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CHEMISTRY

11th Redox Reaction NEET

Practice Sheet-02

1. The decomposition of KClO3 to KCl and O2 on 7. A sulphur containing species that cannot be an
heating is an example of; oxidising agent is;
(1) Intermolecular redox change. (1) H2SO4 (2) H2S
(2) Intramolecular redox change. (3) SO2 (4) H2SO3
(3) Disproportionation or auto redox change.
(4) None of these 8. Which combination is odd with respect to oxidation
numbers of S, Cr, N and H respectively?
2. In the conversion of Br2 to BrO3 , the oxidation (1) H 2SO5 , H 2S2 O8 , H 2SO 4 ,SF6
number of Br changes from; (2) K 2 Cr2 O7 , K 2 CrO4 ,CrO5 ,CrO 2 Cl2
(1) 0 to +5 (2) +1 to +5
(3) 0 to –3 (4) +2 to +5 (3) NH3 , NH4 , N3H, NO2
(4) CaH 2 , NaH, LiH, MgH 2
3. What weight of HNO3 is needed to convert 5 g of
iodine into iodic acid according to the reaction, 9. The weight of FeSO4 (Mol. wt. = 152) oxidized by
I 2  HNO3  HIO3  NO2  H 2 O ? 200 mL of 1 N KMnO4 solution is;
(1) 12.4 g (2) 24.8 g (1) 30.4 g (2) 15.2 g
(3) 0.248 g (4) 49.6 g (3) 60.8 g (4) 158 g

4. HBr and HI reduce H2SO4, HCl can reduce KMnO4 10. The oxidation number of N and Cl in NOClO4
and HF can reduce; respectively are;
(1) H2SO4 (1) +2 and +7
(2) K2Cr2O7 (2) +3 and +7
(3) KMnO4 (3) –3 and +5
(4) None of these (4) +2 and –7

5. Among NH3 ,HNO3, NaN3 and Mg 3 N 2 , the number 11. Magnesium reacts with acids producing hydrogen
of molecules having nitrogen in negative oxidation and corresponding magnesium salts. In such
state is; reactions, magnesium undergoes;
(1) 1 (2) 2 (1) Oxidation.
(3) 3 (4) 4 (2) Reduction.
(3) Neither oxidation nor reduction.
6. An element A in a compound ABD has oxidation (4) Simple dissolution.
number An–. It is oxidized by Cr2O72 in acidic
medium. In the experiment, 1.68 × 10–3 mol of 12. The oxidation state of +3 for phosphorus is in;
K2Cr2O7 were used for 3.26 ×10–3 mol of ABD. The (1) hypophosphorous acid.
new oxidation number of A after oxidation is; (2) meta-phosphoric acid.
(1) 3 (2) 3–n (3) ortho-phosphoric acid.
(3) n–3 (4) +n (4) phosphorous acid.
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13. How many litre of Cl2 at STP will be liberated by 18. The number of mole of potassium salt, i.e.,
the oxidation of NaCl with 10 g KMnO4? KHC2O4.H2C2O4.2H2O oxidised by one mole of
(1) 3.54 L (2) 7.08 L permanganate ion is;
(3) 1.77 L (4) None of these 2 4
(1) (2) 4/5
5 5
14. Match List-I with List-II. 5
(3) 1 (4)
List-I List-II 4
(Reactions) (Type of Reactions) 19. When an acidified solution of ferrous ammonium
A. V2O5(s) + 5Ca(s) I. Disproportionation sulphate is treated with KMnO4 solution, the ion
which will be oxidised is?
→ 2V(s) + 5CaO(s) reaction
B. (1) Fe2+ (2) SO24
CH4(g) + 2O2(g) II. Decomposition
 
 CO (g) + reaction (3) NH4 (4) MnO4
2

2H2O(l)
20. Which metal exhibits more than one oxidation
C. P4(s) + 3OH–(aq) + III. Combustion
states?
3H2O(l) → PH3(g) reaction (1) Na (2) Mg
+ 3H2 PO 2– (aq) (3) Al (4) Fe

D. 2KClO3(s)   IV. Displacement
reaction 21. Which of the following is not an oxidising agent?
2KCl(s) + 3O2(g) (1) KClO3 (2) O2
Choose the correct answer from the options given (3) C6H12O6 (4) K2Cr2O7
below;
(1) A-IV, B-II, C-III, D-I 22. The oxidation number of C in CH4, CH3Cl, CH2Cl2,
(2) A-IV, B-III, C-I, D-II CHCl3 and CCl4 are respectively;
(3) A-III, B-IV, C-II, D-I (1) +4, +2, 0, –2, –4 (2) +2, +4, 0, –4, –2
(4) A-III, B-IV, C-I, D-II (3) –4, –2, 0, +2, +4 (4) –2, –4, 0, +4, +2

23. The oxidation number of Pt in [Pt(C2H4)Cl3]– is;

15. The number of mole of ferrous oxalate oxidised by (1) +1 (2) +2
one mole of KMnO4 is; (3) +3 (4) +4
1 3
(1) (2) 24. The oxidation number of sodium in sodium amalgam
5 5
is;
2 5
(3) (4) (1) +2 (2) +1
3 3
(3) –2 (4) Zero

16. For the reaction: N 2  3H 2  2NH3 ; if E1 and E2 25. A reducing agent is a substance which can;
are equivalent masses of NH3 and N2 respectively, (1) accept electrons. (2) donate electrons.
then E1 – E2 is; (3) accept protons. (4) donate protons.
(1) 1 (2) 2
26. Equivalent weight of N2 is the change
(3) 3 (4) 4 N2  NH3 is;
28
17. The oxidation state of two sulphur atoms in H2S2O8; (1) (2) 28
6
(1) –6 (2) –2 28 28
(3) +6 (4) –4 (3) (4)
2 3
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27. Equivalent weight of NH3 in the change N2 → NH3 34. In the reaction,
is; 8Al + 3Fe3O4 → 4Al2O3 + 9Fe
17 the number of electrons transferred from reductant
(1) (2) 17
6 to oxidant is;
17 17 (1) 8 (2) 4
(3) (4) (3) 16 (4) 24
2 3
28. What would be the equivalent weight of the 35. What will be the value of x, y and z in the following
reductant in the reaction? equation?
2 Fe(CN)6   H2O2  2OH 
3
xI2  yOH  IO3  zI  3H2O
2 Fe(CN)6   2H2O  O2
4 (1) 3, 5, 6 (2) 5, 6, 3
(3) 3, 6, 5 (4) 6, 3, 5
[Given: Fe = 56, C = 12, N = 14, O = 16, H = 1]
(1) 17 (2) 212 36. When KMnO4 is titrated against FeSO4.(NH4)2SO4.
(3) 34 (4) 32
6H2O the equivalent mass of KMnO4 is;
29. In the reaction, Molecular mass
(1)
2CuSO4 + 4KI  Cu2I2 + 2K2SO4 + I2 10
the ratio of equivalent weight of CuSO4 to its Molecular mass
molecular weight is; (2)
5
1 1 Molecular mass
(1) (2) (3)
8 4 2
1 1 (4) Molecular mass
(3) (4)
2 1
30. Oxidising product of substance Na3AsO3 would be;
37. What is the equivalent weight of P4 in the given
(1) As2 O33 (2) As2 O33
reaction?
(3) AsO24 (4) AsO43 P4 + NaOH  NaH2PO2 + PH3
31 31
31. Compound YBa2Cu3O7 is a super conductor. The (1) (2)
4 3
O.N. of the copper in the compound will be; 31 4
[Oxidation No. of Y = +3] (3) (4) 31
2 3
7
(1) (2) zero
3 38. Equivalent weight of H3PO2 when it disproportionates
(3) + 2 (4) + 1 into PH3 and H3PO3 is;
(mol. wt. of H3PO2 = M)
32. How many electrons should X2H4 liberate so that in
the new compound ‘X’ shows oxidation number of 3M
(1) M (2)
1 4
[Given E.N. : X > H]? M M
2 (3) (4)
(1) 10 (2) 4 2 4
(3) 3 (4) 2 39. One mole of N2H4 loses 10 mol of electrons to form
a new compound Y. Assuming that all nitrogen
33. In a reaction, 4 mole of electrons are transferred to appear in the new compound, what is oxidation state
one mol of HNO3 when it acts as an oxidant. The of nitrogen?
possible reduction product is; (there is no change in the oxidation state of
1 1 hydrogen)
(1)   mol N2 (2)   mol N2O (1) –1 (2) –2
2 2
(3) 1 mol of NO2 (4) 1 mol NH3 (3) +3 (4) +5
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40. Reaction (A) S2  4H2O2  SO42  4H2O 47. Of the following reactions, only one is a redox
(B) Cl2  H 2 O2  2HCl  O2 reaction. Identify it.
the true statement regarding the above reactions is; (1) Ca(OH) 2  2HCl  CaCl2  2H 2 O .
(1) H2O2 acts as reductant in both the reactions. (2) BaCl2  MgSO4  BaSO4  MgCl2 .
(2) H2O2 acts as oxidant in reaction (A) and (3) 2S2O72  2H2O  4SO42  4H .
reductant in reaction (B).
(3) H2O2 acts as an oxidant in both the reactions. (4) Cu 2S  2FeO  2Cu  2Fe  SO 2 .
(4) H2O2 acts as reductant in reaction (A) and
oxidant in reaction (B). 48. What is the change in oxidation number of carbon in
the following reaction?
41. A compound contains atoms A, B and C. The oxidation CH 4 (g) + 4Cl2 (g)  CCl4 (l ) + 4HCl(g)
number of A is +2, of B is +5 and of C is –2.
The possible formula of the compound is; (1) 0 to + 4 (2) –4 to + 4
(1) ABC2 (2) B2(AC3)2 (3) 0 to – 4 (4) + 4 to + 4
(3) A3(BC)4 (4) A3(B4C)2
49. The oxidation number of the underline atom in the
following species. Identify the incorrect option;
42. Assertion (A) : Fe2O3  2Al   Al2O3  2Fe
(1) ClO3– is +5
The above chemical equation is an example of
displacement reaction. (2) K2 Cr 2O7 is  6
Reason (R) : Aluminium being more reactive than (3) HAuCl4 is  3
iron, displaces Fe from its oxide.
(1) Both Assertion (A) and Reason (R) are true (4) Cu 2O is  1
and Reason (R) is a correct explanation of
Assertion (A). 50. Which of the following reactions are disproportion-
(2) Both Assertion (A) and Reason (R) are true ation reaction?
but Reason (R) is not a correct explanation of A. 2Cu    Cu 2  Cu 0
Assertion (A).
(3) Assertion (A) is true and Reason (R) is false. B. 3MnO24  4H   2MnO4  MnO2  2H2O
(4) Assertion (A) is false and Reason (R) is true. C. 2KMnO4 
 K 2 MnO4  MnO2  O2
D. 2MnO4  3Mn 2  2H2O   5MnO2  4H
43. In the reaction: A n2  xe  A n1 , here x will be;
(1) n1 + n2 (2) n2 – n1 Select the correct option from the following;
(3) n1 – n2 (4) n1 . n2 (1) A and B only (2) A, B and C
(3) A, C and D (4) A and D only
44. We have, 2CuI  Cu + CuI2.
This process is called; 51. The correct structure of tribromooctaoxide is;
(1) Redox reaction
(2) Neutralization reaction
(1)
(3) Oxidation reaction
(4) Reduction reaction

45. The zero oxidation state of carbon is observed in the

(2)
compound;
(1) CH2O (2) CO2
(3) CH4 (4) CHBr3
(3)
46. What will be the coefficient of the oxalate ion after
balancing the following reaction?
MnO4  C2O42  H  Mn 2  CO2  H2O
(1) 4 (2) 2 (4)
(3) 3 (4) 5
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ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 2 1 1 4 3 2 2 3 1 2 1 4 1 2 4
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 1 3 4 1 4 3 3 2 4 2 1 4 1 4 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 1 3 2 4 3 2 4 2 3 2 3 1 3 1 1
Que. 46 47 48 49 50 51
Ans. 4 4 2 4 1 1