HOA HQC 11. FN-CHEM' || GW TAP THI GHK2 “+ ON TAP THI GHEII boy FN.CHEM+ Nl Eg DE ON sO 03 1-TULUAN 1. _Bé tic tén goi Ung véi CTCT dai cho hodc CTCT tig voi tan goi di cho Cls-CH-GH-CH=CH CH; Go @ aces ©) (0) CFs—CH.cl = (d) neopentane (e)m-xylene {f) pentyl bromide = 2. Hoan thanh eée phudng trinn phan tig —ghi r6 didu kign (néu c6) (néu phan ting tao nhiBu sin phém, chi viet sén phém chinh) (a) Propylene (propene) + HBr: (b) Bun néng ethyl alcohol (C2H.OH) véi H2S0, dc,170°C: 2, (©) Propyne + Ho (t?, Lindtar): 2. (Gjethyne+ HBr dum (e) Acetylene + dung dich AgNOs/NHs: (f toluene + Bre (FeBrs, 1%): 2% Il- CHON PHAT BIEU DUNG/SAI (ghi B (ding) hodc S (sal) sau mél phat biéu) 8. Cho céc phén tifalkene 06 céng thifc khung phan tir dui day: aw ZA“ Am (A) (B) {C) (a) Trong 3 chat trén, Cla chat co nhiét 46 sdi cao nhét. (b)Ac6 tén thudngla propylene. (6) C83 chat trén khi tdc dung voi HBr, t° déu thu dude hn hop gm 2 dng phan cdut tao. (@) San phdm chin khi cho B téc dung véi HCl cé tén W 2-chloropentane. CH, =CH, maf ae = CH, MOH GMO 4. Cho sod phan ting sau: id (@) Chak A c6 tén gold vinyl chioride. (b) Beco CTCTI8CH-CH-OH ()Claethylene. TUS Phan Vin Wha B 0899. 488. 299 (THPT Uguybe Thasey Win) 1HOA HOC _11.FN-cHmw || ON TAP THI GHK2 5. Acetylene la mot héa chat quan trong trong cng nghidp, dc biét nd cé thé tam nhién tigu trong cong nghé han (@) acetylene c6 CTPTIA Gti. (©) acetylene ¢6 thé digu ché tir calcium carbide. (d) khi cho acetylene qua dung dich Ag(NH,),OH thi co két tla mau tréng xuét hién. 6. MOt dan xuat monohalo A (dan xudt halogen chira 1 nguyén tly halogen) cia alkane co % khdi lugng carbon = 39,735 %. Dun néng hgp chit A trong m6i truting kiém va ethanol, thu duge sn phém chinh [3 2-methylbut-2-ene. (@) Ala mot dan xudt chloride. (6) 2-methylbut-2-ene c6 ding phan hinh hoc. (6) phn ing dun néng A trong mdi trusng kim va ethanol [a phan ting tach. (@) 06.2 dng phan cdu tao théa tinh chat cua A, WW CAU TRA LOINGAN (Hoc sinh ghi dap Gn tra Idi theo yéu cu cia mét cau hdi) 7. $6 ddng phn cu tao la alkyne ting voi CTPT CaHe a bao nhiéu? DAP At pa eiebt 8. Cho cdc chat e6 cing thire: CHsF, CHsCl, CH3Br, CHsl va nhiét d6 s6i cita ching (khGng theo thir tu) la 42 °C, 4% va-78 °C. Xée dinh nhigt dQ si otta CHsBr. BAP AN: 8. Cho hdn hgp ttcd cdc dbng phn rhach hd ctia CcHs téc dung véi H.0 (H',t?) thu dude t6i da bao nhigu sén phém cong? Ao BAP AN: ee 10. Cac arene thutng cé chi s6 octane.cao nén dutge pha tron vao xing dé nang cad kha nang chdng kich né cla xang, nhu toluene va xylene thug chiém téi 25% xang theo thé tich. TI l8 nay véi benzene dug EPA(The U.S. Environmental Protection Agency - Gd Quan Bao ve mdi trudng Hoa Ki) quy dinh phai gidi hen & mute khOng qué 4 % vi chiing la chat c6 kha nang gay ting thu. Gia sif xdng c6 kh6i Luong riéng la 0,88 g/om® thi trong 88 tn xang 66 pha tron khong qué bao nhiéu m? benzene? DAP ANS --.--re 24°C 11. Cho sa 48 chuyén héa sau: hydrocarbon thom X (cé 8,695% nguyén té H vé khdt lurong) —82" > y AY 42.7 la hgp chat don chitc, c6 phd IR nh sa Xée dinh CTCT ctia ¥, Z va cng thite chit A. AP AN: 12. Phan ting chdy cita alkane cé vai tra rt quan trong d6i vii ddi sOng con ngudsi. Bot chay cac alkane cung cap nhiét dé dun ndu, si dm va cung cp ning lugng cho cdc nganh cong nghiép. Cho hai phuong trinh nhiét héa hoc: © CHe(g) + 202 (g) —> COn(e) + 24:0 (e) ArH, =-890 KI (1) 3H (g) + 502 (g) —>3CO2 (g) + 4420 (g) A;HSy. Tinh lugng nhiét téa ra khi dét chdy fan lugt 0,32 kg Ct ‘DAP AN: US Phan Vin Nin B 0899. 33.299 (TAP? Nquyin Thawng Bide) 2HOA HQC _11.¥N-CHEM || ON TAP THI GHK2 IV- PHAN CHUYEN: 18. Xéc dinh CTCT céc chat chura biét trong céc chuyén héa sau: Oz X, (CyHg0,) NRNEE x, (CoHyO2N) 7 ‘AIC, pheno! \r KelCoHrNO) SET Ky (CHeCIOs) = —— (CHD) Tyrosine 2.440 = 14. Cho hgp chat hitu co’ T chita C, H, 0. (2) mot phn phd MS cita T nhur sau: 109 % CS slave 4 x ime (i) Cudng 66 trong Adi cita peak M v3 M+4 la 33.9 va 3.4. Xdc dinh CTPT ctia T. (ii) Tw peak c6 m / e = 119, xac dinh phn phén manh da tach ra tir T. a {b) Phé hing ngoat ciza T nhur sau: ‘00 +0. ° 7 s S000" 3000 ‘00 1800 1000 300 waverunber/om* Xéc dinh nhém chite dc trung cho tinh higu & peak V va W? = TUS Phan Vin Man B 0399, 498. 299 (TAPT Mguyin Mhuopug Biba) 3HOA HQC _11.FN-CHEM* || ON TAP THI GHK2 1) Cho pho "HNMR cua T trong dung méi CDChs nh sau on aa ho 8 8 7 6 6b a 5 2 TO Stopm + khi cho D0 vao T thi thay céc tin higu trong "H NMR khéng thay déi. Xde dinh cde CTCT c6 thé 6 cita T? = @ important IR peaks: Bond Wave number Bond Wave number (em) (cart) C-Cl (chloroatkanes) 600-800 | C=O (ketones) 1680-1850 C-O (alcohols, esters, ethers) | 1050-1410 1720-1840 2850-3000 C=C (alkenes) 1620-1680 -O (amides) 1630-1680 | O-H (acids) 2500-3500 C=O (aldehydes) 1660-1745 | 0-H (alcohols) 3200-3600 C=0 (acids) 1680-1740 | N-H (amines and amides) 3300-3500 ‘1H NMR chemical shift Downfield Petal ‘ ou, —NH ey De oy one xeei (420, C1 Br. 6 saa pon ates aw £ faa feo rer |Carbenylie Acide Pe CEC. paar pt Pe ETO eee ee He eee eee te eee teeta tet 8 (ppm) —»_——_ I-75 Phan Vin Whan B 0399. 483.299 THPT Nguybe Thang Bike)