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Spectroscopic Organic Material Online Sensor Operation Manual
Table of Contents
Chapter 1 Specifications ..............................................................................................................................1
Chapter 1 Specifications
Specifications Details
Weight 3.2KG
Cable Length 10-meter standard cable which can be extended up to 100 meters.
Note: The specifications of the product are subject to change without prior notice.
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Spectroscopic Organic Material Online Sensor Operation Manual
2mm:
5mm:
50mm:
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Spectroscopic Organic Material Online Sensor Operation Manual
Chapter 3 Installation
3.1 Installation of Sensors
3.1.1 Handrail-style Installation
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Spectroscopic Organic Material Online Sensor Operation Manual
Installation steps: (this installation is only applicable to sensors with 2 and 5mm optical path)
1. Place the main body of the flow chamber at the position of the measuring tank;
2. Install the O-ring on the main body of the flow chamber;
3. Install the flow chamber cover;
4. Fix the flow chamber cover to the main body of the flow chamber with screws;
5. Install the flow chamber cover for support;
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Spectroscopic Organic Material Online Sensor Operation Manual
6. Fix the flow chamber and the probe on the mounting part with screws;
7. Install the assembled kit on the customer site with screws;
8. Connect the water inlet pipe, drain pipe, and sewage pipe.
Serial No. 1 2 3 4 5
Special note: In order to protect the UVTOC sensor, please be sure to ground the sensor
Figure 5
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Spectroscopic Organic Material Online Sensor Operation Manual
4、Make sure the side of the filter is tight to the edge of the sensor, as shown in the red circle in
Figure 6.
Figure 6
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Spectroscopic Organic Material Online Sensor Operation Manual
Note: After the slave address is changed, the new address will be used for communication and the
slave address for the next time connection is also the most recently changed address.
2、Click “Connection” on the menu bar, select the first line in the drop-down menu “Connection
setup” (The baud rate for the first time is the slave label) and click “OK”.
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Spectroscopic Organic Material Online Sensor Operation Manual
online sensor includes factor calibration、zero point calibration、sample calibration and standard solution
calibration. Factory default is standard solution calibration.
4、Slowly immerse the sensor into the TOC standard solution and ensure that the optical path is
measured horizontally;
5、Wait for the value to be stable and record the measured value;
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Spectroscopic Organic Material Online Sensor Operation Manual
6、Calculate the correction factor. The correction factor equals to the standard solution value divided
by the value measured in the 5 step. (Factor = standard solution value / measured value);
7、Select “16” in the menu bar to enter “226” for Address and “2” for Quantity in the dialog box,
change type into “Float CD AB”. Double-click the up on the right to enter “Factor Value” for the Value
(The factor value is the calculated value in step 6). Click “OK”, then click “Send”.
Assume that the factor value calculated in step 6 is 0.84, as shown in the figure below. Finally the
TOC value and TOC calibration standard solution are close at address 0:
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Spectroscopic Organic Material Online Sensor Operation Manual
5、After waiting for the value to stabilize, calibrate the zero point according to the communication
protocol: select “06” in the menu bar and enter “90” for Address in the dialog box, and the following
operations keep Address: “90” unchanged
Enter “62” in Value (62 zero point calibration menu), and click “Send”
Enter “25” in Value (25 Preparation), click “Send”;
Enter “18” in Value (18 ready), click “Send”;
Enter “61” (61 calibration status) in Value, and click “Send”;
Enter “85” in Value (85 wipe) and click “Send”;
Enter “61” (61 calibration status) in Value, and click “Send”;
Enter “19” in Value (19 Wait Steady), and click “Send”;
Enter “42” in Value (42 End of calibration), click “Send”;
Enter “52” in Value (52 Return to main value), and click “Send”;
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Spectroscopic Organic Material Online Sensor Operation Manual
4、Select “06” in the menu bar and enter “90” for Address and “27” for Value in the dialog box
(Filter calibration menu), click “Send” ;
5、Check 318 address values, select “Setup” in the menu bar, select Read/Write Definition and enter
“318” for Address (Remove the wiper from the marker),“1” for Quantity, click “Send”. Select the address
column and change Format to “Signed” to confirm whether the wiper has been removed. Remove the
wiper is completed (0 indicates incomplete and 1 indicates completed);
6、After removing the wiper, install the filter (For details, see section 3.3), click “Setup” in the menu
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Spectroscopic Organic Material Online Sensor Operation Manual
bar, select Read/Write Definition, “50” for Address (absorbance), “2” for Quantity, click “Send”. Select
the address column and change Format to “Float CD AB”, wait for the absorbance at address 50 to
stabilize;
7、Select “06” in the menu bar and enter “90” for Address and “43” for Value (save data) in the
dialog box, click “Send”;
8、After calibration, remove the filter, select “06” in the menu bar and enter “90” for Address and
“52” for Value (Wiper back to position) in the dialog box, click “Send”.
5、Select “06” in the menu bar and enter “230” for Address and “1” for Value (sample calibration
mode) in the dialog box, click “Send”;
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Spectroscopic Organic Material Online Sensor Operation Manual
6、Wait for the value to stabilize, and record the stable UV254 value; select “16” in the menu bar to
enter “239” (sample calibration 1 UV254 address) for Address and “2” for Quantity in the dialog box,
change Type into “Float CD AB”. Double-click the up on the right to enter sample calibration 1 stable
value UV254 for the Value;
7、Select “16” in the menu bar to enter “243” (sample calibration 1 concentration address) for
Address and “2” for Quantity in the dialog box, change Type into “Float CD AB”. Double-click the up on
the right to enter sample calibration 1 actual concentration value for the Value;
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Spectroscopic Organic Material Online Sensor Operation Manual
9、Take out the sensor, wash the sensor and wipe dry, slowly immerse the sensor in the second
sample of known concentration to ensure the level of the measuring light path;
10、The operation of sample calibration 2 is similar to that of sample calibration 1. From steps 6 to 7,
input “241” for sample calibration 2 UV254 address, Value input sample calibration 2 stable value
UV254; sample calibration 2 concentration address input “245”, Value input sample calibration 2 actual
concentration value. The sample calibration has been completed.
Instructions for calibration of water samples:
Instructions for water sample calibration: Spectroscopic organic material online sensor measures the
absorption of organic matter in water to 254nm ultraviolet light, and expresses the measurement result
with a special absorption coefficient SAC254, as a physical quantity to measure the total amount of
organic pollutants in water. It should be noted that, in order to ensure the accuracy of organic matter
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measurement by spectrometry, it is necessary to calibrate for different solutions, and the organic matter
composition of the measured solution must be exactly the same as that of the calibration solution.
The main reasons are as follows: 1. Not all organic matter absorbs ultraviolet light. Only organic
matter containing conjugated double bonds or polycyclic aromatic hydrocarbons can absorb ultraviolet
light when dissolved in water. 2. Even if the organic substances contained in the solution are organic
substances that absorb the ultraviolet band as mentioned in the first article, their molecular structures are
different, and the absorption intensity at the wavelength of 254nm will also be quite different. Therefore,
the greater the difference between the measured solution and the calibration solution's organic
components, the greater the error, and may even exceed the 100% error range.
The spectroscopic organic material online sensor is calibrated with a single-component potassium
hydrogen phthalate (KHP) solution at the factory. If the components of the measured solution are
inconsistent with the components of the factory calibration solution, it is necessary to re-calibrate
according to the measured solution to ensure accuracy. Generally, the organic components in the actual
water sample are complex, so it is recommended that the water sample calibration should be carried out
when the instrument is tested on-site. At the same time, it should be reminded that the composition of
organic matter in the water sample cannot be completely unchanged, and the actual water sample may
also have been influenced such as turbidity and chromaticity. For these reasons, the accuracy of general
water samples is difficult to achieve, difficult to achieve the accuracy of a single component standard
solution.
5、Select “06” in the menu bar and enter “230” for Address and “0” for Value (standard solution
calibration mode) in the dialog box, click “Send”;
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Spectroscopic Organic Material Online Sensor Operation Manual
6、Wait for the value to stabilize, and record the stable UV254 value; select “16” in the menu bar to
enter “231” (standard solution calibration 1 UV254 address) for Address and “2” for Quantity in the
dialog box, change Type into “Float CD AB”, Double-click the up on the right to enter standard solution
calibration 1 stable value UV254 for the Value;
7、Select “16” in the menu bar to enter “235” (standard solution calibration 1 concentration address)
for Address and “2” for Quantity in the dialog box, change Type into “Float CD AB”. Double-click the up
on the right to enter standard solution calibration 1 actual concentration value for the Value;
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Spectroscopic Organic Material Online Sensor Operation Manual
9、Take out the sensor, wash the sensor and wipe dry, slowly immerse the sensor in the second
standard solution of known concentration to ensure the level of the measuring light path;
10、The operation of standard solution calibration 2 is similar to that of standard solution calibration
1. From steps 6 to 7, input “233” for standard solution calibration 2 UV254 address, Value input standard
solution calibration 2 stable value UV254; standard solution calibration 2 concentration address input
“237”, Value input standard solution calibration 2 actual concentration value. The standard solution
calibration has been completed.
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MODBUS-RTU
Function Code 03
03 Function Code
Absorbance 50 Float 2 R
Remove the
0: incomplete
wiper from the 318 Signed 1 R
1: complete
marker
06 Function Code
Modify the
Measurement Cycle (Unit: Second)
measurement 10 Signed 1 W/R
The shortest 15s 15 times
cycle
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Spectroscopic Organic Material Online Sensor Operation Manual
TOC
0: TOC Standard curve
Measurement 230 Signed 1 W/R
1: TOC sample curve
Pattern
0:4800
1:9600
Modify Baud
61961 Signed 1 W/R 2:19200
Rate
3:38400
4:57600
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16 Function Code
Range:
(2mm Optical Path): ±640
Deviation Value 228 Float 2 W/R
(5mm Optical Path): ±320
(50mm Optical Path): ±28
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Standard
Solution
231 Float 2 W/R UV Value
Calibration
1[1/m]
Standard
Solution
233 Float 2 W/R UV Value
Calibration
2[1/m]
Standard Range:
Standard Range:
Sample
1[1/m]
Sample
2[1/m]
Range:
Sample
(2mm Optical Path): 0~800 mg/L
Calibration 243 Float 2 W/R
(5mm Optical Path): 0~400 mg/L
1[mg/L]
(50mm Optical Path): 0~35 mg/L
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Spectroscopic Organic Material Online Sensor Operation Manual
Range:
Sample
(2mm Optical Path): 0~800 mg/L
Calibration 245 Float 2 W/R
(5mm Optical Path): 0~400 mg/L
2[mg/L]
(50mm Optical Path): 0~35 mg/L
485 analysis:
1、Read the TOC value
01:device address 01
03:Function code 03 for reading register content
04:The length of the returned data is 4 bytes
00 00 40 E0:The TOC value read is 7.00 (analyze 40 E0 00 00 using IEEE 754)
CA 7B:CRC16 check code
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Spectroscopic Organic Material Online Sensor Operation Manual
01:device address 01
03:Function code 03 for reading register content
00 08:The starting register address read is 0008
00 01:Read 1 registers
F5 C8:CRC16 check code
The device returns the analysis:
01:device address 01
03:Function code 03 for reading register content
02:The length of the returned data is 2 bytes
00 0A:The main measuring value unit read is 10
B8 44:CRC16 check code
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Spectroscopic Organic Material Online Sensor Operation Manual
Chapter 7 Maintenance
In order to obtain the best measurement results, it is very necessary to maintain the sensor regularly.
Maintenance mainly includes cleaning, inspecting damage of the sensor. You can also view the sensor’s
status during maintenance and inspection.
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Spectroscopic Organic Material Online Sensor Operation Manual
Caution: Damage to the sealing structure of the probe will cause water to enter the inside of
the probe, which will seriously damage to the equipment, therefore, it should be taken care of
during application.
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Version Number:R1033_230403
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