CHEMISTRY Max. Marks: 80 SECTION —1 (SINGLE CORRECT CHOICE TYPE ) This section contains 7 multiple chaice questions. Each question has 4 choices (A), (B), {C) and (D) for lis answer, out of which ONLY ONE is correct 1 1. CHGl, base 2. Butanoyl chloride, AICI; 3. Zn(Hg), HCI 4. conc HBr, heat 2-bromophenol The IUPAC name of the product in the above reaction is A) 1-butanoyl-3-bromo-4-methoxybenzene B) 2-bromo-4-butylphenol C) 3-bromoe1-butyl-4-methoxybenzene D) 3,4-dibromo-1- butanoylbenzene19. In how many of the following cases ,after dehydration with conc.H;S0j no of sp* stereogenic centers of major product will be same as in reactant? oH Hs ber G& new CH HO’ 20. No of distinguishable possible products (excluding stereo isomers) in the following reaction is/are... ce 1,2-dimethyl cyclohexane-1,2-diol ——* __preduet(s).cosider only carbonyl eampounde,[Narayana IIT Academy 23.0B-13_St-IT4ZCO-SPARK_JEE-ADY_(201 PI_RPTA4_@.Poper 17 on hy, Aromatic Ht ce heme Product CH No of enolisable protons (Consider keto form of the product) in the product is 18. How many of the following phenols are more acidic than p-cresol? POO 9 OCH, oH OH ee at F a oN :ao 7 musts A) Only one product is possible. B) Product(s) cannot have heterocyclic isomer. C) Product is non aromatic compound. 1D) Product is a carbonyl compound, HsC tH nes Jones product(s) Feayent OH A) Only one product is pos: B) One of the compounds (alcohol) gives turbidity very slowly with Lucas reagent. C) All the product(s) have same no of carbons. D) None of the above statement is correct, SECTION -1V INTEGER TYPE {This section contains 7 questions. The onswer to each question is @ single digit Integer ranging from 0 10.9. The correct digit below the question number in the ORS is 10 be bubbled }14 Which of the following are correctly matched? (Avis ‘OH Hs. CH Ox D) oC oH Paragraph for Questions Nos. 15 to 16 ‘Oxidation of alcohols with Jones reagent gives rearranged and also fragmentized product(s). If tertiary alcohol is present, it will give rearranged products with the help of Carbocation formation, . _" A H Be Ncja 9 | a s RO “GHSECTION - Ili (PARAGRAPH TYPE) Thic tection contains 2 paragraphs. Each of those questions has four choices al, b), ¢) ond d} out of which ONLY ONE Is corract PAS$AGE-1 cuel, HP Tet) EO OH ™ oe =e peo 55 eae compound {) EEG) ia ( HCI 12. Which of the following option is incorrect? A) No of positional isomers of G is 2 B)E on heating in the presence of Se gives an aromatic compound. C) D forms blue color solution in the Victor Meyer test. D) No of 2' carbons in E are 8, 13. Gis A) A non aromatic compound, B) Aromatic compound with 2 canonical structures C) RE of G per ring is lesser than that of Benzene. D) A heterocyclic compound.rronayur nt eseen soverny srnsemarnnn gene ayn rine nay sere 8. Which of these is an acceptable synthesis of phenetole (ethyl phenyl ether)? CH,CH,ONa CH,CHL ee A) Chlorobensene B) Sodium phenoxige 100" 70°C : (CHyCH0),80y CH,CH,OH, HS0, 2) Sodium phenoxide Phenol —CHZCHROH HaSOs 9 a 1o0*C D) 70°C 9. neo {O))—at-o-c8 NO; One male of HI ee Products are A) reeo{(C)) ot By Oalt (Cpt Q neo {(C)—arex D) on (CO) cenWhich of the following represents preperation of phenol ? (7 oe LE ie Ay ° HGHy 1. O.373 » Shae 30,Na Cr + anon USE C) cn H (aq) Dd) e Final product of the following sequence is H * Keo, PhMg Br. HOt, pee J Ca,” * e "aa? Which of the following option(s) is/are correct? A) The unsaturated ketone of A is not possible B) C gives blue colour solution in Victor Meyer test C) Dis a homologous of A D) A and C gives turbidity immediately with Lucas reagentWhat would be the major product of the following reaction? re i) NaBHy “a 4 i Nall, EGO “9 o=b=0 Gcusche A) CH\CH,OCH(CH;)CH;CHCH:CHs B) (CHj;CH20);CHCHOHCH2CH2CH3 C) (CH)CH;);CHOHCH;CH;CHOHCH, D) CH\OCH(CHs)CH3CHsCH3CHs E) CHsCH2CH(OCHs)CH:CH:CHOHCHs 7. Which of the following is wrong: A) PMMA is called plexiglass B) PTFE is called teflon ©) SBR is called natural rubber D) LDPE is called low density polyethylene SECTION - Il (MORE THAN ONE TYPE) This section contains 4 multiple choice questions. Each question hos four choices a}, b}, €, d) out of which ONE OR MORE may be correctfresno sowerty sunnenwcornnn seen ere 4. Which is the best way to prepare 3-methoxypentane via the Williamson method? A) CH,OH +CH,CH CHOHCH,CH, + H,SO,, 140°C B) CHO +(CH,), CHCH,CH,OH +H,50,, 140°C C) CH,ONa+ (CHCH,), CHBr D) CHI +(CH,CH,),CHONa 5. The final product, D, in the following reaction sequence, ces cHeHOH Py Ma Vv 0 a ee oh ~ would be? Cr:CHOCH.CH, OM cHiCHCH,cHor A) B) | Cis CH CHyCHCH:CH.OH CHICHOCH.CH, I by CH CHnorayang mi mcogemy soverne atINeR Worn seem (AV! rime ecroper 2. What product is likely to be obtained by the action of Ag’ or Fe’? on the following substance? oH cH, : oO * Ag’ or Fe” oH Which of the fallowing option is incorrect is for this reaction? A) Itis a redox reaction B) Quinone derivative is the final product CC). The final product can show tautomerisation D) The reactant can not be inhibitor in the free radical reactions. Which is the leaving group when the following substance reacts with sodium cyanide in DMSO solution? 1 Br er Il ven Ko. v A) I B) 0 om D) IV21. In how many of the following reactions alcohol is the majar product? me Hy ci 1H Hy Ny HNO, HNO, ES tek Le: ENO sctuct ie CH MgCl 7.) BS oat 8 Co pat 2p HMBC uct 22. How many of the polymers following polymers are co-polymers? ‘Teflon Bakelite Novolac Melamine Glyptal — Buna-S Buna-N Polythene PVC = PHBV =-HDPE_—LDPE Bicarbor ye lic 2 Na HCL LATE, Cu ‘Aromatic, —N&e (g) HCL, ¢)_tHAMHs, (Cu arbenyt compound = gas OTC a OS ov'e 23 (A) None of the compound gives iodoform test. ‘The minimum no of possible C-H bonds in A is 2X.The value of X is CHEMISTRY wo wy o w > » o ns c il6 A e ABCD] 9] AD fio] ABC ai] AB [12] B a alla = o 1s] A jis] D a7] 2 Yas] 7