PROCESS DESIGN SPECIFICATION ConocoPhillips Technology SolutionsNOTE: CONOCOPHILLIPS COMPANY CONOCOPHILLIPS HF ALKYLATION PROCESS PROCESS DESIGN SPECIFICATIONS This manual is the property of ConocoPhillips Company. It is not to be reproduced in any manner, or submitted to outside parties for examination, or used directly or indirectly for purposes other than those for which it was furnished, without written permission. This manual should be considered a single document and should not be distributed in in jdual sections to the various design disciplines. Any proposed deviations from the following specifications shall be submitted to ConocoPhillips, U. S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment. HFA Specs Revision 04-2007TABLE OF CONTENTS CONOCOPHILLIPS HF ALKYLATION PROCESS PR N IFICATIONS 1, COLUMNS AND VESSELS A. General B. Acid Rerun Column C. Acid Settler System 2, HEATEXCHANGERS A. Shell-and-Tube Exchangers B. Acid Vaporizer, Acid Superheater, and Rerun Overhead Condenser C. Double-Pipe or Multi-Tube Hairpin Exchangers D. Air Coolers and Condensers 3. FIRED HEATER 4. PUMPS AND DRIVERS . General Specifications . API 610 Pumps (With Mechanical Shaft Seals) . Mechanical Shaft Seals ). Reboiler Circulation Pumps ASO Pump - Additional Specifications API 685 Pumps (Sealless) . Listed Pumps . Listed Mechanical Seals HOBO FP HFA Specs Revision 04-2007TABLE OF CONTENTS (CONTINUED) 5, INSTRUMENTS AND CONTROLS General > Flow Measurement Liquid Level Measurement Pressure Measurement ‘Temperature Measurement Valves for Process Control . Relief Devices |. Online Process Analyzers Instrumentation and Control Equipment Sources rmpos mS 6. PIPE, VALVES, FITTINGS, AND SEWERS A. General B. Valves ~ Nickel-Copper Alloy Trim C. Carbon Steel Piping Specifications D. Nickel-Copper Alloy Piping Specifications E. Sewers F. Listed HF Service Valves 1. Descote (Tyco) 2. Dureo (Flowserve) 3. Pacific (Crane) 4, PetrolValves 5. W.M. Powell Co. 6 Velan 1. Vogt Flowserve) 8 Xanik 9, Xomox (Crane) HFA Specs Revision 04-2007(CONTI TABLE OF C 7. BUILDINGS 8 SKETCHES 9, MISCELLANEOUS MATERIALS ‘A. General B. Neutralizing Equipment C. Safety Equipment D. Spare Parts Guide — Industrialized Area E. Spare Parts Guide — Remote Area F. Special Handling of Acid Service Equipment 10. METALLURGY AND MATERIALS SPECIFICATIONS A. General B, Acceptable Nickel-Copper Materials Table. Acceptable Carbon Steel Materials Table. Acceptable Shaft Packing Materials Table. Acceptable O-Ring Materials Table. Acceptable Gasket Materials Table, G. Data for Manufacturing Blinds H. HF Acid Detection Paint 1. Maximum Allowable Bolt Stress Table J. ASTM Specifications Referenced in this Document BESO HFA Specs Revision 04-2007SECTION 1: COLUMNS AND VESSELS HE SERVICE SPECIFICATIONS CONOCOPHILLIPS HF ALKYLATION PROCESS A. General All columns and vessels shall comply with the latest revision of the ASME code for unfired pressure vessels and shall be code-stamped. If they are in HF service, their designs shall comply with the following specifications: 1. Except for the acid rerun column, which is fabricated from Nickel-Copper Alloy 400, columns and vessels and their non-removable internals shall be fabricated from ASTM A516 Supplement $54 carbon steel. An acceptable alternative steel for this service is ASTM A537 Class 1 with Supplement S54 of ASTM. ASI6. Plate %-inch (13 mm) and thicker shall be HIC-resistant (Hydrogen-Induced- Cracking-resistant) or shall also meet the following requirements: a, Sulfur limited to 0.005 wt % maximum and treated for shape control. b. Vacuum degassed, c. ASTM A578, Level A, Supplement $1 ultrasonically tested. d. Normalized or quenched and tempered. Pressure-containing components of vessels fabricated of carbon steel pipe, pipe fittings, or plate shall comply with ASTM supplemental requirements for hydrofluoric acid alkylation service. ConocoPhillips requires these ‘components to have a maximum carbon equivalent (CE) of 0.43, which is consistent with these supplements. 2, Fabrication welds shall be in accordance with NACE Standard RP0472. The maximum allowable weld hardness shall be Brinell Hardness Number 200 (BHN-200), which equates to Rockwell B-94 (HRB-94). 3. Seam welds and nozzle welds shall be full-penetration welds and shall be fully radiographed. Where reinforcing pads are used, the nozzle-neck to reinforcing-pad welds shall also be full-penetration welds. 4. Internal welds for the installation of trays, internal piping, ladders, baffles, ete., shall be continuous seal welds or full-penetration welds. Visible slag is not allowed on any internal (process) surface. 5. No post-weld heat treatment is required for vessels fabricated from carbonColumns and Vessels Page 2 (HE Alkylation) steel materials meeting the specifications in Paragraphs 1 and 12 unless it is specified by the applicable pressure code or unless weld hardness exceeds BHN-200 (HRB-94). See NACE Standard RP0472. 6. Cold-formed heads shall not be used unless they have been stress relieved in accordance with Section VIII, Division 1, Paragraphs UW-40, UW-49, and UCS-56 of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code, except as follows: The post-weld heat treatment (PWHT) temperature should be a minimum of 1150°F (621°C) held for one hour per inch (28.4 mm) of thickness for a minimum of one hour. Post-weld heat treatment at a lower temperature with a longer holding time, as permitted by the ASME code, should not be used. Industry experience indicates that PWHT at lower temperatures ins not as effective in reducing heat-affected zone hardness. A temperature range, such as 1175°F +/- 25°F (635°C +/- 14°C), should be used to ensure this minimum is met as well as preventing damage from overheating. 7. Fractionation trays shall be fixed-orifice valve trays (Sulzer V-Grid® or equivalent). Thermosyphon draw trays shall be non-active, Recessed (sumped) tray designs shall be avoided. Tray manways shall be provided for each pass to facilitate maintenance access. 8 Carbon-steel trays made of hot-rolled ASTM A1011 commercial steel (CS) grade sheet are satisfactory for HF-service fractionation columns, Trays must be a minimum thickness of 10 gauge. No corrosion allowance is required for removable trays or tray supports. Stainless steel or chromium-alloyed steel with over 0.20 wt % chromium shall not be used for construction of any tray component. Trays shall be assembled without the use of tray packing or gaskets, Bolting for trays and downcomers shall be carbon steel, ASTM A307 Grade B. Bolts must be fully annealed or normalized after fabrication if cold- headed. Tray bolting shall be specified to be installed hand-tight plus % turn. NickelCopper-Alloy trays shall be B127 UNS N04400 material of 3/16-inch (48 mm) thickness. 9. ‘The weight of tray deck components shall be transferred directly to the tray- support rings and, where applicable, to one-piece tray-support beams that are HFA Specs Revision 04-2007Columns and Vessels Page 3 (HF Alkylation) 10. 1. 12, 1B. 14, supported by tower wall gussets. Bolting of tray-deck components and support 1 not be load-bearing. Clamps (clips) may be used for deck-to- support-ring bolting only. Downcomers shall be through-bolted to the beams sh downcomer-support bars and shall be of one-piece construction between downcomer bars and/or gusset-mounted support beams. No internal bolting shall be used except for tray assembly. ‘The minimum size for nozzles in shall be two inches. All manways shall be 20- inch minimum size unless otherwise specified by ConocoPhillips. All nozzles shall be ASME Class 300 raised-face weld-neck flanges (see Paragraph 12) with the nozzle necks made of HF-service pipe or plate. Nozzles for vessels with design temperatures less than -20°F (-29°C) shall be constructed per ASME VIII, Division I. Nozzle necks shall have the same inside diameter as the flanges, Gasket finish shall be either serrated-concentric or serrated-spiral finish per ASME B16.5. The maximum weld hardness given in Paragraph 2 above applies to all nozzles and nozzle parts. Forged-steel weld-neck flanges shall be made of ASTM A105 normalized oF normalized-and-tempered forgings with A961 Supplement S62 or of A350 Grade LF? with A961 Supplement $62. Stip-on flanges are not allowed on any vessel except the Nickel-Copper-Alloy-400 acid rerun column. Gaskets on all ASME Class 300 raised-face flanges, including manways, shall be Nickel-Copper-Alloy-400-Teflon® spiral-wound gaskets (up to 400°F, or 204°C) or Nickel-Copper-Alloy-400-Grafoil® spiral-wound gaskets fabricated to ASME 16.20 dimensions. For protection of the flange face exposed to the process, expanded-Teflon® inner rings or metal inner rings with either Teflon® or Grafoil® facing or encapsulation are preferred (Flexitaltic® Style CGI, Lamons Spira-Seal® WRI, or Garlock FlexSeal® Style RWI. Others require qualification). Virgin Teffon® is recommended. An equivalent flexible graphite material may be used in place of Grafoil”. External bolting shall be ASTM A193 Grade B-7 or B-7M continuous- threaded stud bolts with carbon-steel hex nuts, ASTM A194 Class 2H. ASTM ‘A194 Class 2M nuts may also be used with B-7M bolts. Bolting for compression of manway gaskets shall be ASTM A193 Grade B-7. HFA Specs Revision 04-2007‘Columns and Vessels Page 4 (HF Alkylation) 15, ‘The minimum corrosion allowance specified for HF-service vessels and non- removable internals shall be % inch (3.2 mm) on each exposed surface, except for the ASO caustic washer and the ASO surge tank, which shall have a corrosion allowance of % inch (6.4 mm). 16. Platforms shall be provided to allow adequate access to all sides of nozzles and associated valves for maintenance and normal operation. 17. The outside edges of all flanges shall be painted with Hydrofluoric Acid Detection Paint, To allow detection of paint color changes resulting from exposure to HF, flanges shall not be insulated. For paint suppliers, see Seetion 10, Subsection H. 18, See Section 10, Subsection A, Paragraph 2 for low-residual-elements caution for selection of carbon steel materials. 19. The formula for carbon equivalent (CE) is shown in Section 10, Subsection A, Paragraph 1. B. Acid Rerun Column ‘The shell shall be constructed of Nickel-Copper Alloy 400 with a minimum corrosion allowance of % inch (3.2 mm). Solid Nickel-Copper-Alloy-400 weld-neck flanges are preferred. Nickel-Copper-Alloy-400-faced carbon-steel slip-on flanges are allowed, provided the entire gasket surface of each nozzle flange and manway flange is undercut and the undercut surface overlaid with a pure-nickel butter layer (using consumables such as ERNi-1), which is then followed by a minimum of two layers of ENiCu-7 or ERNiCu-7 weld deposit, After machining to proper dimensions, there shall be a continuous NickelCopper-Alloy-400 surface exposed to the process containing @ maximum of 5 wt % iron. Only the top layer of Nickel-Copper Alloy 400 shall be exposed to the process. ‘The minimum finished thickness of the nickel plus Nickel-Copper-Alloy-400 overlay shall be 3/16 inch (4.8 mm), or as necessary to limit the iron content of the finished surface to S wt %. Nickel-Copper-Alloy-400-faced carbon-steel slip-on flanges shall meet HF-service piping specifications for carbon equivalent and for vanadium plus niobium (columbium) content, but they need not meet any recommended limitations HFA Specs Revision 04-2007‘Columns and Vessels Page 5 (HF Alkylation) on nickel-plus-copper content. Nickel-Copper-Alloy-400-faced slip-on flanges are to be seal-welded on the inside. If they are also seal-welded on the outside, the cavity must be vented to the atmosphere. ‘Trays for the rerun column shall be Nickel-Copper Alloy 400 with a minimum thickness of 3/16 inch (4.8 mm). See Section 10, Subsection B, for a table of acceptable Nickel-Copper-Alloy materials. HFA Specs Revision 04-2007‘Columns and Vessels Page 6 (HF Alkylation) C. Acid Settler System 1. The acid settler shall have no internal bolting, including trays and tray manways. Trays shall be fabricated from carbon steel plate per Subsection A, Paragraph 1. Tray-support rings shall be used if the acid settler requires stress relief. Trays shall be of dished design at least %-inch (9.5 mm) thick. 2. For design purposes, the acid cooler, acid settler, and acid-cireulation piping are considered to be a single pressure vessel. The evaluation of welds shall be no less than that required by ASME Code Section VIII, Div. 1, Paragraph UW-51. Reactor risers and standpipes shall have a minimum wall thickness of % inch (13 mm). Any proposed deviations from the specifications detailed in Section 1 shall be submitted to ConocoPhillips, U. S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment. HFA Specs Revision 04-2007ECTION 2: AT EXC! SERS HF SERVICE SPECIFICATIONS NOCOPHILLIPS HF TION, ESS Shell-and-tube heat exchangers shall comply with the latest revision of ASME Section VIII Division J Boiler/Pressure Vessel Code, with API 660, and with TEMA Class R Standards, and shall be code-stamped. Double-pipe or multi-tube exchangers shall comply with the latest revision of ASME Section VIII Division I Boiler/Pressure Vessel Code and shall be code-stamped. Air coolers or condensers shall comply with the latest revision of ASME Section VIII Division I B jer/Pressure Vessel Code and with API 661 and shall be code- stamped. If they are in HF service, the following specifications shall be followed for the acid side(s) of the exchangers: A. Shell-and-Tube Exchangers Shells, tube sheets, and/or channels of shell-and-tube heat exchangers shall be fabricated from ASTM A516 Supplement $54 carbon steel. Acceptable alternative steels for this service include the following: a, ASTM AS37 Class 1 with Supplement S54 of ASTM A516. b. ASTM A350 Grade LF2 with Supplement $62 of ASTM A961. Plate % inch (13 mm) and thicker shall be HiC-resistant (Hydrogen-Induced- Cracking-resistant) or shall also meet the following requirements: a, Sulfur limited to 0.005 wt % maximum and treated for shape control. b. Vacuum degassed. ¢. ASTM A578, Level A, Supplement S1 ultrasonically tested. d. Normalized or quenched and tempered. Pressure-containing components of HF-service heat exchangers fabricated of carbon steel pipe, pipe fittings, or plate shall comply with ASTM supplemental requirements for hydrofluoric acid alkylation service. ConocoPhillips requires these components to have a maximum carbon equivalent (CE) of 0.43, which is consistent with these supplements. Fabrication welds shall be in accordance with NACE Standard RP0472. The maximum allowable weld hardness shall be’ BHN-200 (HRB-94). Exchanger seam and nozzle welds shall be full-penetration welds. Where reinforcing pads are used, nozzle-neck-to-reinforcing-pad welds shall also be full- penetration welds. No post-weld heat treatment is required for exchangersHeat Exchangers Page 2 (HF Alkylation) fabricated from carbon steel materials meeting the specifications in Paragraphs 1, 10, 15, and 18 unless it is specified by the applicable pressure code or unless weld hardness exceeds BHN-200 (HRB-94). 3. External bolting of the tube sheet, channel, and/or channel cover shall be ASTM A193 Grade B-7 continuous-threaded stud bolts with carbon-steel hex nuts, ASTM A194 Class 2H. Nozzle bolting in HF-service piping closures with Nickel-Copper-Alloy-400-Teflon® spiral-wound gaskets (up to 400°F, or 204°C) or Nickel-Copper-Alloy-400-Grafoil® spiral-wound gaskets may be either ASTM A193 Grade B-7 or B-7M continuous-threaded stud bolts. ASTM A194 Class 2M nuts may also be used with B-7M bolts. An equivalent flexible graphite material may be used in place of Grafoil®. 4, Tube bundles shall be of U-tube construction. Baffle-to-shell clearance for exchangers in HF service on the shell side shall be double those listed in Table RCB-4.3 in the TEMA standards, as allowed by TEMA provided the increased clearance has no significant effect on either shell-side heat transfer coefficient or mean temperature difference. ‘Tubes shall be at least BWG 12-gauge average ASTM A179 seamless carbon steel, without jointers, except as noted for Subsection B exchangers (acid vaporizers, acid superheaters, rerun overhead condensers). No extended-surface tubes, finned tubes, or twisted tubes are allowed in HF service. Work-hardening of tube bends shall be minimized, Exchangers in HF service on the tube side shall have I-inch minimum diameter tubes. Exchangers in HF service on the shell side shall have %inch minimum diameter tubes, shall have square pitch (or square pitch rotated 45 degrees) to facilitate mechanical and chemical cleaning, and shall have skid bars if the shell diameter is 40 inches or larger. Where carbon-steel tubes would not be satisfactory because of corrosive cooling water, 70-30 cupro-nickel tubes may be used. Admiralty-brass, Inconel®, or Incoloy® tubes shall not be used. ‘Tube-to-tube-sheet joints shall be step-rolled the full width of the tube sheet, less % inch measured from the shell side of the tube-sheet face, in accordance with TEMA RB-7.511. In no case shall the expanded portion of the tube HFA Specs Revision 04-2007Heat Exchangers Page 3 (BF Alkylation) 10. extend beyond the shell-side tube-sheet face. The “controlled-rolling” expansion method shall be used, with the desired tube-wall reduction between 4% and 6% of the original wall thickness. Strength-welding of tubes is allowed unless the shell side of the exchanger is in HF service. Strength-welding of tubes is preferred over seal-welding. Internal welds on the shell and/or channel and any external welds on the tube bundle shall be either continuous seal welds or full-penetration welds. Visible slag is not allowed on any internal (process-side) surface. The minimum size for all nozzles on heat exchangers shall be two inches. Nozzles installed on heat exchangers (excluding Subsection C exchangers) shall be ASME Class 300 raised-face weld-neck flanges with the nozzle necks made of HF-service pipe or plate (See Paragraph 18 below.). Nozzle necks shall have the same inside diameter as the weld-neck flanges. Gasket finish shall be either a serrated-concentric or serrated-spiral finish per ASME B16.5. Tube-sheet gaskets on the acid side of newer shell-and-tube exchangers without nubbins in the gasket-seal area can be Nickel-Copper-Alloy-400 double-jacketed gaskets with Grafoil® filler; Nickel-Copper-Alloy-400- Grafoil® spiral-wound gaskets (Metal inner rings with Grafoil® facing or encapsulation are preferred.); or Grafoil®-faced or Grafoil®-encapsulated corrugated Nickel-Copper-Alloy-400 gaskets. An equivalent flexible graphite material may be used in place of Grafoil®. Tube-sheet gaskets on the acid side of older shell-and-tube exchangers with nubbins in the gasket-seal area can continue to be ¥é-thick (3.2 mm) solid soft iron or low-carbon steel with a hardness of less than BHN-120 (HRB-68). Asbestos, asbestos-filled, or Teflon®-filled gaskets shall not be used. The corrosion allowance on the shell side of shell-and-tube exchangers in HF service shall be % inch (3.2 mm) minimum. Where HF service is on the tube side, a minimum of % inch (3.2 mm) corrosion allowance shall be provided for the channel and the channel cover. Cold-formed heads shall not be used unless they have been stress relieved as described in Section 1, Subsection A, Paragraph 6. Couplings installed in nozzles of heat exchangers for vents, etc., shall be kept to HFA Specs Revision 04-2007Heat Exchangers Page 4 (HF Alkylation) ul. 12. 13. 14, 15. 16. 1. 18. a minimum and shall be %inch minimum 60004 forged-steel full couplings made of ASTM A234 Grade WPB or A420 WPL 6 with Supplement S78 of ‘ASTM A960, installed in accordance with ConocoPhillips Drawing No. HF- 1008, Built-up bosses that have been drilled and tapped, half-couplings, and ‘Weldolets® shall not be used. See Paragraph 12 for the sole exception to this requirement. Plugs installed in couplings on HF-service heat exchangers shall be hexagonal plugs at least 3 inches (75 mm) long made of solid carbon steel bar stock. All plugs shall be installed with heavy-duty industrial-grade (extra-dense) Teflon® ‘Tape (Federal Process Company Thred-Tape® or equal). See Section 6, Subsection C, Paragraph 15. ‘Acid coolers shall have no couplings or chemical-cleaning nozzles installed on the shell side, Exchangers with cooling water on the tube side shall be of the AEU type, with removable channel covers. ‘A double tube sheet is required if the pressure on the cooling-water side or steam side of an exchanger is not maintained below the minimum operating pressure on the HF-service side. ‘Tie rods shall be threaded into the tube sheet with Teflon® tape covering the threads. Welding on the tube shect is allowed only for installation of skid bars and as required for RODbaffle exchangers. When the shell side is in HF service, all carbon steel material to be welded shall have a maximum carbon equivalent of 0.43 (See Paragraph 23). ‘Stab-in reboilers should be of the A-U type or B-U type with threaded tube sheets. Feed-to-bottoms exchangers and steam reboilers should be of the AEU type or BEU type with threaded tube sheets. Forged-stee! nozzles and shell flanges shall be ASTM A105 with Supplement 62 of ASTM A961, normalized or normalized-and-tempered forgings with added controlled chemistry per Paragraph 1 above. Forged flanges are also allowed per ASTM A350-LF2 with Supplement S62 of ASTM A961. Slip-on flanges are prohibited for shell-and-tube exchangers in Subsection A. For HEA Specs Revision 04-2007Heat Exchangers Page 5 (HF Alkylation) 19. 20. 2. 22. design minimum temperatures less than -20°F (-29°C), nozzles shall be constructed per ASME VIII, Division I. For design minimum temperatures - 20°F (-29°C) or greater, nozzle necks shall comply with the HF-service piping specifications in Section 6. Exchangers in HF service on the shell side shall have vertically-cut baffle plates or shall be of RODbaffle design compatible with HF service. Longitudinal baffles shall not be used in HF-service exchangers. Exchanger deflector plates shall be fully seal-welded to the bundle skeleton rather than to the exchanger shell. ‘The outside edges of all flanges and tube sheets and all screwed fittings shall be painted with Hydrofluoric Acid Detection Paint. To allow detection of paint color changes resulting from exposure to HF, these painted connections shall not be insulated. For paint suppliers, see Section 10, Subsection H. See Section 10, Subsection A, Paragraph 2 for low-residual-clements caution for selection of carbon steel materials. ‘The formula for carbon equivalent (CE) is shown in Section 10, Subsection A, Paragraph 1. HFA Specs Revision 04-2007Heat Exchangers Page 6 (HF Alkylation) B. Acid Vaporizer, Acid Superheater, and Rerun Overhead Condenser ‘Acid vaporizers, acid superheaters, and rerun overhead condensers shall comply with all HF-service specifications for shell-and-tube exchangers shown in Subsection A with the following exceptions: 1. These exchangers shall be BEU exchangers with double tube sheets. The tube- bundle surface area shall be based on a maximum heat-transfer rate of 50 BTU/hour/square foot/*F. ‘Tube bundles for the acid vaporizers and acid superheaters shall be four-pass or six-pass bundles of symmetrical design such that the bundles can be rotated 180 degrees to extend bundle life. Tube-side velocity for acid vaporizers and acid superheaters shall be limited to 50 feet per second (15 meters per second). Tube-side exchanger inlet velocity and tube inlet velocity for rerun overhead condensers shall be limited to 25 feet per second (7.6 meters per second). ‘Copper-Nickel-Alloy or Teflon® ferrules are required in the tube inlets. 2, Materials of construction are as follows: Tubes: One-inch 12 BWG ASTM BI163 seamless Nickel-Copper-Alloy-400 tubing, without jointers. Shell: Carbon steel: ASTM A516 Supplement S54, ASTM A537 Class 1 with Supplement $54 of ASTM A516 carbon steel, or ASTM A350 Grade LF2 with Supplement $62 of ASTM A961 per Subsection A, Paragraph 1. All welds shall have a maximum weld hardness of BHN-200 (HRB-94), Double Tube Shee Solid Nickel-Copper Alloy 400 on the tube side (a side), with “inch (3.2 mm) minimum corrosion allowance. The shell-side tube sheet shall conform to all HF-service shell-and-tube-exchanger specifications detailed in Subsection A, Paragraph 1, regardless of the fluid on the shell side. The double tube sheet shall be drilled and tapped ¥-inch NPT bottom and top for vent and drain connections, The vent connection shall be plugged and the drain connection shall be left open. HFA Specs Revision 04-2007Heat Exchangers Page 7 (HF Alkylation) Channel, Channel Cover, and N Solid Nickel-Copper Alloy 400 with a minimum of %-inch (3.2 mm) corrosion allowance, or Nickel-Copper-Alloy-clad carbon steel. If carbon-steel slip-on flanges are used, the entire gasket surface of each nozzle flange and channel flange shall be undercut and the undercut surface overlaid with a pure-nickel butter layer (using consumables such as ERNi-1), which is then followed by a minimum of two layers of ENiCu-7 or ERNiCu-7 weld deposit. After machining to proper dimensions, there shall be 2 continuous Nickel-Copper-Alloy-400 surface exposed to the process containing a maximum of 5 wt % iron. Only the top layer of Nickel-Copper ‘Alloy 400 should be exposed to the process. The minimum finished thickness of the nickel plus Nickel-Copper-Alloy-400 overlay shall be 3/16 inch (4.8 mm), or as required to limit the iron content of the finished surface to 5 wt %. Nickel-Copper-Alloy-400-faced carbon-steel slip-on flanges shall meet HF-service piping specifications (Section 6) for carbon equivalent and for vanadium plus niobium (columbium) content, but they need not meet any recommended limitations on nickel plus copper content. Nickel-Copper- Alloy-400-faced slip-on flanges are to be seal-welded on the inside. If they are also seal-welded on the outside, the cavity must be vented to the atmosphere. Nickel-Copper-Alloy-400-clad ASTM AS16 carbon steel may be used for the channel and channel cover, provided % inch (3.2 mm) minimum Nickel- Copper-Alloy-400 cladding is used, and provided the requirements above for corrosion allowance and for nozzle-flange and channel-flange facing are met. Couplings installed in channel nozzles shall comply with Subsection A, ickel-Copper Alloy 400 with plugs made of solid Nickel-Copper-Alloy-400 bar stock. Paragraph 10, except that they shall be made of } HFA Specs Revision 04-2007Heat Exchangers Page 8 (HF Alkylation) Channel-to-Tube-Sheet Gask For newer exchangers without nubbins in the gasket-seal area, use Nickel- Copper-Alloy-400 double-jacketed gaskets with Grafoil® filler; Nickel: Copper-Alloy-400-Grafoll® spiral-wound gaskets (Metal inner rings with Grafoil® facing or encapsulation are preferred.); or Ys-inch thick Grafoil®- faced or Grafoil?-encapsulated corrugated Nickel-Copper-Alloy-400 gaskets of the Kammprofile® type. An equivalent flexible graphite material may be used in place of Grafoil®. For older exchangers with nubbins in the gasket seal area, solid soft annealed Nickel-Copper-Alloy-400 gaskets of %-inch (3.2 mm) minimum thickness can continue to be used. Shell-to-Tube She sasket: For newer exchangers without nubbins in the gasket-seal area, use spiral- wound gaskets compatible with cooling water or heating medium. For older exchangers with nubbins in the gasket-seal area, solid or corrugated soft-iron or low-carbon steel gaskets of %-inch (3.2 mm) minimum thickness and with a hardness of less than BHN-120 (HRB-68) can continue to be used. 2. The outside edges of all flanges and tube sheets and all screwed fittings shall be painted with Hydrofluoric Acid Detection Paint, To allow detection of paint color changes resulting from exposure to HF, these painted connections are not tobe insulated. For paint suppliers, see Section 10, Subsection H. 3. See Section 10, Subsection B, for a materials. ting of acceptable Nickel-Copper Alloy 4. See Section 10, Subsection A, Paragraph 2 for low-residual-clements caution for selection of carbon steel materials. HFA Spees Revision 04-2007Heat Exchangers Page 9 (AF Alkylation) C. Double-Pipe or Mutti-tube Hairpin Exchangers Brown Fintube (or equal) double-pipe exchangers may be used where practical in HF service. ‘Tubes shall be bare (finless) seamless carbon steel 12 BWG ASTM A179, or ASTM A524, or ASTM A106 Grade B, or Nickel-Copper-Alloy-400 ASTM B163 UNS N04400 tubes conforming to HF-service piping specifications (Section 6). Shells shall be of seamless carbon steel, ASTM A524 or ASTM ‘A106 Grade B, conforming to HF-service piping specifications (Section 6). The tube-to-shell and the tube-to-piping closures shall be separate and shall have separate bolting, with a minimum of four bolts. ‘The shell side shall have 2-inch minimum ASME Class 300 raised-face flanged connections conforming to HF-service piping specifications (Section 6). Gaskets on all ASME Class 300 raised-face flanges in HF service shall be ‘Nickel-Copper-Alloy-400-Teflon® spiral-wound gaskets (up to 400°F, or 204°C) ‘or Nickel-Copper-Alloy-400-Grafoil® spiral-wound gaskets fabricated to ASME 16.20 dimensions. For protection of the flange face exposed to the process, expanded-Teflon® inner rings or metal inner rings with either Teflon® or Grafoil® facing or encapsulation are preferred (Flexitallic” Style CGI, Lamons Spira-Seal® WRI, or Garlock FlexSeal® Style RWI. Others require qualification). Virgin Teflon® is recommended for gasket assembly. An equivalent flexible graphite material may be used in place of Grafoil”. End-plate gaskets (return-bend gaskets) are preferred to be Y-inch (3.2 mm) minimum solid soft-iron or low-carbon-steel gaskets with a hardness of less than BHN-120 (HRB-68) (No exceptions). Tube-side gaskets shall be solid soft-iron gaskets, or low-carbon-steel gaskets, or spiral-wound Nickel-Copper-Alloy-400-Teflon® or Nickel-Copper-Alloy- 400-Grafoil® gaskets as described above. 2, Brown Fintube multi-tube exchangers (or equal) may be used where practical in HF service, provided they have the separate head closure, Carbon-steel tubes shall be BWG 12-gauge average ASTM A179 tubes, without jointers. Carbon-steel tube sheets shall be used with carbon-steel tubes. HFA Specs Revision 04-2007Heat Exchangers Page 10 (HF Alkylation) Nickel-Copper-Alloy tubes shall be BWG 12-gauge average ASTM B165 UNS 104400 tubes, without jointers. Nickel-Copper-Alloy tube sheets shall be used with Nickel-Copper-Alloy tubes. ‘Tubes smaller than %-inch shall not be used. Tubes shall be bare (finless). Shells shall be seamless carbon steel, ASTM A524 or ASTM A106 Grade B, conforming to the HF-service piping specifications (Section 6). ‘The tube-to-shell and tube-to-piping closures shall be separate and shall have separate bolting, with a minimum of four bolts. ‘The shell side shall have 2-inch minimum ASME Class 300 raised-face flanged connections conforming to the HF-service piping specifications (Section 6). Gaskets used with ASME Class 300 raised-face flanges shall be as described above in Paragraph 1. 3, Forged-steel weld-neck nozzles and shell flanges in HF service shall be of ASTM A350 or ASTM A105 normalized or normalized-and-tempered flanges meeting HF-service piping specifications (Section 6). Slip-on flanges are permitted for Subsection C exchangers, provided they are seal-welded on the inside, If slip-on flanges are also seal-welded on the outside, the cavity shall be vented to the atmosphere. Nozzle necks shall be made of HF-service pipe as noted in Paragraph 1 for shell fabrication. 4. Welds in the HF-service side of double-pipe and multi-tube exchangers shall have a maximum hardness of BHN-200 (HRB-94). Shell longitudinal and circumferential welds and nozzle welds shall be full-penetration welds and shall be fully radiographed. 5, Double-pipe and multi-tube exchangers shall have a minimum diametrical clearance between baffles and shell of % inch (6.4 mm). 6. Multitube exchanger tube-to-tube-sheet joints shall be expanded. Strength welding of tubes is allowed except when the shell side of the exchanger is in BF service. Strength welding of tubes is preferred over seal welding. 7. Double-pipe hairpin exchangers are recommended for use as stripping isobutane heaters and defluorinator heaters. Multi-tube hairpin exchangers are not recommended for these services. HFA Specs Revision 04-2007Heat Exchangers Page 11 (HF Alkylation) 8, The outside edges of flanges and closures and all screwed fittings shall be painted with Hydrofluoric Acid Detection Paint. To allow detection of paint color changes resulting from exposure to HF, these painted connections are not to be insulated. For paint suppliers, see Section 10, Subsection H. 9. See Section 10, Subsection B, for a table listing acceptable Nickel-Copper Alloy materials. 40, See Section 10, Subsection A, Paragraph 2 for low-residual-clements caution for selection of carbon steel materials. HFA Specs Revision 04-2007Heat Exchangers Page 12, (HF Alkylation) D. 9 COOLERS AND CONDENSERS HF-tervice air coolers and condensers are shown on the process flowsheets where required. ‘Tubes shall be J-inch, 12-gauge average minimum thickness, ASTM A179 ‘carbon steel, without jointers, covered with tension-wound fins, ‘Tube sheets and header boxes shall be fabricated of ASTM A516, A537, oF 'A350 carbon steel per Subsection A, Paragraph 1. Corrosion allowance on the HF side shall be % inch (3.2 mm) minimum. Header boxes shall be equipped with solid removable plate covers (not plugs) for cleaning purposes. Closure bolting shall be ASTM A193 Grade B-7 continuous-threaded stud bolts with carbon-stecl hex nuts, ASTM A194 Class 2H. Header-box gaskets shall be solid or corrugated soft iron or low-carbon steel with a hardness of less than BHN-120 (HRB-68). Asbestos, asbestos-filled, or Teflon®-filled gaskets shall not be used. The minimum size for nozzles on header boxes shall be 2 inches. Nozzles shall be forged-steel ASME Class 300 raised-face flanges meeting HF-service piping specifications (Section 6), Nozzle necks shall be of the same inside diameter as the flanges and shall be fabricated of seamless pipe meeting HF-service piping specifications. Couplings welded into header boxes for vents and drains shall be %inch~ minimum-size 6000# full couplings made of ASTM A234 Grade WPB or A420 WPL 6 with Supplement S78 of ASTM A960 and installed in accordance with ConocoPhillips Drawing No. HF-1008. The notch shown on that drawing shall be provided for all drain installations. Vent valves and drain valves shall be plugged with hexagonal plugs at least 3 inches (75 mm) long made of solid carbon steel bar stock and installed with heavy-duty industrial-grade (extra- dense) Teflon® tape (Federal Process Company Thred-Tape” or equal). See Seetion 6, Subsection C, Paragraph 16. Welds in air coolers and condensers shall have a maximum hardness of BHN- 200 (HRB-94). The outside edges of flanges and all serewed fittings shall be painted with HFA Specs Revision 04-2007Heat Exchangers Page 13 (HF Alkylation) Hydrofluoric Acid Detection Paint. To allow detection of paint color changes resulting from exposure to HF, these painted connections are not to be insulated. For paint suppliers, see Section 10, Subsection H. 10, See Section 10, Subsection A, Paragraph 2 for low-residual-clements caution for selection of carbon steel materials. ‘Any proposed deviations from the specifications detailed in Section 2 shall be submitted to ConocoPhillips, U. S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment, HFA Specs Revision 04-2007ECTION 3: _ FI HEATE! HESERVICE SPECIFICATIONS NOCOPHILLIPS HF A. TION PROCES! Heater design shall conform to normal engineering practices regarding insulation, wall construction, setting, tube supports, hangers, steam-out connections for the firebox, etc., and all necessary operating/maintenance appurtenances. Alloy tubes are not required in the heater. The tubes shall have @ Yeinch (3.2 mm) minimum corrosion allowance. Heater design loads shall be at least 125 percent of the normal operating load. The maximum allowed pressure drop through the reboiler heater shall be 30 PSI (2.1 Kg/em’), The heater shall be equipped with burners to fire gas or oil and shall have adequate pilot lights. ‘The heat flux density in the radiant section shall be limited to a maximum of 10,000 BTU/hour/square foot on the exposed surface at the design load. A John Zink special oil burner with series "ZOR" register, Drawing No. A-ST- 1046, shall be provided for burning acid-soluble oils (ASO) from the acid rerun column if incineration is the chosen manner of ASO disposal. The burner shall be floor-mounted. No asbestos, stainless-steel, or Ni ‘kel-Copper-Alloy-400-Teflon® gaskets shall be used in the reboiler cireuit. In this and other applications where resistance (o both high temperature and corrosion is required, Nickel-Copper-Alloy-400- Grafoil* spiral-wound gaskets shall be used (Flexitallic® Style CGI, Lamons Spira-Seal* WRI, or Garlock FlexSeal® Style RWI. Others require qualification). An equivalent flexible graphite material may be used in place of Grafoil*. See Section 6, Subsection C, Paragraph 10 for additional gasket recommendations, Stainless-steel thermowells shall not be used in the reboiler circuit.Fired Heater (HF Alkylation) Page 2 Any proposed deviations from the specifications detailed in Section 3 shall be Submitted to ConocoPhillips, U.S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment. HFA Specs Revision 04-2007— ae —— fees — oes JOHN ZINK COMPANY an mene {50 Ot BERSECTION 4; PUMPS AND DRIVERS ERY SPEC (CONOCOPHILLIPS HF ALKYLATION PROCESS A. General S) ns 1. Process pumps in hydrocarbon (non-acid) service shall be refinery process pumps designed specifically for the service. Maximum duplication of pumps within practical economic limits should be considered in order to minimize spare-parts requirements. The maximum number of pumps from one vendor is preferred. ‘Pumps shall conform to API Standard 610, 10" edition, or to API Standard 685, 1“ edition. Sealing systems shall conform to API Standard 682, 3" edition. 2, The rated capacity of all pumps shalll be at least 125 percent of normal operating capacity or should be the rated capacity set by the pump design summary sheet. ‘The discharge pressure of pumps at the rated capacity shall be based upon the pressure drop in the system at a flow rate equal to the rated capacity with control valves at 85% of maximum Cy. ‘The Best Efficiency Point (BEP) should be at or above the normal operating capacity but not above the rated capacity. 3. For initial operation, each pump shall be equipped with a temporary basket-type strainer located in the suction of the pump. This requires the use of a short spool piece between the suction-side block Ive and the pump suction nozzle. 4, Performance curves for all pumps shall be furnished by the contractor and should include: a. Capacity versus Head Curve Horsepower Curve Efficiency NPSH Curve Bid Impeller Diameter Tabulate Maximum Impeller Diameter meme eos Tabulate Minimum Impeller Diameter h. APT 610 data sheet. 5, Pump drivers shall conform to API 610, Section 6.1.Pumps and Drivers Page 2 (AF Alkylation) 6. In addition to the document requirements above, the contractor shall furnish cross-sectional drawings of pumps selected for HF service to ConocoPhillips for review and comment. The drawings shall show the materials of construction (including ASTM designations where applicable), details of Nickel-Copper- Alloy-400-overlaid surfaces, and clearances (case-to-cover, wear-ring, and throat-bushing), to be in accordance with the following HF-service pump specifications. Cross-sectional drawings showing materials of construction shall be furnished for all H¥F-service mechanical seals. The contractor shall make arrangements with the selected pump vendor to supply these drawings before the vendor begins fabricating the pumps. 7. The outside edges of all flanges and all screwed fittings for HF-service pumps shall be painted with Hydrofluoric Acid Detection Paint. To allow detection of paint color changes resulting from exposure to HF, these painted connections shall not be insulated. For paint suppliers, see Section 10, Subsection H. 8. Bolting on pressure joints for HF-service pumps shall be ASTM A193 Grade B- 7M continuous-threaded stud bolts with carbon-steel hex nuts, ASTM A194 Class 2H or ASTM A194 Class 2HM. ‘An acceptable alternative for bolting on pressure joints is Nickel-Copper Alloy K-500 (See Nickel-Copper-Alloy-K-00 stud-bolt specifications in Section 10, Subsection A, Paragraph 3). Nuts for Nickel-Copper-Alloy-K-500 stud bolts shall be carbon-steel hex nuts, ASTM A194, Class 2H. Internal bolting in contact with the pumped fluid shall be Nickel-Copper Alloy K-500 (See Nickel-Copper-Alloy-K-500 stud-bolt specifications in Section 10, Subsection A, Paragraph 3.). Nickel-Copper-Alloy-N04400, Nickel-Copper- Allloy-NO4405, or Nickel-Copper-Alloy-NOS500 hex nuts shall be used for internal bolting. _Nickel-Copper-Alloy-NOS500 nuts shall have a maximum hardness of HRC-30. Nickel-Copper Alloy K-500 is resistant to corrosion from HF, but can crack if overstressed while exposed to HF and oxygen. Proper tensioning procedures shall be used and overstressing should be avoided when using K-500 bolts. HFA Specs Revision 04-2007Pumps and Drivers Page 3 (HF Alkylation) B. API 610 Pumps (With Mechanical Shaft Seals) 1. Type: Conventional pumps in HF service shall be horizontal process pumps with radially (vertically) split cases. Although ConocoPhillips considers top suction and discharge nozzles desirable for HF-service pumps because of accessibility and pipe-stress considerations, pumps with top suction are not required. Wherever possible, single-stage overhung pumps shall be used. Large impellers shall meet API shaft-deflection requirements as outlined in API 610, 10" edition, Section 5.6.9. For large impeller sizes, double-suction designs, or 2-stage pumps, between- bearings pumps should be considered. Mechanical-seal flush requirements will be greater for a between-bearings pump than for an overhung pump because two seal chambers will be flushed instead of one. 2. Pressure Casing (Case and Cover): ASTM A216 WCA or WCB with Supplement S16.2, The gasket-fit area between case and cover shall be undercut and the undercut surface overlaid with a pure nickel butter layer (using consumables such as ERNi-1), which is then followed by a minimum of two layers of ERNiCu-7 or ENiCu-7 weld deposit. After machining to proper dimensions, there shall be a continuous Nickel-Copper- Alloy-400 surface exposed to the process. Only the top layer of Nickel-Copper Alloy 400 shall be exposed to the process. The minimum finished thickness of the nickel plus Nickel-Copper-Alloy-400 overlay shall be % inch (3.2 mm), or as required to limit iron in the finished surface to 5 wt Case fit shall be a metal-to-metal joint with clearance of approximately 0.003 inch (0.08 mm) and shall be on the atmospherie side of the gasket. On the fluid side of the gasket, the case-to-cover clearance shall be a minimum of % inch (3.2 mm) in any areas not overlaid with Nickel-Copper Alloy 400. Case-to-drum fit areas on double-suction or two-stage pumps shall be undercut, overlaid with Nickel-Copper-Alloy-400 weld deposit as described above, and remachined to proper dimensions. No external bolting of internal case or drum components is allowed (j.e., bolt- HEA Specs Revision 04-2007Pumps and Drivers Page 4 (HF Alkylation) through features are not allowed). Case-to-cover gaskets for newer-style pumps designed for them shall be Nickel- Copper-Alloy-400-Teflon® or Nickel-Copper-Alloy-400-Grafoil® spiral-wound gaskets (Flexitallic®, Lamons Spira-Seal®, or Garlock FlexSeal®). Virgin Teflon® is recommended. For temperatures above 500°F (260°C), only Nickel-Copper- Alloy-400-Grafoil® spiral-wound gaskets shall be used. An equivalent flexible graphite material may be used in place of Grafoil®. Case-to-cover gaskets for old-style pumps designed for them can continue to be solid soft-iron or low-carbon-steel gaskets with a hardness of less than BHN-120 (HRB-68). 3. Impeller: Nickel-Copper Alloy 400. The impeller nut and locking devices shall be Nickel- Copper Alloy K-500. The impeller shall be keyed to the shaft with a Nickel- Copper-Alloy-K-500 key. 4, Wear Rings: ‘Case Wear Rings: Nickel-Copper Alley 400 with ERNiCr-C or ENiCr-C (Colmonoy #6) facing. Case wear rings shall be attached to the case by spot-welding or with Nickel Copper-Alloy-K-500 set screws (Allen-head or slotted-head). The area under the ring shall be overlaid as described for the pressure casing in Paragraph 2 above. Impeller Wear Rings: ERNiCr-C or ENICr-C (Colmonoy #6) overlay on the Nickel-Copper-Alloy-400 impeller or Nickel-Copper-ANloy-400 wear ring with ERNiCr-C or ENiCr-C (Colmonoy #6) overlay. Impeller wear rings shall be attached to the impeller by spot-welding or with Nickel-Copper-Alloy-1 500 set screws (Allen-head or slotted-head). Maintain at least a 100-BHN difference between case and impeller wear rings. Wear-Ring Clearance: 0.025 inch to 0.030 inch (0.64 mm to 0.76 mm). 5. Shaft: Nickel-Copper Alloy K-50 with a maximum hardness of HRC-30. HFA Specs Revision 04-2007Pumps and Drivers Page 5 (HF Alkylation) Shaft Sleeves: Nickel-Copper Alloy 400. The mechanical-seal shaft sleeve shall be one piece, extending from the throat bushing through the mechanical-seal gland plate. ‘Shaft-Sleeve Gasket: Shaft-sleeve gaskets for new-style pumps shall be Kalrez” or Chemraz” O-ring gaskets, Shaft-sleeve gaskets for old-style pumps can continue to be solid soft- iron or low-carbon steel gaskets with a hardness of less than BHN 120 (HRB-68). 6. Two-Stage Pumps Stage Bushing: ‘The stage bushing (or the intermediate bushing between stages) shall be made of age-hardened beryllium copper or bearing bronze (SAE No. 660) with a 0.015- inch (0.4 mm) clearance between bushing and shaft. Equalizing Lines: Equalizing lines on two-stage between-bearings pumps shall at a minimum be of Yeinch ASTM A106 Grade B seamless carbon-steel pipe with 3,000# forged-steel screwed fittings. All equalizing lines shall be self-draining. All piping shall be screwed but shall not be seal-welded. All joints are to be made up using heavy- duty industrial-grade (extra-dense) Teflon® tape (Federal Process Co. Thred- Tape® or equal.) No other type of pipe-joint compound shall be used. Equalizing line components shall meet HF-service piping specifications (Section 6. 7. Case Vents, Drains, Ete.: Connections for case vents, bleeders, pressure gauges, ete., shall not be drilled and tapped into the pump case. These connections shall be provided in the suction and discharge piping. If a ease drain is needed, it shall be %-inch minimum size threaded Schedule 80 HF-service pipe (See Section 6, Subsection B, Paragraph 4 and Section 6, Subsection C.), Internal overlay of the casing in the case drain area per Section 4, Subsection B, Paragraph 2, is recommended. Because on-line inspection of this installation is difficult, these threads and associated screwed drain fittings should be inspected whenever the pump is overhauled. Vent valves and drain valves shall be plugged with hexagonal plugs at least 3 HFA Specs Revision 04-2007Pumps and Drivers Page 6 (HF Alkylation) inches (75 mm) long made of solid carbon steel bar stock and installed with heavy-duty industrial-grade (extra-dense) Teflon® tape (Federal Process Company Thred-Tape® or equal). See Section 6, Subsection C, Paragraph 16. HFA Specs Revision 04-2007Pumps and Drivers Page 7 (HF Alkylation) C. Mechanical Shaft Seals 1. Mechanical Seals: ‘Mechanical seals shall be Jobn Crane Type 8BI, Code X11F31MPS58M or equal (Gee Subsection H, Listed Mechanical Seals). Hard-face materials shall be limited to nickel-binder tungsten carbide, or alpha-sintered silicon carbide. Carbon faces shall be limited to John Crane 8175, Union Carbide AUT-72, or Morganite EY-9106C. Elastomeric O-rings are limited to Kalrez® or Chemraz®. Metal component parts of the seal shall be Nickel-Copper Alloy. 2. Mechanical-Seal Gland P' ‘The gland plate shall be Nickel-Copper Alloy 400. The gland plate shall be drilled and tapped %-inch NPT on the top vertical centerline for the flush connection. A Yinch NPT drain from the quench area shall be drilled and tapped on the bottom vertical centerline. The gland plate shall be fitted with @ bronze throttle bushing and fitted with an auxiliary gland plate packed with braided Teflon®. Gland-Plate Gasket: The gland-plate gasket shall be Kalrez® or Chemraz* O-ring. 3. Throat Bushing: ‘The area under the throat bushing shall be overlaid with Nickel-Copper Alloy 400 as described above for the pressure casing (Subsection B, Paragraph 2). ‘Throat-Bushing Clearance: 0.025 inch to 0.030 inch (.64 mm to .76 mm). HFA Specs Revision 04-2007Pumps and Drivers Page 8 (HF Alkylation) D. Reboiler Circulation Pumps Although the reboiler circulation pumps are considered to be in non-acid service, these pumps may occasionally be exposed to HF. ‘The pumps shall be horizontal process pumps with radially (vertically) split cases and top suction and discharge nozzles. The case, cover, and impeller shall be low-carbon cast stecl, ASTM A216 Grade WCA or WCB. ‘The wear rings may be Nickel-Copper Alloy K-500 or carbon steel overlaid with ERNICr-C or ENiCr-C (Colmonoy #6). ‘The pump shaft may be AISI 4140 with a maximum hardness of HRC-22. ‘The mechanical seal, mechanical-seal shaft sleeve, mechanical-seal shaft sleeve gasket, mechanical-seal gland plate, gland-plate gasket, and case-to-cover gasket shall be the same as required on HF-service pumps. Each pump shall be equipped with an individual pump-flush cooler, a ¥-strainer, a restrictive orifice, two %-inch HF-service gate valves for isolating the pump-flush system, and one Yinch HF-service gate valve drain. Stainless steel or chromium- alloyed steel shall not be used for the pump-flush cooler or associated piping. ‘The seal-flush piping shall be %-inch minimum size and shall meet all HF-service piping specifications (Section 6). Vent valves and drain valves shall be plugged with hexagonal plugs at least 3 inches (75 mm) long made of solid carbon steel bar stock and installed with heavy-duty industrial-grade (extra-dense) Teflon® tape (Federal Process Company Thred- ‘Tape® or equal). See Section 6, Subsection C, Paragraph 16. ‘The contractor shall furnish cross-sectional drawings for these pumps and their mechanical seals as required for HF-service pumps in Subsection A, Paragraph 6 above. HFA Specs Revision 04-2007Pumps and Drivers Page 9 (HF Alkylation) E. ASO Pump ~- Additional Specifications 1. Shaft Sleeves: Do not use shaft sleeves if the pump is equipped with stuffing box and packing. 2. Throat or Insert St Box: Pumps shall be equipped with a stuffing box and packing rather than mechanical seals. The throat bushing shall be Nickel-Copper Alloy 400 and shall be attached to the case cover with Nickel-Copper-Alloy-K-500 stud bolts and Nickel-Copper-Alloy-K-500 nuts. Clearance shall be 0.020 - 0.025 inch (0.51- 0.64 mm). 3. Stuffing Box: Stuffing boxes shall be extra-deep and arranged for water cooling. Stuffing boxes shall be long enough for a minimum of seven rings of %-inch packing and also allow for a minimum throat-bushing length of 2 % inches (68.9 mm). The packing gland shall be of carbon stee! with a brass bushing. Pump Packing: Rings numbered from the throat bushing, RingNo. _Type of Packing Teflon® (solid ring) Garlock #934 or equal Garlock #934 or equal Crane #896, Crane #2 Superseal, or equal Lantern gland Crane #896, Crane #2 Superseal, or equal Garlock #934 or equal Garlock #934 or equal ea Ane wen HFA Spees Revision 04-2007Pumps and Drivers Page 10 (HF Alkylation) E__API 685 Pumps (Sealless) Sealless pumps in HF service shall conform to API 685, “Sealless Centrifugal Pumps for Petroleum, Heavy Duty Chemical, and Gas Industry Services”. If a licensee wishes to use a sealless pump instead of an API pump, ConocoPhillips can assist in selecting a pump. 1, Magnetic-Drive Pumps (MDP) ConocoPhillips recognizes that Magnetic-Drive Pumps are being used to reduce the risks of toxic and volatile emissions. ConocoPhillips does not have enough experience with this type of pump to recommend features and styles. Beeause of the slightly magnetic nature of Nickel-Copper alloy, the containment shell of a Magnetic-Drive Pump for HF service should be Hastelloy® C276. Some Magnetic-Drive Pumps are now being offered with secondary containment at the outer magnetic assembly driveshaft. 2. Canned-Motor Pumps (CMP) ConocoPhillips recognizes that Canned-Motor Pumps are being used to reduce the risks of toxic and volatile emissions. ConocoPhillips does not have ‘enough experience with this type of pump to recommend features and styles. Any proposed deviations from the specifications detailed in Section 4 shall be submitted to ConocoPhillips, U. S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment. HFA Specs Revision 04-2007Pumps and Drivers Page 11 (HF Alkylation) G. Listed Pumps HF-service pumps are specially-modified API-type centrifugal pumps. The following models have been successfully modified for HF Service. The contractor shall make arrangements with the selected pump vendor to supply cross-sectional drawings of both pumps and seals for ConocoPhillips’ review prior to vendor's commencing fabrication of pumps (See Subsection A, General Specifications, Paragraph 6.). Non-HF-service pumps may be specified according to refinery preference. 1. Single-Stage Overhung Pumps Flowserve HPX Type HPXM Type BWIP "SC-7" Wilson-Snyder "ESN" Dresser"SVC" Ingersol Rand "A" Sulzer "OHH" David Brown Union "HHS" Goulds 3700 2. Between-Bearings Single-Stage Pumps Flowserve HDX Type BWIP "DVSHF" BWIP "DSJH" Sulzer "CDA" David Brown Union "HOL" HFA Specs Revision 04-2007Pumps and Drivers Page 12 (HF Alkylation) 3. Between-Bearings Two-Stage Pumps Flowserve HED-DS Type BWIP "THF" or "DSTHF" BWIP "GSJH" Sulzer CJ-DB or CMA David Brown Union "HOS" (3-piece-case-cover-type only) HFA Specs Revision 04-2007Pumps and Drivers Page 13, (HF Alkylation) H. Listed Mechanical Seals The single seals listed below have given successful service in HF alkylation service with API 610 Plan 32 flush for all HF-service pumps except for the reboiler circulation pump, for which Plan 41 should be used. 1. Single Seals John Crane ‘Type 8B1 with Segmented Bushing Code: X11F31MO58M Flexibox* RRESLIR Codes: XXXX-XXSS-MBPQK * Confirm seal/application compatibility with manufacturer before ordering. Flowserve Borg-Warner Type "U" Partial Code 7MTY. Specify AUT 72 carbon, silicon-free Stellite® faces, and Kalrez® or Chemraz® O-ring gaskets. 2. Double Seals If dual seals are desired or required, the dual (tandem) seals, dual unpressurized seals, or dual pressurized seals listed below should give good service in HF service. Even if flush to 2 dual-seal system is not required by the pump vendor, an external flush system must be used when there is HF in the unit to keep HF from contacting the seals of idle pumps. John Crane ‘Type 8B1/28LD with segmental bushing (dual un-pressurized) Code: X11F31MPS8M (X11058MO58M required for short primary seal) ‘Type SBIRP/SB1 or 8B1 Double (dual pressurized) ‘Code: X11F31MO58M Flexibox ‘Type DRSM Code: XXXX-XXSS-WMBPQK —Elowserve Borg-Warner Tandem Type “T BX QW” Partial Code 7M7Y. Specify AUT 72 carbon, silicon-free Stellite faces, and Kalrez® or Chemraz* O-ring gaskets. HFA Specs Revision 04-2007DRILLED AND TAPPED 3/4” NPT INTO LOWER PORTION OF ' CHECK VALVE COVER. 1 ATMOS. VENT/DRAIN 3/4" SCREWED PIPING, FITTINGS AND VALVES. INSTALL SO THAT SHORTEST POSSIBLE PIPING IS USED WHILE ALLOWING FOR ADEQUATE CLEARANCE FROM ALL OBSTACLES SO THAT, WITHOUT REMOVING VALVE BONNETS, VALVES MAY BE TIGHTENED (OR INSTALLED) BY SCREWING UP TO A FULL 360° ROTATION. PIPING ‘SHOULD CONTAIN NO UNIONS UPSTREAM OF FIRST VENT ‘VALVE(S). INSTALL SPECTACLE BLINDS SO THEY WILL NOT INTERFERE WITH THE CLEARANCE REQUIRED TO TIGHTEN SCREWED VALVES OR OTHER COMPONENTS AND SO THEY ARE NOT IN THE DIRECT PUMP DISCHARGE. PUMP SUCTION — DRILLED AND TAPPED 3/4” NPT INTO BOSS ON VALVE BODY BETWEEN BLOCK VALVE AND LOWER FLANGE. ATMOS. VENT/DRAIN ~~ TEMPORARY CARBON STEEL START UP STRAINER KEEP SPOOL PIECES AS SHORT AS IS PRACTICAL, PATH OF DISCHARGE FROM VENT/DRAIN. VALVES, ConoosPhillips ‘ALKYLATION PROCESS. TYPICAL LOCATION. OF BLOCK VALVE AND BLIND VENTS FOR PUMP REMOVAL DETAL NOs HF-2000 DATE WO 12/06SECTION 5: _ INSTRUMENTS AND CONTROLS HF SERVICE SPECIFICATIONS (CONOCOPHILLIPS HF ALKYLATION PROCESS A. GENERAL Instruments shown on the ConocoPhillips process flowsheets shall be considered to be in HF service unless they are specifically defined to the contrary. 2. Temperature- and pressure-seale spans should be kept as narrow as practical for maximum sensitivity, particularly for temperature or differential temperature controllers or recorders operating with narrow process limits. 3. Seamless copper tubing shall be used for transmission of all pneumatic control signals. Steam tracing of instruments in HF service is generally undesirable. HF-service instruments shall not contain stainless steel, alloyed steel, or asbestos components. 6. For several instruments, Nickel-Copper-Alloy-K-500 bolting is specified or allowed as an alternative (See the specifications for Nickel-Copper-Alloy-K-500 stud bolts in Section 10, Subsection A, Paragraph 3.), Nuts for Nickel-Copper- Alloy-K-500 stud bolts shall be carbon-steel hex nuts, ASTM A194, Class 2H. Nickel-Copper-Alloy-N04400, Nickel-Copper-Alloy-N04405, or Nickel-Copper- Allloy-N0S500 hex nuts shall be used for internal bolting. Nickel-Copper-Alloy- NO5500 nuts shall have a maximum hardness of HRC-30. Alloy K-500 is resistant to corrosion from HF but can crack if overstressed while exposed to HF and oxygen. Proper torquing procedures shalll be used, and overstressing should be avoided when using K-500 bolts. 7. Calculations for orifice plates and flow-meter runs, complete specifications, manufacturers’ detailed descriptions, drawings, and materials of construction for all process-control valves, relief valves, transmitters, and any other instrumentation in HF service shall be sent by the contractor to ConocoPhillips Company as early as practical for review and comment. 8 Pipe and fittings used to install HF-service instruments or control valves shall meet HF-service piping specifications (Section 6). 9. Instrument vent valves and drain valves shall be plugged with hexagonal plugs at least 3 inches (75 mm) long made of solid carbon steel bar stock and installedInstruments and Controls (AF Alkylation) Page 2 with heavy-duty industrial-grade (extra-dense) Teflon® tape (Federal Process Company Thred-Tape” or equal). See Section 6, Subsection C, Paragraph 16. The outside edges of all flanges and all screwed fittings shall be painted with Hydrofluoric Acid Detection Paint, To allow detection of paint color changes resulting from exposure to HF, these painted connections shall not be insulated. For paint suppliers, see Section 10, Subsection H. 10. HFA Specs Revision 04-2007Instruments and Controls Page 3 (HF Alkylation) B. FLOW MEASUREMENT Measurement of the flow rate of any process stream in HF service should be accomplished by using an orifice plate with a differential-pressure flow transmitter. Specifications for orifice flow-meter runs are as follows: Orifice-plate material: _Nickel-Copper Alloy 400 Orifice-plate bore: Concentric Orifice-plate "Nickel-Copper Alloy 400" and bore identification: diameter stamped on plate tab Flange material: Refer to piping specifications (Section 6) Flange-tap size: Yeinch NPT Flange-tap valves: Refer to piping specifications and ConocoPhillips Drawing No. HF-1005 Specifications for differential-pressure flow transmitters are as follows: Body material: Low-carbon steel Bolting: Nickel-Copper Alloy K-00 Diaphragm: Nickel-Copper Alloy 400 Vents: Yeinch NPT Nickel-Copper Alloy 400 Drai Yeinch NPT Nickel-Copper Alloy 400 Gasket material Kalrez® or Chemraz® Differential-pressure flow transmitters for determining liquid flows in horizontal meter runs shall be installed in an upright position at a point 3 inches (75 mm) above the centerline of the orifice-flange taps. The piping from the orifice-flange valves to the flow transmitter shall be as short as practical, Meter runs for vapor flow measurement shall be in vertical lines. Flow-transmitter installations shall be self draining to eliminate problems experienced when a separate phase of HF forms in the flow-transmitter piping. See ConocoPhillips Drawing No. HF-100S for the proper method of installation of an HF-service flow transmitter on a horizontal line. Flowmeter beta ratios and dP ranges shall be adjusted to give a minimum of 2-inch meter runs if at all possible. If a meter run of smaller size must be used, it shall be isolable with 2-inch Class 300 valves. HFA Specs Revision 04-2007Instruments and Controls. Page 4 (HF Alkylation) C. LIQUID LEVEL MEASUREMENT 1. GAUGE GLASSES: Neoflon™ PCTFE-shiclded gauge glasses shall be used where indicated on the ConocoPhillips process flowsheets. Neoflon™ PCTFE shields shall be at least .0625 inch (1.6 mm) thick. No other gauge glasses shall be installed in HF service. Gauge glasses are limited to four sections. Gauge-glass installations shall be self- draining and have a vent valve at the top of the assembly, a drain valve at the bottom of the assembly, and 2-inch block valves at the upper and lower process connections to allow isolation of the gauge glass from the process exclusive of any other instrumentation, See ConocoPhillips Drawing No. HF-1012 for a typical installation of gauge glasses in a bridle arrangement. ‘When more than one gauge glass is required, the gauge glasses may be connected to a 2-inch standpipe. The standpipe shall have a 2-inch block valve at each vessel connection. The gauge glasses shall each have %-inch (minimum) block valves for independent isolation and shall each have individual vent and drain valves. Piping for both top and bottom gauge-glass connections shall run horizontally to the vessel or standpipe, without pockets. Refer to ConocoPhillips Drawing No, HF-1008 in Section 6 for the acceptable method of welding %-inch 3000# couplings made of ASTM A234 Grade WPB or A420 WPL 6 with Supplement S78 of ASTM A960 to fabricate gauge-glass standpipes. For service above 338°F (170°C), gauge glasses shall be provided with cooling wells to limit gauge-glass temperature to 338°F (170°C). 2. LEVEL TRANSMITTERS AND LOCAL LEVEL CONTROLLERS: Preferred level transmitters and local controllers in HF service include: External displacement level transmitters, Interface level sensors with cast or fabricated steel float barrels and flanges, Nuclear level-measurement systems, ‘Magnetic level-indicating devices, Guided-wave radar level transmitters. Differential-pressure transmitters are also allowed to be used as level-indicating HFA Specs Revision 04-2007Instruments and Controls Page 5 (HF Alkylation) devices provided their diaphragms are gold-plated. The piping between the diaphragm flanges and the process vessel shall be horizontal runs of pipe with no pockets and shall be as short as possible. If displacement level transmitters are used, the float, linkages, torque tube, and all other wetted parts shall be Nickel-Copper Alloy. Restrictive or dampening orifices shall not be used. A steel barrel of the required length for each displacement level transmitter shall be fabricated using ASTM A105 flanges ‘with Supplement S62 of ASTM A961 or ASTM A350 Grade LF2 flanges with A961 Supplement S62. Welds on the float barrel and flanges shall be full- penetration welds. Welds on the fabricated float barrels shall have a maximum hardness of BHN-200 (HRB-94), The barrels shall have 2-inch ASTM Class 300 raised-face flanged connections. Pipe and fittings used for fabrication and installation shall conform to HF-service piping specifications (Section 6). Displacement level transmitter floats for hydrocarbon levels in overhead accumulators shall be 1 foot (305 mm) shorter than the vessel diameter, per ConocoPhillips Drawing No. HF-1001. Displacement level transmitters or local controllers located on the bottom of the acid rerun column shall have Nickel-Copper-Alloy-400 barrels and flanges. Gaskets on displacement level transmitters or local controllers shall be solid soft- iron or low-carbon-steel gaskets with a hardness of less than BHN 120 (HRB-63) or Nickel-Copper-Alloy-400-Teflon® spiral-wound gaskets (up to 400°F, or 204°C) or Nickel-Copper-Alloy-400-Grafoil® spiral-wound gaskets (Refer to Section 6, Subsection C, Paragraph 9.). Displacement level transmitters or local controllers shall be installed so they are absolutely plumb and self-draining to eliminate problems caused by the presence of a separate phase of acid. Level transmitters or local controllers shall have a vent valve at the top of the assembly, a drain valve at the bottom of the assembly, and 2-inch block valves at the upper and lower process connections to allow isolation of the transmitters from the process exclusive of any other instrumentation. See ConocoPhillips Drawing Nos. HF-1001, HF-1012, and HF- 1020 for typical level-transmitter installations. HFA Specs Revision 04-2007Instruments and Controls Page 6 (HF Alkylation) 3. LEVEL SWITCHES: Level switches shall be either nuclear level devices or external displacement level ‘sensors. See the specifications for external displacement float-barrel fabrication in the previous paragraph. RYCOCK COLUMNS: ‘Trycock columns shall be used for local liquid-level indication as indicated on the ConocoPhillips process flowsheets. Trycocks shall be %inch HF-service globe valves or plug valves. Refer to the HF-service piping specifications in Section 6 for suitable trycock valves. Refer to ConocoPhillips Drawing No. HF-1008 in Section 6 for the acceptable method of welding %-inch 3000# couplings made from ASTM A234 Grade WPB or A420 WPL 6 with Supplement S78 of ASTM A960 to fabricate trycock column standpipes. In certain applications (ie., on the acid rerun column, the ASO caustic washer, and the ASO surge drum), trycock valves are installed on individual nozzles instead of a standpipe. In these installations, a %-inch trycock valve is connected with a l-inch by %inch heavy swage to a 2-inch blind flange that has been drilled and tapped 1-inch NPT. A %-inch by %-inch tubing adapter (brass for the acid rerun column, and steel for the ASO caustic washer and ASO surge drum) connects the trycock tubing to the trycock valve. Trycock columns should be located so that there is a minimum of 5 feet of unobstructed area on either side of the trycock column and funnel (tundish) and 4 minimum of 3 feet of unobstructed area in front of the trycock column and funnel to allow for free operator movement. Trycock valves shall be within reach of operating personnel from a platform without the use of ladders or stools of any kind. Trycock funnels constructed per ConocoPhillips Drawing No. HF-1006 shall be located on each platform. Trycock funnels shall be located so that personnel operating any associated trycock valve can see the ends of the trycock tubing. ‘Trycock columns shall be constructed so that all trycock-valve stems are on top and vertical, or at least in the horizontal plane or above. Valves shall not be mounted upside down or with the stems below the horizontal plane, HFA Specs Revision 04-2007Instruments and Controls Page 7 (HF Alkylation) Trycock columns shall be installed with 2-inch block valves at top and bottom to allow isolation of the trycock columns from the process exclusive of any other instrumentation. ‘Trycock tubing shall be secured to tubing raceways with metal clamps, Trycock tubing shall be %inch seamless copper tubing (except on the acid relief neutralizer and the ASO caustic washer, where the trycock tubing shall be %- inch steel) and should not be covered with any insulating or protective material. Trycock tubing shall be cut so that the ends are %inch above the top edge of the trycock funnels. See ConocoPhillips Drawing Nos. HF-1001, HF-1002, and HF-1020 for typical trycock installations. HFA Specs Revision 04-2007Instruments and Controls Page 8 (HF Alkylation) D. PRESSURE MEASUREMENT 1, PRESSURE GAUGES: Forged-steel pressure gauges shall have Nickel-Copper-Alloy-K-500, Alloy 400, or Alloy 405 Bourdon tubes. The hardness of K-500 Bourdon tubes shall be limited to HRC-30, 2. PRESSURE TRANSMITTERS: Pressure transmitters shall have low-carbon steel bodies with Nickel-Copper- Alloy-K-500 bolting and all other wetted parts Nickel-Copper Alloy 400. Bolting of B7M is also allowed. 3. PRESSURE SWITCHES: Pressure switches shall have forged-steel process connections and Nickel Copper-Alloy-K-500, Alloy 400, or Alloy 405 Bourdon tubes. The hardness of K- 500 Bourdon tubes shall be limited to HRC-30. 4, FIELD-MOUNTED PRESSURE CONTROLLERS: Field-mounted pressure controllers shall have forged-steel or Nickel-Copper~ Alloy-400 process connections and Nickel-Copper-Alloy-K-500, Alloy 400, or Alloy 405 Bourdon tubes. The hardness of K-500 Bourdon tubes shall be limited to HRC-30. Field-mounted pressure controllers shall have indicating set-point and process- Pressure scales. 5. PI CONNECTIONS TO PRESSURE INSTRUMENTS: Each pressure instrument shall have a block valve between the instrument and the process. Block valves for instruments connected directly to HF-service vessels or to piping not isolable from an HE-service vessel with block valves shall be 2-inch minimum; otherwise a Y/-inch block valve is satisfactory. A %-inch vent valve shall be installed between each pressure instrument and its process-connection block valve. Process connections inch NPT are allowed for pressure instruments. Pressure-instrument installations shall be self-draining. HFA Specs Revision 04-2007Instruments and Controls Page 9 (HF Alkylation) E. TEMPERATURE MEASUREMENT Temperature-measurement points for local recording, or control shall be located as indicated on the ConocoPhillips process flowsheets. Each temperature transmitter shall have a corresponding independent temperature-indication (TT) checkpoint in the control room. 1. THERMOWELLS: ‘Thermowells used in HF service shall be 1-inch Nickel-Copper-Alloy-400 thermowells. Each thermowell installed in HF-service piping fully isolable from HF-service vessels and in heat-exchanger outlet nozzles shall be screwed into a 1-inch 6000# forged-steel full coupling made from ASTM A234 WPB or A420 WPL6 with ‘Supplement S78 of ASTM A960 that has been install a full-penetration weld in accordance with ConocoPhillips Drawing No. HF- 1008, Built-up bosses that have been drilled and tapped, half-couplings, and Weldolets® shall not be used for thermowell installations. Installation of additional thermowells in HF-service vessels or in piping not \dication, control-room indication, into the process line with isolable from those vessels with block valves is not recommended. Except for thermowells in couplings on the nozzles of heat exchangers complying with TEMA Class R Standards, thermowells located in HF-service vessels shall be installed by screwing the thermowell into a threaded 2-inch blind flange and seal-welding the thermowell to the flange on both sides. The internal seal weld shall be made by first overlaying the carbon steel surface to be seal-welded with a pure-nickel butter layer (using consumables such as ERNi-), then seal welding the thermowell to the nickel layer (using consumables such as ENiCu-7 or ERNiCu-7). The external seal weld can be a carbon steel weld. The assembly is then bolted to a 2-inch, ASME Class 300 raised-face nozzle using a spiral-wound Nickel-Copper-Alloy-400-Teflon® spiral-wound gasket (up to 400°F, or 204°C) or Nickel-Copper-Alloy-400-Grafoil® gasket. See Section 6, Subsection C, Paragraph 9 for additional gasket recommendations. This method of installation shall also be used for thermowells installed in fractionator overhead lines and reboiler vapor return lines that are not isolable from HF-service vessels with block valves. HFA Specs Revision 04-2007Instruments and Controls Page 10 (HF Alkylation) Because the risers and standpipes connecting the acid settler and acid cooler(s) are considered a part of the acid settler, thermowells on risers and standpipes shall also be installed in 2-inch flanged nozzles instead of couplings. ‘Thermowells are required on both outlets of all heat exchangers except where temperature indication is shown on the ConocoPhillips process flowsheets. ‘Thermowells located in fractionator downcomers shall be installed six inches (150 mm) above the tray deck. 2. TEMPERATURE ELEMENTS: Duplex temperature-element assemblies shall not be used. Instead, two independent temperature elements and thermowells shall be installed close to each other. ‘Temperature elements for recording or process-control purposes shall be independent of any temperature elements used for remote indication and/or logging purposes. 3. DIFFERENTIAL-' TI ME: MENT: Conventional single thermocouple or RTD assemblies shall be used for the measurement of differential temperatures. Differential-temperature measurements shall be made with two independent temperature elements connected to a differential-temperature transmitter. It is acceptable to use multiple temperature transmitters for shutdown systems that are actuated by differential temperature between multiple temperature measurement points. In the case of small differential-temperature measurement ranges, such as on a propane stripper (HF stripper), $00-ohm platinum resistance temperature elements shall be used. HFA Specs Revision 04-2007Instruments and Controls Page 11 (HF Alkylation) F. VALVES FOR PROCESS CONTROL, 1. GENERAL: Block valves used for instrument isolation or control-valve piping shall be gate valves or plug valves selected and installed according to the HF-service piping specifications (Section 6). Vent valves or drain valves used for instrument or control-valye piping shall be gate valves selected and installed according to the HF-service piping specifications. Bypass valves used for instrument or control-valve piping shall be globe valves selected and installed according to the HF-service piping specifications. 2. CONTROL VALVES: Control valves shall be globe-body valves or spe: ‘Nickel-Copper-Alloy trim, bonnet gaskets shall be solid soft-iron gaskets with a hardness of less than BHN 114 (HRB-64). Spiral-wound Nickel-Copper-Alloy-400-Teflon® (to 400°F or 204°C) or Nickel- Copper-Alloy-400-Grafoil® gaskets may be used on control-valve bonnet assemblies if the valves have specifically been designed to accommodate them. ° ly-designed plug valves with cluding seats, plugs, stems, and guides, Valve- An equivalent flexible graphite material may be used in place of Grafoi Control-valve packing for lower process temperatures can be chevron-type ° Teflon® continuous rings. Other packing options are Grafoil® (or an equivalent flexible graphite packing) or John Crane 124 packing, which should also be used for higher temperature service. The packing shall not be spring-loaded. Lantern rings are neither required nor desired. Any provision for lubrication of control-valve packing is unacceptable. The minimum diametrical clearance on control-valve lug guides and guide bushings is 0.020 inch (0.1 mm). The minimum diametrical clearance between the control-valve stem and the ‘opening into the packing box is 0.030 inch (0.76 mm). Control valves of odd sizes shall be avoided, The minimum control valve body size is 1-inch. A Micro-Flute®-type plug shall be used on all control valves requiring %-inch HFA Specs Revision 04-2007Instruments and Controls Page 12 (HF Alkylation) and smaller plugs. Control valves shall, in general, be selected for a pressure drop of not less than 25 percent of the system pressure drop at normal operating conditions, with a 10 PSIG (0.70 kg/cm?) minimum pressure drop at normal operating conditions. Control valves shall be sized such that the maximum capacity at design pressure drop is 30 percent greater than the normal required capacity and such that the control valve will be at no more than 85 percent capacity at maximum design process conditions. Control valves shall have positioners. Control valves shall be installed with block valves and a bypass globe valve and shall have a %inch gate valve drain installed on the downstream side of the control valve. Control valve bypasses shall be installed so that the bypass line(s) is self-draining to the process from both sides of the globe valve, If it is necessary to use a control valve with a body size less than 2 inches, eccentric swages are req |. The swaged transition pieces required to increase the pipe size to 2 inches shall be installed with the flat side down on either side of and as close as possible to the control valve. Flanged 2-inch block valves shall then be installed on either side of the control valve. The following acceptable body connections and methods of mounting are listed in order of preference: a, Full-penetration butt-welded connections, welded with a minimum of 2 passes, with a Gas Tungsten Are Welded (GTAW) root pass. b. Four-bolt raised-face flanges with small-bore butt-welds, welded with a minimum of 2 passes, with a GTAW root pass. c. Female NPT screwed connections with special structural support to prevent the control valve from turning after being piped up, installed with unions immediately upstream and downstream of the control valve. A receiver gauge on the output signal from the corresponding transmitter shall be located near each control valve to help in making a switch to use of the bypass valve, HFA Specs Revision 04-2007Instruments and Controls Page 13 (HF Alkylation) 3, UNACCEPTABLE CONTROL VALVES: The following styles of process control valves are unacceptable for HF-service appli Control valves with cage-style trim. ions: Control valves with noise-reduction trim. Control valves with anti-cavitation trim. Split-body control valves of any type. Butterfly or modified-butterfly valves. Disk, modified-disk, or eccentric-disk valves. Ball or modified-ball valves. Seat-guided control valves, HFA Specs Revision 04-2007Instruments and Controls Page 14 (HF Alkylation) G. RELIEF DEVICES L IEF VALVES: Relief valves in HF service shall be balanced bellows-seal valves with Kalrez* or Chemraz® O-ring seat seals and ASME Class 300 heavyweight cast-steel flanged bodies. All parts exposed to the inlet or outlet systems except the valve body shall be Nickel-Copper Alloy. Bonnet bolting shall be Nickel-Copper Alloy K- 500. Gaskets shall be solid soft-iron or low-carbon-steel gaskets with a hardness of less than BHN-114 (HIRB-64) or soft Nickel-Copper Alloy 400 gaskets (no exceptions). Bellows-to-dise gaskets may be Garlock Gylon® Style 35-101. Relief v: upstream and downstream and a gate bypass valve around the relief valve and its block valves such that the bypass installation is self-draining. The inlet piping to each relief valve and its bypass valve shall drain freely to the protected es shall be installed with gate or plug block valves (car-sealed open) equipment, and the outlet piping from each relief valve and its bypass valve shall drain freely to the flare header. Relief valves shall have a %-inch vent valve installed on the downstream side of the relief valve to check for relief valve leakage. Relief valves shall have a Y%- inch vent valve installed on the upstream side of the relief valve for field- checking the set pressure. Rupture discs shall not be used under relief valves. Bonnet vents on relief valves shall be left open (ie., not plugged) so that a Teaking bellows can be detected, but piping shall be installed to direct any bellows leakage away from personnel on the access platform. Relief-valve bonnet vents shall not be piped directly to drains. Relief valves and their associated block and bypass valves are in HF service regardless of the discharge service if the inlet piping is in HF service as shown on the ConocoPhillips process flowsheets. Block valves and bypass valves for relief valves shall be a minimum size of 2-inch Class 300 regardless of the size of the relief valve. HFA Specs Revision 04-2007Instruments and Controls Page 15, (HF Alkylation) 2. RUPTURE DISKS: Rupture disks may be used as bypass safety protection around the acid relief neutralizer. ‘The rupture disk and mating safety head shall be made of Nickel-Copper Alloy 400. Each rupture-disk installation in this service shall consist of two rupture disks in series with a vent valve and pressure gauge installed between the disks. HF-service block valves shall be located upstream and downstream of each rupture-disk installation. See ConocoPhillips Drawing HF-2002. HFA Specs Revision 04-2007Instruments and Controls Page 16 (HF Alkylation) i. N-S. ANALYZERS IN HF SERVICE: Sample-point piping for on-stream continuous process analyzers, ie, chromatographs for hydrocarbon analysis or FTIR (NIR) analyzers for acid composition, shall follow HF-service piping specifications (Section 6). 1. Chromatographs: Block valves on the take-off and return lines shall be %-inch minimum size. Valves and tubing lines downstream of the “inch sample block valve shall be Nickel-Copper Alloy. ‘Sample-conditioning systems for chromatographic process analyzers shall be designed to remove all HF from the sample streams before the samples enter ‘the analyzers. 2. FTIR (NIR) Analyzers: Block valves for motive isobutane, acid sample, and acid return shall be 1- inch minimum size. See ConocoPhillips Drawing No. HF-1013, “Piping Diagram for NIR Analyzer,” for other installation requirements. Any proposed deviations from the specifications detailed in Section 5 shall be submitted to ConocoPhillips, U. S. Refining, Refinery Business Improvement, Downstream Engineering and Licensing Services, Alkylation Technical Service, for review and comment. HFA Specs Revision 04-2007Instruments and Controls Page 17 (HF Alkylation) 1. INSTRUMENTATION AND CONTROL EQUIPMENT SOURCES ‘The following manufacturers can supply the instrumentation and control equipment specified in this section. CAUTION: The instrument model numbers given below are for general reference purposes only, and they do not imply complete adherence to HF service instrument specifications. Purchase specifications should include specific materials, dimensions, configurations, etc., described for HF-service instruments and control equipment. INSTRUMENTATION AND CONTROL EQUIPMENT. Elow Transmitter — Differential-Pressure Type 1, Emerson Rosemount (NiCu alloy diaphragm) 3051CD__44B2A E5L6 (Gold-plated NiCu alloy diaphragm) 3051CD__46B2A ES L6 Float Level Transmitters - Displacement Type: 1, Emerson Fisher Controls (pneumatic) 2500T-249B-HF Emerson Fisher Controls (electronic) DLC3010-249B-HF 2. Dresser Masoneilan (pneumatic) 1280) | (Special) Dresser Masoneilan (electronic) 1212|_| (Special) Level Transmitters - Nuclear Type: 1, Thermo MeasureTech (TN Technologies) Model 4790 or PNF Level-Pro Continuous Level Gauge Detector System (includes a strip source or one or more point sources, ion-chamber detector, and transmitter). 2. The Ohmart Corporation Series LSG-2000 Continuous Process Level Measurement System using point sources or a strip source. HFA Specs Revision 04-2007Instruments and Controls (HF Alkylation) Pressure Transmitter 1, Emerson Rosemount (NiCu alloy diaphragm) (Gold-plated NiCu alloy diaphragm) Contro} Valves - Diaphragm-Operated Type: 1. Emerson Fisher Controls 2. DresserMasoneilan 3, VALTEK Relief Valves: 1. Curtis-Wright Farris 2. Dresser Consolidated Pp Analyzers: 1. Process Chromatographs Siemens Energy & Automation Inc. 4500 West US Highway 60 Bartlesville, Oklahoma 74003 Telephone: 918-662-7409 Fax: 918-662-7057 2. ETIR Analyzers ABB Group Analytical Business 433 Northpark Central Drive Houston, TX 77073-5905 Page 18 3051CG__44B2A E5 L6 3051CG __46B2A E5L6 EZ-HF||ILILIL! YS-HF|_||_LILIL| 3-way mixing 3121005 (special) 3{_1+10000 (special) 3{_|-11805 (special) 3|J-80385 (special) 3-way mixing Mark-1-PHF-|_[-| /L] 26|_[D12-120/M2/PHF 1910-30|_|HA. Reference Dwgs. 453418-453431 Telephone (281) 869-5249 (Ed Orr, FTIR Global Marketing) Internet: www.abb.com/analytical HEA Specs Revision 04-2007LEGEND: MONE@ORIFICE PLATE WITH FLEXITALLIC STYLE C-G, OR EQUAL, SPIRAL WOUND MONEL—TEFLON®FILLED GASKETS ON EACH SIDE. ‘3OOf RF FORGED STEEL ORIFICE FLANGES WITH 1/2" NPT PIPE TAPS. 1/2"~600 OR 800f FS SCREWED GATE VALVE. 1/2°-3000# FS GROUND JOINT UNION WITH STEEL TO STEEL SEAT. 1/2"-3000f FS SCREWED TEE. OOOQOL® © 1/2°-3000f FS SCREWED ELL. NOTE: ALL PIPE NIPPLES SHALL BE MADE FROM 1/2" SCH. 80 SEAMLESS CARBON STEEL PIPE. ASTM A - 106 GRADE B. ALL THREADED JOINTS SHALL SE MADE UP WITH FEDERAL PROCESS COMPANY "THRED-TAPE” OR EQUAL_NO OTHER PIPE DOPE SHALL BE USED. DO NOT SEAL WELD THREADED FITTINGS. d/P CELL TRANSMITTER SUPPORTED FROM PROCESS LINE AND MOUNTED SO THAT PIPE TAPS ARE 3°-4"(76-102 mm) ABOVE ORIFICE TAPS ¢ SO MANIFOLD ING IS SELF DRAINING. 1/2" X 6"(152mm) Filename: _P:\TUL\IND\8050675000\20_CAD\Q\HF-1020.DWG Saved: 10/4/2006 4:08:39 PW_By: MCCL1887 ‘SCH 80 NIPPLE : 7 O 1/2" X 2 1/2°(64mm) SCH 80 NIPPLE iz BAR STOCK CS. PIPE PLUG ConoasPhilips or riow NSTLATON OF 4/e cELL eee DW MEASUREMENT IN. HYDROFLUORIC ACID ALKYLATION BE Ww. PROCESS, AND TRACE SERVICES xXxTRANSPARENT GAUGE GLASS. WITH FISHER OR MASONEILAN DISPLACEMENT LEVEL TRANSMITTER WITH 2"~ 300 LB SARE UPPER AND LOWER SIDE FLANGED. CONNECTIONS. GH) 2° 300 UB ASA RF FLANGED STEEL GATE VALVE ®) 3/2" eto 08 00 Le Fs streweD ATE VANE ©) 1/2"- 600 LB OR 800 LB FS © SCREWED GATE VALVE 18/20uy_ 2:04 12/ Soved: (©) 2°- 300 1B ASA RF NOZZLES ~~ ON VESSEL ©) 3/4" 3000 18 FS SCREWED COUPUNG HE 1012. 0G CF) 1/2" x 3/4" EXTRA HEAVY O7SWAGE NEPLE 4/2" 3000 LB FS. SCREWED Te ALL SCRE PIPE_NIPPLES SHALL 8 NADE FROM SCH. 80 SEAMLESS S] CARBON STEEL PIPE, AST A-106 GRADE & ALL THREADED JOINTS ce S] SVALL BE WADE UP’ WITH FEDERAL PROCESS COMPANY TEFLON® @ Ce eras ZI “THRED-TAPE” OR EQUAL. NO OTHER PIPE DOPE SHALL BF USED. DO fF B] NOT SEAL WELO THREADED FITTINGS. © 374" wae srock pE Plue A ALL 2"- 300 LB RF FLANGES SHALL BE MADE UP WITH FLEXITALUIC SI STYLE C-G OR EQUAL SPIRAL WOUND MONEL® TEFLON@ FILLED o> GQ) 1/2" BAR STOCK PIPE PLUG TPO NSALATOW OF SIE TOR Gee GUS AND LEVEL CONTR R-INDICATOR_IN- HYDROFLUORIC ALKYLATION THEN PROCESS ‘ACI SERVICE (HF STRIPPER, ETC.) 12/08 GASKETS Filename: P:P.\ rut \IND\8050675000\,20_t Filename: PRESSURE GAUGE —, FISHER _OR_MASONEILAN \ DISPLACEMENT LEVEL TRANSMITTER, FLOAT LENGTH TO BE ONE FOOT (305 mm) LESS THAN VESSEL DIAMETER. 2'— 300 LB ASA TOP & LOWER SIDE FLANGED CONNECTIONS. \- SSa00ue NOUV oA (ON | TWLSNI WOIdAL Ta 10) FOAMS JH NI SHOUD} = UITIONINOD 13937 ¥ Thaw 40 N I3ZINvdOde! INANO NATI09 YOODAML HO. (ur CENTERLINE OF THIS NOZZLE TO BE 10° (254 mm) ABOVE BOTTOM OF ACCUMULATOR 3/8" COPPER TUBING TRYCOCK DRAIN LINES: 8" X 10" (152 X 305 mm) reco ‘RAIN FUNNEL 2" SCH 80 DRAIN TO HF SEWER O\O\HE- 1001.0NG_Saved_1/22/200/ o:58:14 PM By: SCOG3678 TRYCOCK COLUMN FABRICATE FROM 2” SCH 80 A-105 GRADE B PIPE WH 2"~ 3CO LB ASA RF FLANGES AND 3/4"~ 3000 LE FS SCREWED COUPLINGS WELDED INTO (SEE(D)FOR TRYCOCK VALVE DESCRIPTION.) 00 LB ASA RF FLANGED GATE. VALVE 600 OR 800 LB FS SCREWED GATE VALVE 1/2'- 600 LB OR 800 LB FS S SCREWED GATE VALVE (0) 3/4" 800 LB FS GLOBE VALVES} = WITH MONEL — TEFLON SPIRAL WOUND BONNET CASKET & EL SEAT OR EQUAL PACING (DIMENSION x) TO 9° (228 mma) FOR VESSELS 6” (1829 mm) DIAM, OR LESS & 12” (305 mm) FOR VESSELS LARGER THAN 6' (1829 mm) DIAM DISPLACEMENT (E) 2"= 300 LB ASA RF NOZZLES Pad ~ ON VESSEL TRAVGMTER. 9" paged TEE Win 2 32” (813 mm) Soo LB ASA RF FLANGES FLOAT LENGTH) 2° FABRICATED ELL WITH 2"— WTH 2" $00 LB 7 300 18 ASA RF FLANGES sen A portow (H)2" FABRICATED TEE SPOOL PECE FLANGED wri) 2° 500 LB ASA RF CONNECTIONS. FLANGES: Os "- 3000 LB FS SCREWED ENTERLINE OF THIS —. COUPLING WELDED INTO 2° FLL NOZZLE TO BE 10" (2) 1/2" X 3/4" EXTRA HEA (254 mm) ABOVE \ ‘SWAGE NIPPLE BOTTOM OF K)1/2"— 3000 LB FS SCREWED ACCUMULATOR, TEE © sie" ane st004 PRE PLS NOTES: ALL SCREWED PIPE NIPPLES SHALL BE MADE FROM SCH. 80 SEAMLESS CARBON STEEL PIPE, ASTM A-106 GRADE BALL THREADED JOINTS: SHALL BE MADE UP WITH FEDERAL PROCESS COMPANY TEFLON@ “THRED-TAPE” OR EQUAL NO OTHER PIPE DOPE SHALL BE USED. 00 NOT SEAL WELD THREADED FITTINGS, ALL 2= 300 LB RF FLANGES SHALL BE MADE UP WITH FLEXITALLIC STYLE C-G OR EQUAL ‘SPIRAL WOUND MONEL® TEFLON@ FILLED GASKETS,By $C063678 17:03. PM 07 Saves: 1/3/20 HF 1002.DWG 10. CAD’ 10675000 Filenome: P:\ /ut\IND\80! Cc GENO ®) 2 300 LB ASA RF FLANGED STEEL GATE VALVE ® Sie SCREWED GATE VALVE RE GAUGE i © 600 OR B00 LB FS SCREWED GATE VALVE @) 800 LB FS GLOBE VALVES FOR TRYCOCK VAL\ ©) 7 300 18 ASA RF NOZZLES ON VESSEL (F) 3/4" 3000 LB FS SCREWED COUPLING WELDED INTO 2” ELL CENTERUNE OF 2" NOZZLE © 1/2" & 3/4 BarRA HEave ©T0 BE 6" (152 mm) SWAGE NIPPLE FROM TANGENT {INE G@) 1/2" 3000 LB FS SOREWED Tee TRYCOCK COLUMN- FABRICATE \. 3/8" COPPER TUBING FROM 2° SCH 80 A-106 TRYCOCK DRAIN UNES GRADE. B PIPE WITH 2" UB ASA RF FLANGES. AND 3/4"~ 3000 LB FS SCREWED COUPLINGS WELDED INTO 2° PIPE AS SHOWN FOR eee COC <5" X 10" (152 X 254 mm) ne TRYCOCK DRAN FUNNEL SEE ® FOR TRYCOCK VALE PLATFORMS. TO GE SPACED SCRIPTION. TRYCOCK VALVES APPROXIMATELY 8 (2440 mm) APART S| 10 BE INSTALLED ON 12" FOR ACCESS TO ALL TRYCOCKS, (305 mm) CENTERS. STARTING AT CENTERLINE OF BOTTOM eee 2" SCH 80 DRAN TO HF SEWER BOTTOM PLATFORM TO BE 1'3" (380 mm) BELOW ¢ OF GOTIOM TRYCOCK COLUMN \ NOZZLE ALL SCREWED PIPE NIPPLES SHALL BE AGE FROM SCH. 80 SEAMLESS CARBON ee ae STEEL PIPE, ASTM A-108 GRADE B. ALL Grobe 6 (a2 we) THREADED JOINTS SHALL BE MADE UP LS WITH FEDERAL PROCESS. COMPANY a tf TEFLON® "THRED-TAPE” OR EQUAL. NO OTHER PIPE DOPE SHALL BE USED. 00 NOT SEAL WELD THREADED FITTINGS. ALL 2"~ 300 LB RF FLANGES SHALL BE MADE UP WITH FLEXITALLIC STYLE CG OR EQUAL SPIRAL WOUND MO TEFLONG FILLED GASKETS. ape TENS TYPICAL INSTALLATION OF BRIDLE FOR WF 1002 ahi, RYCOCK COLUMN IN HF SERVICE — Peioeee HE STORAGE ORUM ie 07JOP NOZZLE AT 6" (152mm) BELOW SETTLER LOWER SIEVE TRAY TRYCOCK VALVE ELEVATIONS ABOVE BOTTOM SETTLER TANGENT 6'-0"(1830mm) §'~6"(1682m) 5'-0"(1526mm) 4°-6"(13720m) TRYCOCKS 10 BE EQUALLY SPACED BOTTOM NOZZLE AT 6"(152mm) ABOVE BOTTOM SETTLER TANGENTS ACID INTERFACE. LEVEL INDICATOR TRYCOCK COLUNN ARRANGEMENT RANGE OF ACID INTERFACE LEVEL INDICATOR IS 5'(1524mm)-TOP OF RANGE AT _7’-0"(2134mm) ABOVE BOTTOM SETTLER TANGENT BRIDLE 10 BE LOCATED 180" FROM SINGLE REACTOR RISER INLET OR 90" FROM REACTOR RISER INLETS WHERE TWO RISERS ARE UTILIZED. INSTALL HOOD TO VESSEL INSIDE WALL OVER BOTH BRIDLE NOZZLES. BRIDLE SETLER NOZZLE 6” SCH 40 STAGGER TRYCOCK VALVES 90° TO ALLOW INSTALLATION OF VALVES WITHOUT SONNET REMOVAL= 2° SCH BO MONEL PIPE ANSI CLASS 300 RF. MONEL FACED Wilk 2 FLANGE 2°— ANSI CLASS 300, RIF. FLANGE ANSI CLASS 300, RF, BLIND FLANGE, TAPPED WITH 1 INCH NPT 2~ SCH 80 PIPE TEE 1” X 3/4" EXTRA HEAVY SWAGE 3/4" TRYCOCK GLOBE VALVE 43/4" NPI TO 3/8" TUBING BRASS COMPRESSION ADAPTOR 3 3/8" COPPER TUBING I (EXTEND. THERMOWELL, | APPROXIMATELY 6” (152 mm) TRYCOCK DETAIL a INTO RERUN VES: zy a RERUN COLUMN 4 TRYCOCKS INSULATE TO TRYCOCK VALVES ONLY. gt ON 8" (203 mm) CENTERS “] SPACING IF PERSONNEL PROTECTION REQUIRED 2 ON COPPER TUBING, WRAP WITH 4 ALUMINUM JACKET ONLY. 00 NOT INSULATE TUBING TRYCOCK VALVES ALL IN HORIZONTAL RUN, VALVE STEMS HORIZONTAL, SPACE TUBING ON 1” (25 mm) NTERS. NO\8050675000\,20_CAD uty onocoPhillip ACID RERUN COLUMN TRYCOCK DETALS PROCESS. HF-1025 Filename: P:11/2" ¥1.1/2" (88 mm PROVIDE 1/6" X 2" X10" Stan | (LONE STRAP COPPER TUBING SUPPORT. \ HOLES 70 MATCH 1/2" (12 mm) @ STUD BOLTS FOR \ CLAMPING COPPER TUBING TO \ SUPPORT. \ \ \ corre TueN 2 YEO Ye — CUT TUBES SO THEY ARE \ 1/2" (13 mm) ABOVE THE (12 mm 6 X 64 mm) SO y , TOP EOGE OF THE FUNNEL STUD BOLTS WITH HEADS WELDED TO BACK SIDE OA S| OPEN FOR AIR: S] caRCULATION re SI a le a tle “ley __-—— CONTINUOUS WELD 3 a 9/20, 8 Saved: 12, PZ AEE ORIENTATION WITH RESPECT TO PREVAILING WINDS. TRYCOCK VALVES SHOULD BE OPERATED FROM UPWIND OF FUNNEL. (203 mm) 8050675000\20_CAD\\O\ HF 1006.00 NOTE: FABRICATE BOX FROM 1/4" STEEL PLATE. LOCATE TRYCOCK FUNNEL ON EACH PLATFORM FROM WHICH OPERATORS Vy | WILL BE OPENING. TRYCOCK VALVES. ee ae eee LOCATE TRYCOCK FUNNEL SO LOCATE FUNNEL SO THAT © OPERATOR HAS CLEAR ACCESS FOR OPERATOR CAN SEE ENDS OF MIN 3 FEET (914 mm) IN FRONT OF TUBING WHEN OPERATING FUNNEL AND NIN. FEET (1524 mm) TRYCOCK VALVE: ON BOTH SIDES GF FUNNEL. TYPICAL TRYCOCK FUNNEL DETAILS 1008 TALKYLATION PROCESS DAE NO, 12/06ag0ud NOLAN Iv sai = 3071T 109 = = 2 F-1003,0WG_Soved: 11/1/20. 2:20:12 PM By SCOG3678 J SEAL WELD MONE! THERMOWEL —. WO INCH 300 LB BLIND FLANGE DRILLED AND TAPPEL FOR THERWOWELLFilename: _P:\.vL\IND\8050675000\ 20_CAD\Q\HF—1013.DWG Saved: 11, '29/20.. 9:52:50 AM By: SCOG3678 ‘SSa00ud NOU ATV (UNA SdITIHdOOONOO) UZZATYNY YIN YOd WVYOVIG ONidld ‘on ava 90711 FON Wwi30 101-34 VENT TO (SEE NoTE 5) (SEE NOTE 4) m ACID DRAIN NOTES 1. THESE PUMPS ARE MORE COMMONLY REFERRED TO AS THE RECONTACTOR, DEPROPANIZER, ISOSTRIPPER, OR MAIN FRACTIONATOR FEED PUMPS DEPENDING ON THE PLANT CONFIGURATION. 2. THIS COUPLING IS TO BE INSTALLED ACCORDING TO DWG. NO. HF-1008. 3. CLOSEST SOURCE OF RECYCLE ISOBUTANE WILL USUALLY BE PUMP FLUSH OR STARTUP ISOBUTANE AT THE RERUN FEED PUNP. 4, LOCATE BLEEDERS AS NECESSARY IN ORDER TO DRAIN ALL LOW POINTS IN THE PIPING. 5, SAMPLE POINTS DIFFERENT FROM TYPICAL STANDPIPE SAMPLE POINT CAN ALSO BE USED. RECYCLE ISOBUTANE (APPROX. 200 PSIG) (SEE NOTE 3) EDUCTOR Nz SOURCE or Kye" ner SAMPLE. CONDITIONING UNIT 1/4" net TO ACID DRAIN (SEE NOTE 1) TO SPARE SETTLER EFFLUENT PUMP COUPLING (SEE NOTE 2)SECTIO! PIPE, VALVES, FITTINGS, AND SEWERS HE SERVICE SPECIFICATIONS CONOCOPHILLIPS HF ALKYLATION PROCESS A. General 1. Piping shall be in accordance with the latest edition of ASME Standard B31.3, Petroleum Refinery Piping Code, except as noted, 2. Piping Specification Key F — HF Service K — Hydrocarbon (Non-Acid) B— Caustic HF-service piping shall be in accordance with the following F specifications. K and B piping shall be in accordance with the contractor's specifications unless otherwise stipulated by ConocoPhillips or the licensee. 3. Piping Specification F shall apply to all lines and valves designated “F” on the process flowshects. Maximum operating conditions for carbon stee! fittings from ASME B16.5, “Pipe Flanges and Flanged Fittings” are as follows: Temperature,*F 100 300 500 Pressure, PSIG 740 655 600Pipe, Valves, Fittings, and Sewers Page 2 (HF Alkylation) B. Valves —-Nickel-Copper-Alloy Trim See Subsection F, “Listed HF-Service Valves”, for listings of valves from various manufacturers that meet HF-service specifications and that have given satisfactory service in the HF alkylation process. The contractor shall furnish cross-sectional drawings from the manufacturers showing the materials of construction of all selected valves to ConocoPhillips for review and comment. ‘The contractor shall comply with the following special instructions for HF-service valves, 1, Ball valves shall not be used in HF service. 2 Plug valves or gate valves (2-inch or larger) shall be installed on all nozzles of vessels in HF service except for fractionator overhead vapor nozzles, reboiler vapor return nozzles, and thermowell nozzles on vessels and non-isolable piping. . A plug vaive or gate valve, a figure-8 blind, and a bleeder assembly shall be used on the suction and discharge of pumps in HF service, as indicated on the process flowsheets. See ConocoPhillips Drawing No. HF-2000 for a typical pump installation, Vent and drain valves on piping, pumps, etc., sball be metal-seated gate valves no smaller than %/-inch, Vent and drain valves shall be plugged with hexagonal plugs made of solid carbon steel bar stock, at least 3 inches (75 mm) Yong. Plugs shall be installed with heavy-duty industrial-grade (extra-dense) Teflon® tape (Federal Process Company Thred-Tape® or equal). See Subsection C, Paragraph 15. Listed Y-inch trycock-service globe valves or plug valves shall be used on all trycock connections. See Section 5, Subsection C, “Liquid Level Measurement”. 6. Globe valves shall be used where hand control of flow may be required. 7. Listed plug, gate, globe, and check valves shall have connection-flange edges and bonnet-flange edges painted with Hydrofluoric Acid Detection Paint for ready identification as HF-service valves. To allow detection of paint color changes resulting from exposure to HF, body and bonnet flanges shall not be insulated. For paint suppliers, see Section 10, Subsection H. Remotely-operated valves installed for isolation or evacuation purposes shall be listed block valves with actuators that can be remotely or manually actuated. HFA Specs Revision 04-2007