Professional Documents
Culture Documents
PDF Agglomeration of Iron Ores 1St Edition Ram Pravesh Bhagat Author Ebook Full Chapter
PDF Agglomeration of Iron Ores 1St Edition Ram Pravesh Bhagat Author Ebook Full Chapter
https://textbookfull.com/product/one-arranged-murder-1st-edition-
chetan-bhagat/
https://textbookfull.com/product/foods-of-non-animal-origin-
chemistry-technology-inspection-procedures-1st-edition-arpan-
bhagat/
https://textbookfull.com/product/a-hunt-of-blood-iron-1st-
edition-cara-nox/
https://textbookfull.com/product/jail-notebook-and-other-
writings-english-edition-bhagat-singh/
Environmental Waste Management 1st Edition Ram Chandra
https://textbookfull.com/product/environmental-waste-
management-1st-edition-ram-chandra/
https://textbookfull.com/product/cast-iron-will-the-cast-iron-
cooking-cozy-mystery-01-jessica-beck-et-el/
https://textbookfull.com/product/toward-balanced-growth-with-
economic-agglomeration-empirical-studies-of-china-s-urban-rural-
and-interregional-development-1st-edition-zhao-chen/
https://textbookfull.com/product/nickel-sulfide-ores-and-impact-
melts-origin-of-the-sudbury-igneous-complex-peter-c-lightfoot-
auth/
https://textbookfull.com/product/spells-of-iron-and-bone-tarot-
academy-1-1st-edition-sarah-piper-piper/
Agglomeration of Iron Ores
Agglomeration of Iron Ores
Authored by
Ram Pravesh Bhagat
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
This book contains information obtained from authentic and highly regarded sources. Reasonable
efforts have been made to publish reliable data and information, but the author and publisher cannot
assume responsibility for the validity of all materials or the consequences of their use. The authors and
publishers have attempted to trace the copyright holders of all material reproduced in this publication
and apologize to copyright holders if permission to publish in this form has not been obtained. If any
copyright material has not been acknowledged, please write and let us know so we may rectify in any
future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced,
transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or here-
after invented, including photocopying, microfilming, and recording, or in any information storage or
retrieval system, without written permission from the publishers.
For permission to photocopy or use material electronically from this work, please access www.
copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222
Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides
licenses and registration for a variety of users. For organizations that have been granted a photocopy
license by the CCC, a separate system of payment has been arranged.
Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are
used only for identification and explanation without intent to infringe.
Dedicated to my parents
The late Ganesh Prasad Bhagat
The late Janki Devi
Table of Contents
Preface.....................................................................................................................xix
Author Biography.....................................................................................................xxi
Acknowledgment.................................................................................................. xxiii
Chapter 1 Introduction...........................................................................................1
1.1 Preamble.....................................................................................1
1.2 Definition and Category.............................................................1
1.2.1 Agglomeration...............................................................1
1.2.2 Sintering........................................................................2
1.2.3 Pelletizing......................................................................2
1.2.4 Briquetting.....................................................................2
1.3 Scope of Agglomeration.............................................................3
1.4 Need for Agglomeration............................................................. 3
1.5 Raw Materials for Agglomeration.............................................. 4
1.6 The Agglomeration Processes.................................................... 5
1.6.1 Sintering........................................................................5
1.6.2 Pelletization...................................................................6
1.7 Iron Making................................................................................6
1.8 R&D...........................................................................................7
1.9 Techno-Economics.....................................................................8
1.9.1 Sinter (Pellet) Plant Operation......................................8
1.9.2 Usage of Agglomerates.................................................9
1.9.3 Reducing Operational Cost...........................................9
1.9.4 Utilization of Slimes and Metallurgical
Wastes.......................................................................... 10
1.10 Evolutionary Phases................................................................. 10
1.10.1 Sintering...................................................................... 10
1.10.2 Pelletization................................................................. 11
References........................................................................................... 11
vii
viii Table of Contents
xix
xx Preface
There are not many books with adequate and broader coverage on the subject; and
hence, I do hope this volume will fill the gap.
The chapters and topics are arranged in a systematic way so that the readers
get thorough knowledge and understanding of the subject. The book comprises
16 chapters. The first Chapter comprises an introduction to agglomeration includ-
ing the necessity and scope. The processes of agglomeration requires raw mate-
rials of specified characteristics in terms of their purity (chemical compositions),
size parameters, as well as mineralogical, thermal, and assimilation behaviors. This
requires their detailed characterization and preparation (enrichment) before these
are used. These are covered in Chapter 2. The third and fourth Chapters cover
topics on iron-making processes and agglomerates in iron making. These topics are
important and relevant to explore the required physical-chemical characteristics of
the agglomerates in order to extract iron metal in an efficient manner. The topics
of sintering and pelletization are covered in Chapters 5 to 10 and Chapters 11 to
16, respectively. The processes, fundamentals, and quality parameters with respect
to each of these agglomeration processes are detailed. In keeping with the exist-
ing trends, topics on newer processes and techniques of agglomeration in the case
of difficult ores, including high alumina ores that prevail in India and other Asia-
Pacific countries, have been included. Lastly, common topics related to the transport
parameters for sintering and pellet induration, and the test of quality parameters with
respect to sinter and pellets are described as Annexures.
I do hope that the present book, updated through the current topics on its theoret-
ical and practical aspects in the iron ore agglomeration, will be a significant addition
to the metallurgical literature in this area.
Author Biography
Ram Pravesh Bhagat (b. 1954) served the Indian Institute
of Technology (IIT) - (ISM) Dhanbad, India, as Professor
(SAIL-NMDC Chair) on two years contract which he joined
in November 2014 after superannuation from the service of
CSIR-National Metallurgical Laboratory (NML), Jamshedpur,
as Chief Scientist. He has over 38 years of research experience
in iron ore beneficiation and agglomeration.
During his initial research career (1978-’89) at R&D
Centre for Iron & Steel - Steel Authority of India Limited
(SAIL), Ranchi, he worked with Soviet experts to implement
R&D Projects in the sintering plants of Bhilai Steel Plant (BSP)–SAIL basically
aimed at to improve the sinter productivity and its quality.
In the 1990s, Dr. Bhagat pursued research projects in the areas of beneficiation
and dewatering in collaboration with IIT Kharagpur, RAS Russia, and with sup-
port from private industries. His subsequent research career at NML (2000–2014)
concentrated on agglomeration, and he initiated and executed several R&D projects
sponsored by the Ministry of Steel, Government of India, as well as private organi-
zations, such as Tata Steel, MECON, Tata Metaliks, etc. Development of pilot-scale
pelletization technology for Indian goethitic/hematite ores, Agglomeration of iron
ore fines following nonconventional routes, Improved granulometry, and Cooling
characteristics of sinter had been some of his recently concluded projects.
As a faculty member of Academy of Scientific & Industrial Research -New Delhi,
also of ISM in the recent past, Prof. Bhagat developed courses and delivered lectures
in agglomeration technology. He has supervised two Ph.D. scholars at IIT Kharagpur
and several M. Tech students at ISM.
He has contributed three book chapters including “Agglomeration” in the
Encyclopedia of Iron, Steel, and Their Alloys (CRC Press). He has published 45
research papers in SCI journals and 56 in conference proceeding volumes, He has
also delivered several invited lectures. Prof. Bhagat is a reviewer of national and
international journals. He is also an examiner of Indian Universities.
Prof. Bhagat received his M. Tech. from IIT Kanpur and Ph.D. from IIT
Kharagpur. He is a life fellow and member of several professional bodies. He is also
the recipient of various awards and fellowships, including CSIR-DAAD.
xxi
Acknowledgment
Numerous professionals have made significant and important contributions to the
field of agglomeration and related literature. The author has used information from
these sources and gratefully acknowledges the authors, journals, publishers, and
also the societies for granting their kind permission to reproduce their data in the
book:
The author has greatly benefited from his work and discussions with the Russian
researchers, Dr. B. M. Boranbaev and Dr. G. A. Grebenkin and acknowledge some
of their input reflected in the book. He is grateful to R&D Centre for Iron and
Steel- Steel Authority of India Limited (RDCIS-SAIL) and Council of Scientific &
Industrial Research – National Metallurgical Laboratory (CSIR-NML) for having
given him the opportunity to be associated the various R&D projects on agglom-
eration, and the sponsors, Tata Steel Limited, Ministry of Steel, and Department of
Science & Technology, Govt. of India, in particular. He acknowledges CSIR-NML
for extending library facility.
The author has had a long academic and research association with his doctoral
guides, Prof. S. K. Gupta and Prof. H. S. Ray, his students at Indian Institute of
Technology (ISM) and Academy of Scientific and Industrial Research, also several
professionals and he records his appreciation to them. Thanks to his fellow col-
leagues associated with the author in various research programs at RDCIS-SAIL
and CSIR-NML. Various professionals: Prof. Kal. V. S. Sastry (Univ. of California),
Prof. S. Komarov (Tohoku University), Mr. S. K. Sarna (Ispat Guru), Prof. F. Matsuno
xxiii
(Japan), my past colleagues, Dr. Nayak and Mr. Hembram have provided their input
in the form of Figure(s) - the author thanks them.
My contribution, as a Chapter on Agglomeration, in the Encyclopaedia of Iron,
Steel and their Alloys (Eds. Rafael Colas, George E. Totten) has given me oppor-
tunity to expend the work in the present form. I thank the publisher, CRC Press/
Taylor & Francis, their team of editing and production for their cooperation at vari-
ous stages of this project.
The cooperation extended by my wife, Manju, enabled me to devote time to
prepare the book. Thanks to my daughters, Puja, Prabha, and Pragya, for their
encouragement.
ABBREVIATIONS
BF Blast furnace
CCS Cold crushing strength
DRI Direct reduced iron
LOI Loss on ignition
OSM Oxygen steel making
NMDC National Mineral Development Corporation
R&D Research and Development
SAIL Steel Authority of India Limited
1.1 PREAMBLE
Agglomeration is an important process in the extraction of iron ore to produce iron.
The process, being the interface between the mineral processing and extractive
metallurgy, is encountered by the professionals in these fields. Optimization of the
agglomeration process is one of the major contributory factors in deciding tech-
no-economics of the entire iron-making process following blast furnace and direct
reduction route(s). The process has undergone through many innovations over the
recent period. The effect of quality parameters of the agglomerates on the perfor-
mance of iron-making practices is required to be studied for the process optimization.
The sintering and pelletization are the pertinent agglomeration processes with
respect to iron making. In addition to knowledge of the basic and fundamental princi-
ples of these processes, insights on correlating the quality parameters of agglomerate
with its mineralogy vis-à-vis the process variables are important for the technology
development in these areas.
The technological innovations on agglomeration in phases has led to the development
of newer practices and their assimilation in the plants. These basically aim to (a) increase
productivity, (b) reduce raw material consumption and other operating costs, (c) improve
the product quality, and lastly, (d) reduce environmental pollution. The influencing param-
eters can be categorized into those that are (a) raw material based and (b) process based.
1
2 Agglomeration of Iron Ores
FIGURE 1.1 Photographs of (a) sinter, (b) pellets, and (c) briquette
The agglomeration process has a much wider application in the iron and steel
industries. It is the common method of burden preparation in the iron making fol-
lowing blast furnace and direct reduction processes. Growth of the steel industry
with depleting resources of high-grade ores has led to a very strong demand for both
pelletizing and sintering of iron ores.
1.2.2 Sintering
The process of sintering involves the agglomeration of the ore fines admixed with fluxes
and other additives into a porous mass by the reactions of ingredient minerals through solid
state diffusion at higher temperature as well as incipient fusion and bonding by slag, which
are caused by the heat produced through combustion (of coke) within the mass itself.
Important steps in the sintering process are:
• Mix preparation,
• Charging the mix into a sintering strand,
• Ignition (of the top layer)
• Sintering
• Cooling
1.2.3 Pelletizing
Pelletization is the process of forming nearly spherical balls by tumbling moist
particulate fines (approximately below 72 micron size) with/without the addition
of binders and additives in a balling drum or disc. The green balls, thus formed,
undergo an induration cycle consisting of drying, preheating, firing at approximately
1350°C (1623 K) temperature. and subsequent cooling.
Important steps in the pelletization process are:
1.2.4 Briquetting
Briquetting is the process of making compressed blocks of particles admixed with
binder such as coal tar and other additives. It is a cold process, and compression is
imparted by the pressure between two blocks.
Introduction 3
The memory of Lettie Fuller and her short swift career upon the
Vanity stage, bright and light as the dance of a butterfly through the
hours of a Summer morning, should still be so fresh in the minds of
play-goers that there is a kind of embarrassment in writing about it.
Anyway, Lettie Fuller was our Letizia, and in the years 1910 and
1911 she was the spirit of youth and London as no doubt to-day that
elusive and lovable spirit is incarnate in some other young woman.