Sisal AGS Coordinate Compounds “Double galt “Complex galt * Double salt Combination of Mise oy pinre Cie Ue compounds Ww stetehiomtiric rao Hat discoviate into simple tons: as ex: incaraghe = cane a Mebr's sales Fesoy(NHS0, -bIhO Sf 1.9% 1 4 | | | TYPES OF SaLT | | | | | Potash aulumn <> KAla (501). oty0 Gom plex Combination of [EOISMAC None Tecisipabe, by w ordinate b ‘ § end . |t retains their tert ty while dissociating. ka Cr H20 ie é aC eceNe] >ok* Tee Con}, ]! ex: COORDINATE ComPauND eel! oes eels eats ae a eaoeeue oa gtoup ef anions or heutyal molewles by coordination bend Alfred werner > father of coordination chemistry / COU - NH 7 Yellow AgNO3 + Bmol of Agds| pokes Medes Rar plea NOME In ean ete AGC coc i (mitt Coll .4NH> > green Agios} | r Col“ 4NHB > Vist panog | "2! oF S8ClL Coc, (wie), Jee J + 1 mol oF Ag Cy) (oc Postulates of werner's Freovy eal ntr ce . . oor dina Hon WMpound,a metal ion Shows 2 types of Wnkog es oy’ vale. ves % prov \ F $200 OAy + Prim ony valency + Roondary yalenay % 1k is lonis able % Ib is non-ionisable % le is satished by onions % Ie iS Satisfied by anions, neutral molecules oy Iigands ¥ \t is non-divechona) * 1b is divechonag % Equal to oxidation number of ~* Equal to coordination contral atom number—— Hlon be wrdideed a> secondary | 2 Cannot pe conSideregy as | ra Faneney primary valency ural wit is in volved in struc ACHAIStIC spate BARA ngermé nt) | | | stnenevral structures | peahedras, tetrahedrt , H qrigonal bipyramidal Ls | on te basis of Sllewing observations | valendes in No jnvolmenk in struct erento rs arrangement ATYang n aquare planet, square pyramidal, made wile aqueous tee metals in solu tons assigned secondary Yet Pollo Wing compounds: | formula motes of AG preipieares om mole 1 of te vom pe unds with excess AgNb3 iD) PaCls ANH . | ) Nice, -/QH30 a il) phetg!2H ol . | iv) Coclg-4NH3 | aypeci,/2NHs : 1B 4 | ii) G ii) 6 } iv) 6 w)4 Gosic sepa of ordination compounds | ‘Coordination entity | stooydination sphere | « counter ion | » Central metal atom (oma) |. oxidation pumber of contyak metal atom | e Ligand , a Coordination numbey ce . aORES Ge rai gatas | ae k p PRR) 5, Er I | | Counter re | Ligand Coordination | di lon numbey | | | | | ™ | Coordination entity Constitutes a moto atom Lohi ich is of Fixed number of eter ex: Felon), “tbe ler dination Sphere Gonstitutes a metal atom whied 18) Boul aee gem of Sxed Been OE (ots mw. , or molecule) gands en Wa Sour! Latkes along wit charges | re Com), ] aa Counter ion The jonisable part Bmesent, ott side | teva eames brackel Exe: foe [ reer), 1] Centra} metal atom J An atom or molecule which js bound to number ops atoms or molecules inside the satare bracket le vois acid (electin acceptor)ee “ug eres : oe “ (Te eS nm atom or group of atoms voliel is directly! attaches He central peta! ator. je iS a Wwis base ( electro, lee? , | | _9 pnioni& ligands x tx: on | > cotionic¢ ligands ex: no* | = Neutral WgandsS Ex: 2°, NH3, | spgands can be Simple atom of molecules Peaster + small yo lecules } ex! ,0,NH3 “Lange no eeu les / mache molecules en- Ethans-|,2-diamin® ee EDTA -EteyleneDiamine Tetrahcetate — pce CHa-N z | ™ m42000 EA CH oO ™~ at, 007 tassification of liganBs on te basis of denticity Denhity- No. f atoms | groups /¢ tes which bound to we control metal atom cHa Ligands I Gwonedentate (or)Unidentate ligand [svidentote ligand | + folydentate ligand * Ambidentate sigan || Monodentate Dec's i ligand bound too metal jon through a. Single donor atem | or site ! : | |og a / Didendate i). le ; ound 49 2 wetal ; : Poaligandsa23t "heehee of Sites z Shy (2x3 ree hoe eo, 2 | Cte Nita Coa alate ae + Poly dendate A ligand bound 45 a metal jon throug h more Hop 2 dont. atom OY SHES Ai — CH, too07 cea aw = CH, Coo7 Ba Ena Coo T cae ct, coo + Ambidentate A ligand which has two differenl dover atoms op Sites buk can ligate through onty | donor atom oy Site ex: p-cN R-NC Chelate Ligand Diden date oy polydendate ligand 4SeS IES, 2 ey, more Bevcy Bivins oy sits = bing (a Single metal joy oud any form a hg -like Shucture. Such Structured ligand is alled a che late Wigant and tte Process is called chola tios 'Jand doney atoms HO spo tee 1, vee contra metal fon js directly boundeg k4Crelen), 7 ROOM nada so. Boe eecae > een | 39 aiongt ‘ + thadlane| Shared with ie. oxidation number 2trenuormay wait Amie ou? 30 33 Blo) =42 ata © hs tH ap anion lon TMT won anny oa ode the charge whieh oF CET unied by, tee contin metal eae JP all tre Eee art remove bith Hw elechron pairs | . | Kislgowiawel pokes gt des GuAl coast ton poly hedren Tht spatial arrangement of Hr» ligand bee aida Cie windan te Ye central metal atom ov ion fy L ie iL E fe ie as L Moss) ia Pe 7 le MS sg pn Welle oa ms a ~. or 1 rg NI our Dea galiat ee Susie , TyPs oF complexes eset iL sort Saarg Bipyramidad VP Paimidal + On the basis of charge ce ct 2 Ghonic Raapexc Lb] ex: E cotnes),]* ci AL Fe Cen), 7 cx. CN cco, )] n +he basis of king ce complex [7 entra | complex: : of ligand = Homoloptie ex: | 4 Came, Kgand) [Fecew,] \> Hetewle phic | Gaifferent ligands’ GN) CNHs), C1] is Sim ple, | | PF Name as it is Pee anion is tomple x =o ZNOME Loand teen metal*nNoming metals stepliv): 1 different ligands > Fellow alphoaberical ligand te metal ? order step (v) : How +° name + No-minhg ligands gand is ction, Name’ lercus tats gtep Cid + 10 Ut ter Cid: if igand ig anion eemcve ©; add ‘o' guiphate > hay oxide —> by | sep (ii): 1p ligand is neutral, H,0 > ODA INGEN => omming en OL 12 co > bong No 7 Nitrosy® -hiammine stepliv):1@ Re ligand is Simple, Mulfple some Wands multple samo ligands Liasge ) + Use pet Step (vu) 10 He Uigand is am bidentate , ~menton the site : Nityito — : witrite - © M<—Noo nN M< eNO Cationic complex | [metals _ | chaoui (64) a EES) Shee otis | | perkabe copper co pperloupram) tng takes Gold (Awe) ovate gir CAg) Silver (Avgentinm) Lig si ie y Platina (Pe) Plano | P lahnate , pluminiwm (AD) Aluminium | Pierce Co loot (Co) Co bal & Cobaltare i Lead Crh? Lead ( Plambum) alun eates pe MOON Cg) | Maer erry (ttydaagyram) | Bydrag ytate ave present). [ \ tuPAL xulest 1 Une partrxes ae Buiowic co mplex cutlp bate daox ide etra, et. rts , bis, tris 5 4etrakis e+e:F Naming some complexes ) ka bre Cem] ed Be we Re [recone | omdaton state tee CCl) = -4 | | pug = = 4 wea meth Poko rtivum, he xacyanidlo ferroateCat) | y CeoCN¥ad, | cl 1 ot | [eo CNHs | Ce oudaton state * +b(o0) = +3 eS h2X22mminece ba It (HL) ertade ce ine laa) cy eee Cn Ht, oxidation state ee pe ASX aie m= +39 Te+raamh ingdiichlorido Ve Cin) cdxtori de. | W) Kala Cerou)s] Boniese,),] oxidaton state 4 2032 3 x =4 Baio) | me as i Potassium tri oxalate cr omote Cll’) ee iSlou, 2 Ce oe = | n) an cf : spi | oni dation i | Mey tee Ga | | A+2(-V) en 2, [coe Cenred | a — rh Hand | | | ae chlor ia a isfettane - yes nin ener ee ek grample an 3" a write the ie (OPAC names of Hw following ja) Crt (nis), aNcubeoy |”? ks ce (CoOL sa ee Later | J [ee Ua Cendaler 3 d) [co CNHK3)5 ceoennce &) Ho ECoesend4] Hy! bt (sen 4 J ina an | Ir) dia mminn cag dasmme ) potassium triex ala tocdt omate (tl) etrone “1, - diam ming ) cobalt Cen) deride 9 dlichtovi de bis ( d) eee yee nae coloalt (1) Ualori de, @) mores oltate Cul) : Intext prestion t Ge ; ) [oot H3)e 4 petra teiveyanidon ev \ I3 J skeciep #28 J Ks” CeCe 043) cobalt (ui) chloride a Cnt) chloride| ae [oUy ay, Fi &, a ee |X? ks Ucr(c20, Deel Ks f [ i ory ] J (o> An Lenser 8) [eo Cntts 5 Ceo] @ e) eg EC. csend4] Hy” Lu mi dor 4 0 OM Mm bey [totea lene Q | eHAC-1) £0 =1 1 | 2 ) e223 du chlovicle bi bislethane 1,2- pa ree Alovi dy ‘omple 4.3 te th wri © IUPAC names of dre following a) [rec a) C NH3)2 ee (Nos) J | | csen ye J 4 a) diommine Pre ori abate lean (1) b) Pe fassiumtriexk alatecht omate cu) U) click tori de bis (etfone -1,2 -diam ming ) cobalt Ce) lor ide 4) pentacmmine eahloonot® cobalt (iy) erlori de, 2) MoreuArg fetra Hrineganida, ania cu) ni | Intext question GR i») Teo(nHs), J 13 | lit | | |] ii) Ky Lpe Cone iv) Kg LFe (enon ad | Pe eC, Ode) ye stiy) #23 , | v) Ka Ces dad eee Vy) LPetnHa)2 cwecHa) Je Wirexaammine cebadk Cui)chleride ti) Pentaammi he chloride Cobalt Cit) blorideee SS ae — Darncgonido fevrate (nt) iii) Potass: | : tos sin drionatatotervate Cu) | Iv) Po! sam tetra ch Lar idopa ada te C)1) SIU) V) Pokas % : Vi) gmrmnionnelorddelva® tag armine) platinuany( 1) Clstor ide ed write the formulas fey the following coordinator omPoungy )Tetranmmintagua ehlovido olalt Lill) Bloride &)potassiwm tetra bydrenido tincate C1) 0) Potassium tri oxalate aluminate (II!) (dy didhlovide bis(eHane-/,2-diammine ) cobalt Civ) €) Tetra Arbony! nickel (0) &) [& (nk, C0) cr] cry b) kL en CoH), | 9 ks0Al (e204) 4] 4) [toe Cen), |" e) [Ni (0), ] Write +e formulas ») Tetraoming liogua, Cobalt Citi) chloride U1) Potassium tetra Cyanide rickelate () 1) Trasc Ctrane-t,2- ob ) Bremiumn MN) bteride iv) Ammine bromide Ko ,; olbuchrnoS N= b latnate Gu) Vv) pi ‘ ‘ \ )viebLovi do bis ( "E-1)2-diamminey platinum ( ! ty) nite |!) Drom (111) he anido Fervate( tr) eo) BUNH3)4 (Hs0), J Us b) Ky Den), ] c | talen), J 4) ret. ee CL) (NO s)7a [ectts)len), J (woz). 4) Fe [Fe CN] : ee Jsomerism in Coordination wm pounds | ISOMERISM ee Structural Isomerism i | ae ree itie y | eee ey me ae eh Gmisation Mad vate Linkoge Ceotelination (ne ormo-trical ore “TeoreriSm (or) solvate Tyomerism Ts pmuayiSmn a Stereo Tsomerisim i ruttuyoal Lsomevism | in deeiy Structural | Same molecular formula bub differ aYrangement of atom Eeniaahon \sovmevism lsomerism arises when counter ion in a tomplex fom pound ds more potential and an displa@ & ligand | jmake jt ag vwounter jon i Ex: Leo(ntts e+ S04) Br > [Co(NHade Br] S04 f “Hydvate of soluate isomerism IsonmeriSm arises when there is chan ge in es moleeules attached to notal atom (directly attached j to metal or present as woun ter jon) | ex! ere 20), Jes Ce ci] Cla: #20 0 Low, Ale || Hote: Applicable only wher Hr0 ts present i ises due to + presente of ambidentate ) ee in wha two donor SiteS can pound + Hw entree meted oto Ext [o,(NH9T 2 ——» [eo(wus)onoJus NOz yellow wlousx Red» colevrpee mevis™ : 4 toodinate 18° 5 From He inter CRAG aie 36 9 4 / ise Igorabrism ayl Pe i, 4nd, er ea Ca iak) cue Rated ik4pheres ) “he al eer ecu ere o com plexes be ext [eoten >.) [er cwts ), J > [eo Ws). ] [er tadgy # Stereo Isomerismm | Same molecular formula but different Structuy | op. or womPounds * Geometrical Isomerism lanay complexes meen.” ne PoRMULA [Somers I, | Ma, bz | Co CvH3), C1, i | : | cL i | | | ; | | | t rf tre Ma, be | Wo CNH3 DCI. By oo me 1 rah “py . } ¢ a } C | onoc bi: fe { | | Mabed [Co Ws) ee Br(i,0) ere ae NH [| | | | Nore: ‘i iS €! Tetrahedra| Structure does not show geonwt, mc omericm beause of tte {relative Position oP unidentate (Tiga mols atta chad to Hk entrad metal eer Same wr ae vespect tf cach ok hoy, yif Masba Si zotahedrol complexes | to (nr), cs + Optiwl Ieomervis™ or ' NH3 # wes | ee a nig | ir Nig Us NHS \ a Ce i | nila E and) Nee, AN | NH nie jeeps ae i 1 LeemeRs De a. on \\ ik JH, 4. | * ; te Nie ge A 12. eos | 2 Zop (6 Hs pitty 2 jsome i Atta } r IM oF wt aa F to bi ae! an| book back questions ee i) Tetra hydroxide zinate (1) | Len cong iD) potassium telmehler idopalladate (),) eahed too, 7% | 1 oiaramine deel tori do platinum (1) [Pt Cnis), cea ] IV) Potassium tetracyanidonicn elate (I!) ka LN Cen), | Y) Rentaammine nitro “0 halt Cu) at [ CNH3)¢.0N0 | Vi) Hex camming cobolt(i) sulphate [/c> tnes),], 604), 1) potassium triCovalato) chromate i) k, [o(a0), J Vil) tena ammine plabiwun Civ) pea [ Pecnits 2, ] ix) Tebabromidecuprate Ll!) ate eal X) Pentaomnmuneyctrite +N - cobalt Cul) Hesaom minecobalt (111) chloride. ) [Pe(wns), Ce (wis. cH3 d] ce Jiarrmine chloride (metrylamine ) platinum (u) cAkss ide[nr (20). 3+ enibyoos 4 ure AL aay Aas Hercaqa Htanium (11) V) Leo (NHS) 4 otro) J & Fe Han sininwah order Ne eee lO hires: vy) LMnl4s0), J°* Hexaague mang ansie cn) vi) Lice, J” Tetra chberidowiclelt') | Yi) Potassium tri Coxelato) Che mate (iil) | kK, Ler (ox), ] Vit) Hexaammint cobolt Clit) sulphate ee S2 T, 0,9, _ ix) Exi(nts), Jot.» ] 1 Hexoammine riche CU) chloride >) Leo Cen), ] 3t Tau: S(eane -U,2-damming) colooLt (111) BE) wn (co). J | Ta crbonyt nicket Co) Draws Structures of geometrical isomers [reCnHs), Cen), ]7 cw | intl Are ns Sorryf ; Bi foo wordinatow entites ' r : - out of we folowing ed | unad Loptelly acne) 2 \ 2 ies ' | aur - [orcestox)a] Din ar | by trans -Lorcla Cons } | 2 Ny, Cte = Lotts lox), J iS Chiral os 42% Mirror image S nok super Umposable Be ees ol Leocnerigm ents biked by the Following mom Plexes, a1 4 draw Ht Strictunos for tHwse Somers Dien CHs.0, (er04),] ) Hie, Cen),] Ce, TD) Ceo (nrg De (N02? ] (Nos), "DT Pe(nHa)(H,0) Ble, ') Cometricat ISonerism -Mar(bb), % optiAl iSomarigm ys igomy ix trothsNog NH: NG Ne Gos os ce NI sg dH 2 Linkage iomerism YT Co(N 3 5s (Nor) ] (N02), [ite Cetra Ja (MBL bads Ye >. lowiSa Hon isomerism | i 1] [eo WWH3 l Js Cnor)] (N03), 5 [ (Wits Js (nios )] (NOs cna) |Y) Guometicd isomerism 1 How mang geometrical jsomerS “wor dination entities ? i | NG (¢104)3 ) ea 4 - Zee geometries TGOMAS ‘ ’ Nig es a | =o2, g ions oe possible || i | Four Drawd all the | |!) [eoclzcen),)+\ [TRANS Isom €@ { ‘ es re hag | e { o a) yt} ni el ) te ee a ’ Z sche li) [00 cntts)cecend2 J @ | geese? fy | Oe ee. De oe peatet | AEN | : | ee ee | Ras somet ; x | | + ii) [oo (M322 ceter J | ¢ ae He ote 1} t i : | isom er of [ PE cna veerrerer] : gical i een: : write all Hae geome ox spit opeical isomers ose willl Fond Wow 4 ciBonds in coatination om pouncls eno of wernek's theory fed tp explain bonding. In Coorde nation Compound a eles to explain divectonal pwperties of bonds ty werdination compounds ~Patled te explain the reason for only a feu metal eg | form coordination compounds - Unable +o Justey * wlour x magnetic properties * optical properties ‘Valence Bond Theory “Crystal Frey foeer * Ligang Fretd Theory *Meleculay Orbital theory VALENCE Bond TH EORY | the ligand should howe elections Lilled oma) old make availaLiu " Hoands donate electron pos +o central metal atom eo coordinate ¢ovatent. Si9MA,(7-) bend. “Metal atom of in ies orbike| ty of vacant orbitalg vate ov bite Sunde 40 form hy brid orbita After ny bridiSatio TAEeS hy ridisochien | \ ¥ pe Babplog of 90nd orbitals " £ Contral metal atom +o form! * Thner orbital lo ws SpindSpin paired complex: If 2 inner d-oerbital (haya) Inevives in hug by jdittte) and forms a complex , that complex js called own inne orb ite | complex, In such a osmpler all tie elections wv Porved sore fore it iS called gpin pares compiler. Hybridisation: d*sp3- Ouker cetod te sade spn ee unpaired Lorn pie et 1 tee outer, Jepyeieas Gd) 0 ee eeu hybridisation, ond Porms & complex , aot complex is called cn Cuter Pe iow In such o& Lomp lex, all the electrons Ar UNnpaired Pe coore it is tlled spin un polred worn plex. | Kybrtdis ation : sp °d | NOTE: Strong ligand => pairing Linney orbital) weak "gand => unpairing (outer oxbital ) ovealapping << strengir of bond skreng tt of ara Pane CONS CC 82 F “Zon eo roe KO NES < at Cums Len en” € Co gredittion of Hybridisation, meometry ,Nature and +y pe of complex _ sing veT COORDINATION NUMBER HY BRIDISATON MEoMETRY F op? Tetra hadval ds p> Syrote Planar _ ge sped Trigonol Bi pyramidal x sp3d~ Oetahedrel ee A*sip® ortahedral /) CNiCwr4 J Ni > js? 252 2p6 3573p 4s? ad? as umber sok Ni : w+ 4(e)<0 7 {0} oxidatio outermost orbital sta ‘ i => faa te | oF Ni : oat 3a Dui bridisatony: ] ing by b vidt Sa4¢on : Fufae[aufwia) | | Pei | | ad 45e? hybrid orbitals \eee ot ne iy of es Nick -. don ting e pair | to e} 5 1s gach o-Grouh 2 Hybridisation - SP StruckuAt Te trahedral Na trr : Dimag rede Type of complex: Inner oxbitod DEN Ca) | ; Sue | at LavJ adF4s | puidahon numba of Nit x+UC-1)-8 me ot Dweed a Nj eS) ade Outermost orbitol > Ue of nitt Dwaing ky bridisetion : No paring Ligand 1s Weak) Hybridisation : Sipe Structure ; Tetrabedral Nature: tanamagnetic Type oF complex : Outer Magnetic momentyr disodion: dsp” Styuchre + SY one plano Nature: Dimag rene Type of complex: Inne? orbital okback exercise aig nature of bending in the following Is Diswss wordination entites pa e ' Fe - LAr] 45> 34° te Bee ean edie | : ; “ouken mest sbi bal Hybrid | Sation + ol’sp3 Structure : ockahed ral Notune | Pimagnettc Type of comple: Inner orbitalTrees | fee fiea ee i 2c fe? Card 3° [mw] 24°48" | oukermed+ a | ch cee" During yb’ Hybridisation: Beedi= Structarr :pctaby dial Notane » Pasameagnet c Type of complex: Outer orb tal ti) fiteCezc,); )> Ea Grr) 34° =) VT of Outerrest orbital opeas | Dureg hybridisation => Whridig ation: sp 34? Strneture: peta he de at Nature > Potamagnetic Type of complex: outey“or bit ied el a co > Barge Cuter most orbital | ora ce oe ih mdisahen =? |1 [a littl fil mH o.oo fav fli cme, Magnetic moment = nCniy > Tsay) °Nzs : | jae {att Ps | Magnes mortnd = Vata | -Jaq a Fale| During Mybridisah ee a a i TT @ ett eee — A yral* i Hy bucdidation: cp >d* Notre : Para rmad nadie a ou com per: owter ov bite mosmeric mement = Jntnra) | é Jau+s) one | [pIMiTATIONS OF VALENCE Bond THEORY — iQ Evkine ly com prised plain tte wolourk e* of assumptions |. Does vot om ibited by coordinator wompounds ‘ sertie een Mie I) Goes not Grrr failed to explain te explain abe lacn to © ptatively explain tee mag are pla ganas(steng wn com nay corm plexes y vee) pouhds frabedral and SH I: fated + ut strength of |i oe tallity of coordinat® CRYSTAL FIELD meory (Splitting theory) * Poiled seo coment Higand) , ch arises dug to elect mele bond 12 pune y ponic whe! Goree attraction petwech them ) and dipoles >LioAND : ane considered aS point (anions Fecleeales) ug ands (rent val 4 sy hon ligand approachis , d-orbitals ‘degen ea “s Peciroyed, wesalid im splitting ef orbitels a £24 > trip y genrrate orbitals i ey ae lacie) | 3 wlly generate orbitals | | 7 aanTE een : seals iS Called estat Feld spig ' : to Tig splitting oe: lene a tt ee eed © Sle Oa | ound wee oe | Cees. energy (crse) : Gece) Sone Daa Sealer lyf | CESEL => Beak Wgond => Stability Y Crystal Field splitting + Octaha drol compler j | | 6 Ligands Suisound HL moteb _clm ockaledial CC, 0 Osan SOUSA eee re | atom & ion : | |" Repulsion is present betwen tee electrons in cM Dand electrons jn Hur ligands “Ligand spprwaches along tHe axis trotfove repulsion | ig more when metal d orbitals, are directed touiurds} the Wgand - { q ~ Repulsion fs USS when d orbital is ooay from feo | ligand 4 ‘ | = Since Satys and di, orbitals presenti metho see eo Ox1S experience more repulsion and will be raised MH enegy (4 set) a . 4 my dua i tie, ores comity buhq, between He on experience lees repulsion aay (tag et) n& will be lowe jw boyoeaaa tery ordre | AO-eergy Spuahow YAO ey AY dye 119 eb— - Splitting of degenerate orbitals dug to the Pree a eo Kgords tn a definite geometry is called ry stat fold spitting 2 cFS depends on ligand Beld and tee charge of 4e0 wntvar metot otom Strafig Wgand field => Splitting (Ae) f => pairing tak ligand field => Splitting (40) | = unpeixi 4 XPILUNG OF ELECTRONS IN D-ORBITALS eo C1 etechon) * 1) Cf | A> Caetectrons) : R] ft] C1! a? (Seleebons) + fy] my th | A*C4 creetwns) : 3 electrons in faq, | €lectron in eq | 4 electrons in £39 2 ia p Gse Gi): ie mimes atte Ht 4H electron occupies eg orbital BUS pals 3 : wnfiguaton : 43 24 i YM4dS tat hane Ao

p, ome called Strng field ligands, [Tetra hedval pomple meted atom and tye elechon, in tre Lgandy Ligand approaches beducen the ais turelre repulsion 5 loss when metal cd orbitals are divecked torords’ — (| -> J pnt | ‘ SS d orbitals [av fat oy —— | [ay] fi 4 3 | ov bideu | mdvee stote | marjal len Colom in Coordination com pounds % presenw of unpaired electrons (Posomagnetic) % weak ligands * High spin complex * Ouke, orbital complex ex: Enero), Jt > a Goliad Sinee water is a weak Gand, Ao is less. IR U'ght is absorbed by Hee Complex It ould excite He electron from tig 40 ey Unel/d-orbitad Effect of lig andSine water is a weak “absorbed by Hu Cmple bs ay fa) Ao is less. (Rtg ht is ould excite te electron| Pees chat Geld epliiieg. does: | J nck take Place Haeecc Vee te eine | | [OM Calo as ee ot ees ONO) aon Crean, Pade lout [Ni Crt se Jen) ee Foe blug i me | gue LNI (0), (en), J + €AH,0 | bly puaple : a+ [™ CHO 2, Cen), J eh [Ni (enya Le ne ble /purple purple ils Leo Lee Mca | 586 / Hela iL - ngt Umitations of Cystad Field Theomy : oR RUnoble to explain s and p. Rbitods * bending is onic (co valent) * pi bond is also possible % negative ligands lanionS) ane weak Bonding in me tol Ar bonyls Donors weak Lig and Stong ligend youl & Near gil Nittegi coo 4 Pro spony Homolep he canbony) witt transihon metals Metal corbony | bohd possesses bolt. Sigm ale) andpi Cry Horactey *M-c o bond => formed log donation of pair of electrons from the toubouyl to He vacant d-orbital to metal atom or joy, peaceM = < Che. Sos a : ae eS atom | how Ss Courlor nag h >> oan by Moahon ob a pauace metok lore Cekryons Poem Hw torbony! oY, tow +o the crbony! 's anti eceetae Synergic bonding K™ pybitad 2 M- C bond a Synergic bond Meroe Atom or Ton and ligand by reverse donation of electrons ist. Soo pi established between a | Hw Mmetol atom or ih +o ligand | Sy NAGQic effece Synecgic bending occus +o increase Stability, The SAbow gets attracted te tao naetal atom , Z Important Metyol Carbony | Structuves | ENE Cal) - Teta cn bonuh Nickal Co) ete U Co Das Penta Cathohye Inen(o) CO ieee Arloongl Uiemitim Co) “ Mno( Co) T Seca crbonyldimangansie L °) 2CCOdg_ Prarcarbonyt dicobat} Co) { F NiCCo), Ni oe PAR CANS : a igo a bipylard dod: abn es | _ Synngic bonding K™ py bitad Gia Roy 9 Ce ae : Metal ae ae *M-c 7 bond cD Pree os Neatowch A. padace rah atom eleckrwons Fem tte carbone] or, tom to tte erbony) $s anti eeneting | ‘ Syrersic bond ts ao pi established between a Metal atom or jon and ligand by reverse donation of electrons from He metag atom or ion to ligand Synegic effect | Synergic bending eccurs to increase stability, Te | CAbow GEtS attracted te tet metal atom i Se Important metral carbony! stuchives : “Ni (Co), ) - Tetra cat bony? Nickel Co) ; a Fe (Co Deepen casbohy! Taso) , d : \ COCO), = tener crloonye Bsomiumio) : Bg eebangdimnng andib sy Can ae Oe Octocarbonul dicobat} ts) > Nico), vo } ' Ni' lo. , E Has a OckoN edad ee tt cs ms 4 Mn (lo) 5 | if co ol fat si) ra Pe | oe 0 nad, SEM OAL ws HL aA | | oe Wo lf: 2 Co | to Co | sta to) lity in coordinaton compounds Associaton of qwo spectesC metal and ligand) is Pripton as stability M4 t ML = ML if es Me ee ML MEY Ll Mes 2a ae st Baws kak, : bee ‘ [McijJeeg oor se Steler lity Condtonts J ‘ kee Emits} a eae | Loe JOry ke UmMLy] eMisJLU} ees Ba ate ae asst ae Proveatt: <5 { bane! sei. Cu?* + Nits 2+ i Leacwits)J ioe emececnuae (Fee 2+ J CNt2) ay 4 Hy — > [eaCnits)) Lp u 2 (eatntayg +N 3——> Eeucnits)s J ae Ceutnits),| | (enn 32] (Na) 2+ Ut Ceutnits>, J Ech sve COMUNE C a ey ee los Coutnitaray” | CeaCnrts Yo CNA] Cen (Nta)s J°F+nH3 > UeuNitg), J] ky = ce Gna) 7 Cults 59 CNH3 4 | fogk. + oaks + Log k3 tlogka > Py BRO SS FF hae mi jae : Be Grete pmount of |: - i wee tS ce fomed, | Instability constant : con Application of weYdinaton com pounds * Anoly he chem istry * Biolegical process * Industrict harm stry %* NeAUnad eI G * anobytical chemistry | euotitotive aunglysis cC to detect tie/metol| ions present in tre Solutew | | | (Cotowr Arachon ) Guanh tafe ovalysis » sestim ates 22 amount of motel lon (aera a | doly Moms EX: EDTA , DMG ( dinattyraty oxime ) “ESH motes «2 AmoUNt of hoard use jr Vater | tt, Mg*t———— Na, EDTAi[piote gio Procens: ae Heemogiebin - Vitamin Bla ~ ee | Mag nut UM Con pend. ae | Enzymes - Corbony peptidase Caro 0 Wie CUNY JAA $e 1 Incastriok importance Wid or a catady st A Rodium vomplax [(Pha Ps Willingen cat aby Ake Heydiegeraction Of | a a | acer | | ; Elecboplahing, | EL chive electroplating witty a sgmooth& nish 1s 1 | performs d by complexes | ex. CAuCcend2 I, Dg Cov J | . Extraction of metals | Ores A onveted into wmpl xs Hen decom posed to elbtarh metals E =e ee Ais Oras, | eas Ne [Pu Cay, J] ——= [2encn),) fe ctate. | Puritication of metady Impure cee Ge) ae? (Ni Cw 4 Z Ne form Ni d Wrins, comp les makes tHe metol very purr and ures (ess Mmergyg Undeesm pod ger ond forms .com plexes Ne ccna chemistry 16 is-plath —> Stunts Sapid growig of fumer eptn | kK ‘ : ae peckces \ =pevicillaming dersfermioxime-» Redkuces Copper & Tin |