 2p orbital with ‘one electron. ©) (asp ) 4s (o3d ) 3p ‘Aceroding to Bohr Bury's (1 +) rule, increasing order of energy (D)<(B)=()= (A), ‘Note: Ifthe two orbitals have same value of (+1) then theorbital with lower value of willbe filled firs (©) Among isoelectronic species ionic radi inereases as the negatives charge increases, Onder ofionic radi Ca®* — 16+2= 180 (Wot isoelectronic) © Li 0c c- (not isoelectronic) Be VCE=17+1 = 18e°, =20-2= 18", Sel*=21 -3 = 18e (isoetectronie) © @ (not isoelectronic) *. umber felons xp siean-n] ® cor se3 aay beeleoronic 03-6403 +2=32) Sete NOs +7+8x34 | so} lees coe 2 not isoelectronic ‘species Noy 2 Or stele : [isoelectronic e Ny—arasia | oeeion 6x2 +29688] Pri a1. PO} —+15+8%4+3=50) | | soctetronic a SOP —s16+8+2=50 | IS 10g 17 +84 50) Hence the species in option (b) are not iso-electronic (a) The energy ofan orbital is given by (n+) rule. (n+) value for option (E) and (D) is (3 +2)=5 hence they will hhave same energy, since their values are also same, (2) The possible quantum numbers for 4/ electron are Ll 2 OF various possiblities only option (a) is possible. m3, 20,12, Sand 2. 8 84, (0) Electronic configuration of Cr atom (Z~24) #220 ap 38° 3p 308 4s! when J= 1, p-subshell, Numbers of electrons = 12 when J=2, d-subshell, Numbers ofeleetzons = 5 (0) Ks gia 9 80% :C each contains 18 electrons. (©) Fe Q6-2=24)= 1220 296 323p"40"34*hence no, of d electrons retained is6 [Two 4s electron areremoved] (a) NP, F and Na contain 10 electrons each,