DPP
CLASS – 12th
Q.- Complete the reaction :
acidic NH3 NaO Br
(1) CH3 — CH2 — OH (A) (B) (C)
K2Cr2 O7
PCI5 KCN Partial
(2) CH3 — CH2 —OH (A) (B) (C)
Hydrolysis
0 - 5ᵒC
Conc.HNO3 Sn NaNO2 H2O Zn
(3) (A) (B) (C) (D) (E
H2SO4 HCI HCl ∆ ∆
Br2 NaNO2 CuCN
(4) C7H7NO Aniline (B) (C)
(A) Alc. K— OH + HCI
(D)
Reagent
CH3 Mg I HOH KMnO4
(5) H — C — H (A) (B) (C)
ǁ H+ acidic
O
FeBr3 Mg CO2 H2O/H+ NH3/∆
(6) + Br2 (A) (B) (C) (D) (E)
Dry
ether
NO2
Sn/HCI NaNO2 CuCN complete hydrolysis
(7) (A) (B) (C) (D)
HCl H2O/ H+
LiAIH4 SOCl2 KCN Ni/H2
(8) CH3 — C — H (A) (B) (C)
ǁ
O
CH3 + K—OH
FeBr3 Sn/HCI NaNO2/HCI + H2O H3O+
(9) + Br2 (A) (B) (C) (D) (E)
H3PO2 KMnO4
NO2
1
CH3
KMnO4 H3O+ LiAIH4 PCI3
(10) (A) (B) (C) (D)
+ K—OH
O
ǁ CH2COOC2H5
(11) NaBH4 (A)
LiAlH4 NOCl KCN H2O/H+
(12) CH3 — NO2 (A) (B) (C) (D)
Complete hydrolysis
HOH CH3 MgBr H2O/H+
(13) CH3— C — Cl + CH3 — MgBr (A) (B) (C) (D)
ǁ H+
O
Dry HOH
(14) Br + Mg (A) (B)
Ether
(15) Toluene to Benzene
Cu CH3 MgI HOH/H+
(16) CH3 — CH — CH3 (A) (B) (C)
573 K
OH
HNO2 acidic SOCI2
(17) CH3 — CH2 — NH2 (A) (B) (C) (D) (E)
K2Cr2 O7 CH3 — MgI HOH/H+
AICI3 Conc.HNO3
(18) + CH3 — C — CI (A) (B)
ǁ + H2SO4
O
AICI3 KMno4 H2O/H+ H2SO4
(19) + CH3 — CI (A) (B) (C) (D)
+ K — OH Conc. HNO3
OH
Zn neoPentyl
(20) (A)
Chloride
Alcl3
2
HBr
Conc.HNO3 Sn/HCl NaNO2 Cu2Br2 AlCl3
(21) (A) (B) (C) (D)
Conc.H2SO4 HCl CH3—C—Cl
O - 5ᵒC ǁ
O
H—C—H
ǁ
dry O HOH/H+ K2Cr2O7
(22) CH3 — Br + Mg (A) (B) (C) (D)
ether acidic
O
ǁ
C —CI
CH2 — OH
acidic NaOH
(23) (A) (B) (C)
K2 Cr O7 + CaO AICI3
O
ǁ
C—H MgBr
HOH Cu/573K
(24) + (A) (B) (C)
H+
Q.- Conversion :
1. Nitrobenzene to Benzoic acid
2. Aniline to Benzylamine
3. Benzene to Phenol
4. Ethyl amine to Methyl amine
5. Bromo benzene to Benzoic acid
6. Benzyl alcohol to M – nitro Benzoic acid
7. Ethyl chloride to propanoic acid
8. Benzyl amine to Benzoic acid
9. Acetone to tert Butyl Alcohol
10. Hexane nitrile to pentane – 1-amine
