ORGANIC REAGENTS S.No. | Reagent Function 1 PCh, PBrs, Pls Alcohols into Alkyl halides 2 [SoCh, PCls Alcohols into Alkyl chlorides & _ Carboxylic acids into Acid Chlorides 3 | AC/ZnC, HBr. AI Alcohols into alkyl halides 4 | Ch/Fe or FeCl Cl group substituting on Benzene S___ | NaNO; /HCI_0-5°C Diazotisation 6 | CuCl,CuBr,CuCN,KI,H20, | Diazonium Cholride into Chlor Benzene, HPO; Bromo Benzene, Benzo nitrile, lodo Benzene , Phenol,Benzene respectivel, 7___ | HBF, or NaBFy Diazonium Chloride into Floro Benzene 8 Agr or HgxF) or SbF; or _ | Alkyl halides into alkyl florides k ‘OF 2 9 Na/ dry ether Alkyl halides into alkanes _ 10 | NaOH 623/4437368K. Chloro benzene to phenol | Br /FeBr3 Bromination of Benzene 12 | Chy/FeCly Chlorination of Benzene 13 | CH;CI/AICIs alkylation of benzene and its derivatives 14 [CH-CO-CI/AICh ‘Acylation on benzene 15 [H,SO,/HNO; ‘| Nitration of benzene 16 | (CHCO),0 /AICI, Q * Acylation of Ph 17 | H,SO4 Sulphonation on Benzene 18 | H,0/ HO, alkenes into alcohols ‘Aq KOH Alkyl halide into alcohol 19 | BH3/H202/0H" Alkenes into alcohols (Anti Markownikoff product) 20 |NaBH,/LiAIH,(LAH) __| Aldehydes, ketones, acids into alcohols, a Nito & Cynides , Isocyanides into amines | 21 or H,/Pd reduction of aldehydes, ketones and cynides 22__| RMgXx/H,0" Aldehydes, ketones into alcohls 23 | O/H" ‘Cumene to phenol 24 ~|Na Alcohol or phenol into Sodium alkoxide/Phenoxide "25 |(CHCO),0/CH-CO-CI__| 0 acylation on phenol or N acylation on Aneline or amine [26 | Cone.HS0/443K Conversion of primary alcohols into pe ee | alles = | 27__| Cone.H2S0,/410K Conversion of alcohols into Ethers 28 | 85% HPOs/ 440K Secondary alcohol into alkene 29 | 20% HsPOs/358K Tertiary alcohol into alkene Alcoholic KOH Alkyl! halide into alkeneORGANIC REAGENTS 30 | CrO/KMnO, or KzCr,07 | oxidation of alcohols into acids in acidic medium 31 | CuS73k dehydrogenation of alcohols gives 1” alcohols into aldehydes and 2” alcohols into ketones & 3° alcohos into alkenes 32___ | Dil. HNO; Mono nitration of Phenol 33__ | Conc.HNOs tri nitration of phenol 34 | Bry/H;0 tri bromination of phenol 35__ | Bry/Csy mono bromination of phenol 36 | NaOH /CO2 Phenol to salicilic acid 37__ | CHCI,/NaOH Phenol to salcilaldehyde [38 [Zndut [Phenol to Benzene z= 39 | NaxCr,0;/H,SOs or air | Phenol to Benzo quinone 40 | Zn/Cr03 200t0 300 atm | CO & H into methanol 573 ~ 673K. 41__ [invertase Sucrose into Glucose or Fructose 42___ | Zymase Glucose or Fructose into ethanol 43 [HI Ether into alcohol & alkyl halide 44__|PCC alcohol to aldehyde 45__| Pd /BaSO,.H2 [acid chloride into aldehyde 46 | SnCl,/HCV/H;0° Cyanides into aldehydes _ 47__ | AIH(-Bu))/H,0 Cyanides into aldehydes 48_| DIBAL-H/H:0 Esters into aldehydes 49 | CrO2Cl:/H20 Toluene to aldehyde 50__ | CrO;/(CH3CO);0 Toluene into Benzaldchyde St | Ch/hv Chlorination on alkyl group of Benzene or he 52__ | CO, HCl anhydrous AICI;_| Benzene to Benzaldchyde 53__|(CH3)2Cd acid chloride into ketones 54 __| RMgX/H,0™ Cyanides into ketones 55__|HCN Carbonyl compound into cyanohydrin 56 | NaHSOs addition to aldchyde and ketone 57__ | H3NOH carbonyl compound into oxime carbonyl compound into hydrazone _ carbonyl compound into Phenyl hydrazone carbonyl compound into 2,4 dinitro phynyl hydrazone 61___ | H2N-NH-CO-CHs carbonyl compound into semi carbazide 62 [| ROH/HCI Aldehydes & ketones into hemiacetal and acetal 63 | HO-CH,-CH2-OH/HCI__| Aldehyde or ketone into ethelene glycolORGANIC REAGENTS ketone 64 | Zn-Hg/HCl carbonyl compound into alkane 65 | H:N-NH/KOH | carbonyl compound into alkane 66 | KMnO/OH7 K3Cr,0; Ketones into mixture of carboxylic acids /HySO, or HNO3 on prolonged oxidation 67_|(Ag(NH)),)NOs+NaOH | Tollen’s test 68 | Cu(OH); Fehiling’s test 69 [NaOH+h Todoform 70 | NaOH or Ba(OH): aldal condensation 71___| Conc KOH or NaOH Cannizaro’s reaction [72 | KMnO, /KOH Toluene/alkyl Benzene into Benzoic Acid 73 | HO" Cyanides into carboxylic acids, amides into carboxylic acids, esters into carboxylic acis and alcohols, acid chlorides or anhydrides into carboxylic acids 74 |NaOH Saponificaiton of ester, acid into salt of acid (75 ['NasCO; or NaHCO; Carboxylic acid test (76 POio or P20s Dehydration of acids into anhydride, amides into nitriles [77__|ROH/concH,SO; ___| Caroxylic acids into esters 78 | PCI, SoCh, PCls ‘boxylic acids into acid chlorides CHCO):0 (79 | NH; heating boxylic acids into amides [80 | NaOH/CaO A xylation (acids into alkanes) jst | LiAlHy xylic acids into alcohols, amides into amines 82__[Chied Ps HVZ reaction 83 _ | Sn/HCl or Fe /HCI, Hi/Pd | Reduction of nitro compounds into amines 84_[ NH; Alkyl halides into amines = | 85__| H2/ Ni or H2/Pd LiAIHy __| Amides into cyanindes 86__| KOH/R-X Phthalamide into amine 87__| NaOH /Brz Hoffman bromamide, amide into amine with one :C “less 88 | KOH,CHCh ‘Amines into Carbyl amines [89 | NaNO,/HCI 1” aliphatic amines into alcohols [90 |NaNOJHCI_075°C___| Aniline into diavonium chloride [91 | CuHsSO.Cl Distinguishing 1°,2° & 3° amines 92 | Bry/H30 Aneline into tri bromo aniline 93 | Bry/ CH-CO-CI Aniline into Bromo Aniline