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Essays in the Philosophy of Chemistry
Essays in the Philosophy
of Chemistry
1
1
Oxford University Press is a department of the University of Oxford.
It furthers the University’s objective of excellence in research, scholarship,
and education by publishing worldwide. Oxford is a registered trade mark of
Oxford University Press in the UK and certain other countries.
Published in the United States of America by Oxford University Press
198 Madison Avenue, New York, NY 10016, United States of America
9╇8╇7╇6╇5╇4╇3╇2╇1
Printed by Sheridan, USA
Eric Scerri would like to dedicate this volume to his late mother,
Ines, who passed away in 2015 and who spent a good deal of her life in
nurturing and encouraging his academic interests.
Grant Fisher dedicates this volume to his late mother, Jeannette.
The editors together also dedicate the volume to the Estonian
philosopher of science, Rein Vihalemm, one of our contributors
to this volume, who passed away in 2015.
Contents
Contributors ix
Introduction 3
Index 381
viii | ContentsContents
Contributors
5
A list of meetings and their locations, has been published in a recent editorial of Foundations of
Chemistry. E.R. Scerri, Editorial 46, Foundations of Chemistry, 16, 1–2, 2014. Since that editorial
appeared the 2014 meeting was held at the London School of Economics and the 2015 meeting
in Rio de Janeiro, Brazil.
6
Harré, R., and Llored, J.-P. “Mereologies as the grammars of chemical discourses,” Foundations
of Chemistry 13, 63–76, 2011.
introduction | 5
been reduced, and Scerri highlights how important it is to keep a close eye on
scientific developments and to seek more accurate experimental data.
Other contributions shed light on old as well as enduring problems in the
philosophy of science. Hinne Hettema argues in chapter 13 that engaging with
chemistry can shed new light on the concept of a theoretical term. He tackles
Hempel’s “theoretician’s dilemma”: Theoretical terms either serve a purpose
in establishing definite connections between observables or they do not. If
they serve their purpose they can be dispensed with, and if they don’t they
should be dispensed with. While Hempel’s response was to argue that theoret-
ical terms do more than provide links in derivational chains, motivating a re-
alist constructive account of theoretical terms in chemistry is difficult because
many of its theoretical terms are inconsistent with those having counterparts
in physics. Hettema illustrates these difficulties by drawing on Fukui’s frontier
orbitals and Paneth’s classification of an element, offering a resolution to
Hempel’s dilemma based on a specific proposal for the ontology of chemical
objects based on existence and grounding claims.
While Hettema resurrects an old and perhaps by now a somewhat neglected
topic, Hasok Chang (chap. 11) confronts one of the most central issues in con-
temporary philosophy of science—scientific realism. Chang describes how the
debate about scientific realism is distinctive in chemistry and how that distinc-
tiveness might inform the debate as it applies across the sciences. The history
of chemistry reveals the complexity of epistemic attitudes to unobservable enti-
ties like atoms in the nineteenth century. Chang argues that there was no re-
alism tout court in chemistry. Realism is partial and selective. Empirical success
confers warrant only on parts of theories. Empirical success can result from a
very partial knowledge of the systems of interest, as in nineteenth-century
structural chemistry. Chang goes on to critique preservative realism because
success need not correlate with those parts of theories which get preserved
in theory change. He defends “conservationist pluralism,” a position which
accepts that empirical and interventionist success has been achieved by many
theoretical routes and that we should retain them and add new ones with their
own specific domains of application.
The contributions to this volume can enlighten the philosophies of the nat-
ural sciences because the neglect of chemistry can often end up polarizing
metaphysical debates. In chapter 9, “Causality in Chemistry: Regularities and
Agencies,” Rom Harré surveys the intellectual terrain comprising the meta-
physics of causation. He highlights the neglect of the active, agentive powers
of substances in the philosophies of the natural sciences. Causality in chem-
istry, Harré argues, is of a hybrid structure, residing in the observable regulari-
ties between events and powerful particulars capable of bringing about both
chemical change and the maintenance of chemical stability. Conversely, it
could hardly be claimed that “chemistry” is neglected in discussions con-
cerning the status of natural kinds. Gold and water, after all, have a central
place in these debates. But Robin Hendry argues (chap. 12) that a priori require-
ments for natural kinds are undermined by chemistry. There are various ways
2
Boyle used phrases such as “the most general causes,” “first principles,” “atomic principles,” and
“the primitive affections of the smallest parts of matter” to refer to those fundamental causes not
themselves in need of explanation. I have used the term “ultimate causes’ to encapsulate all of this.
IV
The President held the treaty seven weeks before signing, and this put
the Federalist leaders to the torture. Among themselves they made no
concealment of their chagrin and indignation. Cabot, writing to King,
confessed that the President’s hesitation ‘renews my anxiety for the welfare
of the country.’ He would suggest to the Boston merchants that they make
‘a manly declaration of their sentiments’ to Washington. He had ‘too much
respect for the character of the President to believe that he can be deterred
from his duty by the clamor or menaces of these city mobs,’ but he realized
that something should be done to counteract their influence.[1082] If Cabot
kept a rein on his patience, it was not true of all. In a great house known as
‘Elmwood’ at Windsor, Connecticut, surrounded by elm trees and filled
with books and religion, a stern and forceful master was literally walking
the floor, and tossing restlessly on a sleepless bed, for Oliver Ellsworth was
doubting Washington’s firmness and courage. In bitterness he was writing
that ‘if the President decides right or wrong or does not decide soon his
good fortune will forsake him.’[1083] In commercial circles in New York
many were already turning upon the man they made a virtue of pretending
to worship. About the middle of July, Washington and his family left
Philadelphia for Mount Vernon, he in a two-horse phaëton for one, his
family in a coach with four horses and two servants, another servant leading
a saddle horse—and without giving the slightest intimation of his intention.
[1084]
Then came the scandal involving Randolph and the French Minister
Faucet. There was infinite joy in the Federalist camp. Pickering and
Randolph hastened a summons to Washington to return. There was a
dramatic scene, in which Washington is described as winking at Pickering,
and setting a trap for his Secretary of State, who was the sole member of his
original Cabinet chosen by the President to please himself. Randolph was
dismissed—and Washington signed the treaty. The merits of the treaty were
in no wise affected by anything Randolph may have done, and it is fair to
assume that there was no connection between the disgracing of the
Secretary and the signing.[1085] The strategy of the Federalist now outlined
itself, and Washington became the treaty and the treaty became Washington,
and to oppose the treaty was to insult Washington. The popular President
was literally pushed to the front line in the fight. Pickering was writing Jay
suggesting that Washington be persuaded to issue ‘a solemn public
declaration ... of the principles of his Administration,’ appealing to the
record of his life ‘for the purity and patriotism of his conduct’;[1086] and Jay
was replying that while ‘in many respects useful,’ he doubted the wisdom.
[1087] Christopher Gore was writing King inquiring if it were not ‘possible
for Col. Hamilton and yourself to induce the President to adopt some
measures that would decidedly express his sentiments in favor of the
treaty.’ He was positive that ‘in New England the word of the President
would save the Government.’[1088]
This plan of using the prestige of Washington for a party measure was
not made for this particular occasion. Pickering and Gore wrote on the same
day,[1089] one from Philadelphia, and the other from Boston. It had long
been a favorite feature in the party strategy. Ellsworth regained his
composure and wrote Wolcott that ‘the current I believe is turning in
Massachusetts, though you may perhaps hear of some obscure town
meetings.’[1090] Senator James Ross, writing to Pickering from Pittsburgh,
thought that after all it was well that Washington had taken his time. ‘His
sanction after hearing all the objections will quiet the minds of the
thoughtful.’[1091]
All that was required to make Washington the issue in the treaty fight
was a stupid attack upon him from the Democratic press, and that was
instantly forthcoming. When Fenno’s paper announced that the treaty had
been signed, Bache wrote that since ‘no information has been filed for a
libel on the Executive ... it may be fairly presumed, the character of the
President for patriotism and republicanism notwithstanding, that the
assertion is well founded.’[1092] And when a great crowd attended the next
presidential levee, Bache capped the climax of asininity with the comment
that ‘it was certainly necessary to let the public know that the just
resentment of an injured and insulted people had not reached the purview of
Saint Washington.’[1093] These bitter expressions convinced the Federalists
that the fight was not yet over. The public had too bitterly and generally
resented the treaty to be so quickly won. Instinctively the friends of the
treaty thought of Hamilton and the prowess of his pen. ‘Mr. Hamilton might
do great good,’ wrote Murray of Maryland to Wolcott, ‘by giving the public
his luminous pen.’[1094] Even as Murray wrote, Hamilton sat in his office
writing ‘Camillus’ for Noah Webster’s paper. His health was failing at the
time, but King and Jay had promised to assist. For weeks and months the
papers appeared, thirty-eight in all, in the most effective argumentative
style, covering every possible phase. ‘It is to pass for Hamilton’s,’ wrote
John Adams to his wife, ‘but all three consulted together upon most.’[1095]
Two months after the series began, the enemies of the treaty were
circulating the story that Hamilton and Webster had quarreled because of
the latter’s decision to limit the number of papers. ‘More than a hundred
columns have already been run, to the exclusion of news, and the people are
tired, no doubt,’ suggested an editor.[1096]
Unhappily, while Hamilton wrote, England was up to her old tricks upon
the sea again. Scarcely had the treaty been ratified, when Pickering was
officially protesting against an outrage on the United States by the British
ship of the line Africa, and by the British Vice-Consul in Rhode Island,
[1097] and was writing complainingly to John Quincy Adams in London that
‘if Britain studied to keep up the irritation in the minds of Americans ...
some of her naval commanders appear perfectly qualified for the
object.’[1098]
The enemies of the treaty made the most of these affronts. ‘A Loyalist of
‘75’ was urging Hamilton to ‘discontinue his laborious work of defending
the treaty’ to give some attention to the justification of Captain Home of the
Africa, and to the defense of the other sea captain who stole a peep ‘at Mr.
Monroe’s despatches.’ ‘Camillus’ could resume on the treaty after quieting
‘the minds of the swinish multitude’ on these later outrages.[1099] Thus
Hamilton’s efforts were being constantly neutralized in effect by the
conduct of the English, and the ‘swinish multitude’ chortled not a little over
the doggerel:
‘Sure George the Third will find employ
For one so wise and wary,
He’ll call “Camillus” home with joy,
And make him Secretary.’[1100]
In truth, even as he wrote, Hamilton was raging not a little over these stupid
insults to America, and was writing Wolcott proposing that the exchange of
ratifications be refused until the order to seize our vessels with provisions be
rescinded.[1101]
Far away on his hilltop, Jefferson was observing Hamilton’s literary
efforts with real concern, if the rank and file of his party were not.
‘Hamilton is really a colossus to the anti-republican party,’ he wrote
Madison, apropos of the defense of the treaty. ‘Without numbers, he is a
host within himself. They have got themselves into a defile where they can
be finished; but too much security on the republican part will give time to
his talent ... to extricate them.... When he comes forward there is no one but
yourself who can meet him. For God’s sake take up your pen and give a
fundamental reply to Curtius and Camillus.’[1102] But neither ‘for God’s
sake,’ nor for Jefferson’s, did Madison comply. He was enjoying his
vacation with Dolly. Even so, the Federalists were still in the woods on the
treaty—and there was yet a memorable fight ahead.
CHAPTER XIII
II
III
Quite a different type was Albert Gallatin—and yet both were born
aristocrats. From the beginning of the republic at Geneva in the sixteenth
century, his family had been second to none in prestige and power. The
governmental system was aristocratic; his people were uncompromising
aristocrats, and five Gallatins had been, at one time or another, head of the
State. Into this reactionary atmosphere he was born, and in it he passed his
youth. At the home of his grandmother, a domineering but clever old
autocrat, who believed in the divine right of the aristocracy to rule, he often
met Voltaire. Strange couple, that old woman worshiping tradition, and that
cynical old philosopher sneering it away. And yet in his family Gallatin was
an exotic. Instinctively he despised the system his people thought sacred.
Rousseau may have influenced him, but he was probably born with
democracy in his blood. When his grandmother arranged to get him a
commission in the mercenary army of her friend the Landgrave of Hess, and
he scornfully refused on the ground that he would ‘never serve a tyrant,’ the
old woman boxed his ears—but without jarring his principles.[1108] He was
a grave disappointment in the family circle. It is a notable coincidence that
like Hamilton he was remarkably precocious. He graduated from the
Academy of Geneva in his seventeenth year, first in his class in
mathematics, natural philosophy, and Latin translation. There, too, he had
studied history under Müller, the eminent historian, and in the facts and
philosophy of world history he was to have no equal in American public
life. Nothing contributed more to his desertion of his country than his hatred
of its petty aristocracy, its autocratic rule.
He was a dreamer in his youth. Was it Rousseau who planted in him a
dislike of cities and a passion for the wilderness? Secretly he left Geneva
and came to America, landing in Boston. He carried a letter of introduction
from Benjamin Franklin to his son-in-law, the father of the editor of ‘The
Aurora’ at Philadelphia. A few dreary months in Boston, a happier winter in
a cabin in the wilderness of northern Maine, a year at Harvard as a teacher
of French, a short time in Philadelphia in a boarding-house with Pelatiah
Webster, the political philosopher, and the lure of land speculation led him
to Virginia. There, in Richmond, some of his happiest days were passed.
Society was courteous, kindly, and there he came in contact with great
minds. John Marshall invited him into his office with the prediction that he
would distinguish himself at the Bar, and Patrick Henry advised him to go
West, with the observation that he was intended for statesmanship. At this
time he was a youth of twenty-one with a pronounced foreign accent.
Washington met him, and, impressed with his keenness, offered to make
him his land agent—an honor happily declined. Then into the wilderness of
Pennsylvania; a house on a hilltop which he called ‘Friendship Hill’; a
domestic tragedy—the death of his young wife; and soon the Whiskey
Boys, keen of vision as Marshall, Henry, or Washington, literally swept him
into public life.
He was primarily a democrat and an opponent of strong government.
Fascinated by the work of the Constitutional Convention, he thought the
Executive had been given too much power. But he was opposed to tinkering
with constitutions once adopted.[1109] As a member of the convention to
revise the Constitution of Pennsylvania, he worked as earnestly as had
Madison in the greater convention, fighting with moderation, but
persistence for a popular government, for the freedom of the press, and
popular suffrage. It is significant that when the subject of courts was
reached he sought the advice of John Marshall—and received it.[1110] His
views on the French Revolution were those of Jefferson. He recognized the
many excesses, the greed of demagogues for power, and he did not expect ‘a
very good government within a short time,’ but he knew ‘their cause to be
that of mankind against tyranny’ and that ‘no foreign nation has the right to
dictate a government to them.’[1111] One glance at Genêt revealed to him
the naked man—‘totally unfit for the place he fills,’ his abilities
‘slender.’[1112] Yet, like Jefferson, despite the massacres in Paris and the
Genêt excesses in Philadelphia, he clung to France because, ‘if France is
annihilated, as seems to be the desire of the combined powers, sad indeed
will the consequences be for America.’[1113] If he opposed the Excise Law,
as was his right, he had a reason, and it was sane.[1114] The charge the
Federalists were to make, that he had incited the hard-pressed pioneers to
violations of the law, was maliciously false. Throughout that insurrection,
his part was hard, and he met it with sanity and courage.
This was the background of this remarkable man when, at the age of
thirty-five, he stepped forward with the confidence of a veteran to assume
the intellectual leadership of the Jeffersonians in the House. A shy man in
social relations, he was utterly fearless in debate. There was no mind in that
body so well stocked with facts, and none with a broader vision or deeper
penetration. There was no one more masterful in logic, more clear,
downright, incisive in statement, and none more impervious to abuse. His
was the dignity of a superior mentality. If his foreign accent was still
pronounced, and members, priding themselves on their refinement and taste,
sneered openly, he remained the perfect gentleman, indifferent to such jeers.
In the midst of excitement, he was calm. When others were demoralized, he
kept his head. No greater figure ever stood upon the floor of an American
Congress than when Albert Gallatin appeared, to force notable reforms in
the fiscal system, and to challenge the Federalists to an intellectual combat
that would call forth their extreme exertions.
IV
One of the most important and brilliant debates in American history,
surpassing that on the Foote Resolutions, was precipitated early in March
when Edward Livingston threw a bomb into the complacent camp of the
Federalists with resolutions calling upon the President to lay before the
House the instructions and papers pertaining to the Jay Treaty. There was
some maneuvering in the beginning to feel out the position of the enemy,
and then the members settled down to a month of memorable debating. On
the whole, the discussion was pitched upon a high plane, for the question
was one of constitutional interpretation. Throughout, there was scarcely a
touch of personalities, albeit Tracy, described by his admirers as the ‘Burke
of Connecticut,’ and by his enemies as the ‘Burke of Connecticut without
his intelligence,’ could not restrain a stupid sneer at the accent of Gallatin
who led for the enemies of the treaty. A Pennsylvania member denounced
Tracy’s vulgar conduct as ‘intolerable,’ and there were many cries of
‘order.’ With the brazen effrontery of his school, Tracy asked Speaker
Dayton to decide, and that rather disreputable speculator, if not peculator,
held it in order to insult Gallatin with impunity.[1115] But this incident was
happily unique.
The Livingston Resolutions were based upon the theory that the House
was a party to the treaty in that it would be asked to make appropriations to
carry it into effect, and that the facts were necessary to the determination of
its course. This was in perfect accord with the position of Jefferson.[1116]
The Federalists contended that the President and Senate alone were
officially concerned, and that the House was obligated to carry out any
financial arrangements entered into in a treaty. Did not the Constitution
specifically say that the treaty-making power was lodged in the President
and the Senate? Conceded, replied the opposition, but the Constitution also
said that money bills must originate in the House, and in making
appropriations for any purpose the popular branch of Congress is
constitutionally bound to use its own discretion. Both sides could, and did,
appeal to the Constitution. There was nothing merely factious or obstructive
in the fight of the opposition, and it is impossible to peruse the seven
hundred and nine pages of the debates without a realization of the complete
sincerity of the participants. Into the debate dashed all the leaders of the first
order. The galleries were packed. The discussion was the sole
conversational topic in streets and coffee-houses. The newspapers printed
the leading speeches in full. Even the Federal courts injected themselves
into the controversy, and one jurist introduced a denunciation of the enemies
of the treaty into his charge to the grand jury.[1117] Fenno stupidly stumbled
into the blunder of proving the opponents of the treaty a ‘Robespierre
faction’ by quoting the London ‘Morning Chronicle,’[1118] and Cobbett, the
Englishman and Federalist pamphleteer, selected this particular time to
outrage the Philadelphia ‘rabble’ by filling his windows with pictures of
kings, queens, princes, dukes, Pitt, Grenville, and George III. With studied
insolence, he added some portraits of American Revolutionary heroes, and
‘found out fit companions for them.’ Thus he ‘coupled Franklin with Marat’
and ‘M’Kean and Ankerstrom.’[1119]
The burden of the debate was borne by Gallatin, Madison, Livingston,
and Giles for the Resolutions, and by Sedgwick and Griswold against them.
Livingston spoke with spirited eloquence and with that power of reasoning
which was afterward to compel his recognition as one of the foremost
political thinkers of his time.[1120] Giles sustained his reputation as a fluent,
forceful, slashing debater. Madison spoke with moderation; but the honors
of primacy fell to Gallatin. He was a revelation, and the Federalists were
beside themselves with rage. Tall, and above medium size, his fine face
aglow with intelligence, his black eyes burning with earnestness, his profile
resembling in its sharp outlines that of a Frenchman, his accent foreign, his
delivery slow and a little embarrassed, he spoke with a clarity and force that
made the Federalists wince. Livingston was more showy, Giles more
boisterous, Madison more academic. This new man was another Madison
with greater punch.[1121] He did not wander a moment from his argument—
the constitutional rights of the House in the case of treaties involving
appropriations.
‘The House has a right to ask for papers,’ he said, ‘because their
coöperation and sanction is necessary to carry the Treaty into full effect, to
render it a binding instrument, and to make it, properly speaking, a law of
the land; because they have a full discretion to either give or refuse that
coöperation; because they must be guided in the exercise of that discretion
by the merits and expediency of the Treaty itself, and therefore they have a
right to ask for every information which can assist them in deciding that
question.’ Whence led the argument of the foes of the Resolutions? ‘The
Constitution says that no money shall be drawn from the Treasury but in
consequence of appropriations made by law. But treaties, whatever
provisions they may contain, are law; appropriations may therefore be made
by treaties. Then the shortest way to carry this treaty into effect would have
been to add another article appropriating the money.’ Turning to the power
of the House of Commons in the case of treaties involving an appropriation,
he found an analogy to the constitutional power of the President and the
Senate, in the power of the King to make treaties. But no one in England
challenged the right of the Commons to appropriate or not in putting the
provisions of a treaty into effect—and the speaker cited instances where the
Commons had rejected treaties by refusing appropriations. ‘Are we in a
worse situation than Great Britain?’ he asked. ‘Is the House of
Representatives ... the immediate representatives of the American people
ranked below the British House of Commons? Shall the Legislative power
be swallowed up by the Treaty-making power as contended for here, though
never claimed even in Great Britain?’ The issue raised by the opposition to
the Resolutions was clear, and their rejection would be ‘tantamount to
saying that the House abandons their share in legislation, and consents that
the whole power shall be centered in the other branches.’
Such, in general, was the tenor of the argument for the Resolutions;
while the Federalists insisted that the House possessed no power to refuse
any appropriation called for by a treaty—and thus the discussion went round
and round like a wagon wheel in motion. Sedgwick, in justifying the
Senate’s power, made a blunder on which the supporters of the Resolutions
seized and with which they played throughout the discussion. The Senators
were safer than the Representatives, he thought, because the former were
not chosen by ‘an ignorant herd, who could be cajoled, flattered, and
deceived.’
At length the vote was taken, and the Resolutions adopted by 61 to 38.
Gallatin and Livingston, chosen by the House, personally presented the call
for the papers to Washington, who promised an answer after consideration.
An answer, sneered Bache, which sounds like that which the King of France
used to give to his subjects.[1122]
VI