= RP RBKLARARS A Ds & Ss UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO..LTD \ 7) actry ace: No.2 Linowo Rows, Thogin inausnat Park. dinar, Shangoal 201508, China SAY GHEE ENS taatsor ne-tieseosssor tee: €0-21-34082007 mee fits iawwunionagrachem.com Email into@unionagrochem com CERTIFICATE OF ANALYSIS [PRR 500g HEN SORL ARAMA Th ] B84 | Unioneagrochem Product Name 500g/L. Chlorpyrifos + SOg/L Cypermethrin EC_| Supplier = des 202 eat 5000 Liters | Bach No. eer Quantiny—_| $00 | dere ea 2 fe EA 20.11.24 Manufacturing Date_| 7770-110 Test Date aN 4038 1M Ha HREM | 59991120 inspect Kind Leave the factory Inspect Expiry Date | ~ sete | Ro ele MER TES lL Items specifications Results Conelusin Sh Stable homogeneous liquid Stable homogeneous liquid oe Appearance serait seat Qualified 15 Lae = aie | Chtorpyrifos Contents git_| 50° 502 Qualified RMSRaR == > sy 7 oe | Cypermethrin Contents — g/l. a] Qualified PH ae Pu asp oo Qualified RE Bie Moisture % S05 4 Qualified JLieEtE CORE 20 TD | A [ait ae wulsion stability Qualified | Qualified Qualified | TAGE. Cimin = Yay lo aE Persistent foaming, ml a Qualified & & ate Remark Qualified Hae « aie Conclusion Qualified Tu Ling EER: Cai Tianchen WEG: Xu Mingmin checker: Examine: ALARA REA as CROP PROTECTION FECHNOLOGY CO.IT. % BRLhBRGKLARAR SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Lindo Road, Tingin industrial Park, JinShan, Shanghai, 201508, China Office Tel. 86-21-34092901 86-21-34092607 Fax: 86-21-34092937 Hitp-//www.unionagrochem com Email: info@unianagrochem.com MATERIAL SAFETY DATA SHEET Manufacturer/information service: Manufacturer: Union-agochem Crop Protection Technology Co., Lid Add; NO.2 Linbao Road, Tinglin industrial Park, JinShan, Shanghai, 201505, China Tel: 86-21-3409290 1, 86-21-34092907 Fax: 86-21-34092937 1, Chemical Produet Identification Product Name: chlorpyriphos Molecular Formula: C9HI1CI3NO3PS Molecular Weight: 350.6 Structural Formula: a ao s I cl N OP(OCH CH)» SS cl cl Chemical Name: O, O-diethyl O- (3, 5, 6-trichloro-2-pyridinyl) phosphorothioate Form: Colorless erystals. Color: Colorles Odor: Mild miereaptan $ No. 2921-88 LEMBULART HE A oe Nema Iwo HCH COP ROCRON CLO. eRheh BkLLABRARS SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory edd: No 2 Linbao Road. Tinglin industrial Park, JinShan, Shanghai, 201505, China Office Tel: 86-21-34092901 86-21-34092907 Fax: 86-21-34092937 Hetp://www.unionagrochem.com Email: info@unionagrechem.com Product Name: cypermethrin Molecular Formula: C22H19CI2NO3; Molecular Weight: 416.3 Structural Formula: LO 00 cl AL Chemical name: (RS) -eyano-3-phenoxybenzyl (IRS, SRS: 1RS, 38R)-3-(2, 2dichlorovinyl)-2, 2-dimethyleyclapropanecarboxylate Form: Clear, yellowish-brown, free flowing emulsifiable concentrate that forms a white emulsion on dilution with water Color: Clear, yellowish-brown Odor: Highly aromatic hydrocarbon (xylene). CAS No.: 52315-07-8 2.Composition / Information on Ingredients ‘Composition CAS No. Content % chlorpyriphos 2921-88-2 30 cypermethrin 52315-07-8 3 Other ingredients 5 3.Hazards Identification Toxicity class: WHO II; EPA II (data for technical material). It was a moderately toxic insecticide Likely routes of exposure: Skin and cye contact, ingestion and inhalation. Eye contaet: Minimally toxic. The product may cause moderate to severe irritation and damage. Skin contact: Minimally toxic. The product may cause moderate to severe irritation. It may be a weak skin sensitizer. LRM LARA aed WO-AGROCHEN COP PRTECTONTCANOLOGT CO, BRLeERBKLABRARS SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO..LTD Factory add: No.2 Linkeo Road, Tinglin industrial Park JinShan, Shanghai, 201505, China Office Tel: 86-21-34092901 86-21-34092907 Fax: 86-21-34092937 weer ‘Http: l/www.unionagrochem.com Email: Info@unionagrochem.com Ingestion: Moderately to severe toxic if ingested. Inhalation: Moderately toxic by inhalation. High concentrations could be fatal. Potential Physical Hazards: Combustible liquid and vapor, 4. First Aid Measures General: When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. IF INHALED: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth, Get medical attention. IF ON SKIN: Wash with plenty of soap and water. Get medical attention. IF SWALLOWED: Do not induce vomiting, Call a physician immediately IF IN EYES: Flush eyes with plenty of water for 15 minutes. Call a physician, NOTE TO PHYSICIAN: This product is an organophosphorus ester that inhibits cholinesterase. In cases of severe acute poisoning, the decision of whether to induce vomiting or not should be made by the attending physician. If lavage is performed, endotracheal and/or esophageal control is suggested, Danger from lung aspiration must be evaluated against toxicity when considering emptying the stomac! ANTIDOTE: Atropine only by injection is an antidote. Oximes such as 2-PAM/protopam may be therapeutic but should only be used in conjunction with atropine. There is no specific antidote available. Prevention of further absorption in case of pyrethi overexposure: Washing the contaminated skin and hair thoroughly, removal of vomiting materials, Gastric aspiration and lavage with water, or 5% sodium bicarbonate solution, for cases of ingestive poisons. Alleviation of symptoms: Symptomatic and supportive treatment, bed rest until disappearance of symptoms. For cases of severe pyrethroid poisoning: Admission to hospitalalleviation of life- threatening effects: using anti-convulsive treatments (e.g.diazepam) for convulsions, maintaining a clear airway, or using assisted ventilation if pulmonary edema occurs. LR MBULART ILE A ee coe ROTO E0870, ahet GK LARAR SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Linbao Road, Tinglin industval Park, JinShan, Shanghai, 201505, China Olfice Tel: 86-21-34092901 &6-21-34082907 Fax: 86-21-34092937 Hitp://www.unionagrochem.com Email: Infe@unianagrochem.com For poisoning induced by pyrethroid and organophosphate mixture: sufficient dosage of atropine may be needed; oxygen may also be needed, based on the clinical symptoms, signs and blood cholinesterase measurements. There is no inhibition of blood cholinesterase in patients with acute pyrethroid poisoning. The prognosis of acute pyrethroid poisoning is always better, even in seriously affected patients, symptomatic and supportive treatments as above. NOTE Occupational acute pyrethroid poisoning has often occurred in spray men working in the fields in summer. Therefore heatstroke, respiratory infection, and food poisoning should be cautiously differentiated, Care should be taken not to misdiagnose cases of acute pyrethroid poisoning by ingestion as acute organophosphorous poisoning, as the smell of pyrethroids is somewhat similar to the organophosphorous pesticides, and pulmonary edema can occur in severely poisoned patients of both kinds of poisoning, To differentiate these two kinds of pesticide poisoning, the exposure history is most important. 5. Fire-Fighting Measures Fire and explosion hazard: Product is highly flammable and explosive due to formulant (xylene) content. Extinguishing agents: Extinguish small fires with carbon dioxide, dry powder, or aleohol-resistant foam. Water spray can be used for cooling of unaffected stock, but avoid water coming in contact with the product. Contain water used for fire fighting for later disposal. Fire fighting: Remove spectators from surrounding area. Remove container from fire area if possible. Contain fire control agents for later disposal. Use a recommended extinguishing agent for the type of surrounding fire. Water can be used to cool unaffected containers but must be contained for later disposal. Avoid inhaling hazardous vapours. Keep upwind. Personal protective equipment: LR REL La RFREA MON ALOCHBA ROR POTECHON ECOL COI, 4 BRLB RG KLARARS SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Linbao Road, Tinglin industrial Park. JinShan, Shanghai, 201505, China Office Tel: 86-21-34092801 86-21-34092907 Fax: 8G-21-34092937 Hup://www.unignagrochem.com Email: info@unionagrochem.com Fire may produce irritating or poisonous vapours (toxic fumes of hydrogen cyanide, ehlorine, and oxides of nitrogen and carbon), mists or other products of combustion. Fire fighters and others that may be exposed should wear full protective clothing and self= contained breathing apparatus. 6. Accidental Release Measures In Case of Spill or Leak: Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8, Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. Handling and Storage Handling: Do not use near source of sparks or open flame, Harmful by skin or eye contact, inhalation or ingestion. Avoid contact with eyes and skin, and inhalation of spray and vapour. Use with adequate ventilation. Wash hands before eating, drinking, chewing gum, smoking, or using the toilet. Operators should change and wash clothing daily. Remove clothing immediately if the insecticide gets inside. Then wash skin thoroughly using a non- abrasive soap and pitt on clean clothing. Do not apply directly to areas where surface water is present, or to intertidal areas below the mean high water mark. Water used to clean equipment must be disposed of correctly to avoid contamination. Storage: Do not store near sources of sparks, flame or heat. Keep under lock and key and out of reach of unauthorized persons, children and animals, store in its original labeled container BORLA Thea owas 1? ECON TECHO.OT AD 5 BRii: LAR BKLABRARS A iS fay) = UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD a7 | actory add: No.2 Linbae Road, Tinglin industrial Park, JinShan, Shanghai, 201805, China = Office Tel: 86-21-34092001 86-21-34092007 Fax: 86-21-34092937 wee ‘Hitp://mww.unionagrochem.com Email: info@unionagrochem.com in isolated, dry, cool and well-ventilated area, Not to be stored next to foodstuffs and ‘water supplies. Local regulations should be complied with, 8, Exposure Controls/Personal Protection It is essential to provide adequate ventilation. The measures appropriate for a particular work site depend on how this material is used and on the extent of exposure. Ensure that control systems are properly designed and maintained. Comply with occupational safety, environmental, fire, and other applicable regulations PERSONAL PROTECTIVE EQUIPMENT: If engineering controls and work practices are not effective in controlling exposure to this material, then wear suitable personal protective equipment including approved respiratory protection. Respirator: An approved respirator suitable for protection from dusts and mists of pesticides is adequate. Limitations of respirator use specified by the approving agency and the manufacturer must be observed Clothing: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance, Gloves: Employee must wear appropriate synthetic protective gloves to prevent contact with this substance. Eye protection: The use of safety goggles is recommended. Emergency eyewash: Where there is any possibility that an employee's eyes may be exposed (0 this substance, the employer should provide an eye wash fountain or appropriate alternative within the immediate work area for emergency use. pews adie {wii AGROCE CRO? FROTECTON TECHNOLOGY COD. aRhtRhGRLARAR SS UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Linbao Road, Tinglin industcial Park, JinShan, Shanghai, 201605. China Office Tel: 86-21-34092001 86-21-34092907 Fax: 86-21-34092937 iuww.unlonagrochem com Email: info@unionagrochem.com 9. Physical and Chemical Properties PHYSICAL DESCRIPTION: Colorless crystals. ODOR: Mild aromatic hydrocarbon MELTING POINT: 24-25.75 °C DENSITY: 0.617 gm/em’ at 20°C PH: about 3.8 VAPOR PRESSURE: 2.7 mPa (25°C) VAPOR DENSITY: Unknown WATER SOLUBILITY: In water c. 1.03 mg/l (25°C). Flash point: not applicable Corrosive properties: None to very slight. 10. Stabi and React CHEMICAL STABILITY: Normally stable. However, product will decompose if heated above 300°F for an extended period, which significantly inereases the risk of explosion, CONDITIONS TO AVOID: Avoid temperatures above 100°F (60°C). INCOMPATIBILITY WITH OTHER MATERIALS: Strong alkalis, amines and oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen chloride, Ethyl sulfide, Diethyl sulfide, Nitrogen oxides, especially during combustion. HAZARDOUS POLYMERIZATION: Will not occur. 11. Toxicological Information (a) Acute oral toxicity Rat LDS0 oral: 118.25-130.75 mg/kg bw (b) Acute dermal toxicity Rat LDSO dermal:>1400 mg/kg bw (c) Acute inhalation toxicity LCsp for rats > 0.225 mg/l of air over 4 hours (2) Acute toxicity other routes Not knowns p og 9 px» 9 LARGE 8 INOKAGG Los 2 HOTECON TECHNOLOGY CO. eRhBtRCPKRLARARS SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add No.2 Linbao Road, Tinglin industrial Park, JinShan, Shanghai, 201505, China Office Tel: 86-21-34092001 86-21-34092807 Fax: 86-21-34092937 Hitp.//www.unionagrochem.com Email: Info@unionagrochem.com e.g. intraperitoneal toxicity (©) Skin irritation Mild to moderate irritant (Eye irritation slight to moderate irritant (2) Short-term oral No irritation administration (b) Short-term sensitizing 2 weak skin sensitizer in guinea pigs effects 12, Ecological and Ecotoxicological Information Summary of Effects: This pesticide is extremely toxic to fish, bids, bees and other wildlife. Do not apply directly to water, or to areas where surface water is present. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent aquatic sites. (a) Effects on birds Chlorpyriphos Chlorpyrifos is very highly toxie t0 common grackles (Quisealus quiscula) and ring-necked pheasants (Phasiamus colchicus) with an LDSO of 5.62 mykg and 8.41 mg/kg, respectively Chlorpyrifos is highly toxic to common pigeons (Columba livia) and house sparrows (Passer domesticus) with an LDS0 of 10. mg/kg. Chlorpyrifos is highly toxic to chickens with an 02 mgikg. Chlorpyrifos is moderately toxic to mallard ducks oral LDS0 ranging from 32. (Anas platyrhynchos) with an acute oral LD50 of 490 mg/kg, The American robin (Turdus migratorius) is the most frequently reported avian species killed in field incidents with LEAR LART HE A WNlOK GEOL CA CROP ROTECTON TECHNOLOGY COD. BRtb) © @ Lt RGKLARAR SSA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory ad: No.2 Linoao Road, Tinglin industrial Park, JinShan, Shanghai, 201505, China Office Tel: 86-21-34092901 86-21-34092907 Fax: 86-21-34092937 Hup:f/www.unionagrochem.com ‘Email: info@unienagrochem.com Effects on fish Effects on fish food species Effects on honey bees chlorpyrifos. Currently the acute LDSO for the American robin is unknown. Cypermethrin: Minimally toxic to birds. Acute oral LDSO: > 10000 mg/kg (mallard duck: ). > 2000 mg/kg (chickens). Chlorpyriphos: LC50 (96 hh) for bluegill sunfish 0.002-0.010, rainbow trout 0.007-0.051, roach 0.25, fathead minnow 0.12-0.54 mg/l. Cypermethrin: ‘Toxic to fish. LC30 (96 hr): 0.69ng/l (rainbow trout) Chlorpyriphos: ‘The 48-hour LCSO for Daphnia is |.7ug/L. The LCS0 for Korean shrimp (Palaemon ‘macrodactylus) is 0.0Spg/L. Cypermethrin: Very toxic to Daphnia magna. The 48-hour LC50 is 0.15ug /. Chlorpyriphos: Chlorpyrifos is toxic to bees. The honey bee (Apis sp.) oral LD50 is 360ng/bee.2 The contact LDS0 for honey bees is 0.059 pounds active ingredient per bee, or 7Ong/bee Cypermethrin: Highly toxic to bees LDSO (oral): 0.035pg/bee, EE AU aa ihe A iwi ROUEN CAROTID, eRLGR BKMLARARS A UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Linbeo Road, Tinglin industrial Park, JinShan, Shanghai. 201505. China Office Tel. 86-21-3409290186-21-34092907 Fax: 86-21-34092937 Http://www.unionagrochem com Email: Infa@unionagrachem.com LDS0 (topical): 0.02yg/bee. 13, Disposal Considerations WASTE: Pesticide wastes are toxie and hazardous. Dispose of in accordance with applicable and local laws and regulations. Do not discharge or pour into soil, drainage system or bodies of water. CONTAINER: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puneture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorities, by burning (plastic containers). If burned, stay out of smoke. 14, Transport Information Class: 6.1 Packaging group: [IT 15, Regulatory Information Symbols: Xn harmful N dangerous for the environment R22: Harmful if swallowed RS0/S3: Very toxic to aqui organism may cause long-term adverse effects on the aquatic environment. S46: If wallowed, seek medical advice immediately and show this container or label. 835: This material and its container must be disposed of in a safe way. S57: Use appropriate containment to avoid environmental contamination. 16. Other Information All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to pe RBULG RARE 4 ough aR MEO OORT COD. a\ LAR BKLA RARE SA UNION-AGROCHEM CROP PROTECTION TECHNOLOGY CO.,LTD Factory add: No.2 Linbae Road, Tinglin industrial Park, JinShan, Shanghai, 201505. China Office Tel: 86-21-34092901 86-21-34092907 Fax: 86-21-24092937 Hito-i/www.unionagrochem.com Email: info@unignagrochem.com ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipients subsequently produce formulations containing this product, it is the recipients” sole respons MSDS to their own MSDS, to ensure the transfer of all relevant information from this, 4 sr eateea = : ol ea 01008 4 B®