Computer Programming III Lecture (2) : Process Modeling /Simulation Basics By Aspen HYSYS Chemical and Petrochemical Engineering Department / 7" Semester. Salahaddin UniversityUNIT OPERATIONS Hydraulics + Moving fluids + Pressure change mainly + Friction generation > Temperature + Contains piping-specific unit ops + Pipe Segment (pressure loss) + Various fittings » Decrease Pressure > Valves, expander * Increase Pressure > Compressor/Pump = Transport Fluids > Pipings + Advanced > Gas Gathering ExamplesUNIT OPERATIONS Hydraulics - Pumps + Used to increase pressure in a liquid eee ° + Increase Pressure mr [ager rtomace ens) = Inputs are foo ian = Inlet stream (mass) mee ce = Outlet stream (mass) uate] mae = - + Inlet stream (Work) — = You can assign 1 fluid package for it! « GP, Pressure Ratio, Adiabatic Eff. + Pump Curves, NPSH Curves, Efficiency CurvesUNIT OPERATIONS Hydraulics — Exercise # 1 +014 - Pumps + Input data: = Inlet Stream + T=25°C, P=1atm + Pure water = P final Required = 10 atm * Final Data: + Outlet Temperature * Workload required (KW, HP)UNIT OPERATIONS Hydraulics - Compressor = Used to increase pressure in a gas + Mave a gas + Recover loss of pressure z * Increase Pressure ae ee Re] = Inputs are + Inlet stream (mass) + Outlet stream (mass) * Inlet stream (Work) + dP, Pressure Ratio, Adiabatic/Polytropic Eff.UNIT OPERATIONS | Hydraulics — Exercise # 2 = 015 - Compressor = Input data: = Inlet Stream + Enriched Oxygen Air (34% Nitrox) » T= 30°C, P= 14.7 psia « P final Required = 3000 psig « % efficiency = 65% » Final Data: = Outlet Temperature ad + Workload required (KW, HP)UNIT OPERATIONS Reactors = “Common” « Continuous Stirred Tank Reactor (CSTR) « Plug Flow Reactor (PFR) = “Column” + Gibbs Reactor = Equilibrium Reactor » Conversion Reactor + Yield Shift ReactorUNIT OPERATIONS Reactors - Reactions » You must add and specify the type of reaction = Types: = Conversion » Equilibrium » Kinetic « RateUNIT OPERATIONS Reactors - Reactions = C+02=C02 =C+%02=CO « H20 = H2 + 02 »H20 =2H+0 oe AS oReactors - Conversion « It is based on Conversion of a reactant (X) = Requires Reaction « Stoichiometry! » All other calculations are based upon this + Enthalpy of reaction « Final T, P « Requires exact Stoichiometry = Final CompositionUNIT OPERATIONS Reactors - Equilibrium » Requires Reaction * Stoichiometry! + Forward-Reverse reactions « Based on activity coefficients > Keq » Keq given « Keq calculated via Gibbs Free energy = Keq tabulated - All other calculations are based upor this = Reaction extent = Temperature, Pressure changes = Final CompositionUNTT OPERATIONS Reactors - Exercise 014 - Reactors (Conversion) Reactors Specs = Conversion if 95% - Adiabatic (Q- 0) = Methane Combustion (15% excess oxidant) > CH4 + 202 = CO2 + 2H20 Via pure oxygen Inlet Fuel = 100 mol of CH4 = Inlet Oxidant = 230 mol of OZ - Final T = Final flowrates + composition Via air (21% O2, 79% N2) Inlet Fuel = 100 mol of CHa Inlet Oxidant = 1095 mol of Air (230 mol of OZ, 865 mol of N2) al T al flowrates + composiFile > Options > * Simulation » Reports * Equipment + Units of MeasurementThe Workbook = All info regarding: + Material Streams + Compositions + Energy Streams + Unit OperationsThe Workbook = Workbook “Menu” = Save/Export Workbook« Export to Excel! « Engineers love Excel!Reports * Printable Version of Workbooks « Add multiple datasheet of interest « Can be formatted and fitted to many page-sizes i feo omnes temenoty fama Piessnmey ao, * Ona tas Fh reso1. Statement (Case Study I) « We have a stream containing 15% ethane, 20% propane, 60% i-butane and 5% n-butane at T = 50°F and P = 1 atm. Flow rate is 100 kg/h + It will be compressed to P = 50 psia and cooled down to 32°F. « The chiller has a pressure loss of 10 kPa. « The resulting mixture must be splitted into liquid (valuable product for our client) and a gas (must be burnt with air)1. Statement (Case Study 1) « A) How much mass is lost in flare? = B) How much product is recovered? + C) Specifications of liquid product. « C) Compressor Workload « D) Chiller Heat Duty requirements3. Data Input (Case Study ip + Material Streams Sas" + Feed @ Feed Flash + Warm + Cool lg ) Cool * Stack Gas empress Crier + Product Wark Product + Energy Streams + Unit Operations + Compressor Workload + Compressor + Chiller Heat Load + Cooler * Separator3. Data Input (Case Study wD = Input: Material « Feed + Composition = 15% ethane, 20% propane, 60% i-butane and 5% n-butane (molar) + FlowRate = 100 kg/h + Temperature = 50°F + Pressure = 1 atm = Warm + P= 50 psia = Cool T= 32°F + Stack Gas + Not required + Product + Not required3. Data Input (Case Study i» « Input: Energy = Compressor Workload « Not required « Chiller Heat Duty + Not required3. Data Input (Case Study II) + Input: Unit Operations « Compressor + Efficency: 75% Adiahatic » Cooler = dP =10 kPa « Flash Separator « Not required5. Results & Reporting (Case Study I)6. Analysis & Conclusion(Case Study ID + A) How much mass is lost in flare? = B) How much product is recovered? = C) Specifications of liquid product. = C) Compressor Workload = D) Chiller Heat Duty requirements