Some Basic Concepts of Chemistry ‘The decomposition of a certain mass of CaCO, gave 11.2 dm’ of CO, gas at STP. The mass of KOH required to completely neutralise the gas is (a) 56g (b) 28g (©) 42g (d) 20g (2006) Dalton’s law of partial pressures is applicable to which one of the following systems? (a) NH, +HCl (b) NO+0, () H,+Cl, (4) CO+H, (2007) Molarity of a given orthophosphoric acid solution is 3 M. Its normality is (a) 9N (b) 03N (©) 3N (d) IN (2007) ‘The number of gram molecules of chlorine in 6.02 x 10° hydrogen chloride molecules is (a) 10 (b) 100 (© 50 (a) 5 (2007) Which one of the following has maximum number of atoms of oxygen? (a) 2g of carbon monoxide (b) 2g of carbon dioxide (©) 2g of sulphur dioxide (d) 2g of water (2007) The mass of a metal, with equivalent mass 31.75 which would combine with 8 g of oxygen is (1 (b) 8 (©) 3.175 (d) 31.75 (2007) ‘The volume of 10 N and 4 N HCI required to ‘make | litre of 7 N HCI are (@) 0.50 litre of 10 N HCI and 0.50 litre of 4NHCI (b) 0.60 litre of 10 N HCl and 0.40 litre of 4NHCI : (c) 0.80 litre of 10 N HCI and 0.20 litre of 4NHCl (d) 0.75 litre of 10 N HCI and 0.25 litre of 4N HCL (2007) 8. Forthe reaction, Fe,O, + 3CO—» 2Fe + 3COy, the volume of carbon monoxide required to reduce one mole of ferric oxide is (a) 67.2 dm? (b) 11.2dm? (c) 22.4dm? (d) 44.8 dm? (2008) 9. 10 cm? of 0.1 N monobasic acid requires 15 cm? of sodium hydroxide solution whose normality is (a) 0.066 N (b) 0.66N (©) 15N (a) 0.15N (2008) 10. Mass of 0.1 mole of methane is, (a) 16g (b) O1g (1g (d) 16g (2008) 80 g of oxygen contains as many atoms as in (a) 10 gofhydrogen (b) 5 g of hydrogen (©) 80 gofhydrogen (d) 1g of hydrogen (2008) . Excess of carbon dioxide is passed through 50 mL of 0.5 M calcium hydroxide solution. After the completion of the reaction, the solution was evaporated to dryness. The solid calcium carbonate was completely neutralised with 0.1 N hydrochloric acid. The volume of hydrochloric acid required is (At. mass of calcium = 40) (a) 200 cm? (c) 400 em’ (b) 500 cm* (d@) 300cm* (2009) . A bivalent metal has an equivalent mass of 32. The molecular mass of the metal nitrate is (a) 168 (b) 192 (c) 188 (d) 182 (2009) . An aqueous solution containing 6.5 g of NaCl of 90% purity was subjected to electrolysis, After the complete electrolysis, the solution15. 18. 19. 7. was evaporated to get solid NaOH. The volume of 1 M acetic acid required to neutralise NaOH obtained above is (a) 2000 cm? (b) 100 cm? (©) 200 cm? (4) 1000 cm? (2009) ‘The amount of heat evolved when 500 cm? of 0.1 M HCI is mixed with 200 cm? of 0.2 M NaOH is (a) 2.292 ky (b) 1.292 ky (©) 0.292 kJ (d) 3.392 kJ (2010, 2011) . A mixture of CaCl, and NaCl weighing 4.44 g is treated with sodium carbonate solution to precipitate all the Ca” ions as calcium carbonate. The calcium carbonate so obtained is heated strongly to get 0.56 g of CaO. The percentage of NaCl in the mixture (atomic mass of Ca = 40) is (a) 75 (b) 30.6 (©) 25 (d) 69.4 (2010, 2011) 50 cm’ of 0.2 N HCl is titrated against 0.1 N NaOH solution. The titration is discontinued after adding 50 cm? of NaOH. The remaining titration is completed by adding 0.5 N KOH. The volume of KOH required for completing the titration is (a) 12cm? (b) 10cm? (©) 25cm? (a) 10.5 cm (2010, 2011) In which one of the following, does the given amount of chlorine exert the least pressure in a vessel of capacity 1 dm? at 273 K? (a) 0.0355 g (b) 0.071g (c) 6.023 x 10” molecules (d) 0.02 mole (2010) One gram of silver gets distributed between 10 cm’ of molten zinc and 100 cm? of molten Jead of 800°C. The percentage of silver in the zinc layer is approximately (a) 89 (b) 91 (c) 97 (d) 94 (2010) . One gram of silver gets distributed between 10 cm’ of molten zinc and 100 cm? of molten lead at 800°C. The percentage of silver still left in the lead layer is approximately 21. 22. 24, 25. 27, @ 2 (b) 5 () 3 (dt 2011) Excess of silver nitrate solution is adie to 100 mL of 0.01 M Pentaaquaci chromium(III) chloride solution. The of silver chloride obtained in grams is [Atomic mass of silver is 108.) (a) 287 x 10°? (b) 143.5 x 193 (© 143.5 107 (4) 287% 107 (2911) The equivalent mass of a certain bivaley metal is 20. The molecular mass of iy borg anhydrous chloride is (@) 91 (b) 111 (©) 55.5 (d) 75.5 (2012) . 20 mL. of methane is completely burnt using 50 mL of oxygen. The volume of the gas ie after cooling to room temperature is (a) 80mL (b) 40 mL (©) 60mL (4) 30mL (2012) 100 mL of 0.1 M acetic acid is completely neutralized using a standard solution of NaOH. The volume of ethane obtained at STP after the complete electrolysis of the resulting solution is (@) 12mL (b) 56 mL (©) 224 mL (d) 560 mL (2012) ‘The total number of electrons in 18 mL of water (density = 1 g mL~) is (a) 6.02 x 10% (b) 6.02 x 10° (©) 6.02 x 1074 (a) 6.02 x 18x10" (2012) . The number of moles of hydrogen that canbe added to 1 mole of an oil is the highest in (a) linseed oil (b) groundnut oil (©) sunflower seed oil (d) mustard oil. (2012) ‘The volume of 0.1 M oxalic acid that can be completely oxidized by 20 mL of 0.025 M KMn0Q, solution is (a) 125 mL. (c) 12.5 mL (b) 25 mL. (@) 375 mL (2022) The number of water molecules present in# drop of water weighing 0.018 g is (a) 6.022 x 1026 (b) 6.022 x 10° (c) 6.022 x 10! (a) 6.022 x10” (2013) a‘some Basic Concepts of Chemistry 29. 31. 32. 33. 35, Empirical formula of a compound is CH,O and its molecular mass is 90, the molecular formula of the compound is (@) CHO, (b) C,H,0, (ce) CoH, 30, (d) CH,O (2013) ‘The mass of 112 cm? of NH, gas at STP is (a) 0.085 g (b) 0.850 (c) 8.500 g (d) 80.500 g (2013) 50 cm’ of 0.04 M K,Cr,0, in acidic medium oxidizes a sample of H,S gas to sulphur, Volume of 0.03 M KMnO, required to oxidize the same amount of H,,S gas to sulphur, in acidic medium is (a) 60cm? (b) 80 cm? (©) 90cm? (a) 120cm? (2014) 1.78 g of an optically active L-amino acid (A) is treated with NaNO,/HCl at 0°C. 448 cm? of nitrogen gas at STP is evolved. A sample of protein has 0.25% of this amino acid by mass. ‘The molar mass of the protein is (a) 36,500gmol! — (b) 34,500 g mol (c) 35,400 g mol? — (d) 35,600 g mol (2014) 10 g of a mixture of BaO and CaO requires, 100 cm? of 2.5 M HCI to react completely. The percentage of calcium oxide in the mixture is approximately (Given : molar mass of BaO = 153) (a) 52.6 (b) 55.1 () 44.9 (d) 47.4 (2014) |. 25 cm? of oxalic acid completely neutralised 0.064 g of sodium hydroxide. Molarity of the oxalic acid solution is (a) 0.064 (b) 0.045 (c) 0.015 (d) 0.032 0.30 g of an organic compound containing C,H and O on combustion yields 0.44 g CO, and 0.18 g H,O. If one mol of compound weighs 60, then molecular formula of the compound is (@) C,H,O (©) CH,O (2014) (b) CH,Or (d) C,H,O (2015) 36. 37, 38. 39. 40. AL. 42. 43. 3 ‘What amount of dioxygen (in gram) contains 1.8 x 10? molecules? (a) 0.960 (c) 0.0960 (b) 96.0 (d) 9.60 (2015) ‘The number of oxygen atoms in 4.4 g of CO, is (a) 1.2 10% (b) 6 x 107 () 6x 108 (d) 12x 107 (2016) An organic compound contains C = 40%, H = 13.33% and N = 46.67%. Its emperical formula is (a) C)H,N (b) C,H,N (©) CH,N (d) CHN (2016) If 3.01 x 10” molecules are removed from 98 mg of H,SO,, then number of moles of HS, left are (a) 0.5 x 10 mol (c) 9.95 x 10 mol (b) 0.1 x 10° mol (d) 1.66 x 107 mol (2017) 1.0 g of Mg is burnt with 0.28 g of O, ina closed vessel. Which reactant is left in excess and how much? (a) Mg.5.8g (b) Mg, 0.58 g (©) 00.24 (d) 024g (2018) ‘The mass of AgCl precipitated when a solution containing 11.70 g of NaCl is added to a solution containing 3.4 g of AgNO, is [Atomic mass of Ag = 108, Atomic mass of Na = 23] (a) 5.74g (b) L7g (©) 287g (@) 68g (2019) 0.4 g of dihydrogen is made to react with 7.1 g of dichlorine to form hydrogen chloride. ‘The volume of hydrogen chloride formed at 273 K and | bar pressure is (a) 454L (b) 90.8L (c) 454L (d) 9.08L. (2020) ‘A gas mixture contains 25% He and 75% CH, by volume at a given temperature and pressure. The percentage by mass of methane in the mixture is approximately (a) 25% (b) 92% (c) 8% (d) 75% (2020)