`PAAVAI VIDHYASHRAM SENIOR SECONDARY SCHOOL

(Affiliated to CBSE)
Worksheet 5
Chapter 8: Aldehyde ketone and carboxylic acids
Topic: Preparation of Aldehyde and ketone
1. Oxidation of primary alcohol using CrO3 in 7. The product of the reaction is
anhydrous medium produces 𝐶𝑟𝑂3
→
a. Carboxylic acid
b. Aldehyde
c. Ketone
d. Ester a.

2. The product of the following reaction b. CH3COCH3

c. Mixture of carboxylic acid
d. No reaction
a. RCHO
b. RCOOH 8. When the vapours of a primary alcohol are
c. RCOR passed over heated copper at 573 K
d. RCOOR a. Dehydrogenation takes place
b. Dehydration takes place
3. Oxidation of secondary alcohol using CrO3 c. Reduction takes place
in anhydrous medium produces d. Substitution takes place
a. Carboxylic acid
b. Aldehyde 9. When the vapours of a secondary alcohol
c. Ketone are passed over heated copper at 573 K
d. Ester a. Dehydrogenation takes place
b. Dehydration takes place
4. The product of the following reaction is c. Reduction takes place
d. Substitution takes place
a. RCOR’
10. When the vapours of a tertiary alcohol are
b. RCOOH
passed over heated copper at 573 K
c. RCHO
a. Dehydrogenation takes place
d. ROOR’
b. Dehydration takes place
c. Reduction takes place
5. Oxidation of primary alcohol using
d. Substitution takes place
acidified potassium permanganate produces
a. Carboxylic acid
11. Oxidation of CH3CHCOCH3 using strong
b. Aldehyde
oxidising agents (KMnO4) and elevated
c. Ketone
temperatures produces
d. Ester
a. Ethanoic acid
b. Mixture of ethanoic acid, formic
6. Oxidation of tertiary alcohol using CrO3 in
acid, propanoic acid
anhydrous medium produces
c. Butanoic acid
a. Carboxylic acid
d. Ketone does not undergo oxidation
b. Aldehyde
c. Ketone
d. Tertiary alcohols do not undergo
oxidation reaction
1
12. Propanol on reaction with Cu at 573K 18. Write IUPAC names of the products
produces obtained by the ozonolysis of pent-2-ene
a. Propanal a. Ethanal and propanal
b. Propanone b. Ethanal and propanone
c. Propane c. Propanone and pentanone
d. Propoxyethane d. Butanal and ethanal

13. The product of the following reaction is 19. Write IUPAC names of the products
𝐶𝑢,573 𝐾 obtained by the ozonolysis of 3,4-
→
Dimethyl-hept-3-ene
a. Propanal a. Butanone and pentan-2-one
b. Propanone b. Butanone and pentan-3-one
c. Propane c. Butan-2-one and pentan-3-one
d. Propoxyethane d. Butanal and pentanal

14. The product of the reaction 20. Write IUPAC names of the products
obtained by the ozonolysis of 2-Ethylbut-1-
ene
a. Methanal and pentan-2-one
b. Ethanal and propanone
c. methanal and pentan-3-one
a. d. butanone and pentan-3-one

21. Write IUPAC names of the products

b. obtained by the ozonolysis of 1-Phenylbut-
1-ene
c. CH3CH2CH2CHO
a. Benzaldehyde and butanal
d. CH3CH2COCH3
b. Acetophenone and butanal
c. Benzaldehyde and butanone
15. The product of the following reaction is
d. Acetophenone and butanone

22. An alkene ‘A’ on ozonolysis gives a

16. When propanol is treated with alkaline mixture of ethanal and pentan-3- one. Write
KMnO4, the product obtained is structure and IUPAC name of ‘A
a. Propanal a. pent-2-ene
b. Propanone b. 3,4-Dimethyl-hept-3-ene
c. Propanoic acid c. 3-ethylpent-2-ene
d. Propene d. 2-Ethylbut-1-ene

17. In the given reaction, instead of Cu the 23. An alkene ‘A’ contains three C – C, eight C
metal that can be used is – H σ bonds and one C – C π bond. ‘A’ on
ozonolysis gives two moles of an aldehyde
of molar mass 44 u. Write IUPAC name of
‘A’.
a. But-1-ene
a. Ag
b. But-2-ene
b. Au
c. Both a and b
c. Pt
d. Neither a nor b
d. Pd
2
 28. The product of the following reaction is
24. Propanal and pentan-3-one is the
ozonolysis products of an alkene? The
structural formula of the alkene is

a.
a. Benzene
b. Chlorobenzene
c. Toluene
b. d. Benzaldehyde

29. Nitriles are reduced to corresponding imine

with stannous chloride in the presence of
c. hydrochloric acid, which on hydrolysis give
corresponding aldehyde. The reaction is
called
d. a. Rosenmund reduction.
b. Stephen reaction.
25. The final product of the reaction is c. Etard reaction.
d. Gatterman-Koch

30. The product of the reaction is

a. Ethanal
b. Propanone
c. Butanone a. RCH2CHO
d. Butanal b. RCHO
c. RNH2
26. The final product of the reaction is d. RCONH2

31. The product of the reaction is

a. Ethanal
b. Propanone
c. Butanone
a. RCH2CHO
d. Butanal
b. RCHO
c. RNH2
27. Acyl chloride (acid chloride) is
d. RCONH2
hydrogenated over catalyst, palladium
on barium sulphate. This reaction is called
32. The product of the reaction is
a. Rosenmund reduction.
b. Stephen reaction.
c. Etard reaction.
a. CH3-CH=CHCH2CH2CHO
d. Gatterman-Koch
b. CH3-CH=CHCH2CHO
c. CH3- CH2CH2CH2CH2CHO
d. CH3- CH2CH2CH2CH2CH3

3
33. Complete the following reaction 39. When benzene or its derivative is treated
with carbon monoxide and hydrogen
chloride in the presence of anhydrous
aluminium chloride or cuprous chloride, it
34. Chromyl chloride oxidises methyl group of gives benzaldehyde or substituted
toluene to a chromium complex, which on benzaldehyde. The reaction is called
hydrolysis gives corresponding a. Rosenmund reduction.
benzaldehyde. The reaction is called b. Stephen reaction.
a. Rosenmund reduction. c. Etard reaction.
b. Stephen reaction. d. Gatterman-Koch
c. Etard reaction.
d. Gatterman-Koch 40. The product of the reaction is
(𝐶𝐻3 )2𝐶𝑑
CH3COCl→
35. The product of the reaction is a. CH3CH2CH3
b. CH3COCH3
c. CH3CH2CHO
d. CH3COCH2CH3
a. Benzaldehyde
b. Benzoic acid
41. Treating a nitrile with Grignard reagent
c. Benzene
followed by hydrolysis yields a
d. Benzamide
a. Ketone
b. Aldehyde
36. The product of the above reaction is
c. Carboxylic acid
d. Amide

a. C6H6 42. The product of the following reaction is

b. C6H5CHO
c. C6H5CH3
d. C6H5COOH
a. Propiophenone
37. The product of the above reaction is b. 1-phenylpropanone
c. Both a and b
d. Neither a nor b

43. When benzene or substituted benzene is

a. C6H6 treated with acid chloride in the presence of
b. C6H5CHO anhydrous aluminium chloride, it affords
c. C6H5CH3 the corresponding ketone. This reaction is
d. C6H5COOH known as
a. Friedel-Crafts acylation reaction.
38. The product of the above reaction is b. Friedel-Crafts alkylation reaction.
c. Etard reaction
d. Rosenmund reduction

a. Benzaldehye
b. Benzene
c. Toluene
d. Benzoic acid

4
44. The product of the reaction is products will be formed on addition of
water to but-1-yne under these conditions.

a. Acetophenone
b. Benzophenone 50. Structure of ‘A’ and type of isomerism in
c. Biphenyl the above reaction are respectively.
d. Chlorobenzene

45. The product of the reaction is

a. Prop–1–en–2–ol, metamerism
b. Prop-1-en-1-ol, tautomerism
c. Prop-2-en-2-ol, geometrical
isomerism
d. Prop-1-en-2-ol, tautomerism

a. Acetophenone 51. Compounds A and C in the following

b. Benzophenone reaction are __________.
c. Biphenyl
d. Chlorobenzene
a. identical
46. The reagent used to convert Hexan-1-ol to
b. positional isomers
hexanal
c. functional isomers
a. C5H5NH+CrO3Cl-(PCC)
d. optical isomers
b. K2Cr2O7 in acidic medium
c. O3/H2O-Zn dust
52. Which of the following compounds will
d. (Diisobutyl)aluminium (DIBAL-H)
give butanone on oxidation with alkaline
KMnO4 solution?
47. The reagent used to convert But-2-ene to
a. Butan-1-ol
ethanal
b. Butan-2-ol
a. C5H5NH+CrO3Cl-(PCC)
c. Both of these
b. K2Cr2O7 in acidic medium
d. None of these
c. O3/H2O-Zn dust
d. (Diisobutyl)aluminium (DIBAL-H)

48. The reagent used to convert Allyl alcohol to

53. Assertion : Compounds containing —CHO
propenal
group are easily oxidised to corresponding
a. PCC
carboxylic acids.
b. O3/H2O-Zn dust
Reason : Carboxylic acids can be reduced
c. H2 Pd-BaSO4
to alcohols by treatment with LiAlH4
d. K2Cr2O7 in acidic medium

49. Addition of water to alkynes occurs in

acidic medium and in the presence of Hg2+
ions as a catalyst. Which of the following

5
54. Complete each synthesis by giving missing, 61. Write the structures of products of the
reagent following reactions

55. Complete each synthesis by giving missing

products

56. Complete each synthesis by giving missing

reagent

57. Complete each synthesis by giving missing

reactant

58. Write the structures of products of the

following reactions;

59. Write the structures of products of the

following reactions

60. Write the structures of products of the

following reactions