ZIMBABWE SCHOOL EXAMINATIONS COUNCIL General Certificate of Education Advanced Level CHEMISTRY 9189/3 PAPER 3. Multiple Choice NOV! MBER 2010 SESSION 1 hour Additional materials: Data Booklet Mathematical tables and/or calculator Multiple Choice answer sheet Soft clean eraser Soft pencil (type B or HB is recommended) TIME 1 hour INSTRUCTIONS TO CANDIDATES Do not open this booklet until you are told to do so. Write your name, Centre number and candidate number on the answer sheet in the spaces provided unless this has already been done for you. ‘There are forty questions in this paper. Answer all questions. For each question, there are four possible answers, A, B, Cand D. Choose the one you consider correct and record your choice in soft peneil on the separate answer sheet, Read very carefully the instructions on the answer sheet. INFORMATION FOR CANDIDATES Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. This question paper consists of 16 printed pages. Copyright: Zimbabwe School Examinations Council, N2010, ‘SzIMsECN2010 [Turn over NSection A For each question there are four possible answers, A, B, C and D. Choose the one you consider to be correct. i A sample of chlorine containing the isotopes of mass numbers 35 and 37 was analysed in a mass spectrometer. How many peaks corresponding to C/.” were recorded? yar pune Which configuration represents an element that forms a simple ion with a charge ~3? A 1s? 2s? 2p® 3s? 3p! B 1s? 2s? 2p® 3s? 3p% 3d’ 45° Cc 1s? 2s? 2p* 3s? 3p? D 1s? 2s? 2p® 3s? 3p® 3d? 4s* Which ion has the smallest ionic radius? AF B Na’ Cc Mg* Dea Ina pathology laboratory, a sample of urine containing 0.120 g of urea, NHyCONH> (M; = 60), was reacted with an excess of nitrous acid. The urea reacted according to the following equation. NH,CONHeaq) + 2HNOx9) > CO) + 2Nae) + 34200 COs produced was removed by passing through aqueous sodium hydroxide and the final volume was measured. What was the final volume of No at rp? 9.600 cm> 96.00 cm? 14.40 em? 144.0 cm’ vaomD 9189/3 N2010 dj5 pv 3 Which of the following curves shows the correct graph of pV’ against P for a fixed mass of an ideal gas at constant temperature, A B Cc D BY pv pv P P P P The standard enthalpy change of formation of CO and HzO are -394 kJ/mol and -286 kJ/mol respectively. Ifthe standard enthalpy change of combustion of propyne, CsHs, is -1938 kI/mol, what is its standard enthalpy change of formation? A -+184kI/mol Bo -184 ki/mol C +1258 ki/mol D ~1 258 ki/mol Which equation does the enthalpy change represent the lattice energy of sodium iodide? Nay) + A B Na; @- 5 D = NO and COs (initially containing 3 moles of NO and 0.8 moles of CO;) a s according to the equation below. T= NOx) + CO) At equilibrium 0.1 temperature of this e les of CO2 was present. What is the equilibrium constant, K., at the ment? A 0.21 B 0.50 c 5.00 D213 91893 n2010 [Turn over4 The ionic product of water, Ky, is 1.0 x 10" mol’/dm®, What is the pH of a solution of 0.002 mol/dm’ sodium hydroxide? Ae od B 10.7 c 13 D123 In an acid-base titration a 0.10 mol/dm’ solution of a base is added to 25 em? of a 0.10 mol/dm’ solution of an acid. The pH value of the solution is plotted against the volume, V, of base added as shown in the diagram. pH 10 20«300~=C 4050 Viem? This diagram represents a titration between A aq, and NHy(q) B sg and KOHag). C —HCliag) and NH) D —-HCla3, and KOHag, Tron tablets, which contain iron (II) sulphate, supplement the diet. Which reagent could be used to determine the percentage of iron in the tablets by titration? ethanedioic acid iodine in potassium iodide potassium manganate sodium thiosulphate vamp 1891s Na0105 12 Whatis the standard e.m-f. of a cell shown in the diagram. = platinum brid : ees 1.0 M Fe""(aq) 1.0 M Fe™ (aq) 1.0 M Sui Standard electrode potentials Fe /Fe ~ 0.44 V; Fe" /Fe - Fe™/Fe™* + 0.77 V; 0.91 V 0.09 V 031V 0.63 V came sige 2010 [Turn over13, 14 16 6 ‘The circuit shown in the diagram was set up. switch cathode of platinum anode of brass (copper and zinc alloy) dilute sulphuric acid Which description for each electrode is correct on closing the switch? anode electrode cathode electrode A copper dissolves copper precipitates B copper and zine dissolves hydrogen evolves C zine and copper dissolves copper precipitates D zinc dissolves hydrogen evolves If the reaction A + B > C +D is described as zero order with respect to A, it means that Aisa catalyst in this reaction, the concentration of A does not change during the rea the rate of reaction is proportional to concentration of B. the rate of reaction is independent of the concentration of A tion, wae X, Y and Z are elements in the same period of the Periodic Table. The oxide of X is amphoteric, the oxide of Y is basic and the oxide of Z is acidic. What is the order of increasing atomic number for these elements? Ae eee: B XYZ Cc XZY D ZxXY Ionisation energy generally increases across a period due to effective increase in nuclear charge. increase in atomic size. increase in electronegativity. increase in ionic radii. eawD> 91898 N20107 18 19 20 7 Which property increases on descending group (IV) of the periodic table? vowp acidic character of oxides stability of oxidation state +2 melting points of the elements covalent character of the chlorides Which compound would give a mixture of coloured products on warming with concentrated sulphuric acid? yam sodium bromide sodium sulphide sodium chloride sodium ethanedioate Why is hydrogen iodide a stronger acid than hydrogen chloride? A Which halide is a volatile liquid and is csowP The molecule of hydrogen chloride is more polar than the molecule of hydrogen \dide. covalent bond in the hy< chloride. ‘The enthalpy change of formation of hydrogen iodide is greater than that of hydrogen chloride. The dissociation of hydrogen chloride is suppressed by hydrogen bonding. n iodide molecule is weaker than that of hydrogen hydrolysed by water? AIC, CCly SiCl, PCls 1993x2010 [Turn over21 22 8 Which reaction represents electrophilic addition? NO, pe Ot mo 6) sno BCH, = CH, +H,S0, +CH,CH,0S0,H A CH,COCH, + HCN —*—>CH,C(OH)CN NO. HL, © Fe, Conc HCI © fe Conc HCl Cortisone is a steroid in essential drugs HC ‘OH oO How many chiral centres are present in cortisone. caeD> waa 9189/3 N20109 23 What are the products of the oxidative cleavage of the alkene shown below? CH CH= C(CH.) 2 2 OH OOH B > CH,CH,COOH CH COOH Q Q > CH>C-CH, ° CCH, Q CH,CH,COOH sape 2010 [Tarn over10 24 Which of the following is not a product of the hydrolysis of the amide below? on I C—N—CH>CH. 23 18973 N2010ry 25 Whatis the correct reaction mechanism for the addition of Bry to an alkene? ve Nr c Br —SBr ——> Bry A F Vr A EN 7 Mv Ba OoY™ —B; —+ ry c << aA AK no vy Ms c & pr Si, > opr | mae A kK ‘é Mv Me ie CS — - i Br * By A eX Br- isp 2010 [Turn over12 26 A reaction sequence is shown below. Cl,/uy light Cone NH. Open, Siete oo high pressure What would be the product ¥? CHC! canny A oO 2 B NH, ono: oO” c D cH, cl 3 27 Deduce the order of hydrolysis of each of the compounds below starting with the readily hydrolysed. oO f SHC, CHCH ‘CHCHCI » 8 @ ‘cr x Y Z A X > Y > g B x > z > Y c Y¥ > Zz > x DZ»> ¥ > x 28 Which isomerism is not typical of pentanol? A positional B chain C geometric D optical 29 Which polymer is not a co-polymer? A nylon B nylon 6.6 C nylon 6.10 D terylene 9189/3 N2010 y d13 The alcohol, 2-phenylethanol, has the structure shown below. H H 1 I ©-6~é-on I 1 H H Which statement is true about this compound? A It undergoes nucleophilic addition with HCN in the presence of a base. B It can exhibit chain isomerism, C __ Itreacts with hot aluminium oxide, D _Itdecolourises aqueous bromine. s1g9n 2010 [Turn over14 Section B For each of the questions in this section, one or more of the three numbered statements I to 3 may be correct. Decide whether each of the statements is or is not correct. (You may find it helpful to put a tick against the statement(s) which you consider to be correct) The responses A to D should be selected on the basis of A B Cc D 1,2and3| Iand2 | 2and3 | only are only are | onlyare | is correct | correct | correct | correct No other combination of statements is used as a correct + 31 32 33 nse, ‘The standard potential for the electrode reaction repres nted by the equation Pb'"'aq) + 2e° == Pb?*faq) is +1.69 V ‘What may be deduced from this information alone? Lead (IV) compounds can act as oxidising agent. 2, Lead is more stable in the +2 than in the +4. 3. Pb(SO,)z does not exist. Which statement s) about the reaction Oia) + 2g + Hy + OCL,,, SICK, + 3H,0,, are correct? 1. The oxidation number of the iodine in the iodate ion 105 (49, changes from +5 to -H1. . The oxidation number of chlorine changes from —1 to -2. The oxidation number of iodine in the I;,, changes from ~1 to +2. The activation energy of a reaction is usually 1, different from the forward and backward reactions in an exothermic process, 2. low for a reaction that takes place slowly. 3. unaffected by the presence of a catalyst. 918918 N201034 35 36 37 15 Which statement(s) about the oxides SiOz, PyOjo, SQ2 and C120; are true? 1. They are all covalent oxides. They are all acidic, 3. SiOz is the only one of the four having a giant lattice, Which oxide(s) react(s) with both potassium hydroxide and dilute sulphuric acid? 1 lead (IV) oxide 2 lead (I) oxide 3 silicon (IV) oxide statement is correct about group (VII) elements? 1, Their aqueous halide ions form precipitates with aqueous silver nitrate which dissolve in aqueous ammonia, 2. Their oxidising power decreases down the group. Volatility decreases down the group The compound below is useful in organic synthesis. on 9 CKO Which reagent(s) does it react with? 1. CHsCOC in the presence of a base 2. aqueous bromine 3. aqueous sodium hydroxide susp 2010 [Turn over16 38 Vanilla and carvone are common flavours in food products. WA a oO CH. Zo ‘OCH, Cc. oH? Hc Nou vanilla carvone What is common about these flavours? 1. They give a positive result with Tollen’s reagent, 2. They react with aqueous bromine. They react with 2,4-DNPH but not concentrated potassium permanganate. 39 Which properties are shown by x- amino acids? 1, have high melting points and solubility in water 2. capable of rotating plane polarised ! 3. can act as buffers in aqueous solution 40 Anorganic compound has two functional group isomers shown below OH H H OH I I | 1 O-é-6-» — ©pe-é-0 1 | 1 ' a ae Which reagent(s) can be used to distinguish them? 1. aqueous alkaline iodine 2. hot acidified potassium dichromate 3, Tollens’ reagent 9189/3 N2010