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AI HOC QUOC GIA TP HO CH MINH TRNG AI HOC KHOA HOC T NHIEN C S LINH TRUNG

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THI GIA K HA I CNG B Hc k I /2010-2011

Ma e

TONG SO CAU: 30THI GIAN LAM BAI: 40 phut

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Lu y th sinh: Lam bai tren PHIEU TRA LI.

Khng s dng ti liu, k c Bng H Thng Tun hon, np li thi.

PHIEU TRA LI khong ghi va to ma e se chu iem 0.

<C1> ien tch hat nhan (Z), so proton (p), so neutron (n), va so khoi (A) cua 31 nguyen to 15 X la: a) Z=31, p=15, n=16, A=15 b) Z=15, p=16, n=15, A=31 c) Z=31, p=16, n=15, A=15 d*) Z=15, p=15, n=16, A=31 <C2> ien t cuoi cung cua nguyen to X co bo 4 so lng t la: n = 3, l = 1, ml = 0, ms = -1/2. V tr cua X trong bang he thong tuan hoan cac nguyen to hoa hoc la: a) Chu ky 5, phan nhom VIIA b) Chu ky 3, phan nhom VIIB c*) Chu ky 3, phan nhom VIIA d) Chu ky 5, phan nhom IIIA <C3> Cau hnh ien t cua ion Fe2+ (Z = 26) la: a*) [Ar] 3d6 b) [Ar] 3d4 4s2 c) [Ar] 3d7 4s1 d) [Ar] 3d8 4s2 (Vi [Ar] = 1s2 2s2 2p6 3s2 3p6 ) <C4> Gia tr nao sau ay khong the la gia tr ml cua electron ng vi l=2 a) 0 b*) +3 c) +2 d) -2 <C5> Chon tap so lng t ung e mo ta mot electron trong lp van ao 3p a) n = 3; l = 0; ml = 0; ms = 0 b) n = 3; l = 2; ml = -2, -1, 0, +1, hay 2; ms = +1/2 hay -1/2 c*) n = 3; l = 1; ml = -1, 0 hay +1; ms = +1/2 hay -1/2 d) n = 4; l = 0; ml = -1, 0 hay +1; ms = +1/2 hay -1/2 <C6> Nguyen t Crom (Z=24) co ...... electron khong ghep oi va la .... a*) 6, thuan t b) 4, thuan t c) 5, nghch t d) 3, nghch t <C7> Mot nguyen t trang thai c ban co 33 electron, vay co bao nhieu electron trong van ao p? a) 12 b) 6 c) 3 d*) 15 <C8> Bo 4 so lng t ng vi ien t ke cuoi cua nguyen to co Z = 8 la: a) n=2; l=0; ml=0; ms=+

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b*) n=2; l=1; ml=+1; ms=+ c) n=2; l=1; ml=-1; ms=- d) n=3; l=1; ml=+1; ms=+ <C9> Nguyen to Y co cau hnh ien t la 1s2 2s2 2p6 3s2 3p6 3d5 4s2. V tr nguyen to Y trong bang he thong tuan hoan la : a) Chu ky 4, phan nhom IIA b) Chu ky 4, phan nhom IIB c*) Chu ky 4, phan nhom VIIB d) Chu ky 3, phan nhom VIIB <C10> Gia tr nang lng ion hoa th nhat (I) cua cac nguyen to Na (Z = 11), K (Z = 19), Rb (Z = 37) thay oi nh sau: a*) I (Na) > I (K) > I (Rb) b) I (Na) < I (K) < I (Rb) c) I (Na) < I (Rb) < I (K) d) I (Na) > I (Rb) > I (K) <C11> Gia tr ai lc ien t (E) cua cac nguyen to N (Z = 7), P (Z = 15), As (Z = 33) thay oi nh sau: a) E (N) > E (P) > E (As) b*) E (N) < E (P) < E (As) c) E (P) < E (As) < E (N) d) E (P) > E (As) > E (N) <C12> Trong bang he thong tuan hoan cac nguyen to hoa hoc, cac nguyen to thuoc cung mot phan nhom th: a) Co cung so phan lp electron b) Co cung so van ao c) Co cung so electron d*) Co cung so electron hoa tr <C13> Cac nguyen to: Mg (Z=12), Sr (Z=38), Ca (Z=20) va Be (Z=4), la cac nguyen to thuoc nhom IIA trong bang he thong tuan hoan. Ban knh cac ion tng ng se bien oi theo th t: a) Be2+ > Mg2+ > Ca2+ > Sr2+ b) Be2+ = Mg2+ = Ca2+ = Sr2+ c*) Be2+ < Mg2+ < Ca2+ < Sr2+ d) Be2+ > Mg2+ = Ca2+ > Sr2+ <C14> Trong nguyen t P (Z=15) co bao nhieu ien t co so lng t spin ms=+ a) 15 b*) 9 c) 6 d) 3 <C15> Trong bang he thong tuan hoan cac nguyen to, khi xet t trai sang phai trong mot chu ky th: a*) Nang lng ion hoa th nhat tang b) o am ien giam c) Nang lng ion hoa th nhat giam d) Ban knh nguyen t tang <C16> Cho cac hp chat va ion sau: SF6, NO2 , IBr2 , H2O. Trang thai lai hoa cua nguyen t trung tam, dang hnh hoc cua cac hp chat va ion nay lan lt la: a*) sp3d2 bat dien; sp2 dang goc; sp3d thang hang; sp3 dang goc. b) sp3d2 bat dien; sp thang hang; sp thang hang; sp3 dang goc c) sp3d2 bat dien; sp thang hang; sp3d thang hang; sp3 dang goc d) sp3d2 bat dien; sp2 dang goc; sp thang hang; sp3 dang goc

Trang: 3/4 Ma e:<made> <C17> Trong so cac lien ket sau, lien ket nao co tnh ion ln nhat? Biet o am ien cua C (2,55); N (3,04); O (3,44); F (3,98). a) C-C b) C-N c*) C-F d) C-O <C18> Trong cac phan t: CCl4, H2O, CS2, BF3, SiH4, NH3, C2H2, phan t phan cc la: a) CCl4, H2O, NH3 b) BF3, SiH4, H2O c*) H2O, NH3 d) CCl4, CS2, NH3 <C19> Cho nguyen to M co Z = 27. Cau hnh electron cua ion M2+ la: a*) [Ar] 3d7 4s0 b) [Ar] 3d5 4s2 c) [Ar] 3d6 4s1 d) [Ar] 3d6 4s0 <C20> Goc ket hp cua cac phan t: Cl2O (1), H2O (2), F2O (3) thay oi theo th t: a) 1 > 3 > 2 b) 3 > 2 > 1 c*) 2 > 1 > 3 d) 1 > 2 > 3 <C21> Nguyen to Z co ien tch hat nhan la 34. V tr cua Z trong bang he thong tuan hoan la: a) Chu ky 4, phan nhom VA b*) Chu ky 4, phan nhom VIA c) Chu ky 3, phan nhom IVA d) Chu ky 5, phan nhom IA 80 81 82 <C22> Cac nguyen to 34 Se , 35 Br , 36 Kr co: a) Cung khoi lng nguyen t b) Cung so proton c*) Cung so neutron d) Cung so electron <C23> Chon phat bieu sai: a) Lien ket ion co o phan cc ln hn lien ket cong hoa tr b) Lien ket gia cac phan t cong hoa tr la lien ket yeu c*) Lien ket ion co tnh nh hng va co tnh bao hoa d) Hp chat ion co nhiet o nong chay va nhiet o soi cao <C24> Nhom chat nao co s sap xep theo th t co nhiet o nong chay cao nhat cho en thap nhat? a) HF > H2 > NaF b) NaF > H2 > HF c) HF > NaF > H2 d*) NaF > HF > H2 <C25> Octan (C8H18) la mot thanh phan cua nhien lieu dung cho ong c. Lc lien phan t nao chiem u the trong octan? a) Lc lng cc lng cc b) Lc hydro c*) Lc khuech tan d) Lien ket ion <C26> Nhom chat nao tan tot trong dung moi benzen?

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a*) CH4, CCl4, I2 b) C2H4, H2O, NaCl c) NH3, CCl4, KCl d) BF3, HCl, MgO <C27> Nguyen to Mangan (Z = 25) co: a) Hai ien t hoa tr b*) Bay ien t hoa tr c) Nam ien t hoa tr d) Ba ien t hoa tr <C28> D oan hnh hoc phan t cua ion sulfit SO32a*) Thap tam giac b) T dien c) Tam giac phang d) Dang ch T <C29> Cac ion C4-, N3-, O2-, F- co ac iem: a) Cung gia tr ien tch am b) Ban knh ion nh nhau c*) Cau hnh ien t giong nhau d) So neutron nh nhau <C30> Phan t nao sau ay co hn mot dang cau truc Lewis tng ng, do o co kha nang ton tai dang cong hng? a) BeI2 b*) O3 c) PF3 d) CO2