Conducting Polymoxs Daneel Poles oe dae ae ae lecsriaty is duiod 04 cenduckng Polymass - oq! Poly ailine, poly rwole, aby extpene Classi ficodven ' ae 1 a aid re ™) |Corduct' poly ‘alta ae aay oe a eit, Cenp , cod we IT ‘el penning Pepe! alecrrons Cex Tncbrinsicolly conducting potyrnas, | They trove anckendod Conjugation which is Heapensibte fort conduction Is Conducting pelyrmer with conpugatad 1 @ The ombttals of Tr clecbions svetlan xesuting An the formation of valance Jrand vond conduction band. The highest occupied band is colled valonw bend vand Aust Occuyiod rand 1s Coded Conduction Jband. They OHO. aenaroied with energy gar. . Electrical CenducHen Occur, When elecbions 4ytom valence Jand One enced tp Conduction band dy trowaally on Irhote yt coy, 2 Dope conducting polymers. Thein conductivities, woxo ue ko pontive ot A dhe prow ©f Negative change on poly mor ey oxidation 6% sieduction vand is tenmed as deping, Tk is of two typos. (a) P-deping. Th is eno by sridative powers. In this Pau some olerwon from the tT Lond’ ef Conpugatad deulte bend ox2 memeved wand -heles vax couotd usaich con meve valong the polymer molecule . Thus adhe Jsecome Conductive. The chonged Eeefloskcles tosimed Jy doping is knewn 0d peloson. The pelanens ax molilo and can move tne folymeric — Chouin Joy tho remuanged of dingo and) deubte Ubsond. Hena the Polipmar Isecomes Conductive tn nokure. Sridatve yoioass is Conmudd bub by dewiy odds Juke Feels. WA Dea ASS of, Poly acetylene + Parpogation eb a pelovon serugh oO Conjugqaled polymer me (by neidening: flracanlis “BRS Sh Aes byes Tn tus syne of doping some slecbions vaxe indieduud into the pelymen Aavi conjugated Plenitc ond by seduction with Jowis base scdium nayieHhanide. This mowults tn Ake feumation of Polaaon votich can mora along Mu paymanic chain susulting tn Gonduczion - W Envinsicolly Conducting PEW: Thene ane conducing pelymans vohose conductvidy Feyciws a ine (en of external -ingredionts added to them . aU) Conductive clement filed pelyrnurs In this polymere acts as the Minder .to Msld the Conducting elements together 4n tho Asud entity. Merits» Low det, light tn voeight , duralte and sneng. (2) Brended epee n pslymost ‘These folymors axe ebtnined by Arlending a Condurcting pelymox with a CenvenHonal polymers (inswlatosy). These pstymens have Avetiaa pupical, Chomital vanct mechanical poroporttios and tan aie, oily rrocossed . Polyacetyleme ' Ayntres ts t Tr con be aannest ged doy posky maorizah on oO} 2 An poiosence 8} Blegler- Natta Catalyst. pi — cee — 1 Seen Nalin catalyst Ky Acetylene in GQ Peay loreConductivity in Polyacetytene Polyacorylone conatsts of Chains 6} Jnundsod s fo thousands 0} Carton atoms tunlad by alteanata Aingle and double Joondg, The conductivity Of Pstyocelrtene is wdbout bet KL” S/em Gut ne ae ty ened with onidining Gap gee Conducrivly pineoieo ton On Coau Toe ae PGS ten7 Pohprcokylene we ip ely e Fist Gnidation Ta in CCL, < da t/2Ia—> £3) a ZA Uy (we Partial @nidation 015 IN AN AN a e | Gecond Oridaton Pe aa ZA : ore | Bos bY Boliton @ls Sac Consucing Run dlyne FAe When dhe ridotive dopant, AU os Te is ab rakes away en 2techon fiom tha T- backbone tho fistyarerylane chain. This Crookes Positive cortey Uhote) on she of ro carbon: &The Other T election whith rasides on the Other (eM Ene ein; it 0. Svecitolmmlnemenacicale ten formed is Coed Polaxen. 4 On furthoy exidation , 0 dieloxon (or) aoliten ts foomacd . Those nadicals than migrate ond combine to -form Jratkbone owe bond. x As the Sawo Llecbions anaveneved , the chain wil Jove two pexrtive. conten Colas) - * The poritive neles a2 mobile. When .o petental ds Lonpliad , Dw. poritive Jsles mignate, fom One Coben +o -onothon . The miguation oO} peritive hslos acount for bo x When a W ond is formed , valence Gand (ve) and Conducton Band (cB) ane excoted ,4 lhe depart is added , polancns ond Aalitens aro AME swexutt 4n the caeation of Nous Aoralized Aedkonic Atetes “thot RW eno Rnwigy gay etivean v® and cp. When subbidont Solitons 072 -onmod , a new mid gan Enoagy band 43 cswated ushich pverlans with the vB And CB Alleusing clectrons fo plow. * The Changed solitons ora responsible for making helyacet one conducting ty nature . ] | L | Conduction band pssscerentia (| ee : bit = Valenco rand " Sn, Nausea} Poioson Lortton Seiko, cxoin Propoxtios eh Conducting Prdtymans . # Conducting peymow Arave igh melting a ae They Anew entedllonls chomital, thermal rand Oridatre madi Bralatihy due to leur Iydooqen covtnel vand 1 je Atiueunte - tly x02 insoluble tn many commen solvents. — ° & ,Applications °} Conducting poly marts | $ Thay sora wed in Might enitieg ielad: ¥ They ase used in display AQviies - ¥ They ou vsed os elediode mabetials -ho™ Hechargealte Jratterios , ¥ They wane used iin vontstaric matonials. ¥ They wsie used as co roristor fon Aithopianhy * They ase used os tual Cols 08 ale choca belie Mokestials - # They ane wed 0s momtane ox gas seperation. * They ara Used as Aurnid chy Aensors , Gas senrsons Hodiotton Aensons te. eiipen ane used as Conductve track on printedPant (Poly 3- hexyttriophene ) r ct Lo q bk ia je iS Faly (9- heswpbrriophane -2,15- cli ) commaumliy kentwon Os PaHT is a dew band wan prelymon donor wetth applications un organic phetovettaics , polymer solar Colly, OLEDE and OFETs, TE can conduct trough positive Changes (holes).