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I
6
I 5 6 2 A

4
7 5 8
5) Amines, a

CH3
-
2

CHICH,CH2 NI C3HqN
3 9
Y
CH
-

3 9 S -
position 90 is
xy ...
=

90
xy
=

CMqN
C1 -CH N
-

Functional Isomers
2:
-1
-> same molecular
formula -> differentchemical properties CHgN

Aldehyde 6) Amides
Cty-CHCty--NH
Ketone
O

leana
3
I
CHO

4
cis-at
2a
5

2) Alcohol (Ether 7) Cyanide


D
oH

S
⑧ -CN -N
·C E
I

3) Alcohol/Phenol OH
I
-> phenol
Nitro/ Nitride
8)

CH3
*

·
CHOH HOL ON10
A

I
⑧ Metamers:divalenttrivalent

O

c-o-C -
"-o-
27

Carbonylic Acid (Ether


C
3) -5 -
C c - N -

I
↳-ctor as hous - - -
c
Monovalent Tantomers H

I -O o
I 1 I R
-H
=
CH-
-

-
c-It -H

i4 not Keto end


do metarism

NOTE

18am
SH
is of
keto
form
-

Usually more stable because


high
bond dissociation
enthalpy for c0 = and its route
nature

LR ->
Different ⑤
>
Keto /enol
Aromatic >
⑳>
>
Non-aromatic Anti-aromatic
-

Intermolecular H-Bond
Acetyl Acetone
Ph 91111111 H -0

Bu
o

Not Isomens
-"-a-cy ----CH,
I

Keto
enol (more stable)

⑭ Functional Chelation
00


11 Il
H
CH3 2-CHs
-
-

I
Reto

Order: Tautomerism has almost of eno



Functional bond allows rotation
I single
Metamers

chain Position
For
eg. Cky-"I-CH3 ->
cr---c

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