Professional Documents
Culture Documents
Page: 1/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Additive EX 93008
Chemical name: cyclohexyldimethylamine
CAS Number: 98-94-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: catalyst, polyurethane component
Company:
BASF Polyurethanes GmbH
Postfach 1140
49440 Lemfoerde, GERMANY
Flam. Liq. 3
Acute Tox. 3 (oral)
Acute Tox. 3 (dermal)
Acute Tox. 3 (Inhalation - vapour)
Eye Dam./Irrit. 1
Skin Corr./Irrit. 1B
Aquatic Chronic 2
For the classifications not written out in full in this section the full text can be found in section 16.
Pictogram:
Signal Word:
Danger
Hazard Statement:
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H411 Toxic to aquatic life with long lasting effects.
No specific dangers known, if the regulations/notes for storage and handling are considered.
Chemical nature
Cyclohexyldimethylamine
CAS Number: 98-94-2
EC-Number: 202-715-5
For the classifications not written out in full in this section, including the hazard classes and the
hazard statements, the full text is listed in section 16.
3.2. Mixtures
Not applicable
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. If not breathing, give artificial
respiration. If necessary, give oxygen.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
Page: 4/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical
attention. Never induce vomiting or give anything by mouth if the victim is unconscious or having
convulsions.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: lacrimation, coughing, respiratory disorders, asthmatic complaints, irritation to the lungs,
skin eruptions
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. Cool endangered containers with water-spray.
Does not contain components with substance specific occupational exposure limits.
PNEC
freshwater: 0.002 mg/l
DNEL
worker:
Long- and short-term exposure - local effects, Inhalation: 35 mg/m3
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374)
polyvinylchloride (PVC) - 0.7 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
Form: liquid
Colour: milky white
Odour: amine-like
Odour threshold:
Not determined since toxic by
inhalation.
pH value: 12
(water, 5 g/l, 20 °C)
Literature data.
Melting point: < -77 °C
Literature data.
Boiling point: 162.3 °C (measured)
(1,013 hPa)
Flash point: 41 °C (DIN 51758, closed cup)
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.
Flammability: Flammable.
Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: 200 °C (DIN 51794)
Vapour pressure: 3.17 hPa (OECD Guideline 104)
(21.5 °C)
dynamic
Density: 0.85 g/cm3
(20 °C)
Literature data.
Relative density: 0.85
(20 °C)
Literature data.
Relative vapour density (air):4.4
(20 °C)
Solubility in water:
13.4 g/l
(20 °C)
Page: 8/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Partitioning coefficient n-octanol/water (log Kow): 2.01 (OECD Guideline 107)
(25 °C)
The data refers to the dissociated
form of the substance.
Self ignition: Based on its structural properties the Test type: Spontaneous self-
product is not classified as self- ignition at room-temperature.
igniting.
Substances to avoid:
acids, oxidizing agents, metal
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): 272 - 289 mg/kg
LC50 rat (by inhalation): >1,7 - 5,8 mg/l 6 h (similar to OECD guideline 403)
The vapour was tested.
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: Corrosive. (BASF-Test)
Serious eye damage/irritation: As the product corrodes the skin, it can be expected to have a similar
effect on the eyes also.
Respiratory/Skin sensitization
Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.
Experimental/calculated data:
Page: 10/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Mouse Local Lymph Node Assay (LLNA) mouse: Non-sensitizing. (OECD Guideline 429)
Assessment of mutagenicity:
No mutagenic effect was found in various tests with bacteria and mammalian cell culture. The
substance was not mutagenic in studies with mammals.
Carcinogenicity
Assessment of carcinogenicity:
Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in
animal studies.
Reproductive toxicity
Developmental toxicity
Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies. The results
were determined in a Screening test (OECD 421/422).
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Aspiration hazard
No experimental evidence available for genotoxicity in vitro (Ames test negative). Together with
nitrosating agents (f. i. nitrites, nitrogen oxides) nitrosamines may be formed under certain
conditions. Nitrosamines showed a carcinogenic effect in animal experiment.
Page: 11/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Toxicity to fish:
LC50 (96 h) 31.58 mg/l, Leuciscus idus (DIN 38412 Part 15, static)
Nominal concentration. The product will cause changes in the pH value of the test system. The result
refers to an unneutralized sample. After neutralization, it is no longer toxic.
LC50 (96 h) 28 mg/l, Oncorhynchus mykiss (OECD 203; ISO 7346; 84/449/EEC, C.1, static)
Aquatic invertebrates:
LC50 (48 h) 75 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
The statement of the toxic effect relates to the analytically determined concentration.
Aquatic plants:
EC50 (72 h) > 2.0 mg/l (growth rate), Scenedesmus subspicatus (DIN 38412 Part 9, static)
Nominal concentration.
EC10 (72 h) 0.0784 mg/l (growth rate), Scenedesmus subspicatus (DIN 38412 Part 9, static)
Nominal concentration.
Elimination information:
90 - 100 % DOC reduction (18 d) (OECD 301 A (new version)) (aerobic, activated sludge, domestic,
non-adapted)
Bioaccumulation potential:
Bioconcentration factor: 35.66 (calculated)
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT
(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification
The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone
layer.
Waste key:
07 02 08¤ other still bottoms and reaction residues
Contaminated packaging:
Page: 13/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
Land transport
ADR
UN number UN2264
UN proper shipping name: N,N-DIMETHYLCYCLOHEXYLAMINE
Transport hazard class(es): 8, 3, EHSM
Packing group: II
Environmental hazards: yes
Special precautions for Tunnel code: D/E
user:
RID
UN number UN2264
UN proper shipping name: N,N-DIMETHYLCYCLOHEXYLAMINE
Transport hazard class(es): 8, 3, EHSM
Packing group: II
Environmental hazards: yes
Special precautions for None known
user:
Sea transport
IMDG
UN number: UN 2264
Page: 14/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
UN proper shipping name: N,N-DIMETHYLCYCLOHEXYLAMINE
Transport hazard class(es): 8, 3, EHSM
Packing group: II
Environmental hazards: yes
Marine pollutant: YES
Special precautions for None known
user:
Air transport
IATA/ICAO
UN number: UN 2264
UN proper shipping name: N,N-DIMETHYLCYCLOHEXYLAMINE
Transport hazard class(es): 8, 3
Packing group: II
Environmental hazards: No Mark as dangerous for the environment is needed
Special precautions for None known
user:
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: IBC
Shipment approved: 1
Pollution name: N,N-Dimethylcyclohexylamine
Pollution category: Y
Page: 15/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
Ship Type: 2
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
Assessment of the hazard classes according to UN GHS criteria (most recent version)
Full text of the classifications, including the hazard classes and the hazard statements, if mentioned
in section 2 or 3:
Flam. Liq. Flammable liquids
Acute Tox. Acute toxicity
Eye Dam./Irrit. Serious eye damage/eye irritation
Skin Corr./Irrit. Skin corrosion/irritation
Aquatic Chronic Hazardous to the aquatic environment - chronic
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H411 Toxic to aquatic life with long lasting effects.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
Page: 16/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 18.12.2015 Version: 7.0
Product: Additive EX 93008
(ID no. 30575957/SDS_GEN_EU/EN)
Date of print 19.12.2015
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.