DPP No.
G2
GENERAL ORGANIC
CHEMISTRY
Instructions
Total Qn.: 19 Total Marks: 76 Time: 38 Min
SCQ: Correct +4 Incorrect -1 Not Attempt 0
INTEGER: Correct +4 Incorrect -1 Not Attempt 0
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CHAPTER: GOC DPP No. G2 CLASS: JEE Dropper
1. Resonance effect involves:
(A) Delocalization of π-electrons along a conjugated system
(B) Delocalization of lone pair along a conjugated system
(C) Delocalization of negative charge along a conjugated system
(D) All are correct
2. Resonance structures of a molecule do not have:
(A) Identical bonding (B) Identical arrangement of atoms
(C) The same number of paired electrons (D) Nearly the same energy content
3. In which of the following delocalisation of π-electron is possible.
(A) CH2==CH—CH2—CHO (B) CH2==CH—CH==O
(C) (D) CH2==CH—CH2—CH==CH2
4. Which of the following compound show resonance?
(A) (B) (C) (D)
5. Number of delocalised π electrons in the following structure is:
(A) six (B) eight (C) four (D) ten
6. Find the total number of positions where positive charge can be delocalized by true resonance.
(Excluding the given position)
(A) four (B) eight (C) two (D) six
7. Identify the number of compounds in which positive charge will be delocalised?
(A) two (B) three (C) four (D) five
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CHAPTER: GOC DPP No. G2 CLASS: JEE Dropper
8. How many of the following species, the negative charge is delocalised?
(A) seven (B) four (C) six (D) five
9. In which compound delocalisation is not possible:
(A) 2-Butene (B) 1, 3-Butadiene (C) 1, 3, 5-Hexatriene (D) Benzene
10. Which of the following pairs are resonating structures?
(A) (B)
(C) (D) CH3—CH==CH—CH3 & CH3—CH2—CH==CH2
+
11. Stability of C H2—CH==CH2 can be explained by:
(A) Inductive effect (B) Electromeric effect (C) Resonance (D) Polar effect
12. How many equally stable resonating structures are possible for (tropylium cation)?
(A) 2 (B) 4 (C) 5 (D) 7
13. Which of the following is not acceptable resonating structure of Buta-1,2,3-triene?
(A) (B) (C) (D)
14. The least and most stable resonating structure respectively are:
(i) (ii)
(iii) (iv)
(A) (i), (iv) (B) (ii), (iii) (C) (iv), (i) (D) (iii), (ii)
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CHAPTER: GOC DPP No. G2 CLASS: JEE Dropper
15. Which will be the least stable resonating structure?
(A) (B)
(C) (D)
16. HNCO (isocyanic acid) has following resonating structures:
The order of stability is:
(A) I > III > II (B) I > II > III (C) II > III > I (D) II > I > III
17. The decreasing order of stability of the following resonating structures is:
(A) I > II > III (B) II > III > I (C) III > II < I (D) I > III > II
18. Which of the following resonating structure will contribute minimum to resonance hybrid?
(A) I (B) II (C) III (D) All contribute equally
19. In each of the following pairs which ion is more stable:
(x) (y)
(i) &
(ii) &
(iii) &
(iv) &
(A) x | y | y | y (B) y | x | y | x (C) x | x | x | x (D) y | x | y | y
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CHAPTER: GOC DPP No. G2 CLASS: JEE Dropper
ANSWER KEY
01 (D) 02 (A) 03 (B) 04 (D) 05 (B) 06 (B) 07 (D) 08 (D)
09 (A) 10 (B) 11 (C) 12 (D) 13 (D) 14 (A) 15 (A) 16 (A)
17 (A) 18 (B) 19 (B)
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