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:
C .
(I :
G
E = 15 V C
C C = 2000F
. 1 C .
(1 C . .Q
(2 2 .C
C>C
Q1 Q2 C C . .
(3 U
.= 10V
( C C .
(II : C
I0 = 10 mA
) ( 2 U
. t :

(U(V

(t(s

0.1

0.2

0.3

0.4

(1 U U .t

 q I0 .t

(2
dq
dt

=i

(3 1 2
C
.
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C R = 1 K
E = 10V .K t =0

:
(1
.
(2 :

) RC

uC = E (1 e

(3 uC
(4 RC
.s
(5
= RC

 :
/1 VA = 20 ml R-COOH Ca
Sb ) ((Na+(aq),OH-(aq . Cb=2,5.10-2mol/l
PH :
1-1 .

1-2 ,Va ,cb,Vb :

Ca

1-3 .
1-4 VbE .
1-5
.

,Va ,cb ,VbE

Ca Ca

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:
R-COOH(aq) +H2O() = R-COO- (aq) +H3O+ (aq

2-1 KA R-
.( ( -COOH/R-COO
2-2
:
pH = pKA + Log([R-COO-]/[R.([COOH
2-3 Sb Vb= VbE/2
2-4 ) Xf=Cb VbE/2 (.

 2-5 Vb= VbE/2 :

[[R-COOH]aq =[ R-COO

aq

2-6 2-2 pH =Vb

.VbE/2
2-7 pKA .
pKA

1,3

HCl2-COOH/HCl2-COO

2,9

H2Cl-COOH/H2Cl-COO
-

3,8

HCOOH/HCOO

4,8

CH3-COOH/CH3-COO

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