The document presents various problems related to solubility, including calculations for saturated solutions and concentration percentages of different salts in water at specific temperatures. It provides answers for each problem, detailing the solubility of salts like KNO3, NaCl, KCl, and NH4Cl at various temperatures. Additionally, it discusses the effects of temperature changes on solubility and includes specific calculations for weight separation upon cooling.
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Problems On Solubility
The document presents various problems related to solubility, including calculations for saturated solutions and concentration percentages of different salts in water at specific temperatures. It provides answers for each problem, detailing the solubility of salts like KNO3, NaCl, KCl, and NH4Cl at various temperatures. Additionally, it discusses the effects of temperature changes on solubility and includes specific calculations for weight separation upon cooling.
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Problems based on solubility
1. To make a saturated solution, 136 g of a salt is
issolved in 500 g of water at 294K. Hind ils solubility
AC this temperature Ans. 27.26
2. @) A solution contains 15 g of sodium chloride 1
285 g of water, Calculate the concentration of the
solution Ans. 5%
(b) 4 litres of an organic compound, acetone, is present
iN 90 litres of an aqueous solution, Calculate its
Volume percent. Ans, 444%
3. The following table gives the solubility of different
salts at different temperatures.
{ Temperature (in K) | Substance dissolved (in g)
L KNO, NaCl KCI NH,CI
| 383 Ya % 35.
203 | 32 6 35 37
i 3 } 62 36 40 41
333 106 37 46 55
&s Nal S77 iad ea
Answer the following questions based on the table
given above.
(a) What mass of KNO, would be needed to produce
a saturated solution of KNO, in 50 grams of water
at 313 K.
(b) If a saturated solution of KCI is made at 353 K
and then cooled at room temperature, what would
you observe? Explain.
(c) Find the solubility of each salt at 293 K.
(d) Which salt has the lowest solubility at 283 K ?
(e) What is the effect of change of temperature on
the solubility of a salt.
Ans.(a) 31 g (b) Crystals of KCI (c) KNO, - 32 g,
NaCl - 36 g, KCI 35 g, NH,Cl~ 37 g (d) KNO,
(a) Find the solul of KNO, at 20°C when the mass
of the is 50 g, the mass of dish and
41ee oe
solution is 65 g, while the mass of dish and residue
is 54.3 g. Ans. 40.18 g
(b) What weight of sodium nitrate will separate when
a saturated solution containing 50 gram of water
is cooled from SO°C to 30°C ? The solubility of
NaNO, at 50°C and 30°C is 114 g and 86
oO
respectively.
o
Ans. 14 g
5. To make a saturated solution, 36 g of sodium chloride
is dissolved in 100 g of water at 293 K. Find its
concentration at this temperature. Ans. 26.47%