Cambridge International Advanced Subsidiary and Advanced Level

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Cambridge Assessment International Education

Cambridge International Advanced Subsidiary and Advanced Level
*6968103562*
CHEMISTRY 9701/52
Paper 5 Planning, Analysis and Evaluation February/March 2019
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
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Do not use staples, paper clips, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES.
Answer all questions.

Electronic calculators may be used.
You may lose marks if you do not show your working or if you do not use appropriate units.
Use of a Data Booklet is unnecessary.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part question.
This document consists of 9 printed pages and 3 blank pages.
IB19 03_9701_52/3RP
© UCLES 2019 [Turn over
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2
1 The reaction between hydrogen peroxide, H2O2(aq), and iodide ions, I–(aq), takes place in acidic
conditions.
H2O2(aq) + 2I–(aq) + 2H+(aq) I2(aq) + 2H2O(l) reaction 1
The rate of this reaction can be found by measuring the time taken for a given amount of iodine,
I2(aq), to form.
This is done by adding a known amount of thiosulfate ions, S2O32–(aq), and allowing the I2(aq)
formed in reaction 1 to react with the S2O32–(aq).
I2(aq) + 2S2O32–(aq) 2I–(aq) + S4O62–(aq) reaction 2
After the S2O32–(aq) ions have all reacted in reaction 2, any further I2(aq) formed in reaction 1 can
be detected using an indicator.
A student carried out a series of experiments to determine the order of reaction with respect to the
concentration of I–(aq) ions in reaction 1.
The student prepared the following solutions.
solution A 0.100 mol dm–3 KI(aq)
solution B 0.0500 mol dm–3 Na2S2O3(aq)
The student also had access to the following chemicals.
solution C 0.100 mol dm–3 H2O2(aq)

0.2 mol dm H2SO4(aq)
–3
distilled water
a suitable indicator
(a) The student prepared solution A in a 250 cm3 volumetric flask.
(i) The student used a balance accurate to two decimal places and a weighing boat. A
weighing boat is a small container used to hold solid samples when they are weighed.
Determine the mass, in g, of KI needed to prepare 250.0 cm3 of solution A.

[Ar: K, 39.1; I, 126.9]
mass = .............................. g [2]
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3
(ii) The student weighed the empty weighing boat. The student then added solid KI to the
weighing boat until the mass of KI calculated in (i) was reached. The student transferred
all of the KI from the weighing boat into a 100 cm3 beaker.
Describe how the student could check that the mass of KI transferred into the 100 cm3
beaker was exactly the same as the mass calculated in (i).
.............................................................................................................................................
....................................................................................................................................... [1]
(iii) The student dissolved the KI in the 100 cm3 beaker in distilled water and transferred the
solution formed into a 250 cm3 volumetric flask. Distilled water was added to the volumetric
flask until the volume of the solution was exactly 250 cm3. Care was taken to avoid parallax
errors.
Describe:
● how the student should transfer all the KI solution from the beaker into the 250 cm3
volumetric flask
● how the student should fill the volumetric flask exactly up to the 250 cm3 mark.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
(b) The student rinsed a burette with solution A before filling it with solution A.
Explain why this improves the accuracy of the results.
....................................................................................................................................................
.............................................................................................................................................. [1]
(c) The student was given a solution of 0.400 mol dm–3 Na2S2O3(aq).
Determine the volume, in cm3, of this solution that should be added to a 100 cm3 volumetric
flask to prepare 100.0 cm3 of solution B. Give your answer to two decimal places.
volume = .............................. cm3 [1]
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(d) Experiment 1 was carried out using a series of steps.
step 1 The student used a measuring cylinder to measure 25 cm3 of 0.2 mol dm–3 H2SO4(aq).
This was transferred to a conical flask.
step 2 The student added 20.00 cm3 of distilled water from a burette to the conical flask.
step 3 The student added 5.00 cm3 of solution A from a burette to the conical flask.
step 4 The student added 5.00 cm3 of solution B from a burette to the conical flask.
step 5 The student added 1.0 cm3 of indicator from a teat pipette to the conical flask.
step 6 The student used a burette to add 10.00 cm3 of solution C to a small beaker. The
contents of the beaker were added to the conical flask and a stopclock was started
immediately. The stopclock was stopped when the I2 formed caused the indicator to
change colour.
In Experiments 2–6 the student repeated steps 1–6 but using the volumes of distilled water
and solution A given in the table.
The student carried out two trials of each experiment.
volume of time for the indicator

volume of volume of volume of volume of to change colour, t
distilled
experiment H2SO4(aq) solution A, v solution B indicator /s
water
/ cm3 / cm3 / cm3 / cm3
/ cm3 trial 1 trial 2
1 25.0 20.00 5.00 5.00 1.0 218 220
2 25.0 15.00 10.00 5.00 1.0 112 113
3 25.0 12.50 12.50 5.00 1.0 100
4 25.0 10.00 15.00 5.00 1.0 77 76
5 25.0 5.00 20.00 5.00 1.0 59 59
6 25.0 0.00 25.00 5.00 1.0 47 49
(i) In Experiment 3, trial 2, the indicator changed colour as soon as the student added
solution C to the conical flask. No results were recorded for Experiment 3, trial 2.
Suggest which step the student did not carry out in Experiment 3, trial 2.
....................................................................................................................................... [1]
(ii) Suggest why the results shown in the table could be considered reliable.
.............................................................................................................................................
....................................................................................................................................... [1]
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5
(iii) What was the percentage error in the burette reading for measuring the volume of
solution A in Experiment 5?
percentage error = .............................. % [1]
(iv) Suggest why a measuring cylinder was used to measure the volume of H2SO4(aq) rather
than a more accurate piece of apparatus, such as a burette.
....................................................................................................................................... [1]
(v) For Experiments 1–6, state:
● the independent variable .............................................................................................
● the dependent variable. ...............................................................................................

[2]

6
(e) The rate equation can be written as rate = k[I–]n where [I–] is proportional to the volume of
solution A and n is the order of reaction with respect to I–.
(i) Use only the results of Experiments 1–6 given in (d) to complete the table where:
● v is the volume of solution A used in cm3

● tav is the average time taken in trial 1 and trial 2 in s.
Give all values to three significant figures.
experiment v / cm3 log v tav / s (1/tav) / s–1 log(1/tav)
1 5.00
2 10.00
3 12.50 100 0.0100
4 15.00
5 20.00
6 25.00
[2]
(ii) Rate can be expressed as (1/tav).

The rate equation can be expressed as shown.
log(1/tav) = nlog v + c
where:
● c is a constant
● v is proportional to [I–].
On the grid:
● Plot a graph of log(1/tav) against log v. Use a cross (×) to plot each data point.
● Draw a line of best fit.
[2]
(iii) Use your graph to determine the gradient of the line of best fit. State the coordinates of
both points you used in your calculation. Give the gradient to three significant figures.
Determine the order of reaction with respect to I–(aq).
co-ordinates 1 ............................................. co-ordinates 2 .............................................
gradient = ..............................
order of reaction with respect to I–(aq) = ..............................

[3]
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7
–1.60
–1.70
–1.80
–1.90
–2.00
log (1/tav)
–2.10
–2.20
–2.30
–2.40
–2.50
0.6 0.7 0.8 0.9 1.00 1.10 1.20 1.30 1.40
log v
[Total: 20]

8
2 A student was given a sample of an unknown Group 2 chloride. The student dissolved 3.172 g
of the unknown Group 2 chloride in distilled water in a beaker and added an excess of aqueous
silver nitrate, AgNO3(aq), to the beaker.
A white precipitate of silver chloride formed.
(a) Write the ionic equation, including state symbols, for the reaction occurring.
.............................................................................................................................................. [1]
(b) To separate the filtrate from the residue, filtration can be carried out using gravity or by using
reduced pressure.
The student decided to filter the mixture under reduced pressure.
(i) Complete the labelled diagram to suggest how the student could filter the mixture under
reduced pressure.
to suction pump
(to reduce the pressure
in the conical flask)
filtrate
[2]
(ii) Suggest one major advantage of filtering the mixture under reduced pressure compared
with filtering using gravity.
....................................................................................................................................... [1]
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9
(c) The student rinsed the residue, transferred it to a crucible and placed it in a warm oven to dry it.
(i) What should the student do to ensure that the drying process is complete?
....................................................................................................................................... [1]
(ii) The student recorded the masses shown in the table.
Complete the table to calculate the mass of dry silver chloride formed. Use this value to
determine the number of moles of silver chloride formed.
[Ar: Cl, 35.5; Ag, 107.9]
mass of crucible + dry silver chloride / g 24.898
mass of empty crucible / g 19.162
mass of dry silver chloride / g
moles of silver chloride formed = .............................. mol [1]
(iii) Use your answer to (ii) to calculate the mass of one mole of the Group 2 chloride and
hence identify the Group 2 metal present in the chloride.
If you were unable to calculate an answer in (ii), assume that 0.0304 mol of silver chloride
formed. This is not the correct value.
[Ar: Be, 9.0; Mg, 24.3; Ca, 40.1; Sr, 87.6; Ba, 137.3]
mass of one mole of the Group 2 chloride = .............................. g
identity of the Group 2 metal = ..............................

[3]
(iv) State and explain how the number of moles of silver chloride formed in (ii) would change
if the student used tap water instead of distilled water to dissolve the Group 2 chloride.
.............................................................................................................................................
....................................................................................................................................... [1]
[Total: 10]

10
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Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.
Cambridge Assessment International Education is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of the University of
Cambridge Local Examinations Syndicate (UCLES), which itself is a department of the University of Cambridge.
© UCLES 2019 9701/52/F/M/19


*1086226346*
CHEMISTRY 9701/51
Paper 5 Planning, Analysis and Evaluation May/June 2019
1 hour 15 minutes

This document consists of 11 printed pages and 1 blank page.
IB19 06_9701_51/5RP
2
BLANK PAGE
© UCLES 2019 9701/51/M/J/19

3
1 A student investigates the charge (z+) carried by aqueous manganese ions, Mnz+(aq). The
electrochemical cell shown is set up for this investigation with the following two half-cells:
● a standard copper(II) ion / copper half-cell (E o = +0.340 V)

● a half-cell made from manganese and 0.500 mol dm–3 Mnz+(aq).
(a) Label the items P and Q and state the concentration of the copper(II) ion solution in the copper
half-cell.
P ........................................
copper manganese
copper(II) ion 0.500 mol dm–3

solution aqueous Mnz+(aq)
Q ........................................
concentration of the copper(II) ion solution in the copper half-cell = ........................................

[1]
(b) During the investigation the student plans to use solutions of Mnz+(aq) of lower concentration
than 0.500 mol dm–3.
(i) Calculate the volume of 0.500 mol dm–3 Mnz+(aq) needed to prepare 100.0 cm3 of
0.200 mol dm–3 Mnz+(aq).
volume = .............................. cm3 [1]
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(ii) Describe how, using a 100 cm3 volumetric flask, the student should prepare exactly
100.0 cm3 of 0.200 mol dm–3 Mnz+(aq) using the volume of 0.500 mol dm–3 Mnz+(aq)
calculated in (b)(i) and standard school or college apparatus.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
The cell potential of the electrochemical cell in (a) is measured. The 0.500 mol dm–3 Mnz+(aq) is
then replaced by the 0.200 mol dm–3 solution and the cell potential is measured again. This is
repeated for other lower concentrations of Mnz+(aq). All measurements are made at 25 °C.
(iii) The results of the experiment are shown in the table.
Complete column three of the table, calculating log[Mnz+] to two decimal places.
Complete column four of the table, calculating E, the electrode potential of each manganese
half-cell, to three decimal places, using the equation shown.
E (manganese half-cell) = Ecell + 0.340 V
electrode potential
[Mnz+]
cell potential, Ecell / V log[Mnz+] of each manganese
/ mol dm–3
half-cell, E / V
5.0 × 10–1 –1.529 –0.30 –1.189
2.0 × 10–1 –1.541
1.0 × 10–1 –1.550
7.5 × 10–2 –1.553
2.5 × 10–2 –1.567
8.0 × 10–3 –1.582
6.0 × 10–3 –1.590
4.0 × 10–3 –1.591
3.0 × 10–3 –1.594
5.0 × 10–4 –1.617
[2]
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5
(c) Plot a graph of electrode potential of manganese half-cell (y‑axis) against log[Mnz+] (x‑axis).
Use a cross (×) to plot each data point. Draw a line of best fit.
log[Mnz+]
–3.0 –2.0 –1.0 0.0
–1.16
–1.17
–1.18
–1.19
–1.20
–1.21
electrode
potential of
manganese
half-cell, E / V
–1.22
–1.23
–1.24
–1.25
–1.26
–1.27
–1.28
[2]

6
(d) (i) Circle the most anomalous point on your graph. [1]
(ii) The student is careful to ensure that all solutions used are at the same temperature in all
experiments.
Suggest a possible explanation for the position of the anomalous point circled in (d)(i)
relative to the line of best fit.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(e) Your graph is a plot of E against log[Mnz+] and can be analysed using the Nernst equation at
25 °C.
0.059
E = Eo + log[Mnz+]
z
z is the value of the charge carried by the manganese ion

E is the electrode potential / V
E o is the standard electrode potential / V
Use the Nernst equation and your graph to find the standard electrode potential, E o, of the
manganese half-cell.
E o = .............................. V [1]
(f) (i) Determine the gradient of the graph.

State the co-ordinates of both points you used for your calculation.
Record the value of the gradient to three significant figures.
co-ordinates 1 .............................................. co-ordinates 2 ..............................................
gradient = ..............................
[2]
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7
(ii) Use your answer to (f)(i) and the Nernst equation to calculate the value of z to three
significant figures and give the formula of the manganese ion.
Your calculation must show the use of the Nernst equation.
(If you were unable to calculate an answer to (f)(i) you may use the value 0.0197. This is
not the correct value.)
z = ..............................
formula of manganese ion = ..............................

[2]
(g) Lowering [Mnz+] causes the value of the electrode potential of the manganese half-cell to
become more negative.
Suggest why this happens.
....................................................................................................................................................
.............................................................................................................................................. [1]
[Total: 16]

8
2 A student plans to prepare propanone from propan-2-ol and test the product. Reagents provided to
the student and some of their hazards are shown in the table.
reagent hazard
propan-2-ol flammable
concentrated sulfuric acid corrosive
potassium dichromate(VI) oxidising
distilled water non-hazardous
(a) (i) The full equation for the reaction between propan‑2‑ol and acidified potassium
dichromate(VI) is shown.
3CH3CH(OH)CH3 + K2Cr2O7 + 4H2SO4 3(CH3)2CO + K2SO4 + Cr2(SO4)3 + 7H2O
Calculate the minimum mass of potassium dichromate(VI) that is needed for complete
oxidation of 5.00 g of propan‑2‑ol to propanone. Give your answer to three significant
figures.
[Ar: K, 39.1; Cr, 52.0; O, 16.0; C, 12.0; H, 1.0]
mass K2Cr2O7 = .............................. g

[2]
© UCLES 2019 9701/51/M/J/19

9
(ii) The student is provided with a set of instructions to prepare the propanone.
step 1 Add concentrated sulfuric acid to 5.0 g of propan‑2‑ol in a round‑bottomed flask,

a few drops at a time.
step 2 Dissolve the mass of potassium dichromate(VI) calculated in (a)(i) in a few cm3
of distilled water.
step 3 Add this aqueous potassium dichromate(VI) slowly to the mixture in the
round‑bottomed flask.
step 4 Heat the mixture under reflux.
step 5 Separate the propanone from the reaction mixture using distillation.
The student is also provided with the boiling points of propan-2-ol and propanone.
compound boiling point / °C

propan-2-ol 82.5
propanone 56.5
Complete the diagram to show how the propanone is separated from the reaction mixture
in step 5.
Label your diagram fully including the location of propan-2-ol and propanone after
distillation has taken place. There is no need to include clamps.
clamp
heated collection
water-bath flask
round-bottomed
reaction flask
mixture
[3]

10
(iii) The reaction mixture needs heating for reflux to take place.
Explain why a water‑bath is used to heat the mixture.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(iv) The propanone separated from the mixture in step 5 contains sulfuric acid as an impurity
which needs to be removed.
Name a reagent that could be added to remove the sulfuric acid and explain how the
student would ensure that all of the acid is no longer present.
reagent ...............................................................................................................................
explanation .........................................................................................................................
.............................................................................................................................................
[2]
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11
(b) (i) When propanone reacts with a solution of 2,4-DNPH an insoluble compound, X, is
produced according to the following equation.
2,4-DNPH
CH3
N C
H2N NH HN CH3
NO2 NO2
CH3COCH3 + + H2O
NO2 NO2
The melting point of X can be used to confirm the identity of the carbonyl compound that
has reacted with 2,4-DNPH. To do this, solid X must be separated from the mixture.
This can be done using method A or method B.
Buchner funnel
suction pump
Buchner flask
method A: gravity filtration using a filter funnel, filter paper and a conical flask
method B: filtration under reduced pressure using a Buchner funnel and Buchner flask,
filter paper and a suction pump to reduce the pressure in the Buchner flask
Suggest one major advantage of using method B rather than method A.
.............................................................................................................................................
....................................................................................................................................... [1]

12
(ii) The student places a washed sample of X in a drying oven for an hour. The student
records the mass of X. The student wants to ensure that X is completely dry.
Describe what the student should do to ensure that X is completely dry.
.............................................................................................................................................
....................................................................................................................................... [1]
(iii) 5.00 cm3 of propanone reacts with an excess of 2,4‑DNPH. The mass of dry X produced is
11.84 g.
Calculate the percentage yield of X in this reaction.
Mr X = 238
Mr CH3COCH3 = 58
density CH3COCH3 = 0.789 g cm–3
percentage yield of X = .............................. %

[3]
(iv) Explain why a 100% yield in the preparation of a pure sample of X is not possible.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
[Total: 14]
© UCLES 2019 9701/51/M/J/19


*9915509939*
CHEMISTRY 9701/52
Paper 5 Planning, Analysis and Evaluation May/June 2019
1 hour 15 minutes
MODIFIED LANGUAGE

This document consists of 10 printed pages and 2 blank pages.
IB19 06_9701_52_ML/RP
2
1 (a) A student is provided with samples of six metal carbonate ores, known to be ores of the metals
barium, calcium, copper, iron, lead and zinc. All the ores contain carbonate ions and some
might also contain hydroxide ions.
Each ore sample is ground up and a measured mass of the ore is reacted with an excess of
dilute hydrochloric acid. The carbon dioxide produced by the reaction is collected over water.
The volume of gas collected is recorded. Each ore is tested three times.
(i) Name the independent variable.
.............................................................................................................................................
Name the dependent variable.
.............................................................................................................................................
[2]
(ii) Apart from mass of ore, state a variable that should be controlled.
....................................................................................................................................... [1]
(iii) The student plans to collect the carbon dioxide produced over water.
Draw a labelled diagram of the apparatus that could be used to do these experiments.
The apparatus should allow the accurate recording of the carbon dioxide produced.
[3]
(b) State one weakness in the procedure of collecting carbon dioxide over water.
Suggest a change in apparatus that could be made to avoid this problem.
weakness in procedure
....................................................................................................................................................
change in apparatus
....................................................................................................................................................
[2]
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3
(c) Three experiments for each of the six ores are done and the final gas volumes are recorded in
the table. All 18 experiments use exactly the same mass of ore.
volume of CO2 collected / cm3

metal ore calculated
Expt 1 Expt 2 Expt 3
average
barium witherite 67 70 69 69
calcium calcite 81 79 82 81
copper malachite 47 45 46 46
iron siderite 68 55 70 64
lead cerussite 75 73 72 73
zinc smithsonite 53 55 52 53
(i) The student uses the results to obtain an average volume of CO2 produced for each ore
and records it in the table.
Suggest another reason why each ore is tested three times.
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) The student made an error in processing the data to obtain the average volume of CO2
produced for one of the ores.
State the error made by the student and calculate the correct value.
error ....................................................................................................................................
.............................................................................................................................................
correct value = .............................. cm3

[1]
(d) A second student suggested that the percentage of carbonate ions could be obtained by
titrating the ground-up ore samples with hydrochloric acid.
Explain why a titration would not be a suitable method to determine the percentage of carbonate
ions in some of these ore samples.
....................................................................................................................................................
.............................................................................................................................................. [1]

4
Rhodochrosite is the carbonate ore of manganese and does not contain hydroxide ions.
(e) (i) 2.00 g of rhodochrosite produced 148 cm3 of carbon dioxide under room conditions in its
reaction with excess hydrochloric acid.
MnCO3 + 2HCl MnCl 2 + H2O + CO2
Calculate the percentage of MnCO3 in rhodochrosite. Give your answer to three significant
figures.
The molar volume of a gas is 24.0 dm3 under room conditions.
[Ar: Mn, 54.9; C, 12.0; O, 16.0]
percentage of MnCO3 in rhodochrosite = .............................. %

[3]
A teacher suggested that the mass change from the thermal decomposition of a ground-up
sample of rhodochrosite could be used to determine the percentage of carbonate in the sample.
The teacher told the students to strongly heat a ground-up sample of the ore in a crucible.
(ii) State the measurements the students should make to determine the percentage of
manganese carbonate in the sample of rhodochrosite.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(iii) Explain how the students can ensure the results in (e)(ii) are as accurate as possible.
.............................................................................................................................................
....................................................................................................................................... [1]
[Total: 16]
© UCLES 2019 9701/52/M/J/19

5
2 (a) An investigation is done to find the percentage of copper in a brass nail. The brass nail is
dissolved in concentrated nitric acid and the resulting solution is diluted with distilled water.
Cu2+ ions are formed in this reaction.
Use the electrode potentials shown to write a balanced ionic equation for the reaction between
the copper in the brass nail and the concentrated nitric acid.
equation electrode potential, E o / V

2H+(aq) + 2e– H2(g) 0.00
Cu2+(aq) + e– Cu+(aq) +0.15
Cu2+(aq) + 2e– Cu(s) +0.34
NO3–(aq) + 2H+(aq) + e– NO2(g) + H2O(l) +0.81
.............................................................................................................................................. [2]
(b) A balance accurate to two decimal places was used to weigh a small beaker and the mass of
the beaker recorded.
The brass nail was placed in the beaker and the mass increased by 3.76 g.
Calculate the percentage error in measuring the mass of this nail.
percentage error = .............................. %

[1]
(c) 50 cm3 of concentrated nitric acid was added to the nail in the beaker. When the reaction
finished and the nail had dissolved, the solution was completely transferred to a 250.0 cm3
volumetric flask along with the washings. The solution was made up to the mark with distilled
water.
Concentrated nitric acid is corrosive.
State one precaution related to this hazard that must be taken when using concentrated
nitric acid.
....................................................................................................................................................
.............................................................................................................................................. [1]

6
(d) (i) A colorimeter can be used to determine concentrations of metal ions in solution. When
light passes through solutions of metal ions some of the light may be absorbed.
The quantity of light absorbed is called the absorbance and is measured by a colorimeter.
The absorbance of solutions of known concentration of copper(II) ions can be used to
determine an unknown concentration of copper(II) ions.
A solution of copper(II) nitrate of concentration 0.800 mol dm–3 is required for this
investigation.
Calculate the mass of copper(II) nitrate, Cu(NO3)2, needed to prepare 100.0 cm3 of
0.800 mol dm–3 solution. Give your answer to three significant figures.
[Ar: Cu, 63.5; N, 14.0; O, 16.0]
mass of copper(II) nitrate, Cu(NO3)2 = .............................. g

[2]
© UCLES 2019 9701/52/M/J/19

7
Question 2 continues on the next page.

8
Volumes of 0.800 mol dm–3 copper(II) nitrate are diluted with distilled water to prepare a series
of ten solutions of different concentrations of copper(II) ions.
(ii) The total volume needed of each solution is 20.00 cm3.
The absorbance of each solution is recorded in a colorimeter at a wavelength of light of

630 nm and recorded in the table.
Complete the table to show the volumes of 0.800 mol dm–3 copper(II) nitrate and distilled
water needed to prepare each solution. Give all volumes to two decimal places.
volume of concentration
volume of
solution 0.800 mol dm–3 of Cu2+(aq) absorbance
distilled water / cm3
copper(II) nitrate / cm3 / mol dm–3
1 0.00 20.00 0.00 0.00
2 0.04 0.12
3 0.12 0.36
4 0.16 0.48
5 0.22 0.66
6 0.30 0.89
7 0.36 1.06
8 0.42 1.25
9 0.48 1.41
10 0.60 1.76
[1]
(iii) Name a suitable piece of apparatus for accurately measuring the volumes you have
calculated in (d)(ii).
....................................................................................................................................... [1]
© UCLES 2019 9701/52/M/J/19

9
(e) (i) The plot produced by comparing the absorbance of each solution with its concentration is
referred to as a calibration graph.
Plot a calibration graph of absorbance (y-axis) against concentration of Cu2+(aq) (x-axis).

Use a cross (×) to plot each data point. Draw a line of best fit.
2.00
1.80
1.60
1.40
1.20
absorbance
1.00
0.80
0.60
0.40
0.20
0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70
concentration of Cu2+(aq) / mol dm–3
[2]

10
(ii) State the relationship between concentration of Cu2+(aq) and absorbance.
.............................................................................................................................................
....................................................................................................................................... [1]
(f) (i) The absorbance of the solution prepared in (c) from the brass nail was found to be 0.56.
Use your calibration graph to find the concentration of Cu2+(aq) in this solution.
concentration of Cu2+(aq) = .............................. mol dm–3 [1]
(ii) Use your answer to (f)(i) and the information in (b) and (c) to calculate the percentage of
copper, by mass, in the brass nail. Give your answer to three significant figures.
(If you were unable to obtain an answer to (f)(i) you may use the value 0.22 mol dm–3. This
is not the correct value.)
[Ar: Cu, 63.5]
percentage of copper in the brass nail = ..............................%

[2]
[Total: 14]
© UCLES 2019 9701/52/M/J/19

11
BLANK PAGE
© UCLES 2019 9701/52/M/J/19

12
BLANK PAGE
© UCLES 2019 9701/52/M/J/19


*7026641451*
CHEMISTRY 9701/51
Paper 5 Planning, Analysis and Evaluation October/November 2019
1 hour 15 minutes

This document consists of 12 printed pages.
IB19 11_9701_51/FP
2
1 Yttrium barium copper oxide, YBa2Cu3O7, is a crystalline compound.
You are to design an experiment in which YBa2Cu3O7 is first synthesised and then analysed by
titration.
(a) YBa2Cu3O7 can be synthesised by reacting Y2O3, BaCO3 and CuO using the following method.
● Place solid Y2O3, BaCO3 and CuO together in a mortar and grind the mixture well with a
pestle.
● Transfer the mixture to a porcelain crucible and place this in an oven set at 920 °C.
● Heat the mixture for 12 hours, then allow the crucible and its contents to cool slowly in the
oven to below 100 °C before removing it.
The equation for the reaction is given.

1
Y2O3 + 4BaCO3 + 6CuO + 2 O2 → 2YBa2Cu3O7 + 4CO2
(i) YBa2Cu3O7 contains Y, Ba and Cu in the molar ratio of 1 : 2 : 3.
Calculate the minimum masses of BaCO3 and CuO that are needed to react with 0.750 g
of Y2O3, to give a Y : Ba : Cu ratio of 1 : 2 : 3.
[Ar: Y, 88.9; Ba, 137.3; Cu, 63.5; O, 16.0; C, 12.0]
mass of BaCO3 = .............................. g
mass of CuO = .............................. g

[3]
(ii) State what should be done once the solid product has cooled to ensure that the highest
possible yield of YBa2Cu3O7 has been produced.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
© UCLES 2019 9701/51/O/N/19

3
YBa2Cu3O7 contains some copper ions in the unusual +3 oxidation state.
The proportion of Cu3+ in YBa2Cu3O7 can be determined by titration.
● Step 1
A sample of YBa2Cu3O7 is reacted with an excess of concentrated aqueous HBr. Cu3+ ions are
reduced to Cu2+ ions and Br3– ions are formed.
2Cu3+(s) + 3Br –(aq) → 2Cu2+(aq) + Br3–(aq)
● Step 2
A solution of 1.0 mol dm–3 sodium citrate is added to the mixture from Step 1. The resulting
mixture is then neutralised with a minimum volume of concentrated NH3(aq).
● Step 3
Excess I– is added which reacts with Br3– to form I2.
Br3–(aq) + 2I–(aq) → 3Br –(aq) + I2(aq)
● Step 4
The I2 is titrated with a standard solution of S2O32– and starch solution as an indicator.
2S2O32–(aq) + I2(aq) → S4O62–(aq) + 2I–(aq)
The concentration of I2(aq) can therefore be determined and hence the concentration of Br3–(aq).
From this the amount of Cu3+(s) can be determined.
(b) The table gives some electrochemical data.
reduction process Eo/V

I2 + 2e– 2I– +0.54
Cu2+ + I– + e– CuI +0.86
O2 + 4H+ + 4e– 2H2O +1.23
Use these data and the information given above to answer the following questions.
(i) The citrate anion forms an insoluble complex with Cu2+ and so removes Cu2+ from solution.
Explain why this is necessary.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) Explain why it is necessary to neutralise the mixture in Step 2.
.............................................................................................................................................
....................................................................................................................................... [1]
© UCLES 2019 9701/51/O/N/19 [Turn over

4
(iii) When starch indicator is added in Step 4, the mixture turns blue-black due to the presence
of I2(aq). The end-point of the titration with S2O32–(aq) is a colourless solution.
The number of moles of S2O32–(aq) needed for complete reaction with I2(aq) can be
calculated from the mean titre value. Hence the moles of I2(aq) can be determined.
State the expression for the moles of Cu3+ in the sample of YBa2Cu3O7. Use A to represent
the number of moles of I2(aq) in Step 4.
moles Cu3+ = .............................. mol [1]
(c) (i) Calculate the mass of hydrated sodium citrate, Na3C6H5O7•2H2O, that would be required
for the preparation of 250.0 cm3 of a solution of 1.0 mol dm–3 citrate ions, C6H5O73–.
[Mr: Na3C6H5O7•2H2O, 294.0]
mass of Na3C6H5O7•2H2O = .............................. g [1]
(ii) A student places the mass of Na3C6H5O7•2H2O calculated in (c)(i) into a beaker.
Describe how the student can prepare exactly 250.0 cm3 of a solution of 1.0 mol dm–3 citrate
ions from the sample in the beaker.
Give the name and capacity, in cm3, of any apparatus used.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [3]
© UCLES 2019 9701/51/O/N/19

5
(d) A different student records the following titration data in Step 4.
experiment rough 1 2
final reading / cm3 21.20 24.60 47.75
initial reading / cm3 0.00 3.10 25.30
titre / cm3 21.20 21.50 22.45
Identify the problem with the student’s titration method and suggest how it could be improved.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [2]
[Total: 13]

6
2 The viscosity of a substance is a measure of how quickly the substance flows when it is subjected
to a force such as gravity. The viscosity of a liquid or solution is dependent on:
● size of molecules
● strength of intermolecular forces of attraction
● temperature.
It is possible to calculate the mean molecular mass (mean Mr) of a polymer in solution by measuring
the viscosity of solutions of the polymer at different concentrations.
Measurements related to the viscosity of a solution can be made using a capillary viscometer,
shown in the diagram.
bung
mark A
reservoir
direction of
mark B flow of solution
capillary
section
solution
● The apparatus is set up as shown.

● The bung is removed and the solution falls through the capillary section.
● The time taken for the top of the solution to pass between the two marks at the top (A) and
bottom (B) of the reservoir is recorded.
● This time taken is related to the viscosity of the solution.
A student plans an experiment to calculate the mean Mr of molecules of poly(phenylethene). The

student plans to make solutions of different concentrations of poly(phenylethene) dissolved in
methylbenzene, C6H5CH3, an organic solvent.
(a) Before the experiment, a mixture of concentrated nitric acid and concentrated hydrochloric acid
is passed through the capillary viscometer. The capillary viscometer is then rinsed, first with
water, and then with propanone.
Suggest why the capillary viscometer is rinsed with water and then with propanone.
rinse with water ..........................................................................................................................
....................................................................................................................................................
rinse with propanone .................................................................................................................
....................................................................................................................................................
[2]
© UCLES 2019 9701/51/O/N/19

7
Question 2 continues on the next page.

8
(b) A constant, η, related to the viscosity of a solution can be found by plotting a graph of
() ()
1 log t on the vertical axis against c on the horizontal axis.
c t0
c = concentration of poly(phenylethene) in C6H5CH3 (in g dm–3)
t = time taken for the solution to pass between marks A and B (in s)
t0 = time taken for pure C6H5CH3 to pass between marks A and B (in s)
The results of a series of experiments using different concentrations of poly(phenylethene) in

t
C6H5CH3 are shown. The values of have been calculated for you.
t0
Process the results to complete the table.
Record all your data to three significant figures.
concentration of 1
time taken, t ( 1c )log(tt )
poly(phenylethene), c
/ g dm–3
c
/ dm3 g–1
/s
t
t0 ()
log t
t0
/ dm g3
0
–1
16.0 176 2.26
14.0 164 2.10
12.0 151 1.94
10.0 138 1.77
8.0 125 1.60
6.0 113 1.45
4.0 102 1.31
2.0 89 1.14
[3]
© UCLES 2019 9701/51/O/N/19

9
c () ()
(c) Plot a graph on the grid to show the relationship between 1 log t and c.
t0
Use a cross (×) to plot each data point. Draw the straight line of best fit.
0.0310
0.0300
0.0290
0.0280
0.0270
() ()
1
c
log
t
t0
/ dm g
3 –1
0.0260
0.0250
0.0240
0.0230
0.0220
0.0210
0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 16.0
c / g dm–3
[2]

10
(d) (i) Capillary viscometer measurements are usually made at 25 °C.
Predict the effect on the time taken for the solution to fall between marks A and B if a
solution of temperature 18 °C is tested in the viscometer.
Explain your answer.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
(ii) Suggest how a student could ensure that a measurement is made at 25 °C.
.............................................................................................................................................
....................................................................................................................................... [1]
(e) The data you have plotted shows an anomaly that comes from the results obtained.
Circle the anomalous point on the graph.
Suggest a reason for this anomaly. Assume that for this result, the concentration of the solution
was correct.
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [1]
© UCLES 2019 9701/51/O/N/19

11
η
(f) The y-axis intercept on the graph in (c) is equal to , where η is a constant for
2.30
poly(phenylethene) at 25 °C.
(i) Use the graph you plotted in (c) to find a value for η.
η = .............................. dm3 g–1 [1]
The relationship between η and the mean Mr is shown.

(K and a have specific values for solutions of poly(phenylethene).)
η = K × (mean Mr)a
For a solution of poly(phenylethene) dissolved in C6H5CH3 the relationship can be expressed

as shown.
log (mean Mr) = 1.59 log η + 7.03
(ii) Use your value of η calculated in (f)(i) to calculate a value for the mean Mr of
poly(phenylethene) in this experiment.
mean Mr = ..............................
[2]
(iii) Poly(phenylethene) forms when molecules of phenylethene, CH2CHC6H5, undergo addition

polymerisation.
x CH2CHC6H5 (CH2CHC6H5)x
Use the value of mean Mr you calculated in (f)(ii) to calculate a value for x, the number of
repeat units in the polymer.
Your answer should give the nearest whole-number value of x.
If you were unable to calculate a value in (f)(ii), then you may use mean Mr = 1.56 × 105,
but this may not be the correct answer.
[Ar: C, 12.0; H, 1.0]
x = ..............................
[1]

12
(g) In the equation, η = K × (mean Mr)a, a depends on the strength of the intermolecular forces
between the solvent and the solute.
The value of a increases as the intermolecular forces between solvent and solute increase.
Predict how the value of a for poly(ethenol) dissolved in water differs from a for
poly(phenylethene) dissolved in C6H5CH3.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [2]
[Total: 17]
© UCLES 2019 9701/51/O/N/19


*7075992122*
CHEMISTRY 9701/52
Paper 5 Planning, Analysis and Evaluation October/November 2019
1 hour 15 minutes

This document consists of 12 printed pages.
IB19 11_9701_52/4RP
2
1 Many organic reactions performed in the laboratory require heating under reflux.
4‑nitromethylbenzene can be converted directly to 4‑aminobenzaldehyde by heating it under reflux

with an excess of solution A. Solution A is an aqueous alkaline mixture of Na2S•9H2O and S8.
Ethanol is used as a solvent for the reaction.
4-nitromethylbenzene 4-aminobenzaldehyde
CH3 CHO
solution A
O2N H 2N
The apparatus for this reaction is shown in the diagram.
reflux condenser
tap funnel
solution A
round-bottomed
flask
4-nitromethylbenzene
dissolved in ethanol
(a) (i) Show, using a labelled arrow, where the cooling water enters the reflux condenser. [1]
© UCLES 2019 9701/52/O/N/19

3
(ii) After the complete addition of solution A to the solution in the round‑bottomed flask, a
vigorous exothermic reaction takes place.
What should be done to control the vigorous exothermic reaction during the addition of
solution A?
.............................................................................................................................................
....................................................................................................................................... [1]
(iii) The mixture is heated to increase the rate of reaction. This is carried out under reflux.
Other than to increase the rate of reaction, explain why a reflux process is used for heating
the mixture.
.............................................................................................................................................
....................................................................................................................................... [1]
(iv) A student suggests that placing a bung in the top of the condenser would improve the
experiment.
Comment on whether the student is correct. Explain your answer.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]

4
(b) Once the reaction is complete, the round‑bottomed flask is removed from the set‑up on page 2
and included in a new set‑up for distillation.
The distillation process separates the substances in the mixture in the flask.
(i) Complete and label the diagram to show how the apparatus could be set up for distillation.
[2]
(ii) The mixture in the round‑bottomed flask is heated until all of the first substance distils off.
The heating is then stopped. After distillation a hot solution remains in the round‑bottomed
flask.
The table shows some data relevant to the experiment.
substance melting point / °C boiling point / °C
CHO
72 138
H 2N
H2O 0 100
CH3CH2OH –114 78
Use the data to identify the liquid that is first distilled off.
.............................................................................................................................................
....................................................................................................................................... [1]
© UCLES 2019 9701/52/O/N/19

5
(iii) 4‑aminobenzaldehyde is soluble in hot water, but not in cold water.
Starting with the hot solution in the round‑bottomed flask, suggest how pure crystals of
4‑aminobenzaldehyde can be obtained.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
(c) Under acidic conditions, 4‑aminobenzaldehyde (C7H7NO) forms a solid compound with
molecular formula C14H12N2O.
2C7H7NO C14H12N2O + H2O
A student carries out two experiments according to the method on page 2 to make C7H7NO.
In Experiment 1, the student obtains 6.00 g of solid.
In Experiment 2, the student uses the same method as in Experiment 1 but adds acid to
neutralise the alkali in the mixture in the flask after heating under reflux.
The same quantities of reagents are used in Experiment 1 and Experiment 2.
Suggest how the mass of solid obtained in Experiment 2 compares to that of Experiment 1.
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [2]

6
(d) 4-aminobenzaldehyde can be reacted with a halogenoalkane to form

4‑(dimethylamino)benzaldehyde, compound D.
4-aminobenzaldehyde compound D
CHO CHO
halogenoalkane
H 2N (CH3)2N
Some data is given that is relevant to this reaction.
carbon-halogen
boiling point
halogenoalkane bond energy
/ °C
/ kJ mol–1
CH3Cl –97 340
CH3Br 4 280
CH3I 43 240
Give two reasons why CH3I is the preferred halogenoalkane in the conversion of
4-aminobenzaldehyde to compound D.
1 .................................................................................................................................................
....................................................................................................................................................
2 .................................................................................................................................................
....................................................................................................................................................
[2]
[Total: 13]
© UCLES 2019 9701/52/O/N/19

7
2 Naphthalene, C10H8, is an aromatic organic compound that is a solid at room temperature and
pressure.
The enthalpy change of fusion, ΔHfusion, of naphthalene is the enthalpy change that occurs when
naphthalene melts. It cannot be directly measured.
C10H8(s) C10H8(l)
The melting point of naphthalene depends on its purity. When other compounds dissolve in liquid
naphthalene its melting point is lowered.
Diphenylamine, (C6H5)2NH, dissolves in liquid naphthalene. By varying the amount of diphenylamine

and measuring the melting points of the different mixtures, the enthalpy change of fusion of
naphthalene can be calculated.
(a) The equation that links the melting point of a naphthalene‑diphenylamine mixture with its
enthalpy change of fusion, ΔHfusion, is shown.
ΔHfusion
log Y = A –
2.30 × RTm
Y = mole fraction of naphthalene

R = molar gas constant, 8.31 J K–1 mol–1
Tm = melting point of naphthalene in K
A is a constant
(i) A series of experiments is performed using the same amount, 0.100 mol, of naphthalene
each time.
Calculate the mass of naphthalene, C10H8, that should be used for each of these
experiments.
[Ar: C, 12.0; H, 1.0]
mass of naphthalene = .............................. g [1]

8
(ii) The melting point and freezing point of a substance are the same. The melting point, Tm,
of a substance can be found by recording the temperature at which the substance freezes,
measured when crystals first start to appear on cooling.
The results of a series of experiments using 0.100 mol of naphthalene and different masses
of diphenylamine are shown.
Process the results to complete the table.
Record all your data to three significant figures.
The mole fraction of naphthalene, Y, is calculated as shown.
nN
Y=
nN + nD
nN = amount in moles of naphthalene, C10H8, = 0.100

nD = amount in moles of diphenylamine, (C6H5)2NH
temperature at
amount of
mole fraction which crystals
(C6H5)2NH, nD log Y
of C10H8, Y appear, Tm
/ mol / 10–3 K–1
/K
0.00 1.00 353 2.83 0.00
0.00888 349
0.0178 345
0.0266 341
0.0355 338
0.0444 334
0.0533 331
0.0621 329
0.0769 325
[3]
© UCLES 2019 9701/52/O/N/19

9
(b) Plot a graph on the grid to show the relationship between and log Y.
Use a cross (×) to plot each data point. Draw the straight line of best fit.
0.000
–0.050
–0.100
log Y
–0.150
–0.200
–0.250
2.80 2.85 2.90 2.95 3.00 3.05 3.10
1
Tm / 10 K
–3 –1
[2]

10
(c) (i) Use the graph to determine the gradient of the line of best fit. State the co‑ordinates of
both points you used in your calculation.
co‑ordinates 1 .............................................. co‑ordinates 2 .............................................
gradient = .............................. K
[2]
(ii) Use your answer to (c)(i) to determine the value of the enthalpy change of fusion of
naphthalene, ΔHfusion, in kJ mol–1.
ΔHfusion = .............................. kJ mol–1 [1]
(d) (i) Do you consider the results obtained to be reliable? Explain your answer.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
© UCLES 2019 9701/52/O/N/19

11
(ii) Different literature values for the enthalpy change of fusion of naphthalene suggest that
10.00 g of naphthalene require between 1.45 kJ and 1.47 kJ to melt.
Use this information to calculate the range of ΔHfusion values of naphthalene, C10H8, given
in literature.
Use your values to comment on the accuracy of the experimental procedure.

[Ar: C, 12.0; H, 1.0]
If you were not able to calculate ΔHfusion in (c)(ii), you may use 18.4 kJ mol–1, but this may
not be the correct answer.
range ..................................................................................................................... kJ mol–1
comment .............................................................................................................................
.............................................................................................................................................
[2]
(e) The enthalpy change calculated in this reaction is actually ΔH1, shown in the Hess’ cycle.
ΔHfusion
C10H8(s) C10H8(l)
ΔHmixing
ΔH1
C10H8(l) mixed with
diphenylamine
It is assumed that the enthalpy change when C10H8(l) and diphenylamine are mixed, ΔHmixing, is
zero, and therefore ΔH1 = ΔHfusion.
State how the value of ΔH1 compares to the value of ΔHfusion if the mixing of naphthalene and
diphenylamine is endothermic.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [2]

12
(f) A student incorrectly uses a value for the Mr of diphenylamine that is too low. This produces
incorrect values for the mole fraction, Y.
(i) Predict the effect this will have on the calculated values of Y.
nN
Y=
nN + nD
nN = amount in moles of naphthalene

nD = amount in moles of diphenylamine
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) The student uses the incorrectly calculated value of Y from (f)(i) in the determination of
ΔHfusion.
ΔHfusion
log Y = A –
2.30 × RTm
Predict how the student’s calculated value of ΔHfusion is different from the actual value.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
[Total: 17]
© UCLES 2019 9701/52/O/N/19

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Cambridge Assessment International Education

READ THESE INSTRUCTIONS FIRST

Answer all questions.

This document consists of 9 printed pages and 3 blank pages.

H2O2(aq) + 2I–(aq) + 2H+(aq) I2(aq) + 2H2O(l) reaction 1

I2(aq) + 2S2O32–(aq) 2I–(aq) + S4O62–(aq) reaction 2

The student prepared the following solutions.

solution A 0.100 mol dm–3 KI(aq)

solution B 0.0500 mol dm–3 Na2S2O3(aq)

The student also had access to the following chemicals.

solution C 0.100 mol dm–3 H2O2(aq)

(a) The student prepared solution A in a 250 cm3 volumetric flask.

Determine the mass, in g, of KI needed to prepare 250.0 cm3 of solution A.

mass = .............................. g [2]

© UCLES 2019 9701/52/F/M/19

Explain why this improves the accuracy of the results.

volume = .............................. cm3 [1]

© UCLES 2019 9701/52/F/M/19 [Turn over

(d) Experiment 1 was carried out using a series of steps.

The student carried out two trials of each experiment.

volume of time for the indicator

© UCLES 2019 9701/52/F/M/19

percentage error = .............................. % [1]

(v) For Experiments 1–6, state:

● the independent variable .............................................................................................

● the dependent variable. ...............................................................................................

© UCLES 2019 9701/52/F/M/19 [Turn over

● v is the volume of solution A used in cm3

Give all values to three significant figures.

experiment v / cm3 log v tav / s (1/tav) / s–1 log(1/tav)

3 12.50 100 0.0100

(ii) Rate can be expressed as (1/tav).

co-ordinates 1 ............................................. co-ordinates 2 .............................................

order of reaction with respect to I–(aq) = ..............................

© UCLES 2019 9701/52/F/M/19

© UCLES 2019 9701/52/F/M/19 [Turn over

A white precipitate of silver chloride formed.

The student decided to filter the mixture under reduced pressure.

© UCLES 2019 9701/52/F/M/19

(ii) The student recorded the masses shown in the table.

mass of crucible + dry silver chloride / g 24.898

mass of empty crucible / g 19.162

mass of dry silver chloride / g

moles of silver chloride formed = .............................. mol [1]

mass of one mole of the Group 2 chloride = .............................. g

identity of the Group 2 metal = ..............................

© UCLES 2019 9701/52/F/M/19 [Turn over

© UCLES 2019 9701/52/F/M/19

© UCLES 2019 9701/52/F/M/19

© UCLES 2019 9701/52/F/M/19

Cambridge Assessment International Education

READ THESE INSTRUCTIONS FIRST

Answer all questions.

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© UCLES 2019 9701/51/M/J/19

● a standard copper(II) ion / copper half-cell (E o = +0.340 V)

copper(II) ion 0.500 mol dm–3

concentration of the copper(II) ion solution in the copper half-cell = ........................................

volume = .............................. cm3 [1]

© UCLES 2019 9701/51/M/J/19 [Turn over

(iii) The results of the experiment are shown in the table.

E (manganese half-cell) = Ecell + 0.340 V