PHYSICS MAX.MARKS: 100 SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2, (3) and (4) for its answer, out of which ONLY ONE option can be correct. Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct. i In u— v method to find focal length of a concave mirror, the object distance is found to be 10.0 em and image distance is also found to be 10.0 cm, then find the focal length is A) (5.00 0.05)em B) (5.004 0.02)cm C) (5.0040.01)om D) (5.004.0.09 em In the given circuit the current through Zener Diode is close to 5000 v= a femo verve A) 6.7 mA B)0.0 mA ©) 4.0mA D)6.0mA ‘A body moves along a path PQR in horizontal plane from P to R. When the particle is at Q,) its speed is decreasing. The acceleration of the particle at Q is best represented by the vector.(A, B, C and D are vectors) AJA B)B oc D)D ‘A man holds a ball of mass (1/2) kg in his hand. He throws it vertically upward. During this process his hand moves up by 40 em and the ball leaves his hand with an upward velocity of 4ms''. The constant force with which the man pushes the ball is (g = 10 mis’) A)2N B)10N C)ISN D)7N6. Given in the figure are two blocks A and B of weight 20 N and 100 N, respectively. These are being pressed against a wall by a force F as shown. If the coefficient of friction between the blocks is 0.1 and between block B and the wall is 0.15, the frictional force applied by the wall on block B is A) 100N, B)80N ©) 120N D) 150 This question has Statement-I and Statement-II. Of the four choices given after the Statements, choose the one that best describes the two Statements. Statement-I: A point particle of mass m moving with speed v collides with stationary point particle of mass M. If the maximum energy loss possible is given as {dm} then ¢=[ 7 } Mem Statement-II: Maximum energy loss occurs when the particles get stuck together as a result of the collision. A) Statement-I is true, Statement-II is true, Statement-II is a correct explanation of Statement-I B) Statement-Iis true, Statement-II is true, Statement-II is not a correct explanation of Statement-1 C) Statement-1 is true, Statement-II is false. D) Statement-1 is false, Statement-II is true. A thin long smooth tunnel is dug along the diameter of the earth from North pole to South pole. A body starts form rest from the North Pole and travels along the tunnel to the center of the earth. The speed of the body when it reaches the center of the earth is [Mis mass of earth and R- is radius of earth, G Universal gravitational constant J A) zero © PomeMatch column -I with column -IL Column -I Column -IT p) Equation of continuity 1) Less than critical velocity 4) Bernoulli's theorem 2) Formation of eddies & vortices 1) Turbulent flow 3) Law of conservation of mass s) Stream line flow 4) Law of conservation of energy P q Te of B) 3) 4 1 2 gq 4 3 2 L D2 a 4 Statement-1: Two identical uniform elastic rods are lying horizontally on smooth horizontal surface under the action of forces as shown in figure. The elongation in two rods will be same. Statement-2: The magnitude of acceleration of rod will be same in both cases. A) Statement-I is true, statement-2 is true and statement-2 is correct explanation for statement-1. B) Statement-| is true, statement-2 is true and statement-2 is NOT the correct, explanation for statement-1. C) Statement-1 is true, statement-2 is false. D) Statement-1 is false, statement-2 is true.10. A gas is expanded from volume V, to 2¥, under three different processes. Process 1 is isobaric process, process 2 is isothermal and process 3 is adiabatic. Let AU,,AU, and AL; be the change in internal energy of the gas in these three processes. Then A) AU, >AU, > AU, B) AU, . The final temperature (Ty, for monoatomic and Tp for diatomic) attained will be A)Tw=To>Ti —B)Tw ToT, DY To < TaesTi Specific rotation of freshly prepared aqueous solution of I and I are +112 and +18.7, respectively. On standing the optical rotation of aqueous solution of I slowly decreases to give a final value of +52.7 due to equilibration with HL. Under this state of equilibrium, what is the ratio of IEI? CHO A) 0.57 B) 1.00 ©) 1.75 D)59 The half life of a first order reaction varies with temperature according to A)Intaa@l/T — B)IntweaT Oti2a VT? D)t2aT? The overlap between the atomic orbitals sketched below is g os" A) Positive B) negative C) zero D) No overlap Identify the correct reagents required for the following transformation eH o-@ A) (i) NaBH, (ii) H30° B) (i) LiAIHy, (ii) Hx0" ©) (i) HOCH,CH,OH, H’: (ii) LiAIH,; (ili) yO" D) (i) HSCH,CH;SH, H’; (ii) Ni/H; (iii) HO"42. 43. 44. Among the following complexes, (ji) [Ru(bipyridyt)s]” Gi) [CHEDTAy~ (iii) Trans-[CrC1(C,0,);]° iv) Cis-[CrCl(C;0.)3] — The one that show chirality are A) (i. (i, 9)— BY), Gi), ii), ©) Gi), Git), Gv) D)@, Git, (iv) Identify “M’ in the following sequence of reactions a. CH caer NES caer EO “e Q Ly Co x J A) B) * . . The major product(s) obtained from the following reaction of | mole of hexadeuterio a 8 (1 me). Fe ono ee ok A given amount of Fe” is oxidized by ‘x’ mol of MnO,_ in acidic medium. The number of moles of Cr0;7" required to oxidize the same amount of Fe™ in acidic medium is A)x B) 0.83 x ©) 20x D) 12x benzene is/are46. 47. 4B. 49, 50. 250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO, and 0.1 M AuCl. The solution was electrolyzed at 2V by passing a current of LA for 15 minutes. The metal/metals electrodeposited will be [Being = 9-807, E,, 71.697] A) Silver and gold in equal mass proportion B) Silver and gold in proportion to their atomic weights © Only gold D) Only silver The reaction of (+) 2-iodobutane and Nal* (I* is radioactive isotope of iodine) in acetone was studied by measuring the rate of racemization (k,) and the rate of inversion (ki). ()on,cn (Nc CH, + Nal’ + CHCH(')CH,CH, + Nat For this reaction, the relationship between k, and kj A) k= 2k, B) ki =0.5k, C)ki=k, D)ki= In the Lassaigne’s test for the detection of nitrogen in an organic compound, the appearance of blue coloured compound is due to 33k, A) ferric ferricyanide B) ferrous ferricyanide ©) ferric ferrocyanide D) ferrous ferrocyanide In the following reaction, The product P is RMgBr + HC(OEt), 2 P A)RCHO B) R:CHOEt C) RCH D) RCH(OEt); Assertion (A) : PCI, exists but NCI, does not exist. Reason (R) : d— orbital in P — atom takes part in chemical bonding: which is lacking in N-atom A) Both A and R are true and R is the correct explanation of A B) Both A and R are true but R is not the correct explanation of A C) Ais true but R is false D) Ais false but R is trueSECTION-II (NUMERICAL VALUE ANSWER TYPE) This section contains 10 questions. The answer to each question is a Numerical valve. If the Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be ing to the following ma +4 for correct answer, -1 in all other cases. 51. Ksp of solution BaSO, at 25°C is 4 x10 ©. The solubility of BaSO, in 0.1 M NaxSOs at this temperature will be P « 10 M. then the P is equal to 52. The charge carried by | millimole of M™ ions is 193 coulombs. The value of n is 53. _ In the study of the water gas reaction CO, +, 200... +H,0,,,, a mixture of Ct and Hp initially containing 40 mol% Ho was brought to equilibrium in a closed vessel. At equilibrium, there was 15% of H2. The value of Kp is .. 54, The enthalpies of combustion of C(graphite) and C(diamond) are —393.5 kJ mol! and —395.3 kJ mol”, respectively. The enthalpy change of the reaction C(graphite)—> C(diamond) is P « 10 J mol~'. Then Pis.. 55. The dihedral (torsional) angle (in degrees) between the two methyl groups in the most stable conformation of n-butane is ......(molecule is observed through C-2 and C-3 bond) 56. The total number of all possible isomers of [Co(H2NCH CH NH)) [Co(H,NCH,CH.NH,);]” together is J’ and 57. The number of lone pairs present in XeOFis... 58. How many structural isomers are C,H, react with CH,MgBr to evolve CH, gas? 59. The number of hydrogen bond(s) present in a guanine-cytosine base pair is... 60. Among Zn(OH),, Sn(OH);, Cu(OH)3, Fe(OH)s, Pb(OH);, Al(OH); The number of hydroxides which are soluble in excess of NaOH solution isMATHEMATICS MAX.MARKS: 100 SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2, (3) and (4) for its answer, out of which ONLY ONE option can be correct. Marking scheme: +4 for cor 61 62. 63. 64. 65. tee ree er 1 9 at ag eee) k sx€R, kn eN, and if ‘A’ denotes the set of ordered pairs (,k) where |f(x)|=n has exactly '4" distinct real roots , 'B' denotes the set of ordered pairs (n, k) where |f(x)|=n has exactly '7' distinct real roots. Then cardinality of AxB is A)24 B)25 ois D) 10 Two distinct complex numbers z, &7, satisfy the equation z +1+8i=|z\(1+/), then ke i A) 16 B) 18 OB D) 8v2 Let A be the set of natural numbers which are multiples of 5 strictly less than 100, and B be the set of natural numbers which divide 100. The cardinalities of the following sets BAA (the set of elements in B but not in A), ACB, and B are p, man respectively Then p +m +n= A) 20 B) 16 C18 D)14 The number of real value of 'x' for which Ke-x- 2x? 2x? 2x 2x |=0is 2 2 1-x-x’ A)l B)2 o3 D4 Words with or without meaning) of 8 letters are formed using the letters of the word EQUATION. If the number of such words where exactly one letter is repeated twice and no other letter is repeated, is k.8! then k = A) 38 B) 28 ©) 20 D)2266. 67. 68. 69. (8); if nis even -1 (2). if nis odd For n= 1,2, 3,..........50. Let A=4a, /a, = and B is the set of all distinct elements of A. The number of permutations of all the elements of set B such that even integers are in increasing order, is 26! 50! 26! Ay = c — vF 7 . 13! > 241261 6! 13112! G7) -32x-3) s Ix +6)—2¥3x-5 23 39 31 34 A) n B) zB co) 31 D) rr 4x? 4 2[x]x it-Zsx<0 Let f(x where [x] denotes the greatest integer function. ax? — bx if0Sx<— 2 Then A) f(x) is continuous and differentiable in (- ) for all real a, provided b ane 22 B) f(x) is continuous and differentiable in (- ) only if a=4,b=2 C) f(x) is continuous and differentiable in (+ ) ifa=4 and b=0 wl NI= 2 D) There exists no real a and b such that f(x) is differentiable in (-5 5) If xe R® and nN, we can uniquely write x= mn+r where me W and 00&£(2)=0, then £(4)= ix A)l B) 0.75 ©) 0.25 D)0.5 Locus of centre of circle touching perpendicular lines from origin and the line x + y= 1 is A) 2xy-2x-2y+1=0 B) 2x? +2y?-x-y=0 C) 2xy+2x+2y+1=0 D) x? +y?-2x-2y+1=0 The sides of AABC are 2x-y+5=0, x+y-5=0 & x—2y—5=0. Sumof the tangents of its interior angle is 27 3 A)6 B) — os D) -= ) ) 4 ) ) 4 The point P(ap’,2ap) lies on the parabola y* =4ax, where a is a positive real constant. F is focus & ‘O’is origin. Straight line which passes through P & F meets the directrix of the parabola at Q so that area of triangle OPQ is Bar. Then the absolute value of the integral value of *p’ is A) 0 B)1 2 D)3 The straight lines /, and ¢, have the following vector equations r Ti+ 2h 3k-+2( +ak) andr sk+ afi k) where A, pare real parameters. Acute angle between /, & /, is 60” at their point of intersection. Then maximum value of a+b is Aya By) 2 o2 D)= Equation of the line of shortest distance from P(p) to the line r=a + tb is (t, s are parameters) +s((xb)xb A) B) r=p+s(pxb+pxa) ©) F=p+s(pxb+bxa) b) F=p+s(axb+i+8)SECTION-II (NUMERICAL VALUE ANSWER TYPE) This section contains 10 questions. The answer to each question is a Numerical valve. If the Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be evaluated according to the following marking scheme: Marking scheme: +4 for correct answer, -1 in all other cases. 81. IFA’ square matrix of order less than 4 such that |aai(A)—adi(A")|+0 and B = 4adj(4), and if |A|=4, then hadi(AB*A“B)| +|AB* —B?A|+[adj(adj(B))|=2, then units digits of 2 is 82. If principle argument of a complex number lies in [-n,7.), the principal argument of the complex number "sin +( 2420055 \nis "A then [A= 5 5 10 i i 83. Consider I, -|o5" and J, hea Vn>m andn,meN. ix ror Ro 1, 72 1, Let A=|J,, 63 J,;|andB=|I,, 63 1,5), ks 56 Sus Is 56 Ins then find the value of det (A) — det(B) 84. If K is anon zero constant real number and (2+kx)° =a +bx + bx? + ex) + .. then [atb+e (Llis G.LF) 85. Suppose that x, x7 -24 and x +x* are consecutive terms in arithmetic progression, the sum of all possible values of the common difference of sequence is 16(2n+1) L and sina =, where a,b €N, then the least (Q@n+1)'-4(2n+ 86. tro Sean| value of (a +) is87. 88. 89. 90. “Ishan” opens a bag which contains 8 orange flavoured sweets & 12 lemon flavoured sweets, 2 of his friends pick a sweet each at random from the bag and then Ishan takes a random sweet for himself. Probability that Ishan chose a lemon flavoured sweet is M, then 10M = The probability of ‘Sandesh’ being late to school is 0.1. The last 20 days that sandesh went to school are examined. Then the mean and variance of the number of days that sandesh was late in those 20 days are x & y respectively then 10xy = 3. Locus of midpoints of focal chord for it is a curve ‘C’.Eccentricity for is 2, then 3 Fundamental period of the function f(x) = Si04X—Ssin’ x608% _ 4 ooeax 4 sin ax. sinx is“ then a 2(MODE! GTM-20(N) Date: 18-01-24 SEE-MAIN Max. Marks: 300 KEY SHEET PHYSICS A 2 B 3 c 4 c 5 c 6 D t D 8 A 9 D 10] A 11] 8B 12|_D 13| A 14|_ 8B 1s|_D 16] D 17 ¢ 18] A 19] ¢ |20[ pb ai{ 192 | 22) 10 | 23 6 24/15 |[25| 422 26] 9 |27]| 4 |2s z 29 9 30| 4 CHEMISTRY 31] a |[32/| a_[33|_ B_ |34] B_ [35] a 36] 2 37 B 38] c |39] a |4o| a 41] c¢ |42/ a_f43{_ B_ |44]_a_ [4s] B 46| 3 47 B |48| c_ |49| a [so] a si] 4 52 2 53 1 54] 18 |55| 180 56] 5 s7|_15__ [58 4 sol 3 |eo] 4 MATHEMATICS 61] c |e2| B |e3{_c |e] a _ [es] B 66| B_ |e67| B_ |es/ a_|eo| a_ 70] B mje |72[ ec |73l a [7] p (75/8 76|/ A |77/| B |7s[_ bp |79/ B_ [sol] a 81 8 |s2|] 9 |83| o | 84] 299 |85| 50 s6| 9 |s7| 6 |[ss/ 36 |s9| 3 90] 212 13, 14, SOLUTIONS PHYSICS 2 |f|=(5 £0.05) am OSem Centripetal acceleration is towards “D’ and tangential acceleration is opposite to ‘B’. So net acceleration can be towards °C” Acceleration of te ball = 2s «2x04 =20 ms? (20.410) =15N Hence force applied by the man =m (a +g)= 2 Here frictional force is equal to the weight of the body. uR=mg=W W=0.2«10=2N. If the bodies are of equal mass and second body is at rest, then after impact they exchange their velocities i.e body one comes to rest and body two moves with velocity of body 1 and hence the maximum transfer of momentum takes place when m, =m, and m, is at rest =3-txS1 0 = x-x-2=0 0 =x=-lorx=2 -GmM, _-3GmM, 1) > R pp 2 Acceleration is same but elongation is greater in first rod Process 2 is an isothermal process. Hence, aU, =0 Process | is an isobaric (P = constant) expansion .Hence, temperature of the gas will increase. Process 3 is an adiabatic expansion. Hence, temperature will decrease ‘Therefore , aU, » AU, > AU, is the correct option wk Feat By argument of symmetry, it will be half of the potential produced by the full sphere Charge on hemisphere = Q , so charge on sphere = 292 310) _ko yet py KQ_9x10°x5x10" _ soy, R 15xIf 15. Let q 4rC be the charge on two capacitors C, and Cy. ‘Then +30 5 4230 or 4 Gq voll) pU/2) _ ptli2) ane 16. ptli2) _ pl/2) ary xr) Power loss, P=J?R -, Voltage drop, V = IR Current density , oe A 17, dF =Bidl dF =dFui+dF, Fg = dF =Bi(2na)sin9 18 Bajy[h+M) texto” (2.00 so /tat0°)=s20.00° 7 19, Emfwill always induces whenever, there is change in magnetic flux, The current ‘will induced only in closed loop. 20. Let R be the radius curvature of each surface one joel For water lens22, 24, ‘The z-component of the force and the x-component of displacement are ineffective here AW =E,y==3uydy (-2=0) 6atde(v y-32) Integrating between x =0 and x =2 gives the result By CO.AM lv ven ~i) are te VV, cos (V, sind gt)0| Fil g The terminal velocity of the spherical body of radius R, density falling through a liquid of density ois given by: (e-o)e 7 Where 7s the coefficient of viscosity of the liquid. ARO) ni y, AO) On On According to the given problem; —U; R(A-2)=R(2.-2) ace Substituting the given values, we get; RE _(Ilx10'-2x10°)_ 93 (10-2510) 62 5 . 2 f, =42745 =432 or 422 According o given condition, fy = 422 Net capacitance of the system, C, =28, 29, 30, 31 34, 35, (300) “100 100=| —"— |r R4+(oly > 100 =| 60) _ log (900) +(300L) (300) +(100)° 2? P=16, L=4H FlAle Powers radiated by the slits are in the ratio 1:4 sme (EE 900, 0 = 22 f =22 x 122-300 = = (500) “Wav ‘The given wave is superposition of 3 waves with frequency, pot anand &% —O Op, =( +O) CHEMISTRY Imin De-Broglie wave length the magnetic moment of an octahedral Co(II) complex is 4.0 ys the electronic configuration of the complex is tz,” e.’ (There is three unpaired electrons) —— Linda ena oe Zalkene —Ealkone waexd 1.610 Cx1.27%10 mt = 203x107 Cxm Actual Dipole moment = 1.08 D => 1.08% 0.334x10°"Cm =0.36 x 10"Cm Actual 0.3610 Cm Calculate ze” 2.03%10Cm onic radii values are gradually decreases from La to Yb Formation of charge = =0.17737, 39, 40. 4 For monoatomic gas y =1.67:7V~ = constant ae Ty (ey (0) ony For diatomic gas We Tvs rn(2) 40 Equating (1) and (2) ey ob sins 14,4) ne (2) 31, (I) Also in acidic medium COP +141" +60"! > 2Cr* +70 And Fe’? > Fe +e? So, number of moles of C10} Emotes (2) moles of MnO; = x moles of MnO; xo5x 3 ut this value in equation (2) | itt be &* 6 6 So, the number of moles of Cr,O;- required to oxidise. The same amount of Fe" in acidic medium 5x (on) 088 is 5x (o9 ome47, 48, 49, SI 53, 54. When 0.5 mole of Nal* reacts with (1), then it causes formation of 0.5 mole of (I1) (i. inversion product), but 0.5 mole of (1) and 0.5 mole of (ID), give 1 mole of racemic mixture (1). So rate of racemisation is twice of inversion K,=2k; therefore ki =0.5 ky Toa part of soclium extract, FeSO, solution is added and the contents are warmed. A few drops of FeCl, solution are then added and resulting solution is acidified with conc. HCI. The appearance of bluish green or Prussian blue colouration confirms the presence of nitrogen. The reactions that occur during thi solubility of saturated sol" = solubility product Ksp =4x10° (for BaSO,) Let the solubility of BaSO, in 0.1M Na,SO, be ‘x BaSO, — Ba”? + SO? Na,SO,—*2Na* + S02 Total SO} =x+0.1=0.1M Thus Ksp =[Ba* [SO ] 4x10* =2x0.1=1 solubility =4x10°M Pa4 One millimole = 0,001 mol i.e., 1x10 mol 96500C is required for Imol of electrons 1931 193C giv eve 96500 =0,002mole ie, 2x10%mol of electrons 0.002 0.001 COs) + Hyg PCO + Hy, 0.6mol 0.4mol 10g 0.35mol —0.1Smol——0.25mol_—_—0.25mol (0.25) (035)(0.15) | Ghenie) + Oye) COygy AH, =-393.SKI mol ¢, +0,,, > CO, AH, =-395.3KJ / mol ‘oman + Orcs is) ‘Thus, value of ‘n’ is m+n is, k 12 A=AH,~AH, =[-393.5-(-395.3)] =1.80kdmol = 1.810’ Jmol" =18x10" Jmol"55, 36. 58, 60, 61 63, 64, Anti/Staggered @= 180° Isomers of (Co(en),) TICStemI" Isomers of [Cofen,ci> +f a Sho | feta 1 eee Co nf de , Pb(OH)>, Al(OH); are amphoteric, hence they are soluble in excess of NaOH solution, MATHS nk =16 => (n,k) =(16,1),(8,2),(4,4),(2,3),(16,1) nk =19=>(n,k) =(9,1)(3,3,)(1,9) n(AxB)=15 Assume 2 S x41 and y+8= >y=Sor-3 = 7=1245i of 4-31 ={5,10,15,20,, B/A ={1,2,4,100} B{1,2,4,5,10, 20,25, 50,100} AMB={5,10,20,25,50} la-b-c 2a 2a 2b b-a-c = -.2b_ |=2(a+b-+e)" by factor theorem x? +x-+1=0 has only one 20 2c e-a-b| real solution65, 66, 67, 68, 69, 70, 1 22, 7B, 74, B={0,-1,2,-3,4,-5,--—-,-25} q n(B)=26 of which 13 are even = 3) 3(4)_ 173x434 +92(x+6)—8(3x—5) 2(3) 23x2x3 23 oy: g(x) = {2% -28%x<0 ax? —bx3x 20 >aeR &b=2. Discontinuous at 24,68 (ey)(m)+x(m)+ x=05y=1 om-2-2 i) at +2m=0 (2) 40" (e) 12m ae dt 12 a, +2a,x+3a, a 0 has roots 3& -3 => a, =0 =I as its decreasing at x > —20 “Two curves intersect at (0,1) & (9,4) Area = st tx —4" dx =93 227-28 3 Ina =27-27log,e =27log,(4/e)75, 16. 7, 80, 81 [yet x a hnly+ 1] In |+c apr y+i]=5 ay-3 when x=4 Radius: [b+k-1] “ro Sh? +k? =h? +k? +2hk-2h—-2k +1 = 2xy-2x-2y+1=0 1 Slopes are 2, -1 and > nae I+] 4 yal, 141/2 P:(ap?,2ap) Q:(-a,2) =P=3 a 4 2-b -2 a=0&b=4 oe ell lo 2 V2V2+a2 2 oe a=dap=2 ‘The line lying in the plane of p—a and 6 & which is triangularto b is (@ ~a)x 5) xb Order of A is 2 as jaai(a) o adi(A")| =[aai(a")- adi(A)| B=4x4x A '=>AB=BA =161=>|B|=64 = |B) +0+ |B] > Units digits is 8.82, 83, 84, 85, 6, 87, 88, 89, 90, 3x 4cos’ = =n-+tan™ 5 asin cos 55 63 =0(C, >C,+C,) Jas eae CI= B1= T= RD B=|I,, 63 +|=0(c,+¢,-c,) Hs 56 b=6(2')(k) b=6C,(2*)(k*) c=6C,(2")(k’) 1p 268 _ 2088" ay = se eos 2x +x? =2x?-48 x?-2x-48=0 (x-8)(x+6)=0 Difference = ~-=32 or 18 Ply tan! al 4 meet) Homogeneous mixture => Probability 12023) (22=e8-N) 4 10xy =10(np)(npq) =10x 20x 20x. L Eccentricity is same s(x) sindxlsinn) x = Period is 1