ST-101 HX-102 SM-101 HX-104 ST-201 ST-204 F-301 EX-301 BM-501

CHClF2 Storage Tank Water Pre-heater Static Mixer Partial Condenser TFE Storage Tank Paraffin Wax Filter Hexane Heater Ball Mill
Storage Tank
V-101 B-101 HX-103 EV-101 ST-202 R-201 ST-301 HX-302 ST-501
CHClF2 Vaporizer Boiler Cooler Evaporator Ammonium Perfluorooctanoate Polymerization Reactor Hexane Storage Tank Air Pre-heater Polytetrafluoroethylene
(APFO) Storage Tank Storage Tank
HX-101 R-101 KD-101 ST-102 ST-203 M-301 D-301
Tetrafluoroethylene Reactor HX-301
CHClF2 Heater Knockout Drum HCl Solution Ammonium Persulfate (APS) Washing Tank Hexane Heater Dryer
Storage Tank Storage Tank

15
SECTION 1: PRODUCTION OF TETRAFLUOROETHYLENE
SECTION 2: POLYMERIZATION OF
CHClF2(g)⇌CF2(g) + HCl(g) 11 16 To Stream 1
TETRAFLUOROETHYLENE
2CF2(g)⇌C2F4(g) HX-104
SM-101
900 -50
1 1
APFO APS Paraffin Wax
From HX-104 2 3 KD-101
8 9 10 ST-202 ST-203 ST-204 C2F4→(C2F4)100 (s)
850
150 30 30 30
1 900
CHClF2 1 150 1 1 1
HX-101 1
HX-103 0.5 22 To ST-201
V-101 R-101
ST-101
1 13 To Waste Treatment
18 19 20
30 30 6
17.76 1
EV-101
7 12 100
1 R-201 23 To M-301
ST-201 17 75
B-101 4
H 2O 4 5 ST-102 30
1
1
900 14
1
1
90 30 From R-201
HX-102 1 H 2O 21

HCl Solution

SECTION 3: TREATMENT AND STORAGE OF POLYTETRAFLUOROETHYLENE

Hexane
1
1
50
HE-301
ST-301
H 2O 29
1 35 Vent Air
5 30
30
PTFE
D-301
M-301 EX-301 BM-301 ST-302
F-301
36 37 30
From R-201 24 26 28 1 32 1 1
1 50 1 30
30 120

1
30
34 33 Air
27 To Waste Treatment 31 To Waste Treatment
1
1
120
HE-302

LEGENDS:

PROCESS 1:
Pressure (atm) Gas

Temperature (°C) Liquid

Stream Number Solid VIA PYROLYSIS OF CHLORODIFLUOROMETHANE