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1. Transition elements show variable oxidation states and many of the transition metal ions are attracted
by a magnetic field.
a) Give reason for variability of oxidation state. (1)
b) Name the two types of magnetic behaviour. (1)
Ans: a) This is because in transition elements d and s electrons have comparable energies. So along
with s-electrons, d-electrons also participate in chemical reactions.
b) Diamagnetism and paramagnetism
2. The observed magnetic moment of Sc3+ was found to be zero. Calculate the magnetic moment of Sc3+
using the spin-only formula and compare the result of observed and calculated magnetic moment. (2)
[March 2008]
Ans: The valence shell electronic configuration of Sc3+ ion is 3d0.
So the number of unpaired electrons (n) = 0
Magnetic mpment, µs = √n(n+2) = √0(0+2) = 0.
i.e. the observed magnetic moment is in agreement with the calculated magnetic moment.
3. A list of Lanthanide ions are given:
La3+, Ce4+, Yb2+, Lu3+
Atomic numbers of La, Ce, Yb and Lu are 57, 58, 70 and 71 respectively.
a) Give the number of unpaired electrons in each ion. (1)
b) Identify the ions which are paramagnetic. Justify. (1½ )
c) Identify the ions which are colourless. Give reason. (1½) [SAY 2008]
Ans:
a) The valence shell electronic configuration of La3+ ion is 4f 0. So the number of unpaired electrons = 0.
The valence shell electronic configuration of Ce4+ ion is 4f 0. So the number of unpaired electrons = 0.
The valence shell electronic configuration of Yb2+ ion is 4f 14. So the number of unpaired electrons = 0.
The valence shell electronic configuration of Lu3+ ion is 4f 14. So the number of unpaired electrons = 0.
b) All these ions are diamagnetic, since they contain only paired electrons.
c) All these ions are colourless, since they do not contain any partially filled orbitals.
4. Potassium permanganate is a powerful oxidising agent in neutral, acidic and alkaline medium. In the lab,
students were asked to convert an iodide to iodate. One of the students obtained I 2 instead of iodate.
a) i) What is the reaction to be carried out by the students who got iodate? Write the chemical
equation. (1½ )
ii) What may be the reaction carried out by the student who got I2 as one of the products? (1)
b) i) Suppose you are going the same experiment with the iodide using Potassium dichromate (K 2Cr2O7).
What are the products going to be obtained? Write down the chemical equation. (1½ )
ii) What is Baeyer’s reagent? (1) [March 2009]
Ans: a) i) In order to get iodate, the reaction should be done in alkaline or neutral medium. The
chemical equation for this reaction is: 2MnO4– + H2O + I –→ 2MnO2 + 2OH –+ IO3–
ii) The student who got I2 as one of the product conducted the reaction in acidic medium. The chemical
equation for this reaction is: 10 I – +2 MnO4– + 16H+ → 5 I2 + 2 Mn2+ + 8H2O
b) i) The products obtained are Iodine, Cr3+ and water as follows:
6I – + Cr2O72– + 14H+ → 3I2 + 2Cr3+ + 7H2O
ii) Alkaline KMnO4 solution is called Baeyer’s reagent.
5. Potassium permanganate and Potassium dichromate are oxidising agents.
a) Name the ores of the above compounds from which they are prepared. (½ )
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c) Due to lanthanoid contraction, Zr and Hf have similar radii and hence similar physical properties.
So their separation is difficult.
18. a) Which of the following oxidation state is not shown by Manganese?
(i) +1 (ii) +2 (iii) +4 (iv) +7 (1)
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