CHE SPRY PAPER: (THEORY) Maximum Marks: 70 Time Allowed: Three Hours + ‘This paper is divided into four sections-A,B,C and D. Answer all questions + Section A consists af one question having sub-parts of one mark cach. Section BB consists of ten questions of two marks cach. Section C consists of seven questions of three marks each and Section D consists of three questions of five marks exch, + Internal eholees have been provided in one question each In Section B, Section C, and Seeton D. + All working , including rough work should be done-on the same shect as, and adjacent to the rest of the answer + Theintended marks for questions and parts of questions are given in brackets. + Balanced equations must be given, wherever possible and diagrams where they are helpful, Wien solving rumerical problems, all essential working must be shown + In working out problems, use the Following data: + Gas Constant (R)= 1.987 cal deg" mot'=8.3140K ‘mot'=00821dm' atm Knot! ‘A ater=1 din’ atm =101 3 J, 1 Faraday=96500 Coulomb. Avogadro’s number (N= 6.025 x 10 SECTION -A (14 MARKS) QUESTION NO -1 (A). Fill in the blanks by choosing the appropriate word(s) from these given in the brackets [4] Negative, Cane Sugar, Dibydric, greater, positive, Tei hydric, basic, pseudo first ordee} 1) Greater the __strength of the Tigand, __is the stability of the complex. 2) Inversion of __ is amexample ofa_reaction. 3) For a non-spontaneous reaction.AG® and F9y are and_ respectively. 4) Glycol is an-example of ___ alcohol and glycerol isan _alcohol (B). Choose the correct answers from the following. fal '5)'The rate constant of first order reaction is 10% min'!."The half-life period of the reaction is (@) 693 min (6)69.3 min (€) 6.93 min ¢@) 0.639 min 6)Zr and Hf have similar radii because of (a) Lanthanide contraction (b) Actinide contraction (¢)d-d transition (d) Group number 7) Which of the following compounds will give a secondary alcohol on reduction with Grignard reagent followed by acid hydrolysis @) HCHO (b)CHKCHO (©) CHECOCHs (@) RCOOGHs,8) The product formed when aniline is warmed with chloroform and caustic potash a) Phenyl chloride bb) Methyl isocyanide ©} Phenyl isocyanide 4) Nitro phenol 9) Which reactant is used te prepare aniline using FefHC! as reagent a)Benzene —b)Nilrobenzene ©) Phenol 4) Anisole 10) Assertion: Chlorine is an ortho-para directing group in electrophilic aromatic substitution reaction. Reason: Chlorine is an electron withdrawing group. a) Both assertion and reason are true and reasot the correct explanation of assertion +b) Both assertion and reason are true but reason is not the correct explanation of assertion ©) Assertion is truc but reason is false d) Assertion is false but reasa I) Assertion: The resistivity for a substance is its resistance when it is one meter long and its area of Cross-seetion is one square meter. Reason: The SI units of resistivity are ohm meter (m). ) Both assertion and reason are true and reason is the correct explanation af assertion 1h) Both assertion and reason are truc but reason is not the correct explanation of assertion ©) Assertion is true but reason is false 4) Assertion is false but reason is true but (C) Read the passage given below carefully and answer the questions that follow. BI ‘The components containing carbonyl group, ic...carbon-oxyzen double bond (represented as C=O) are known as carbonyl compounds, Depending upon the atoms or group of atoms attached on either side of the carbonyl group, carboxyl compounds are divided into three classes, i. aldehydes, ketones and carboxylic acids. Aldehydes and Ketones can be reduced to a variety of compounds under different conditions. Aktehydes and Ketones are reduced to primary and secondary alcohols respectively by NaBHsor LiAlHsas well as catalytic hydrogenation Aldehydes differ from Ketones in their oxidation reactions. Aldehydes are casily oxidized to carboxylic acid 0 with different oxi gents mainly Tollen's reagent and treatm ing agents, Even mild oxidizing Febiling’s solution also oxidize aldehydes. Ketones eannot be oxidised by weak oxidizing agent. Ketones are generally oxidised under vigorous conditions.4) Give an example and its IUPAC name of a compound that produces an optically active product on reaction with LiAIHA? (i) Write the product formed by reduction of Ketone or aklehyde with Hl and red P? (iii) The oxidation of CHsCOCH;CHCH; by acidified K:Cr;0, produces two products, Name them. SECTION -B (20 MARKS) Question no -2 Give reason for the following. BI (i) Zn, Cd and Hg are not considered 2s transition metals. Why? ii) Acidified KMnQs solution is treated with KI and forms Question no -3 21 Answer the following questions: {G) Give one example of an a —amino acid. (i) Write the structure of the dipeptide using this example, Question no -4 rF3) A solution containing 0.5¢ of KCI dissalves in 100g of water and freezes at -0.24°C, Calculate the degree of dissociation of the Salt, (Ky for the water=1.86K Kg mol) Question no -5 A (2) is constructed by dipping a zine rod in 0. IM zine nitrale solution and a lead rod in 0.2M lead nitrate solution Ee peony) =-0.13V and E°izmar20) =-O.76V 1D Write the spontaneous cell reaction TH) Calculate standard emf and emf af the cell, Question no -6 Which compound in each of the following pairs will react faster in Sy? reaction with OH’ and why’? () CH:BrorCHsl_ Gi) (CH:):CCI or CHSCL RI Question no -7 i) Arrange the following carboxylic acids in decreasing order of their acidie strength, BI Formic acid, propionic acid, Isobutyric acid, Acetic acid. (i Boiling points of carboxylic acids are higher than those of alcohols of same molar mass. Justify the statement.‘Question no 8 I Give reasons for the following. Gi) Cu’ is diamagnetic but Cu” is paramagnetic (2-29). Gi) The transition metals and many of their compounds act as good catalyst. (OR) (i) KsCrs0)4H:SQ.4 FeSO.» + - - Gi) MnOs-+NOx +H"... Question no 9 Arrange the following compounds in order of the feature given. (2) i) o-eresol, phenol, o-nitro phenol (Acidic character). Gi) Phenol, Benzene, chlorobenzene (Reactivity towards clectrophilic substitution). 8 Question na -10 [2] Give one chemical test for each to distinguish between the following pairs of compounds. (i) Phenol and cyclohexanol ii) Butan-2-01 and 2-methylpropan-2-o} ‘Question no <1 2 ‘The elements of 3d transition series are given below. Se, Ti, Cr, Mn, Fe and Co Answer the following. (@ Write the name of the element which shows maximum number of oxidation states. Give reason. Gi) Which element has the highest melting point’? SECTION -C (21 MARKS) ‘Question no «12 (i Mention a test to distinguish between glicose and sucrose’? i31 GWhat are proteins? (Gia) How are proteins classified on the basis of molecular shape? ‘Question no -13 BI Arrange the following, compounds: ‘CHCOOH, (CH:):COOH, HCOOH, (CH); C-COOH 4) In decreasing order of their reactivity towards esterification, (i) In decreasing order of their solubility in water.Question no -14 Ina reacti [3] between A and B, the initial rate of the reaction (ro) was measured for different in concentrations of A and B as given below. ‘A (Mol Ly 0.20 0.20 040 B (MolL') 0.30 0.10 0.05 ro(Mol LS) SO7X10° SOTX10" 1.43 X10" Find the order of reaction with respect to A and B. Question no -15 a A solution containing 0.01 Tkg barium nitrate in 0.1kg of water boils at 100.46°C. for water, Ki is 052K kg mol and the molar mass of barium nitrate is 0.2613 ke mol. i) Find aT, Gil) Calculate degree of ionisation of the salt. Question no -16 BI A solution is prepared by dissolving 9.25g of non-volatile solute in 450ml of water. It has an osmotic pressure of 350mm of Hg al 27°C. Assuming the solute is non-clectrolyte, determine its motecular mass. (R=0.0821 L atm K mot) Question no -17 How will the following be converted? (Given chemical equations) BI () Nitrobenzene into aniline (i) Ethanoie acid into methanamine (OR) ‘Write the chemical equation for the following named organic reactions for Williamson's ether synthesis and Wurtz reaction, Question no -18 il Tdenti the compounds A,B and C in the following rexctions, ()CHe-CH CH _ 1m Peroxide, (A) Nal accione , (B)_KCN_ (©) (i) CH»Cl_wen, (A) cumecs , (B) 10", (C)ECTION -D (15 MARKS) Question no-19 4) Starting with ethanol, how will the following compounds be synthesized? (5) (a) But-leyne (b) Propane nitrite (©) Propanol (Sulphuric acid is not used dusing the reaction of alcohols in the conversion of an alcohol to alkyl iodide. Explai Question no -20 (i) Name the type of isomerism shown by the following pair of coordination compound. 15) ICr(NHs)s(SCN)|Cla_ and [Cr(NHa)s(NCS}}Cl> i) What is the CFSE of high spin and tow spin d metal complexes in octahedral complex? Question no-21 [5] G) A current of 1.70 A is passed through 300-0 ml of 0.160 M solution of ZnSO, for 230s with a current efficiency of 90%, Find out the molarity of Zn’* after the deposition of zine, Assume the volume of the solution to rermaia constanl during electrolysis. Gi) A current 10 A is passed for 80 min and 27s through a cell containing dilute sulphurie seid How many moles of oxygen gas will be liberated at the anode? (oR) (i) How long a current of 3A hus to be passed through a solution of silver nitrate to coat a metal surface of 80 cm? with a 0,005 mm thick layer? [Density of Ag = 10.5 g cm? and atomic weight of Ag=108.0 u} (i From the graph piven below, which will be the weakest electrolyte and which will be the strongest and why?