PUNJABI UNIVERSITY, PATIALA (Established Under Punjab Act No. 35 of 1961) ~ B.SC (HONOURS) CHEMISTRY PART-II SEMESTER V & VI SESSION 2023-24 & 2024-25 CHOICE BASED CREDIT SYSTEM PUNJABI UNIVERSITY, PATIALA (All Copyrights reserved with the University) 1 Ye ProfessofK Hod Deptt. of Chemis Punjabi University, PaticSYLLABUS B.Sc. (Honors) Chemistry SEMESTER V and VI Ir 24 |C CHEB3PUP SEMESTER V Paper Code Title of Paper No. of | Credits] Time [Lectures Allowe CHEB3501T | Organic Chemistry-IV | 60 4 3 hrs CHEB3502T | Physical Chemistry -V ] 60 4 3 hrs ‘CHEB35031 — | Inorganic materials oF | 60 7 3 his industrial importance CHEB3504T | Research methodology | 60 7 Shs for chemistry CHEB3505T Punjabi Compulsory-I/ 60 4 3 hrs Elementary Punjabi CHEB3506P_ Organic Chemistry Lab- |” 60 2 3 hrs CHEB3507P | Physical Chemistry Lab- | 60 2 3 hrs CHEB3508P | Inorganic materials of | 60 2 3 hrs industrial importance | SEMESTER VI Paper Code Title of Paper ‘No.of | Credits | 1 i __Leeture _|_ me. CHEB3601T_ |Inorganic Chemistry-IV 60 4 3 CHEB36021 [Organic Chemistry- 0 a 3 CHEB3603T Industrial chemicals and 60 4 a novel inorganic solids CHEB3604T Instrumental 60 4 3 methods of chemical CHEB3605T Punjabi compulsory ~11/ 0 7 3 [Elementary Punjabi CHEB3606P | Inorganic Chemistry Lab- | 60 2 3 [CHEB3607P Organic Chemistry Lab] 60 2 3 CHEB3608P Instrumental 60 2 3 methods of chemical 21 OF D023 2 Professor & Deptt. of Punjabi University, Pattatsasf SCHEME SEMESTER V Paper Code | Title of Paper Credits). Max Marks [Examination Time Total | Ext. | Int CHEB3501T | Organic Chemistry-IV 4 5 60 [15 | 3hrs | Physical Chemistry - 4 Z: 60 | 15 hrs CHEB3503T [Inorganic materials of | 4 5 60 [15 | 3hrs industrial importance CHEB3504T Research _ methodology | 4 3 60 [15 | Shs for chemistry CHEB3505T _ | Punjabi Compulsory) 4 100 [75 [25 | Shhrs [Elementary Punjabi CHEB3306P_ | Organic Chemistry | 2 70 30/20 | 3hrs Lab-IV CHEB3307P_| Physical Chemistry | 2 70 30°20 | 3hrs Lab-V CHEB3508P = |inorganic materials _o1 2 70 50 20 3 hrs lindustrial importance Lab Semester-VI CHEB3601T finorganic Chemistry-IV a [5 60 15 ]3hrs CHEB3602T Organic Chemistry-V 4 195 60 15 | 3hrs CHEB3603T [industrial chemicals and 4] 75 60 15 | 3hrs novel inorganic solids CHEB3604T instrumental methods of 4] 75 60 15 | 3hrs chemical analysis CHEB3605T [Punjabi compulsory — II] 4 | 100] 75 25 | Shs [Elementary Punjabi CHEB3606P_ Inorganic Chemistry Lab- Z 70 50 20 3 hrs Vv CHEB3607P_ ganic Chemistry Lab-V| 2 70 50 20 3 hrs CHEB3608P [instrumental methods of 2 | 70 50 20 | 3hrs hhemical analysis Lab eF-22 Professor & Head, Denti. of PutlabF University, aaySemester V CHEB3501T: ORGANIC CHEMISTRY-IV (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections : A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and will carry 10 marks each, Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each, INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9 question being compulsory) selecting two questions from each of A and B sections, SECTION - A Nucleic Acids Components of nucleic acids, Nucleosides and nucleotides; Structure, synthesis and reactions of: Adenine, Guanine, Cytosine, Uracil and Thymine: Structure of polynucleotides. (7 Lectures) Amino Acids, Peptides and Proteins Amino acids, Peptides and their classification, aAmino Acids - Synthesis, ionic properties and reactions. Zwitterions, pK, Values, isoelectric point and electrophoresis; Study of peptides: determination of their primary structures-end group analysis, methods of peptide synthesis, Sunthesis of peptides using N-protecting, C-protecting and C-activating groups - Solid-phase synthesis (16 Lectures) Enzymes Introduction, classification and characteristics of enzymes. Salient features of active site of enzymes. Mechanism. of enzyme action (taking trypsin as example), factors affecting enzyme action, coenzymes and cofactors and their role in biological reactions, specificity of enzyme action (including stereospecificity), enzyme inhibitors and x qe their importance, phenomenon of inhibition (competitive, uncompetitive and ‘non-competitive inhibition including allosteric inhibition), W-3 cee 4 Profesor Koa? Deptt. of Chemistry Punjabi University: Pafiot,(7 Lectures) SECTION - B Lipids Introduction to oils and fats; common fatty acids present in oils and fats, Hydrogenntion of fats and oils, Saponification value, acid value, iodine number. Reversion and ranci (8 Lectures) Concept of Energy in Biosystems Cells obtain energy by the oxidation of foodstuff (organic molecules). Introduction to metabolism (catabolism, anabolism). ATP: The universal currency of cellular energy, ATP hydrolysis and free energy change. Agents for transfer of electrons in biological redox systems: NAD+, FAD. Conversion of food to energy: Outline of catabolic pathways of carbohydrate- alycolysis, fermentation, Krebs cycle. Overview of catabolic pathways of fat and protein. Interrelationship in the metabolic pathways of protein, fat and carbohydrate. Caloric value of food, standard caloric content of food types. (10 Lectures) Pharmaceutical Compounds: Structure and Importance Classification, structure and therapeutic uses of antipyretics: Paracetamol (with synthesis), Analgesics: Ibuprofen (with synthesis), Antimalarials: Chloroquine (with synthesis). An elementary treatment of Antil and detailed study of chloramphenicol, Medicinal values of curcumin (haldi), azadirachtin (neem), vitamin C and antacid (ranitidine). (12 Lectures) Reference Books: . Berg, J.M., Tymoczko, J.L. and Stryer, L. (2006) Biochemistry. Vith jon, W.H. Freeman and Co. Nelson, D.L., Cox, M.M. and Lehninger, A.L. (2009) Principles of jochemistry. IV Edition, W.H. Freeman and Co. . Murray, R-K., Granner, D.K., Mayes, P.A. and Rodwell, V.W. (2009) Harper's Illustrated Biochemistry. XXVIII edition. Lange Medical Books/ McGraw-Hill Wins G23 Professor & Det of Cheney “University, Pafiote36) CHEB3502T: PHYSICAL CHEMISTRY-V (Credits: 04) Maximum Marks:7S (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three s is: A, B and C. Sections A and B Will have four questions each from the respective section of the syllabus and will carry 10 marks each. Section C will consist of 10 short answer questions that Will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9" question being compulsory) selecting two questions from each of A and B sections, SECTION-A Quantum Chemistry Postulates of quantum mechanics, quantum mechanical operators, Schrodinger qluation and its application to free particle and “particle-in-a-box" (rigorous treatment), quantization of energy levels, zero-point energy and Heisenberg Uncertainty principle: wavefunctions, probability distribution functions, nedal Properties, ‘Extension to two and three dimensional boxes, separation “of variables, degeneracy. Qualitative treatment of simple harmonic oscillator model of vibrational motion: Setting [up of Schrodinger equation and discussion of solution. and ‘wavefunctions. Vibrational energy of diatomic molecules and zero-point energy. Angular momentum: Commutation rules, quantization of square of total angular momentum and z-component, Qualitative treatment of hydrogen atom and hydrogen-like ions: setting up of Schrodinger equation in spherical polar coordinates, radial part, quantization of cherey (only final energy expression). Average and most probable distances of, electron from nucleus. Setting up of Schrodinger equation for ‘many-clectron atoms (He, Li). Need for (aac 6 Professor & Head, Deptt. of Puntahl Untvereity Battatsapproximation methods. Statement of variation theorem and application to simple systems (particle-in-a-box, harmonic oscillator, hydrogen atom). Chemical bonding: Covalent bonding, valence bond and molecular orbital approaches, LCAO-MO treatment of H+. Bonding and antibonding orbitals. Qualitative extension to Hs. Comparison of LCAO-MO and VB treatments of H2 (only wavefunctions, detailed solution not required) and their limi Refinements of the two approaches (Configuration Interaction for MO, ionic terms in VB). Qualitative description of LCAO-MO treatment of homonuclear and heteronuclear diatomic molecules (HF, LiH). Localised and non-localised molecular orbitals treatment of triatomic (BeH2, H2O) molecules. Qualitative ‘MO theory and its application to AH» type molecules. (30 Lectures) SECTION-B ‘Molecular Spectroscopy: Interaction of electromagnetic radiation with molecules and various types of spectra; Born- Oppenheimer approximation Rotation spectroscopy: Selection rules, intensities of spectral lines, determination of bond lengths of diatomic and linear triatomic molecules, isotopic substitution. Vibrational spectroscopy: Classical equation of vibration, computation of force constant, amplitude of diatomic molecular vibrations, anharmonicity, Morse potential, dissociation energies, fundamental frequencies, overtones, hot bands, degrees of freedom for polyatomic molecules, modes of vibration, concept of group frequencies. Vibration-rotation spectroscopy: diatomic vibrating rotator, P, QR branches Raman spectroscopy: Qualitative treatment of Rotational Raman effect; Effect of nuclear spin, Vibrational Raman spectra, Stokes and anti-Stokes lines; their intensity difference, rule of mutual exclusion. Electronic spectroscopy: Franck-Condon principle, electronic transitions, singlet and triplet states, fluorescence and phosphorescence, dissociation and predissociation, calculation of electronic transitions of polyenes using free electron model. Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR spectroscopy, Larmor precession, chemical shift and low resolution spectra, different scales, spin-spin coupling and high resolution spectra, interpretation of PMR spectra of organic molecules. Electron Spin Resonance (ESR) spectroscopy: Its principle, hyperfine structure, ESR of simple radicals. i (20 Lectures) Photochemistry Characteristics of electromagnetic radiation, Lambert-Beer’s law and its Professor & Head, limitations, physical significance of absorption coefficients. Laws, ; LT i Dent of Chem i University, Patios st)Photochemistry, quantum yield, actinometry, examples of low and high quantum yields, photochemical equilibrium and the differential rate of photochemical reactions, photosensitised reactions, quenching. Role of photochemical reactions in biochemical processes, photostationary states, chemiluminescence. (10 Lectures) Reference Books: + Banwell, C. N. & MeCash, E. M. Fundamentals of Molecular ‘Spectroscopy 4" Ed. Tata McGraw-Hill: New Delhi (2006). . Chandra, A. K. Introductory Quantum Chemistry Tata McGraw-Hill (2001). . House, J. E. Fundamentals of Quantum Chemistry 2™ Ed. Elsevier: USA (2004). . Lowe, J. P. & Peterson, K. Quantum Chemistry, Academic Press (2005). : Kakkar, R. Atomic & Molecular Spectroscopy, Cambridge University Press (2015), - Mars Profesdbe& tae Dent of Chemistry »bi University Paar 33/cCHEB3503T: INORGANIC = MATERIALS OF INDUSTRIAL IMPORTANCE (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections : A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and will carry 10 marks each. Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9 question being compulsory) selecting two questions from each of A and B sections. SECTION-A Silicate Industries Glass: Glassy state and its properties, classification (silicate and non-silicate glasses), Manufacture and processing of glass. Composition and properties of the following types of lasses: Soda lime glass, lead glass, armoured glass, safety glass, borosilicate glass, fluorosilicate, coloured glass, photosensitive glass. Ceramics: Important clays and feldspar, ceramic, their types and manufacture. High technology ceramics and their applications, superconducting and semiconducting oxides, fullerenes carbon nanotubes and carbon fibre. Cements: Classification of cement, ingredients and their role, Manufacture of cement and the setting process, quick setting cements. (12 Lectures) Fertilizers: Different types of fertilizers. Manufacture of the following fertilizers: Urea, ammonium nitrate, calcium ammonium nitrate, ammonium phosphates; _ polyphosphate, superphosphate, compound and mixed fertilizers, potassium chloride, potassium sulphate. (8 Lectures) Surface Coatings: Objectives of coatings surfaces, preliminary treatment of surface, classification of surface coatings. Paints and pigments-formulation, composition and related properties. Oil paint, Vehicle, modified oils, Pigments, toners and lakes pigments, Fillers, Thinners, Enamels, cmulsifying agents. Special paints (Heat retardant, Fire retardant, Eco-friendly paint, jPlastic paint), Dyes, Wax polishing, Water and Oil paints, additives, Metallic coatings (electrolytic and electroless), metal spraying and ano (10 Lectures) SECTION-B Batteries: Primary and secondary batteries, battery components and their role, Characteristics of Battery. Working of following batteries: Pb acid, Li-Battery, Solid state electrolyte battery. Fuel cells, Solar cell and polymer cell. (8 Lectures) Alloys: Classification of alloys, ferrous and non-ferrous alloys, Specific properties of elements in alloys. Manufacture of Steel (removal of silicon decarbonization, demanganization, esulphurization dephosphorisation) and surface treatment (argon treatment, - heat tveatment, nitriding, carburizing). Composition and properties of different types of steels. (10 Lectures) Catalysis: General principles and properties of catalysts, homogenous catalysis (catalytic steps and examples) and heterogenous catalysis (catalytic steps and examples) and their industrial applications, Deactivation or regeneration of catalysts. Phase transfer catalysts, application of zeolites as catalysts. (8 Lectures) Chemical explosives: Origin of explosive properties in organic compounds, preparation and explosive properties of lead azide, PETN, cyclonite (RDX). Introduction to rocket propellants. (4 Lectures) Reference Books: +E, Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK. + RUM. Felder, R. W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi. + W.D. Kingery, H. K. Bowen, D. R. Uhlmann: Introduction to Ceramics, Wiley Publishers, New Delhi. + J.A. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi, + P.C. Jain, M. Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi. +R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas Publications, New Delhi. + BLK. Sharma: Engineering Chemistry, Goel Publishing House, Meerut Professor & fev Dent, of Chemistry hi University, Pattata(CHEB3504T RESEARCH METHODOLOGY FOR CHEMISTRY (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections: A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and will carry 10 marks cach. Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each, INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9" question being compulsory) selecting two questions from each of A and B sections, SECTION-A Literature Survey: Frints Sources of information: Primary, secondary, tertiary sources; Joumals: Journal abbreviations, abstracts, current titles, reviews, monographs, lictionaries, text-books, Susans peje: introduction to Chemical Abstracts and Beilstein, Subject Index, Substance Index, Author Index, Formula Index, and other Indices with examples. Digital; Web resources, E-jourmals, Joumal access, TOC alerts, Hot articles, Citation index, Impact factor, H-index, E-consortium, UGC infonet, E-books, Intemet disown Ereerana communities, Blogs, Preprint servers, Search engines, Scirus, Google Scholar, Ghemlndustry, Wiki- Databases, ChemSpider, Science Direct, SciFinder, Scopus. [normation Technology and Library Resources: The Intemet and World Wide Web. Internet resources for chemistry, Finding and citing published information (18 Lectures) Methods of Scientific Research and Writing Scientific Papers: Reporting practical and project work. Writing literature surveys and reviews, Organizing 4 poster display. Giving an oral presentation, Wt. scientific papers - justification for scientific contributions, bibliography, description of methods, conclusions, the need for illustration, style, publi Is of Scientific work. Writing ethics. Avoiding plagiarism. (12 Lectures) SECTION-B ‘Chemical Safety and Ethical Handling of Chemicals: environment, protective apparel, Tez, Professor & Hea ringet enty Safe working procedure and protecti University pn sofa/c procedure and first aid, laboratory ventilation. Safe storage and use of hazardous chemicals, procedure for working with substances that pose hazards, flammable or explosive hazards, procedures for working with gases at pressures above ot below atmospheric - safe storage and disposal of waste chemicals, recovery, recycling and reuse of laboratory chemicals, procedure for laboratory disposal of expiosives, identification, verification and segregation of laboratory waste, disposal of chemicals in the sanitary sewer system, incineration and transportation of hazardous chemicals. (10 Lectures) Data Analysis The Investigative Approach: Making and Recording Measurements. SI Units and their tuse.Scientific method and design of experiments. Analysis and Presentation of Data: Descriptive statistics. Choosing and using statistical tests. Chemometrics. Analysis of variance (ANOVA), Correlation and regression, Curve fitting, fitting of linear equations, simple linear cases, weighted linear case, analysis of residuals, General polynomial fitting, linearizing transformations, exponential function fit, r and its abuse, Basic aspects of multiple linear regression analysis. (10 Lectures) Electronies Basic fundamentals of electronic circuits and their components used in circuits of common instruments like spectrophotometers, typical circuits involving operational amplifiers for electrochemical instruments. Elementary aspects of digital electronics. (10 Lectures) Reference Books ; + Dean, J. R., Jones, A. M., Holmes, D., Reed, R., Weyers, J. & Jones, A. (2011) Practical skills in chemistry. 2 Ed. Prentice-Hall, Harlow. + Hibbert, D. B. & Gooding, J. J. (2006) Data analysis for chemistry. Oxford University Press. + Topping, J. (1984) Errors of observation and their treatment. Fourth Ed., Chapman Hall, London. + Harris, D. C. Quantitative chemical analysis. 6" Ed., Freeman (2007) Chapters 3-5. * Levie, R. de, How to use Excel in analytical chemistry and in general scientific data analysis. Cambridge Univ. Press (2001) 487 pages. + Chemical safety matters - IUPAC - IPCS, Cambridge University Press, 1992. OSU safety manual 1.01. Po hee Deptt. of *Mnivarsity, Rafat 12Gn¥) Pur- QODI-2Y B%W2Yy25— CHEB35 05: T/A: PUNJABI COMPULSORY-I (Credits: 04) Potent ook ae nie: 100 ait fee ue oe et nt eye vests feet wn Te ash ier wait viene feet wes Je at niet oaftonnas: 6 Udine A wat: ar Gat, Fu, efi fit rig eS a, a fit der aw: (1) PoP aeey < ew, ereae Mee Alorara fe as HOS) » Remeraare: (i Ua woh Rees, Hee, Resins, Corer wat, Goren mre 2 Ceres feed nae ete er cette! 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Fee fi aes, wat moet w fifo, uel mere, fet.age a ee OPUS (CHEG2S¢98: ELEMENTARY PUNJABI (MUDLA GYAN) ee its: Professor & Head (Credits: 04) of Chemisty, Punjabi University, Patiale arn at ten ee ow ae tore eer om Wider wees me Sloe Br aU) geek eenre # ery Wer bor Yaewe Fe et a), genta Fume Boe eye WWrmer © Rote xvas # fet 2 ay am), Sb 8 meet et eeP 8 fen weer et Bites Fras nevis oem se soe oe oe 2 are he ne oefet see rent) morfen we mead 1 efi fac ig, eG unt ute, wanbates fags, wie gateatict, ufemres. 2004, fe siare face 2. wim ftac ig, genni i, nnn Rega, tira aeteatich, uber, 2011, erat a Lar fine an wud, tart finde, nba faQ’, tira qateatic, uflmrer, 2002 «fet autos fit, ira fies a, cies Haiti goa wis Ste aire), asta ahd, utes 2011, fg. ant Hagdes Babs, Teach Yours Punjab, Publication Bureau, Panhbi University, Patiala, 2011 6: tony A.Glenon and Hijet Singh Gi, A Startn Panjab, ablation Buca, Puja iver. My oss Patiala, 1997. ~ . OR aoc 1 Cj Singh aan uh Singh Waa Iain Pan, Pub ofan University, Patiala, 2003, rofessor & HeagCHEB3S06P: ORGANIC CHEMISTRY LAB-IV 60 Lectures (Credits: 02) Maximum Marks:70 (External-50, Internal-20) 1 Estimation of glycine by Sorenson’s formalin method. 2 Study of the titration curve of glycine. 3 Estimation of proteins by Lowry’s method. 4 Study of the action of salivary amylase on starch at optimum conditions. 5. Effect of temperature on the action of salivary amylase 6. Saponification value of an oil or a fat. I Determination of Iodine number of an oil fat. 8 Isolation and characterization of DNA from onion/ eauliflower/peas. Reference Books: . ‘Manual of Biochemistry Workshop, 2012, Department of Chemistry, University of Delhi. . "Arthur, |. V. Quantitative Organic Analysis, Pearson. My Professor & Head, Dente a rb Ue, 15w7 (CHEB3507P: PHYSICAL CHEMISTRY LAB-V 60 Lectures (Credits: 02) Maximum Marks: 70 (External-50, Internal-20) UV/Visible spectroscopy L ‘Study the 200-500 nm absorbance spectra of KMnO, and KzCr.0y (in 6.1 M HS0.) and determine the Xmay values. Calculate the energies of the two transitions in different units (J molecule”, kJ mol’, cm, eV). n. ‘Study the pH-dependence of the UV-Vis spectrum (200-500 nm) of KxCr20>. ‘ IIL, Record the 200-350 nm UV spectra of the given compounds (acetone, acetaldehyde, 2-propanol, acetic acid) in water. Comment on the effect of structure on the UV spectra of organic compounds. Colourimetry L Verify Lambert-Beer’s law and determine the concentration of ‘CuSO,/KMn0./K2Cr207 in a solution of unknown concentration HL Determine the concentrations of KMnO, and K2Cr07 in a mixture. Il. _ Study the kinetics of iodination of propanone in acidic medium. IV. Determine the amount of iron present in a sample using 1,10- phenathroline Vv, Determine the dissociation constant of an indicator (phenolphthalein). Vi. Study the kinetics of interaction of erystal violet/ phenolphthalein with sodium hydroxide. VIL. Analysis of the given vibration-rotation spectrum of HCI(g) Reference Books : Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand & Co.: New Delhi (2011). : Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8 Ed.; McGraw-Hill: New York (2003). : Halpem, A. M. & McBane, G. C. Experimental Physical Chemistry 37 Ed.; WH. Freeman & Co.: New York (2003), ee Professor, Deptt, ohana, Penjabi University Patots 16exoueene CHEB3S08P ; INORGANIC MATERIALS OF INDUSTRIAL IMPORTANCE LAB 60 Lectures (Credits: 02) Maximum Marks:70 (External-50, Internal-20) Determination of free acidity in ammonium sulphate fertilizer. Estimation of Calcium in Calcium ammonium nitrate fertilizer. Estimation of phosphoric acid in superphosphate fertilizer Electroless metallic coatings on ceramic and plastic material. Determination of composition of dolomite (by complexometric titration). Analysis of solder alloy. Analysis of Cement. Preparation of pigment (zinc oxide). Reference Books: + E,Stocchi: Industrial Chemistry, Vol, Elis Horwood Utd. UK. + RLM Felder, R. W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi + W.D. Kingery, H.K. Bowen, D. R. Uhlmann: Introduction to Ceramics, Wiley Publishers, New Delhi + 1.8. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Deli. + P.C.Jain, M. Jain: Engineering Chemistry, Dhanpat Rai & Sons, Deli. + R.Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas Publications, New Delhi ingineering Chemistry, Goe! Publishing House, Meerut i wip eS Dentt orn Penjabl University ations 7Semester VI CHEB3601T: INORGANIC CHEMISTRY-IV (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections : A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and will carry 10 marks each. Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9" question being compulsory) selecting two questions from each of A and B sections. Section - A Organometallic Compounds Definition and classification of organometallic compounds on the basis of bond type. Concept of hapticity of organic ligands. Metal carbonyls: 18 electron rule, electron count of mononuclear, polynuclear and substituted metal carbonyls of 3d series. General methods of preparation (direct combination, reductive carbonylation,, thermal and photochemical decomposition) of mono and binuclear carbonyls of 3d series. Structures of mononuclear and binuclear carbonyls of Cr, Mn, Fe, Co and Ni using VBT. n- acceptor behaviour of CO (MO diagram of CO to be discussed), synergic effect and use of IR data to explain extent of back bonding. Zeise’s salt: Preparation and structure, evidences of synergic effect and comparison of synergic effect with that in carbonyls. Metal Alkyls: Important structural features of methyl lithium (tetramer) and trialkyl aluminium (dimer), concept of multicentre bonding in these compounds. Role of triethylaluminium in polymerisation of ethene (Ziegler - Natta Catalyst) Species present in ether solution of Grignard reagent and their structures, Schlenk equilibrium. Ferrocene: Preparation and reactions (acetylation, alkylation, metallation, Mannich Condensation). Structure and aromaticity. Comparison of aromaticity and reactivity with that of benzene. (30 Lectures) Section - B Reaction Kinetics and Mechanism Introduction to inorganic reaction mechanisms. Substitution reactions in square 18 ay Wes. Deptt. om Punjabi University, PatiatsmL Planar complexes, ‘Trans- effect, theories of trans effect, Mechanism of Tucleophilic. substitution in square planar Complexes, Thermodynamic and Kinetic stability, Kineties of octahedral substitute Ligand field effects and “eastion rates, Mechanism of substitution in octahedral complexes 20 Lectures) Catalysis by Organometallic Compounds {iudy ofthe following industrial processes and their mechani : {lkene hydrogenation (Wilkinsons Catalyst) I 2 Hydroformylation (Co salts) 31 Wacker Process 4 Synthetic gasoline (Fischer Tropsch reaction) 5 Synthesis gas by metal carbonyl complexes (10 Lectures) Reference Books: Recommended Texts: {Vogel A.L. Qualitative Inorganic Analysis, Longman, 1972 * Gyehla. 6. Fogel's Qualitative Inorganie Analysis, th Edition, Prentice Hall, 1996-03- 07. * Cotton, F.A. G.; Wilkinson & Gaus, P.L. Basic Anorganic Chemistry 3” Eel; wiley india, © Huneey, Es Kelter, EA, & Kelter, RL Inorganie Chemisiry, Principles of Structure and Reactivity 4” Ed, Harper Collins 1993, Pearson, 2006, Shape, AG. Inorganic Chemistry, 4 indian Reprint (Pearson Education) 2005 * Paulas, 8 €; MeDariel,D.H.& Alexander, 1. Concepts ane Mode in Inorganic Chemistry3"Ed,, John Wiley and Sons, NY, 1994, * Greenwood, N.N. & Earnshaw, A. Chemistry of the Elements, Elsevier 2" Ed, 1997 (Ziegler Natta Catalyst and Equilibria in Grignard Solution) 1 Lee, 1.0. Concise Inorganic Chemistry 5” Ed, tohn Wiley and sons 2008, 7 Powell, P. Principles of Organometallic Chemistry, (Chapman and Hall, 1988, * Shriver, D.D. & P. Atkins, Inorganic Chemistry “Ed, Oxford University Press, 1994, * Basolo, F. & Person, R. Mechanisms of Inorganic Reactions: Study of Metal Complexes in Solution 2" Ed., John Wiley & Sons Inc; NY. 1 fatcel KE. & Kotz,1C, Jnorganie Chemistry, W.B. Saunders Co, 1977 1 Mlessler, G. L. & Donald, a. Tart, Inorganic Chemistry 4 Ed, Pearson, 2010, * Gollan, James . et al. Principles and Applications of Organotransition Metal Chemistry. Mil Valley, CA: Unversity Science Books, 1say * Crabtree; Robert H. The Organometalic Chemistry of the Transition Metals. j New York, NY: John Wiley, 2000. * _ Spessard, Gary 0., &Gary L Miessler. Organometallic Chemistry. Upper Saddle River, Ni: Prentice-Hall, 1996, i~ ¢. &. Professor & Haag, Dentt. of cy ™ University, Patlaty(CHEB3602T: ORGANIC CHEMISTRY-V (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections : A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and ‘will carry 10 marks each. Section C will consist of 10 short answer que: that will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9" question being compulsory) selecting two questions from each of A and B sections. Section - A Organic Spectroscopy General principles Introduction to absorption and emission spectroscopy. UV Spectroscopy: ‘Types of electronic transitions, kms, Chromophores and ‘Auxochromes, Bathochromic and Hypsochromic shifts, Intensity of absorption; ‘Application of Woodward Rules for calculation of kmax for the following systems: aP unsaturated aldehydes, ketones, carboxylic acids and esters; Conjugated dienes: alicyclic, homoannular and heteroannular; Extended conjugated systems (aldehydes, Ketones and dienes); distinction between cis and trans isomers. IR Spectroscopy: Fundamental and non-fundamental molecular vibrations; IR ‘absorption positions of O, N and S containing functional groups; Effect of H- bonding, conjugation, resonance and ring size on IR absorptions; Fingerprint region and its significance; application in functional group analysis. NMR Spectroscopy: Basic principles of Proton Magnetic Resonance, chemical shift and factors influencing it; Spin - Spin coupling and coupling constant; ‘Anisotropic effects in alkene, alkyne, aldehydes and aromatics, Interpetation of NMR spectra of simple compounds. ‘Applications of IR, UV and NMR for identification of simple organic ‘molecules. (24 Lectures) Dyes Classification, Colour and constitution; Mordant and Vat Dyes; Chemistry of dyeing; Synthesis and applications of: Azo dyes - Methyl Orange and Congo Red (mechanism of Diazo Couplins Triphenyl Methane Dyes -Malachite Wess. 20 "Professor & Head, Deptt. of Punjabi University, PatialaGreen, Rosaniline and Crystal Violet; Phthalein Dyes - Phenolphthalein and Fluorescein; Natural dyes -structure elucidation and synthesis of Alizarin and Indigotin; Edible Dyes with examples. (6 Lectures) Section - B Carbohydrates Occurrence, classification and their biological importance. Monosaccharides: Constitution and absolute configuration of glucose and fructose, epimers and anomers, mutarotation, determination of ring size of glucose and fructose, Haworth projections and conformational structures; Interconversions of aldoses and ketoses; Killiani- Fischer synthesis and Ruff degradation; Disaccharides - Structure elucidation of maltose, lactose and sucrose. Polysaccharides - Elementary treatment of starch, cellulose and glycogen. (16 Lectures) Polymers Introduction and classification including di-block, tri-block and amphiphilic polymers; Number average molecular weight, Weight average molecular ‘weight, Degree of polymerization, Polydispersity Index. Polymerisation reactions -Addition and condensation -Mechanism of cationic, anionic and free radical addition polymerization; Metallocene-based Ziegler. Natta polymerisation of alkenes; Preparation and applications of plastics - thermosetting (phenol-formaldehyde, Polyurethanes) and thermosoftening (PVC, polythene); Fabrics - natural and synthetic (acrylic, polyamido, polyester); Rubbers - natural and_synthetic: Buna-S, Chloroprene and Neoprene; Vulcanization: Polymer additives; Introduction to liquid crystal polymers; Biodegradable and conducting polymers with examples. (14 Lectures) Reference Books: + Kalsi, P. S. Textbook of Organic Chemistry 1" Ed., New Age International (P) Led. Pub. + Morrison, R. T. & Boyd, R. N. Organie Chemistry, Dorling Kindersley (India) Pvt, Ltd. (Pearson Education). + Billmeyer, F. W. Textbook of Polymer Science, John Wiley & Sons, Inc. * Gowariker, V. R.; Viswanathan, N. V. & Sreedhar, J. Polymer Science, New Age International (P) Ltd, Pub. + Finar, 1 L. Organic Chemistry (Volume 2: Stereochemisiry and the Chemistry of Natural Products), Dorling Kindersley (India) Pvt. Ltd. (Pearson Education). 2o/ LO br ers a Professor & Head, Deo. of Chemistry abi University, PatiataGraham Solomons, T.W. Organic Chemistry, John Wiley & Sons, Ine. Clayden, J.; Greeves, N.; Warren, $5; Wothers, P.; Organic Chemistry, Oxford University Press, Singh, J.: Ali, SM. & Singh, J. Natural Product Chemistry, Prajati Prakashan (2010). Kemp, W. Organic Spectroscopy, Palgrave 2 te Mire, 6 BS Professef A Heed, Dest. of ah] University, Patiala 22 19 keple (CHEB3603T: INDUSTRIAL CHEMICALS AND NOVEL INORGANIC SOLIDS (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER “The question paper will consist of three sections : A, B and C. Sections A and B of the syllabus and will will have four questions each from the respective sectis carry 10 marks each. Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES Candidates are required to attempt five questions (Section C 9" question being compulsory) selecting two questions from each of A and B sections. Section - A Industrial Gases and Inorganic Chemicals Industrial Gases: Large scale production, uses, storage and hazards in handling of the following gases: oxygen, nitrogen, argon, neon, helium, hydrogen, acetylene, carbon monoxide, chlorine, fluorine, sulphur dioxide and phosgene. Inorganic Chemicals: Manufacture, application, analysis and hazards in handling the following chemicals: hydrochloric acid, nitric acid, sulphuric acid, caustic soda, common salt, borax, bleaching powder, sodium thiosulphate, hydrogen peroxide, potash alum, chrome ‘alum, potassium dichromate and potassium permanganate, (10 Lectures) Industrial Metallurgy Preparation of metals (ferrous and nonferrous) ‘and ultrapure metals for semiconductor technology. (4 Lectures) Energy & Environment Sources of energy: Coal, petrol and natural gas. Nuclear Fusion / Fission, Solar energy, Hydrogen, geothermal, Tidal and Hydel, etc. Nuclear Pollution: Disposal of nuclear waste, nuclear disaster and its management. (10 Lectures) Biocatalysis Introduction to biocatalysis: Importance in “Green Chemistry” and Chemical Industry. =Ne Section - Synthesis and modification of inorganic solids: Corventional heat and beat methods, Co-predpitation method, So-gel methods, Hydrothermal ‘method, lon-exchange and Intercalation methods, (20 Lectures) Inorganic solids of technological importance: Sold electrolytes - Cationic, anionic, mixed Inorganic pigments - coloured solids, white and black pigments. Molecular material and fullerides, molecular materials & chemistry - one-dimensional metals, ‘molecular magnets, inorganic liquid erystals. (10 Lectures) Nanomaterials: Overview of nanostructures and nanomaterials: classification, Preparation of gold and silver metallic nanoparticles, self-assembled Nanostructures-control of inoreantiteeture-one dimensional control. Carbon nanotubes and inorganic nanourer Bio- componten materials, DNA and nanomaterials, natural and antisical nanomaterials, blonetg composites. (20 Lectures) Reference Books: 1 E. Stocchi: Industrial Chemistry, Vol-, Ellis Horwood Ltd, UK. * RM Felder, R.W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi, 1 £& Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi. © BB Dara: 4 Textbook of Engineering Chemistry, 8. Chand & Company Ltd. New Delhi 1 EBs. Emironmental Chemistry: New Age Intemational Pvt, Ltd, New Delhi. 1 SM Khopkar, Environmental Pollution Analysis: Wiley Easter Ltd, New Delhi {SB Manahan, Environmental Chemistry, CRC Press (2005), 2 GR Miller, Environmental Science 1 ith edition. Brooks/ Cole (2006) * A Misha, Environmental Studies, Selective and Scientific Books, New Delhi (2005). * Shriver & Atkins, Inorganic Chemistry, Peter Alkins, Tina Overton, Jonathan Rourke, Mark Wieller and Fraser Armstrong, S” Edition, Oxford University Press (2011-2012) 1 Aga, D-M. Inorganle Solids: An introduction to concepts in solid-state structural chemistry. * FrankJ. Ovens, Introduction to Nanotechnology VUess . = Dre rseranens Profes Oferta “University, Patter. | tCHEB3604T: INSTRUMENTAL METHODS OF CHEMICAL ANALYSIS (Credits: 04) Maximum Marks:75 (External-60, Internal-15) Theory: 60Lectures INSTRUCTIONS FOR THE PAPER SETTER ‘The question paper will consist of three sections : A, B and C. Sections A and B will have four questions each from the respective section of the syllabus and will carry 10 marks each. Section C will consist of 10 short answer questions that will cover the entire syllabus and will be of 2 marks each. INSTRUCTIONS FOR THE CANDIDATES: Candidates are required to attempt five questions (Section C 9” question being compulsory) selecting two questions from each of A and B sections. Section - A Introduction to spectroscopic methods of analysis: Recap of the spectroscopic methods covered in detail in the core chemistry syllabus: ‘Treatment of analytical data, including error analysis. Classification of analytical methods and the types of instrumental methods. Consideration of electromagnetic radiation. (4 Lectures) Molecular spectroscopy: Infrared spectroscopy: Interactions with molecules: ‘and scattering. Means of excitation (light sources), separation of spectrum (wavelength dispersion, time resolution), detection of the signal (heat, differential detection), interpretation of spectrum (qualitative, mixtures, resolution), advantages of Fourier Transform (FTIR). Samples and results expected. Applications: Issues Of quality assurance and quality control, Special problems for portable instrumentation and rapid detection, UV-Visible/ Near IR - emission, absorption, fluorescence and photoaccoustic. Excitation sources (lasers, time resolution), wavelength dispersion (gratings, prisms, interference filters, laser, placement of sample relative to dispersion, resolution), Detection of signal (photocells, photomultiplier, diode arrays, sensitivity and S/N), Single and Double Beam instruments, Interpretation (quantification, mixtures, absorption vs. fluorescence and the use of time, photoaccoustic, fluorescent tags). (16 Lectures) Elemental analysis: Mass spectrometry (electrical discharges). Atomic spectroscopy: Atomic absorption, Atomic emission, and Atomic fluorescence. Excitation and getting sample into gas phase (flames, electrical discharges, plasmas), Wavelength separation and resolution (dependence ihe 25 Professor & Heed, Oeptt. f Charalstry Punjabi Universtty, pattatsIe Detection of radiation (simultaneous/scanning, signal noise), Interpretation (errors due to ‘molecular and ionic species, matrix effects, other interferences), (10 Lectures) Section - B Separation techniques Chromatography: Gas chromatography, liquid chromatography, supercritical flu Importance of column technology (packing, capillaries), Separation baced on increasing number of factors (volatility, solubility, interactions with stationary phase, size, electrent field), Detection: simple vs. specific (gas and liquid), Detection as a means of further analysis, (use of tags and coupling to IR and MS), Electrophoresis (plates and capillary) and use Cath DNA analysis. Jmmunoassays and DNA techniques Mass spectroscopy: Making the gaseous molecule into an ion (electron impact, chemical maaion)s Making liquids and solids into ions (electrospray, electrical discharge, laser desorption, fast atom bombardment), Separation of ions on basis of mass to charge ratio, Dagnetic, Time of Might, Electric quadrupole. Resolution, time and multiple separations, Detection and interpretation (how this is linked to excitation). (16 Lectures) NMR spectroscopy: Principle, Instrumentation, Factors affecting chemical shift, Spincoupling, Applications. (6 Lectures) Electroanalytical Methods: Potentiometry & Voltammetry Radiochemical Methods X-ray analysis and electron spectroscopy (surface analysis) (8 Lectures) Reference books: * Principles of Instrumental Analysis - 6th Edition by Douglas A. Skoog, F. James Holler, and Stanley Crouch (ISBN 0-495-01201-7) + Instrumental Methods of Analysis, 7th ed, Willard, Merritt, Dean, Settle * PW. Atkins: Physical Chemistry, + G.W. Castellan: Physical Chemistry. * CN. Banwell: Fundamentals of Molecular Spectroscopy. {Brian Smith: Infrared Spectral Interpretations: A Systematic Approach, + WJ. Moore: Physical Chemistry Ss. 8.22 Professor & Dentt. of cy ‘abi University, Pafiate 26mle (Sem) FIs - 3693-3Y _2 RoaDs- CHEB 36057/A: PUNJABI COMPULSORY-II om (Credits: 04) eos of Chemi Depatr univers, Patiala ae nist. 100 fe fee ue Be ach wt: 3s nig Westar : 25 niet wig wes fet wn Te at nt: 00 mrad uditing: 75 nis wait within fret wn Te met nit | 2 pat: 302 nif: « ons vat ag" frau 3 ure yrrsert wa ween fete te, 2. ofieours fie wos, 2, ners ftw, aie em | fete 2 feoraae: iy me wees ne ae gue", ufewrer es Hau, ys gu, natve, Use RQsug gu nd arsed gui in at Reins, rer @ carl gu, rH ned Quon ize nd wher red Qu sare 2 ware BSL FEU QuSas fawn 3 mares NU Tae eB Ys wats m3 te Tee me oetest 1 aan 2 ard sear RO yas U2 area 2 ue 6 Ps wa, wm v fy etme rear) 3 a0 RB. (iy Pa Rea er Rear ava Beers wt Pela as wre yes (Gis 3 Way 12 wba (iy Posie fees Reve male Be @3e 8 yx (0 FE 2) exete wi Gwen A Ren 2 Ma tse Bow od Per weer (f3es fea flay 09 wi we DO Re ar RS fea Rea ysis ule wear wd feRereet & Bet RB fla wes aes Bear) z Sore Re ue uasa waa feta 3 fewmae e8 wa [83 Hu Gee €@ 1s (9 waka wars feta FES 7 2 fewer (2B 8) yas UB re Refewant ord wpiat @ ris Gaze 8 Dea Ge YR @ nla Deal swe torr vorfies wernt |, gates tity, gar fetora ner vara sap, aaah wafer, BSR, 1075, 28828 far de, art arr efor mes Roorarae cred apes 2 feo ay sar getrat Some fe aes, ee fem 30S, B39 yaHT, sfEore, 2000, 1 Bey fie mrs mes Be, ara am ee Frorass, neha a aro rea Be Ss nafees ft mar, erat ar fein, tare aa one, HTS, 199 Professor & Head Department of Chemistry, Punjabi University, PatialeProfessor & Department oe Punjabi University, Patials CHEBSE05.7/B: ELEMENTARY PUNJABI (MUDLA GYAN) (Credits: 04) ae nia 100 %8 kegs esere 9 FOB). mee ic: mae fst vt wed" (Gy & oped ret & roe itr ey Ps nfed inne mea 18) Hg nfeedt pet ae ar 15 ee (2), ret Sot arc & Receramer wea et ee ) inet dot aaind we fies, ure 3 eat tate, wate, Feira, fin, ffir Reina nef om) Ronratanar eat vi use 3 eat fiat, eR. aM, ae mr) 1 oe FU (1). mae wesst S femrerens floret er frais 3 wee (Shot ore esa! © fiers. ue 3 cat nates, Risa, se, (on) foment Reaint w fits, ware 3 ea? ean, Quwe 3 ea) (2) ret ev Reoreraat ies: fins 3 fora 10 (2). Remens fagt Fee 3 eH 1 es Foe we fii 3 newes mrwtatee eh gra doxt-so wa vier Ye 3 thus fee wel oes! 1. fefenrendt ufsst ova geanh fin? fire a avi Oram mer ob reerantt at ir F nears oe) agit unre fefimrating rir § fimes fe 2a war fee yrs ve rz reas 3 reare yes ye ire | 1 carpe ym 9 vB re) 5. fefonnaiiont § fonecran eh ahead waar mnie Hike yes ua we) Ss mews fefemranh § ee wae BA onto rarfew wo meant 1 roo fiw ry, on ime finite anton GE unre gateatich, ufltomer, 2000, (FEF tim fine fore fitw vig. anand fit, uentatey GS. amet qeteafire?, ufone, 2011, oan F tare fire at ah ane madi, thre fint®, unebams fa3, vine ustatic, ufemren, 2002 «fie A. fies fie, amt firs iat, (atfGze Onadtinrs gases vs che mah anna: fag ami gateatir. uber 2011 5. Haney Bats, Teach Yourself Punjabi, Publication B 6. Henry A. Gleason an Harjoot Singh Gil, A Start in Pun Patiala, 1997, Ujjal Singh Bahri and Paraniit Singh Walia, introductory Punjabi, Publication Bureau, Punjabi — FoF Professor & Head, epartment of Chemist” Panis University, Pati Punjabi University, Patiala, 2011 i, Publication Bure Punjabi University,CHEB3606P: INORGANIC CHEMISTRY LAB-IV 60 Lectures (Credits: 02) Maximum Marks: 70 (External-S0, Internal-20) Qualitative semimicro analysis of mixtures containing 3 anions and 3 cations. Emphasis should be given to the understanding of the chemistry of different reactions. The following PO, NHK, Ba Sr, Ca, Mistures should preferably contain one interfering anion, or insoluble component (BaSOs, SrSOs, PbSOs, CaF: or AlsOs)or combination of anions c.g. CO;*and SO, NOy'and NOs, Cl and Br, CF and [, Brand I, NOy and Br, NOy‘ and F- Spot tests should be done whenever possible. i. Measurement of 10 Dg by spectrophotometric method ii, Verification of spectrochemical series. iii, Controlled synthesis of two copper oxalate hydrate complexes: kinetic vs thermodynamic factors. iv. Preparation of acetylacetanato complexes of Cu”’/Fé v. Synthesis of ammine complexes of Ni(II) and bidentate ligands like acetylacetone, DMG, glycine) by substitution method. Find the Aes of the complex. Reference Books ‘© Vogel's Qualitative Inorganic Analysis, Revised by G. Svebla, © Mare & Rockett Inorganic Preparations. 29 s ligand exchange reactions (e.g. pleCHEB3607P: ORGANIC CHEMISTRY LAB-V 60 Lectures (Credits: 02) Maximum Marks:70 (External-S0, Internal-20) 1 Extraction of caffeine from tea leaves. 2.Preparation of sodium polyacrylate. 3.Preparation of urea formaldehyde. 4.Analysis of Carbohydrate: aldoses and ketoses, reducing and non-reducing sugars. S.Qualitative analysis of unknown organic compounds containing ‘monofunctional groups (carbohydrates, aryl halides, aromatic: hydrocarbons, nitro compounds, amines and amides) and simple bifunctional groups, for e.g. salicylic acid, cinnamic acid, nitrophenols etc. 6.ldentification of simple organic compounds by IR. spectroscopy and NMR. spectroscopy (Spectra to be provided). 7.Preparation of methyl orange. Reference Books: + Vogel, A.l. Quantitative Organic Analysis, Part 3, Pearson (2012). + Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009) + Fumiss, B.S.; Hannaford, A.1; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry, 5" Ed., Pearson (2012) + Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and Quantitative Analysis, University Press (2000). Ahluwalia. V.K. & Dhingra, S. Comprehensive Practical Organic Chemistry: Qualitative Analysis, University Press (2000). Professor & Dept of Ghumaat Chemistry Punjabi Univeraty, Patiats 30ple ‘CHEB3608P: INSTRUMENTAL METHODS OF CHEMICAL ANALYSIS 60 Lectures (Credits: 02) Maximum Marks:70 (External-50, Internal-20) ‘Safety Practices in the Chemistry Laboratory Determination of the isoelectric pH of a protein. Titration curve of an amino acid. Determination of the void volume of a ge filtration column. Determination of a Mixture of Cobalt and Nickel (UV/Vis spec.) Study of Electronic Transitions in Organic Molecules (i., acetone in water) IR Absorption Spectra (Study of Aldehydes and Ketones) Determination of Calcium, iron, and Copper in Food by Atomic Absorption eR Naw ee Quantitative Analysis of Mixtures by Gas Chromatography (ie., chloroform and carbon tetrachloride) 10. Separation of Carbohydrates by HPLC 1. Determination of Caffeine in Beverages by HPLC 12, Potentiometric Titration of a Chloride-lodide Mixture 13, Cyclic Voltammetry of the Ferrocyanide/Ferricyanide Couple 14, Nuclear Magnetic Resonance 15. Use of fluorescence to do “presumptive tests” to identify blood or other body fluids. 16. Use of “presumptive tests” for anthrax or cocaine 17. Collection, preservation, and control of blood evidence being used for DNA testing 18, Use of capillary electrophoresis with laser fluorescence detection for nuclear DNA (Y ‘chromosome only or multiple chromosome) 19, Use of sequencing for the analysis of mitochondrial DNA 20. Laboratory analysis to confirm anthrax or cocaine 21, Detection in the field and confirmation in the laboratory of flammable accelerants or explosives 22, Detection of illegal drugs or steroids in athletes 23. Detection of pollutants or illegal dumping 24, Fibre analysis At least 10 experiments to be performed. Reference Books: + Principles of instrumental Analysis - 6th Edition by Douglas A. Skoog, F. James Holler, and Stanley Crouch (ISBN 0-495-01201-7). + Instrumental Methods of Analysis, 7th ed, Wilard, Merritt, Dean, Settle Professor & Head, Dent. of Punjabi University, Pati 31