TOSOH The Chemistry of Innovation
CHLOROPRENE RUBBER
SKYPRENE
TOSOH CORPORATION Product Grades and Characteristics
Skyprene is classified according to the types of modifier
that is used;
indicated figure
'® Mercaptan-modified
Molecular weight is controlled with mereaptan
‘¢ Xanthogen-modified
Molecular weight is controlled with xanthogen
© Sulfur-moditied
Molecular weight is controlled with sulfur
Skyprene grades are classified according to the range of
money viscosity and the range of crystallization rate as
ur: pen
trie) merit
§ =
é i i ; i
Pep
So
Fal
4050 40 60 40 60 80
Mooney Viscosity ML (1+4)100°C
Figure-2 Skyprene Grades and Characteristics
— 05 sxvrn:
700
Industrial Applications
Development Chart
ar
modified
Grade
Crystalization
resistance
Lower viscosity Loner viscosity
ystaliztion
resistance
Higher viscosity
Higher viscosity
Mercaptan
crystallization
resistance Higher viscosity
Higher viscosity
Crystallization resistance:
Etongation
Grysalizaon”
resistance
Less staining
Higher viscosity
‘Crystaiztion
Less staining
Loss ting
ort tna
a | teecewe
crsaiatonssnce Faeries
Higher viscosity
Hisher viscosity
Extrusion processability
Tonsle erength Higher viscosity
EU | Torsio store
Higher viscosity
a
Higher viscosity
TisAlis a Industrial Applications
Products and Characteristics
ras |e | Srna ‘ae
BSA 40 ~ 60 | VeryHigh | The slowest cxystalzation rate. Extemely small change In hardness et low temperature,
BS 45 ~ 53 |_ Slow crystalization rate. Low change in hardness at low _temperatur
B10 47 ~ 85 Crytalzation at is intomeciate between 0 and BS.
B-10H 65 ~ 86 High mooney viscosity form of 8-10. | beepaeepteeetet
Bt 45 ~ 53 Crystallization rate is intermediate between 8.30 and 8.5. | ; eto cabioe
B12 36 ~ 44 Low moony Wed om of B11. Hoses
B25 Node’ 45 ~ 53 High elongation form of B-6, ace ie es
8.30 45 ~ 53 General purpose grade of mercaptan modiiad type with a medium rate of crystalization.
8.31 36 ~ 44 Low viscosity form of 8-30.
Y.20E 43 ~ 59 | Medium | The best exrusin chracteriscs ofall Syprene aioe, oflerng emooth fishes on exrusions Sulabe forex pas and calender oducts Eau pac
rms as maven TOS nae
y-31 90 ~ 110 Low viscosity form of Y-308. Sot aes a cables
P-20 40. ~ 50 _| Relatively low | Xenthogen moced ype with cnetaization rate sity faster than B-20, offering extremely high mechanical stength, «Craton ruber parts
£20 43 ~ 53 Extrusion grade with siower crystallization rate,
E-20H Xanthogen 84 ~ 74 ii High viscosity form of E-20,
modified Extruded products
E33 43 ~ 53 Medium | Extrusion grade of xanthogen modiod type with a medium rate of crystallization, offering a good balance of mechanical strength and extrusion characteristics. Calender products
630 100 ~ 120 High High viscosity form of E-20H. iad
640 70 ~ 100 | gh | Eaton sade of mecaptan modified pe with excllentcystalization eitance,
TSR.41 40 ~ 50 Low viscosity fom of TSR-51
TSR-42 40 ~ 60 High Low viscosity form of TSA52.
TSR-44 40 ~ 50 | VeryHish | Low viscosity fom of TSAS4.
TSR-48 45 ~ 53 | Medium —_| simi to 8-90 in all respects, furthermore with superior uidity and less staining for injection molding. ea pits
TSR-51 pa 55 ~ 75 Very High Representative grade of TSR series having slow crystalliz, ation rate and slightly high Mooney viscosity. ee —
TSR-52 65 ~ 78 High ilar © TSA-S1 in all respects except crystallization re | sistance, Crysalization rate is intermediate between TSA-48 and TSR-61, ctl wre ae cables
TSR-54 60 ~ 80 |_The most crystallization resistant grade of TSR series, off | ering the best resistance to heat and dynamic fatigue resistance. aoe
TSR-S7 67 ~ @0 High elastic modulus form of TSR-S1
Very High
TSR-61 90 ~ 110 High viscosity form of TSR51
TSR-70 | 81 ~ 95 High mooney viscosity form of 8-5.
R10 ein High lar to 9-22 in al respects except crystallization rate. 7 : Pe
R22 Lae ( Medium ‘General purpose grade in sulfur modified type with medium rate of crystallization, ee
505 $414 _[ Relatively High | Heat resistance close to that of the metcapian modified _giade, offering better dnamie fatigue resistance. Ingstil ber goods
Note +1: Mooney viscosity at the time of production
—— 07 sevnene
SKYPRENE
Pa Industrial Applications
General-Purpose Grades
‘Skyprene general-purpose grades
‘ GENERAL PROPERTIES
B-30, B-31, Y-30S, Y-31, P-90
Skyprene general-purpose grades’ modulus,
tensile strength, and tear strength are
increased
through the use of raw rubber with a high
mooney viscosity. Their properties are shown in
table 1.
SKYPRENE B-30
Skyprene B30 is a mercaptan-modified,
general-purpose grade with a medium rate of
crystallization and moderate mooney viscosity. It
offers good heat, oil, and weather resistance and
‘good storage stability.
‘SKYPRENE B-31
Skyprene B31 is the low-viscosity form of B-30,
It features good fluidity and dimensional stability
because of its low mooney viscosity. This is
why B31 is suitable for extruding, calendering,
and injection molding. It also features low
calorification during mill mixing, which positively
affects the stability of mooney scorch and
overcomes most other problems during mixing.
SKYPRENE Y-30S
‘Skyprene Y-30S is similar to B-30 in all respects
except mooney viscosity, which is considerably
higher. The high money viscosity helps to reduce
Production costs because it makes it possible to
use a large amount of filler or
To improve
product processability, it is possible to blend
Y-308 with other grades. Y-30S is also used for
adhesives.
‘SKYPRENE Y-31
Skyprene Y-31 is the low-viscosity form of Y-30S.
ry and fluidity are better than that
SKYPRENE P-90
Skyprene P.90 is a xanthogen-modified grade
with high mechanical strength and modulus. Its
crystallization rate is slightly faster than B-20's,
| 99 skvpreNe
‘SKYPRENE PRODUCTS [890/81 ¥-009 V3t
Formulation ‘ohn
SKYPRENE 100
Mgo 4
Stearic acid 05
‘SRF Carbon Black (N-770) 30
2n0 5
Accelerator ETU 05
Total 140.0
Raw Rubber Mooney Viscosity
MUt+4)100 49 | 42 | 127| 100
‘Compound Properties =
Mooney Scorch ML(1}1250.
vm || s2| 46 | 5 | 74
5 [min | 79 | et | 61 | 65
Vuleanizate Properties
(Cuz 20min, at 1600)
H,(OuromoterA) 63 69
i 238) 23.4
Fs 380 | 380
Myo mPa |163/ 159] 17.7| 17.41
‘Aging Test T
(7Ohrs at 100°) :
A 4/a}a|s
AT) -16| -16| -18) -16
ALE) -15| -13|| -24 | -21
Compression Set
(ores at 100%) |
cs % | 96 | 97 | 94 | 36
Low Temperatixe Properties
‘Gehman Torsion Test
i -22.0]-31.6}
i -35.4)-28.3)
if -36.3|-26 2)
Teo -41.0|-40.9)
ainsi a 375-37.
Permanent Sat
(10°C, 200%4Elongation)
Ps % | 423] 190| 114] 116
‘These grea ofr rtrence parses ad arefore d ot seve os
Applications
‘Automotive rubber parts industrial rubber goods,
clectrical wire and cables, hoses, belts and rolls,
anti-vibration rubber, and others
Industrial Applications
Crystallization-Resistant Grades
‘Skyprene Crystallization Resistant Grades
GENERAL PROPERTIES
B5, B-5A, B-10, B-10H, B-11, B-12, B25
‘The general-purpose grades gradually crystallize
at low temperatures,
To improve crystallization resistance, the polymer
molecular structure is made more irregular than
that of general-purpose grades. This slows down,
the crystallization rate. Compared to general
grades, the crystallization-resistant grades
generally have lower vulcanizate properties.
‘SKYPRENE B-5
Skyprene BS has superb crystallization-resistant
properties. This compound is as easy to process as
nonerystalline rubber, even in cold weather.
SKYPRENE B-5A
Skyprene BSA is the most crystallization-resistant
grade in the Skyprene lineup.
SKYPRENE B-10
‘Skyprene B-10 offers a crystallization rate between
that of Skyprene general-purpose grade B30 and
‘Skyprene crystallization-resistant grade BS.
‘SKYPRENE B-10H
Skyprene B-10H is the high viscosity grade of B-10,
‘SKYPRENE B-11
‘Skyprene B-II's crystallization rate is almost equal
to B's
SKYPRENE B-12
Skyprene B-12 possesses the same rate of
crystallization as B-Ll and has a low mooney
viscosity
SKYPRENE B-25
B.25 improves upon the elongation of BS, however
the resistance to crystallization is a bit less than
BS.
[SKYPRENE PRODUCT] 6-5 [8-5A]B-10)3-10H B-11[B-12/B25
Formulation (ph
SKYPRENE 100
Mgo 4
Stearic acid os
SRF Catton Bleck (770) 30
2n0 5
‘Accelerator ETU os
Total 140.0
ee teow
MLit+4)1 00% 47 | 43 | 52 | 70| 46 | 30 | 48
conpourd Poperes
Mooney Scorch
muciyr2sc
Vm s2| 47 | 54) 65 | 52 | 45 | 51
6 _min| 89 | 100) @2| 76| 84| a8] 03
ict Prats
(seztnina 1600)
Original
H(Curometera) | 65 | 65 | 66 | 66 | 66 | 65 | 65
T, Pal 245] 21.1|21.1/ 21.4] 21.1) 216] 228
5 % | 390 | 390 | 380 370| 980 | 390] 410
My MPa 182| 14.7| 149] 18.7| 184] 150] 152
‘Aging Test
(ots 100%)
Ay ps| 4] 6| 5 5/4
Adty) —-% | 16] -13| -23 ~16| -15
A(E) __% | -13| -15| -21 -16 | -16
Compression Set |
Obst 1000
Corres) | 95 | 90 | 35 | 25 | 38 | 38 | 37
Tow Tenperaire
Properties,
Caer fose
"e ‘c |-20.2|-289}-302 -20.3|-30.3|-303}-30.1
% ‘c |-92.9-31.7]-336 -34.0|-245)-249)-22.6]
iT °c |-35.9/-34.7]-95.2|-95.|-36.1| 35:9) -36.1
Ti °C |-885}-97,2|-28.9)-29.5|-99.8)-40.3)-36.4
Te |-35.9|-34.7|-36.4) -36.2|-36.4|-36.9]-36.9]
Permanent Sot
(10 consi,
Ps % 118] 7 | 31] 31] 33 | a7 | 25
‘Those tigros ae ony fr refrence purposes a threore dort serve as
‘ecoains
Applications
‘Automotive rubber parts, industrial rubber goods,
lectrical wire and cables, hoses, belts and rolls,
anti-vibration rubber, and others
cyypReNe
49 —— —
Industrial Applications
Injection Molding Grades
‘Skyprene injection-molding grades
TSR-41, TSR-42, TSR-44, TSR-51, TSR-52
‘TSR-54, TSR-57, TSR-61, TSR-70, TSR-48
Each Skyprene injection-molding grade features these
characteristics:
1. Heightoned resistance to mold staining, reducing the
frequency of washing,
2. Smooth separation of parts from the molds, reducing
defects,
3. Excellent flow in the injection machines and molds,
avoids decreasing mechanical strength at the welded
locations of compounds.
4. Superior stability in storage, minimizing such
problems as scorch and the like.
5. Excellent cold resistance and less change in
hardness at low temperature. The brittle point may be
improved with combinations of specific plasticizers.
6. High heat resistance and mechanical strength,
making these compounds ideal for applications
requiring high reliability, such as car safety devices
and gears.
SKYPRENE
SKYPRENE TSR-51
Skyprene TSR4I is a representative grade from our
lineup for injection molding. This grade displays a slow
crystallization rate and a slightly high Mooney viscosity.
SKYPRENE TSR-41
‘Skyprene TSR41 is low viscosity form of TSRSIL.
SKYPRENE TSR-61
‘Skyprene TSR-61 is high viscosity form of TSR-51.
SKYPRENE TSR-52
Skyprene TSR:
except crystallization resistance. Crystallization rate of
‘TSR'2 is intermediate between TSR-48 and TSRSI.
is similar to TSR-51 in all respects
‘SKYPRENE TSR-42
Skyprene TSR-42 is low viscosity form of TSRS2.
SKYPRENE TSR.54
Skyprene TSR-54 is the most crystallization resistant
grade of the TSR series and offers the best resistance to
heat and dynamic fatigue
SKYPRENE TSR-44
‘Skyprene TSR-44 is low viscosity form of TSR-54.
SKYPRENE TSR-57
Skyprene TSR'7 is @ well-balanced grade in modulus and
resistance to fatigue, TSR57 also has excellent strength,
SKYPRENE TSR-70
Skyprene TSR.70 is similar to B-5 in crystallization
resistance, and high viscosity
SKYPRENE TSR-48
Skyprene TSR-48 is similar to B-30 in all respects,
furthermore it possesses superior fluidity and less
staining properties,
Applications
Automotive rubber parts (boots etc.),
industrial rubber parts, electrical wire and cables,
hoses and rolls, and others
GENERAL PROPERTIES
‘SKYPRENE PRODUGT ‘TSR-41]TSR-42]TSA-44]TSA-51 [TSH 62 |TSA-64]TSA-57]TSA-GI |TSA70|TER-AB|
Formulation on
‘SKYPRENE 100
Meo 4
Stearic acid 0s
‘SRF Carbon Black (N-770) 30
210 5
‘Accelerator ETU o
Total 1400
aw Rubber Mooney Viscosity
Mut ra00'° 44 | 44 | 48 | 66 | os | 71 | 74 | 97 | 98 | a7
‘Compound Properties
Mooney Scorch
MUI 25
Vm so | st | 54 | 64 | 62 | 64 | 68 | 70 | 74 | 50
5 min | 97 | 93 | 106 | 86 | es | 93 | a2 | 76 | 77 | 83
Vulcanizate Properties
(Cure: 20min, at 160°C)
Original |
H,(Durometer-A) | 66 | 6s | 65 | 66 | 66 | 66 | os | 67 | 65 | 66
t Mpa | 213 | 218 | 204 | 215 | 221 | 229 | 220 | 221 | 208 | 232
E, % | 990 | 30 | 400 | 370 | 380 | 410 | 380 | 360 | 350 | 400
Mazo wpa | 148 | 147 | 143 | 158 | 160 | 151 | 159 | 165 | 208 | 162
Aare Tost
(7Obrs at 100%)
Ay pee) 3s] 4/4i]sa]s]s]{2]s3]s5]6
AT) % | 1 | 15 | -8 | -t16 | 18] -8 | -9 | -10 | -14 | -15
AE) % | 13 | 18 | -t0 | -16 | -16 | -10 | -13 | -14 | -14 | -18
‘Compression Set
(ons ane) % | 45 | a | 4 | a | as | a5 | a9 | a9 | o7 | a5
Low Temperature Properties
Gehman Torsion Test
t -299 | -904 | -27.4 | -a02 | -00 | -a03 | -31
os -82.1 | -947 | -306 | -227 | -a1.8 | -a42 | -35.6
ik ~850 | -352 | -31.8 | -252 | -347 | -353 | -a89
fa 2877 | -40.1 | -962 | -a8.4 | -37.8 | -a99 | -a1.1
Te i | 36 . z 6
Permanent Set
(10°C, 200%Etongation)
Ps % {| 4s | 6 | ia | a | 6 | | ts | 0 | 126
+ Thove fees are only fr reference purposes and theelore donot serve as spectatons, Industrial Applications
Extrusion Grades
Industrial Applications
Sulfur-modified Grades
‘Skyprene Extrusion Grades ‘Skyprene Sulfur-modified Grades GENERAL PROPERTIES
¥-20E, E-33, E-20, E-20H, 630, 640 oan al R-22, R-10, 505 SKYPRENE PRODUCT R22 [R10 | 505
a Formulation ‘ohn
‘The characteristies of their standard formulations Formulation ‘ohn Skyprene sulfur-modified grades have sulfur ‘SKYPRENE 100
are indicated in table 4. ‘SKYPRENE links (Sx-.x:2 to 6) in their molecular chains. — i
‘Meo ae : ° Stearic acid 0s
SKYPRENE 206 ena Their characteristics, therefore, differ from those SSRF Carbon Black (N-770) 30
ai ‘SAF Carbon Black (N-770) of mercaptan-modified Skyprene grades in the ___2n0 5
ae : 2n0 following respects : Total 1395;
characteristics among the extrusion grades, Accelerator ETU Raw Rubber Mooney Viscosity
but its mechanical characteristics are inferior |_ Total 1. The molecular chains are degraded by MUA+4)100 42 | 40 | 42
to E-33. It is generally blended with Skyprene hae } mechanical shearing forces, which, in turn, Compara Proper
crystalligationsresistant grade B-10 or with | Melt*#1006 telcos the mooney viscosity eS a7 | 22 | 22
Skyprene general-purpose grade B30. Compound Properties 2. The mooney viscosity drops during the intial 6 ___min_|295 | 276 | 192
SKYPRENE £-33 ML(1)125°C. storage period and then rises gradually. frais Pepa (Cu ‘omit 160°C)
vm 62 57 | 60 71 | 95 | 25 1 aptan-mo ae
Skyprene E-33 is the xanthogen-modified grade 6 min | 70 | 68 | 74 | 63 | 58 | 7.4 . Compared with mercaptan-modifed maces, the HOurometer-A) aja | 7
for extruding. The mechanical properties are the Voleanizate Prope - sullr-mossted grades offer supezior mechanical Ts Mpa | 235 | 228 | 238
same 22 B3Vs In addition, B23 hea an excallent (Cure20minat 160°C) strength, including tensile and tear strength. E % | 490 | 490 | 510
_ Original Their heat resistance, however, is inferior to Mao wpe Eames 15-7
processability and extrudability. E-33 is suitable H,(Durometer-A) 66 | 68 | 67 | 68 | 68 | 69 2 " Tag
that of the mercaptan grades. ‘Aging Tost (70hrs at 100°C)
for extruding and calendering. Te MPa | 19.8) 22.6) 21.4 | 21.7 | 21.4) 208 AY pts 3 3 4
E % | 360 | 360 | 340 | 340 | sao | 330 4. The sulfur-moditied grades adhere more easily adi % [ean -13
SKYPRENE E-20 Myo mpa|a1|34|33|as|s4| a4 to textiles and metals. ALE.) % | -21 | -27 | -16
Skyprene E20 is similar to Ein all espects | Age Test 5. Vuleanizaton is possible through the addition Compression Set
except its better crystallization resistance. (70rvs @t 100) wlalelsilsl7|e of metal oxide, mainly zinc oxide, without the 8 HOpesaaie, * ae) 34
os x %
SKYPRENE E-20H Ast) % | -te|-18 | -t4|-17| 13] -14 need of a vulcanization accelerator. (arene pee S361 49
Skyprene E-20H is the high-viscosity form of E-20. ALE) % {AT} -17 | -15 | -18 | -2t | -2 Gehman Torsion Test
‘Compression Set 1, ‘c |-909]-304|-315
It offers less shape deformation at the time of Ohi at 100°C) SKYPRENE R-22 *
‘vulcanization. ge) | 00 | 35 | 96 | 35 | 96 | 40 fe = eee 2
itannie Skyprene R-2 is a sulfur-modified general-purpose 7 c |-355|-35.1 |-359
Eee Gahran Toston Tost grade having medium rate of crystallization. Tho ‘°c |-407 |-995 |-407
Skyprene 630 is the high-viscosity form of E-20H. T, ‘°c |-s01|-31.7|-902]-208 -200|-20.9| « Te © |-369 |-359 | -37.3
= v1 ; 2 Nese
t ‘c |-5.1|-98.|-03.1/-31.8 -a1.8|-2.2 Seen Perranont Set -10%, 200%Elongation
SKYPRENE 640 n | sselanolanilesalaneleca Skyprene R10 and R22 are similar in all respects PS. «| ee | a1 | a6
Skyprene 640 is a mercaptan-modified extrusion te tc |4oal-41.1|-38.9)-37.8|-28.2|-98.1 : except the hetter crystallization resistance of RO. ‘These ees rc fo een aps ad re dot eed os
i ‘pecteaions
grade with excellent crystallization resistance. Its Te © |-378|-7.4|-85.7/-341|-344] sae] i It is easier to process R-10 in cold weather than
money viscosity is between that of E-20H and 630. Pormanent Set Re 25 .
(108, 200KEbongatin) 1 5B
Ps % |100] 110] 15 | 10 | 10 | 44 SKYPRENE 505 8
us panuuuujlwunun cgeinwena Skyprene 505 has heat resistance close to that of ea)
Toone the mereaptanmodified grades and features beter 5
dynamic fatigue resistance. 8
Applications
Hoses, belts end rolls, electrical wire and cables, sponges, window i
Ponaes Applications
Profiles, automotive rubber parts, industrial rubber goods, rubber
3 6 > 12 15
MONTHS:
Figure-3 Stock stability of R-10, R-22 and 505, change in mooney
viscosity at room temperature
Belts, rubber linings, wet suits, sponges,
industrial rubber goods
coated fabrics, and others
43. SKYPRENE Adhesive Applications Adhesive Applications
Development Chart Products and Characteristics
———=J Mooney 10% Solution Jeysiain] Chip
Prod A charac
ETN ch vecosy oh iezty et | viscosity | Visoosiyes | A
PAR) General Purpose
cere 9 ~O5 ‘Typical grade of fast crystallization rate and excellent initial
408] 81~95" | 200~600 | pps gee
fea Gaosiill leiaeo-dl lecc=sconl. cel for uc in MIU raed acesive er sot PV and emntetc
ond ty cet pose szrtn | e407 |96~113") 600~800
in toluene free adhesive Higher viscosity form of G-40S with superior heat resistance.
‘EDS 70 | = | 1600~2400
tow Viscosity a ‘Thiuram stabilized type. Easily masticated, excellent initial ~~]
1 G41H | 75~90" | 250~500 Seay See OPS Easliymactont a
naan @2_| 36~4a" | 70~130 Lower viscosity form of G-40S. Ideal for use in sprays,
G55 ‘80~96' 300~600 ‘Small | Higher reactivity to isocyanate than G-40S.
B- . Fluidity of the solution is low and higher thixotropy than other
Ee... iM... a es ees | = | 200~1500 ae ae
resistenoe — al ‘Typical grade. Medium crystallization rate, higher heat resistance
isles [Aates Sd Ut 1263) 60051100 ‘and tack retention time.
vea0H |= | 1400~2100
Low voy Higher viscosity fom of ¥-208 wth superior hat resistance
i vsona | — | 1900~2600
& (Medium
S| Heh Viscosity Y-31 | 90~110% 340~660 Lower viscosity form of Y-308.
B30S | 45~53°? | 110~170
|. RESIN vse rixotoy soon Lower viscosity form of ¥-31.
esr | ae~aee | —
co ably satel a pon = a
Coot aha ache Bs | 45~s3 | gloy | 48 | Crvstalization resistant form of B.30S. Effective for
Hest resistant
| sR veracity to teooyerte
i pio [ames | the improvement of ack retention time,
EES ERED 0s ts eesve
510 48~60" | 120~260
| RRTEY cosiy asta iting mS Fast Excellent hea resistance and inital bonding stength
on sto. | as~a7~ | 80~170
- . le mai | TBC ede, Wecium crystallization rate, excaiant eat
v 570 42~64! [Medium| Smail | TyPicel er
High Viscosity, High Viscosity: 580 (35~47"" 60~130
7 \ a Soa xytlizton an ower cation! canter of 570
adtoat soon =| SSS eee foctve tor the improvement of fack retontion tins,
is
ore Eco Friendly
7
coe) ee ave @40TN |96~119"] 600~900 | Fast Eco tiendly gras of G40.
i
ysosn | — | 600~1100 Eco iendly grades of Y-30S
- mai 4
Y-30SAN - 1100~1700 |Medium) Eco friendly grades. Higher viscosity of Y-30SN.
y.a0HaN | — | 1800~2800 Eco tienely grades of Y-S0HA, Hishest viscosity of ¥ Type
S1:ML(1425) 1000 #2:ML (144) 1000
'*3: 10% Toluene soltion viscosity (mPa.s/Brokfeld (BL) type viscometer, 23) Adhesive Applications
General-Purpose Grades
‘Skyprene General-Purpose Grades
B-30S, B-31, Y-31, Y-30S, V-30H, Y-30HA, B-5, B-10,
G-40S, G-42, G-40T, G-70, G-40S-1, G-41H, G-55,
G66
CR-based adhesives are used in wide-ranging
applications. They feature excellent adhesion, flame
| resistance, oil resistance, and
sistance, chei
bonding strength. Skyprene general-purpose grades for
adhesive applications are classified by crystallization
rate and range of mooney viscosity.
B-30S, B-31, Y-31, Y-30S, Y-30H, ¥-30HA
ation rates. The B
a
molecular weight. Both can be used as blends to adjust
‘These grades have moderate crystall
types are low molecular weight and the Y types are
adhesive viscosity.
B-5, B-10
These are crystallization-resistant grades. They are
effective in improving tack retention time.
G-40S, G-42, G-40T, G-70
These grades have a high crystallization rate, The
low molecular weight types, represented by G-42, are
used for spray adhesives. The high molecular weight
types, G-70 show higher heat resistance than their low
molecular weight counterparts and can reduce costs by
lowering the CR content of adhesives.
G-408-1
‘The ideal use for this grade is as MMA.grafted adhesive
for soft PVC or synthetic leather. The coloration of this
solution is better than that of other grades.
G-41H
This grade shows easy mastication and the stability of
adhesive viscosity, and the phase separation stability are
better than other grades.
G55
This grade shows higher reactivity to isocyanates.
G66
This grade shows specific solution properties, such as a
low fuidity in solution and higher thixotropy.
2
5S e
é g
Bonding Properties of Heat Resistant Grades
‘Skyprene Heat Resistant Grades
570, 510, S10L, 680, S80 SKYPRENE PRODUCT | 670 | 810 | ¥00S|G40T
Formulation (ph)
cat resistant ed gra Rubber compound (ming)
Neat resistant carboxylated grades can be fs Ta
readily cured with metal oxide. Due to the rapid Meo
formation of ionic crosslinks, these grades exhibit 200
7 . Pre-reaction (23°0 for 16hvs)
superior heat resistance at temperatures over ikyiphenalic resin 40
BOT. MgO 4
Toluene 80
570 Water o4
‘Skyprene 570 is a representative grade of Heat ales
: 7 ® Toluene 134 | 184] 116 | 126
resistant Grades having a medium crystallization Normal Hexane 128 | 128 | 117 | 12a
vate Ethyl acetate 6 | s6 | 78 | 22
is0 Propancl to | to] - | -
510, 510L, Solid content (H) 255 | 255 | 260 | 267
Skyprene 510 and 5101, are fast crystallization rate _| Solution viscosity (mPa-s/25%C)| 2700 | 2900 | 3100 | 3100,
torm of Heat resistant grades, Peal stength
Bonding strength (at 23°C)
580, 580H ‘ater thr N26nm| 101 | 109 | 73 | 79
4 after 7aays Namen) 167 | 145 | 123 | 123
Skyprene 580 and S80H are slow crystallization Bonding strength at high temp.
rate form of Heat resistant grades. after Sein. (at BO) N/2binen Ge ZO) G ee
ater 7days(at 806) N/25nm| 98 | 97 | 62 | 55
ater 7aays (at 100%) N/2smm| 86 | 76 | 21 | 25
‘These gure are only for eererce purposes and therolore do rot serve as
Higher
Carboxyl content
(Heat resistance)
BD. 2s cysiztization
GRD decdium crystattzation
EBD. 800 crystatization
30 40
50 60 70
Mooney Viscosity ML(1+2.5)100°C
Figure-5 Characteristics and Relationship of Heat resistant Grades
80
SKYPRENE
18 —— Adhesive Applications |
Eco Friendly Grades |
‘Skyprene Eco Friendly Grades Bonding Properties of Y-308 and Y-30SN ‘Storage-stability of ¥-908 and Y-30SN Storage temp. 23°C
Y-30SN, ¥-30SAN, Y-30HAN, G-40TN “Typical formulation Eco Friendly Typical formulation with Toluene EZ Eco Friendly Formulation
with Toluene. ame Y-308 Y-30SN Y-308 Y-30SN
‘SKYPRENE PRODUCT | Y-20S | Y-S0SN | Y30s_| Y-308N | | _
Polychloroprene rubber is widely used | Formulation (orn = a
for dry contact adhesives because of _ |P2be compound (miing) 100 100 ae
‘good adhesion, flame resistance, chemical Mgo 4 4 Original
resistance and high bonding strength. 210. 2 z 4
: nee, | Preeaction (23° for 16h
‘These adhesives are made by dissolving | "Aieyiphenotc resin, 40 40
CCR in organie solvent (tol 4 a ie
nic solvent (toluene, MEK, et) Meo Aa oy
To reduce the effect on environment | Toluene #0 _ t
and human health, the harmful solvent — | _Normal Hexane 80 Z
(Benzene, Toluene, Xylene (BTX)) should [Solvents = =
be decreased in the adhesives. aa 1s 80 . ns (
However changing composition of | Normal Hexane 129 80 j
Sot ees ds cade Ethyl aootate 86 80 ener
solvent might cause the problem of phase | Recions ba 5 1 week ‘
separation on adhesives in storage period. [Sod content oy 258 273
TOSOH developed Eco Friendly Grades, | Solution viscosity mPa-s/25t)| 2680 | 2510 | 2410 | 2960
which improve stability against phase | Stability at 230)
‘co Fri ive tike | ofiginal no separation) no seperation ro seperation |no separation
separation for Eco Friendly Adhesive like eer CC eate ene
a toluene-free formulation. aftor 1 month no senaratin|ro separation Phase sparen separation =a
after 3 months Pate sxx separation Pas seat no separa Saas
Peet srength (Original) -
Bonding strength at 23°C After
after thr (N/25mam)) 73 7 103 90 1'month
after Zdays (N/25mm)) 163 | 171 172 | 171
Bonding strength at 80°C
after Zdays _(N/25mm)|_—_ 56. 53 61 e2
+Thes res are ony fo reterencs purposes and hertore donot sere ae specications,
Line up of Eco Friendly Grades
Product | Crystallization Rate | 10% Toluene solution Visooslty (mPa-s) ? ete
| ¥-S0SN Medium {600~1100
¥-S0SAN Medium 4100~4700
Y-S0HAN Medium +1900~2900 j
GAOTN Fast ‘600~900 i
19 sevrrene SKYPRENE 29 —— LATEX Grades
Products and Characteristics
Latex Grades
LA-502, LA-410, LA-710, LA-660, GFL-280, GFL-820
GFL-890, SL-360, SL-390, SL-590, LH-430
Volatilization of organic solvents in the atmosphere
can cause fires and have an adverse effect on the
environment and human health. Therefore the necessity
for more solvent-free products is growing. Tosoh has
developed Skyprene Latex as one type of chloroprene
rubber to replace solvent-based materials used for
industrial and adhesive applications.
Industrial Applications
8 tAbe0
F | tanto LA-410
& GFL-890
8 GFL-280
BB feb fans areal
& i i
= i
: GFL-820 -
Slow+ Crystallization rate Fast
Figure-6 Characteristics and Relationship of Latex Grades,
Product —[Oystalizaton rato Characteristios Replication
LA502__| Medium | Typical grado for industrial application ad
LA-410 [Relatively Fast| Excellent physical properties and ebrasion resistance. aera
LATIO Slow | Excellent erystalization resistance.
Adhesive Applications
i “Anion latex for Bonding urethane foams by 2 components | Adhesive
tA660 | Medium | adhesive. (wet contact)
GrL2e0 | Fast - ;
me Carboxylated anionic latex. Excellent stability and bonding Adhesive
jum | stenath. (ary contact)
ae Medi
Fast
Special Applications
490 = ‘Special anionic latex. Surface treatment
[GFL}is a registred trademark of TOSOH CORPORATION
—— 24 severene
Latex Grades
Industrial Applications
La types General Properties of LA Types
These types have excellent stability [Product EABO2, HAsO, Leno,
and their vuleanization products exhibit | Polymer Type Sobrerrere
superior properties. Products made from [Emus hea =|
bepeeinaieictacd 7 . Solid content (%) | 61 ~ 55 50 ~ 54 50 ~ 84
LAALO show excelent physical properties jy Tada ST aa
and high abrasion resistance. The | Grystalization Rate| Medium | Relatively Fast| Slow
vuleanization product made from LA-710 Suength, Abrasion) Crystallization
has good crystallization resistance. Characteristics [General-Purpose "resistance | _ resistance
Latex Grades
Adhesive Applications
GFL Types
GFL types are designed for dry contact adhesive
applications. They have the advantages of gel-free
components and higher cross-linkability with ZnO.
‘This is superior to those of traditional carboxylated
chloroprene latex. In addition, the GFL types have better
mechanical, chemical and electrolytic stability than
traditional anionic latex.
SL Types
‘The SL types have fast crystallization rate, and they
also display good bonding strength causedl by gel-free
‘components, same as GFL types.
fore
he
SL types can be used for wet-contact adhesive by
‘The stability of latex is influenced by pl value
adjusting the pH.
General Properties of Latex Grades for Adhesive Applications
LA-660
‘The stability of LA-660 has been adjusted for two
components PU foam adhesives. The LA-660 polymer
has a high molecular weight as well as high gel content,
while the crystallization rate is medium. This means that
the bonding strength and heat resistance are very high,
whereas the adhesive layer is soft.
Product GFL-820 GFL-890 GFL280 A660
Polymer Type ‘Chloroprene-Methacryiic acid Chioroprene
Emusifier Aionic Frosin salt
pH ae i2~14 |
Gel content| High
Salid content (%) 51 ~ 56
Molecular Weight Low s Very High
Crystallization Rate| Medium ‘Medium Medium |
‘Stability
Mechanical Good Good
Storage Good Good
Electrolyte Good Unstable ne owe
severene 22 —— TOSOH
TOSOH CORPORATION
Headquarters
‘Addr: 82, Shiba, Minato-ku, Tokyo 105-8823, Japan
Telephone: 8135427 5148 Fax: 48195427 5210
Emailsercam@tosoh.o.p URL: www.t080h 9,
Research Laboratory
‘Aree: 4560, Kaiseicho, Shunanshi, Yamaguchi 746.850", Japan
“Telephone: +81 834 689915. Fax: +81 838 639995
For Direct Import & Ready Stock Contact
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