ISC CHEMIS (THEORY) PRY PAPER-1 Maximum Marks: 70 ‘Time Allowed: Three Hours ‘This paper is divided into foUF sections-A.B.C and D. Answer all questi ‘© Section. A consists of one question having sub-parts of one mark each, Section IB consists of ten questions of two marks each. Section € consists of seven questions of three marks each and Section D consists of three questions of five marks each, ‘+ Internal choices have been provided In one question each In Section B, Section :C, and Section D, ©All working , including rough work should be done on the same:sheet as, and adjacent to the rest of the answer © Theintended marks for questions and parts of questions are given in brackets. Balanced equations must be given, wherever possible and diagrams where they are helpful, When sal ving rhumerical problems, all essential working must be shown, © In.working out problems, vse the following data © Gas Constant (R)=1.987 cal deg" mol'=8.3 147K"! mot '=0.0824dm" atm K'mol! {Vatar=1 den? atm =1601.3 J, 1 Faruday=96500 Coulombs. Avogadro’s number (N,) = 6.023 x 10 SECTION -A (14 MARKS) QUESTION NO -1 (A). Fill in the blanks by choosing the appropriate ord(s) from those given in the brackets [4] { Negative, Cane Sugar, Dihydric, greater, positive, Tri hydric, basic, pseudo first order} 1) Greater the strength of the ligand, is the stability of the plex. 2) Inversion of __is am example of a__reaetion. 3) For a non-spontaneous reaction, AG? and F%,,y are____ and __respectively 4) Glycol is.an example of ___ alcohol and glycerol isan___ alcohol (B). Choose the correct answers from the following. ful 5) The rate constant of first order reaction is 10? mim', The half-life period of the reaction is fa) 693 min (0) 69.3 min (c) 6.93 min (€) 0.639 min 6) Zr and Hf have similar radii because of (a) Lanthanide contraction (b) Actinide contraction (¢) d-d tn wsition —@l) Group number 7) Which of the following compounds will give a secondary alcohol on reduction with Grignard reagent followed by avid hydrolysi (HCHO — (b)CAKCHO——(e) CHACOCH, (@ RCOOCHHs8) The product formed when aniline is warmed with chloroform and caustic potash a} Phenyl chloride b) Methy! isocyanide } Phenyl isocyanide 4) Nitro phenol 9) Which reactant is used to prepare aniline using Fe/HCI as reagent a)Benrene —b) Nitrobenzene —_e) Phenol d) Anisole 10) Assertion: Chlorine is an ortho-para directing group in electrophilic aromatic substitution reaction Reason: Chlorine is an electron withdrawing group. a) Both assertion and reason are true and reason is the correct explanation of assertion b) Both assertion and reason are true but reason is not the correct explanation of assertion ©) Assertion is truc hut reason is false d) Assertion is false: but reason is true 1) Assertion: The resistivity for a substance is its resistance when it is one meter long and its area of ‘Cross-section is one square meter. Reason: The SI units of resistivity are ohm meter (m). a} Both assertion and reason are true and reason is the correct explanation of assertion 1b) Both assertion and reason are truc but reason is not the correet explanation of assertion ©} Assertion is true but reason is fa ) Assertion is false but reason is true but (C) Read the passage given below carefully and answer the questions that follow. BI ‘The components containing carbonyl group, ie., carbon-oxygen double bond (represented as C=O) are known as carbonyl compounds. Depending upon the atoms or group of atoms attached on either side of the carbonyl group, carboxyl compounds are divided into three classes, i.e. aldehydes, ketones and carboxylic acids. Aldehydes and Ketones can be reduced to a variety of compounds under different conditions, Aldehydes and Ketones are reduced to primary and secondary alcohols respectively by NaBH,or LiAIH, as well as catalytic hydrogenation. Aldchydes differ from Ketones in their oxidation reactions. Aldchydes are casily oxidized to carboxylic: with different oxidizing agents. Even mild oxidizing agents mainly Totlen’s reagent and Fehling’s solution also oxidize aldehydes. Ketones cannot be oxidised by weak oxidizing agent, Ketones are generally oxidised under vigorous conditions.(i)-Give an example and its IUPAC name of a compound that produces an optically active product on LiAIHy? ii) Write the product formed by reduction of Ketone or aklehyde with Hl and red P? (ii The oxidation of CHyCOCH:CH2CH) by avidified KzCr20r produces two products, Name them, SECTION -B (20 MARKS) Give reason for the following. Ry) (i) Zn, Cd and Hg are not considered as transition metals. Why? (Gi) Acidified KMnOs solution is treated with KE and forms Is Question no -3 LI Answer the following questions: (@ Give one example of an ec —amino acid. (ii) Write the structure of the dipeptide using this example. Question ne -4 12) A solution containing 0.5g of KCI dissolves in 100g of water and freezes at -0.24°C, Calculate the degree of dissociation of the Salt. (K, for the water=1.86K Kg mot) Question no -5 (2) Ac -a vine rod in 0.1M zine nitrate solution and a lead rod in 0.2M lead ‘constructed by dippin nitrate solution Epoe2ps) = -0.13W and B°(zee2za) =-0.76V 1) Write the spontaneous cell reaction TL) Calculate standard emf and emf of the cell. Question no 6 Which compound in each of the following pairs will react faster in Sy2 reaction with OH’ and why? (i) CH3Br or CH3E (ii) (CH3)CCl or CHCI (21 Question no -7 (i) Arrange the following carboxylic acids in decreasing order of their acidic strength. BI Formic acid, propionic acid, Isobutyric acid, Acetic acid, Gi) Boiling points of carboxylic acids are higher than those of alcohols of same molar mass. Justify the statement.Question no 8 RI Give reasons for the following. (i) Cut is diamagnetic but Cu** is paramagnetic (Z=29). (Gi) The transition metals and many of their compounds act as good catalyst (oR) (i) KoCpOrtH)SOu+ FeSO. + - - Gi) MnOr¢NOP FH? = ‘Question no -9 “Arrange the following compounds in order of the feature given. (2 (4) e-cresol, phenol, o-nitro phenol (Acidic character), (ii) Phenol, Benzene, chlorobenzene (Reactivity towards electrophilic substi s Question no -10 PI Give one chemical test for each to distinguish between the following pairs of compounds, i) Phenol and cyclohexanol (ii) Butan-2-01 and 2-methy|propan-2-al Question no -11 PI ‘The elements of 3d transition series are given belo Sc, Ti, Cr, Mn, Fe and Co Answer the following. (i) Write the name of the element which shows maximum number of oxidation states. Give reason. (ii) Which element has the highest melting point? SECTION -C (21 MARKS) ‘Question no -12 Gi) Mention a test to distinguish between glucose and sucrose? 131 (4) What are proteins? (ii) Tow are proteins classified on the basis of molecular shape? ‘Question no -13 1B) Arrange the following compounds: CH,COOH, (CH;);COOH, HOOOH, (CH); C-COOH ‘@) Indecreasing order of their reactivity towards esterification. (ii) In decreasing order of their solubility in water.Question no «14 Inare: (31 tial rate of the reaction (ro) was measured for different initial between A and B, th concentrations of A and B as given below, ‘A (Mol L") 020 020 040 B (MolL"} 0.30 0.10 0.05 Te(Mol LS) S.07X108 5.07X10° 1.48 X10* Find the order of reaction with respect to A and B Question no -15 BI A solution containing 0.01 tkg barium nitrate in 0. kg of water boils at 100.46°C. far water, Keis 0.52K kg mot! and the molir mass of barium nitrate is 0.2613 kg mol! Gi) Find 8T i) Calculate degree of ionisation of the Question no -16 BI A solution is prepared by dissolving 9.25¢ of non-volatile solute in 450ml of water. It has an osmotic pressure of 350mm of Hy al 27°C. Assuming the solute is non-clectrolyte, deter molecular mass. (R=0.0821 L atm K* mot!) Question no =17 ‘How will the following be converted? (Given chemical equations) 131 (i) Nitrobenzene into aniline (ii) Ethanoic acid into methanamine (OR) Write the chemical equation for the following named organic reactions for Williamson’s ether synthesis and Wurtz reaction, Question no -18 Identify the compounds A.B and C in the following reactions, GO) CHs-CH ==CHs _HBr Peroxide, (A) Nal. Acctone._, (B)_KCN_,(C) Gi) CHsCl_KCN, (A) CHMgCl_, (B) _,0",(C)SECTION -D (15 MARKS) ‘Question no-19 i) Starting with ethanol, how will the following compounds be synthesized? (1 a) Bul-I-yne 4b) Propane nitrile (c) Propanol (ii)Sulphuric acid is not used during the reaction of alcohols in the conversion of an alcohol to alkyl iodide. Explain. ‘Question no -20 (i) Name the type of isomerism shown by the following, pair of coordination compound, 15] ICr(NHa)s(SCN)ICL and [Cr(NH3)s(NCS)ICIz (ii) What is the CFSE of high 5] ‘Question no-21 15] GA current of 1.70 A is passed through 300.0 ml of 0.160 M solution of ZnSO, for 230 s with a current efficiency of 90 %, Find out the molarity of Zn”* after the deposition of zinc, Assume the: volume of the solution to remain constant during electrolysis. Gi) A current 10 A is passed for 80 min and 27s through a cell containing dilute sulphuric acid How ‘many moles of oxygen gas will be liberated at the anode? (OR) (i) How long a current of 3A has to be passed through a solution of silver nitrate to coat a metal surface of 80 cm with a 0.005 mm thick layer’? [Density of Ag = 10.5 g cm* and atomic weight of Ag=108.0 u} (ii) From the graph given below, which will be the weakest electrolyte and which will be the strongest and why?