GRADE aay CHEMISTRY ROLLNO : 40, ed GENERAL, INSTRUCTIONS: Naa pees following instructions carefull {a) There are 33 questions inthis question i es S question paper with internal choice {B)SECTION A consists of 16 multiplechoice questions carrying mark each (€)SECTION B consists ofS short answer questions carrying 2 marks each, (2) SECTION C consists of 7 short answer questions carrying 3 marks each (6) SECTION D consists of 2 case-based questions car tying 4 marks each (0 SECTION & consists o 3 long answer questions carrying § mere, each (8) All questions are compulsory, (h) Use of log tables and calculators is not allowed ' SECTION -A ST. THOMAS CBSE SCHOOL, Ni Alpi RMINAL Choose the correct answer: (16x1 Calculate the molality ofa splution prepared by dissolving 10 g NaCl in 500 g water. (NaCl 0.171 mol/kg 0.342 mol/kg ©) 1.71 mol/kg 4) 3.42 mol/kg 2. Wily does the addition of a solute elevate the boiling point of a solvent? a) Increases vapour pressure ) Lowers freezing point <9 Decreases vapour pressure! ‘i Increases osmotic pressure 3. What does a negative E° value ofa half-cell indicate? 0; 4. Calculate the EMF ofa cell: ‘dation is favored. b) Reduction is favored Zn(s)lzn?*(1M)IICu2*(1M)ICu(s) (E%n = -0.76 V, E°Cu = +0.34 Vv) 1.10 b)-140V 042 d)-042V 5. Which of the following is a Janthanoid? a)Th vce. Qu 4) Pu 6 Chromium forms Cr?* and Cr** ions. Which is more stable in aqueous solution and why? a) Cr?" due to lower charge } Cr#* due to higher hydration energy ©) Cr?* due to larger size d) Cr°* due to lower size 7. Name the compound [Co(NH).Cl]C ) 8.5 4a) ©)Cellis atequilibrium ——d) Currentis zero a) Tetrammine dichlorocobalt(I) chloride boyfetrammine dichlorocobalt(Itt) chloride » ©) Tetraamminechlorocobalt(tl) chloride 4) Tetraamminechlorocobalt(Il) chloride 8, Which of the following has ionisation isomerism? a) [Cr(H20).|Cls A {co([Link]}804- ©) [Ni(CN)4]® 4) [Fe(CN)]* 9. What will be the major product of the reaction of 2-bromobutane with alcoholic KOH? 2) Butanol Bute )Butanaeaed deplore 10. Compare the reactivity ofthe following towards SN1: Choose the correct order: |. tgrt-butyl bromide ILethyl bromide IU isopropyl bromide eine bys ome i> rete 11. Which of the following isa secondary alcohol? a) 1-propanol 2-propanol ¢) Methanol 4) 2-methyl-2-propanol 12. Whysdoes phenol show acidic character? Re eaarance sa blaatlet osetia on b) Presence of OH group c) Hydrogen bonding GXAll of the above Assertion ~ Reason (13-16) Use the following keys to choose the appropriate answer a. Both Aand R are correct and R is the correct explanation of A b. Both Aand Rare correct but R is not the correct explanation of A. Ais correct and Ris incorrect d. Ais incorrect and R is correctTo puCas test can distinguish between primary, secondary, and tertiary alcohols. : Tertiary alcohols give turbidity due to stable carbocation formatior turbidity immediately due to stable carbocal ation. 14, ee Ina galvanic cell, the elec tron flow ts from anode to cathode, 0. 5 pau: Oxidation occurs at the anode, releasing electrons a oun . boiling point ofa solution is higher than that ofthe pure solvent a # Addition of solute increases the vapor pressure of the solvent. Rees {Co(NHs)«}"" ts a coordination compound. , Reason: It contains Co ion surrounded by six ammonia molecules acting as ligands SECTION -B M1. Very short answer type questions: 17. i)Why is phenol more acidic than ethanol? 3 or fi) Write the mechanism of acid-catal lyzed dehydrati hanol t 2 18.4) Define molality and writeits formula, nr ethanol toethene or 41) Why is the freezing point of a solution lower than that ofthe pure solvent? 19. Write the Nernst equation for the cell 2n(s) | Zn2*(1M)||Cu2*(1M)ICu(s) and explain the terms involved 20. i) Why do transition elements form complex compounds? or 4i) Why do transition metals show variable oxidation states? 21. 1) Define coordination isomerism. Give an example. or “li) What is the difference between Sy! and Sy? mechanism? IIL Short answer type Questions: 22.2) Given below is the sketch of a plant for carrying out a process: Piston Pressye>s 4 1)_ Name the process occurring in the given plant |_| ii) To which container does the net flow of solvent take place? iil) Name one SPM which can be used inthis plant. iv) Give one practical use ofthe plant. SPM or b) Determine the amount of CaCl. (i=2.47) dissolved in 2.5 litres of water ‘such that its osmotic pressure is 0.75 atm at 27°C 23. af When a steady current of 2A was passed through two electrolytic cells A and B containin electrolytes ZnSO, and CuSO, connected in series, 2g of Cu were deposited at the cathode of cell B. How long did current flow? What was the mass of Zn was deposited at cathode of cell A? [Atomic mass of Cu =63.5 g/mol, Zn =65g/mol, 1F =96500C/mol] or b) write the chemistry of recharging the lead storage battery, highlighting all materials that are involved during recharging 24. a) Account for the following: [Link] (IV) is more stable than the Ti(It) or Ti(1It) fi, Incase of transistion elements, ions of the same charge in a given series show progressive decreases in radius with increasing atomic number iii, Zincis comparatively a soft metals, iron and chromium are typically hard or 1) Compare the chemistry of actinoids with that of lanthanoids with special reference to i) electronic configuration ii) oxidation states iii) atomic and ionic sizes iv) chemical reactivity[ ® 25, Answer any three of the following questions: / s¥Explain the type of hybridization in [Fe(CN)o|? on the basis of VBT (¢ Draw the geometrical isomers of [PtCl(en).]?" 10 i if) (NCL ]® is paramagnetic while [Ni(CO) is diamagnetic though both are tet ahedral, why iv} Name the typeof isomerism when ambidendate ligands are attached to central metal 1am Give one example of ambidendate ligand. 26. How will you bring about the following conversions” i) Propene to propyne ii) Benzene to biphenyl iii) toluene to Benzyl alcohol 27. a) What happens when. i) n-butyl alcohol is treated with alcoholic KOH ii) bromobenzene is treated with Mg inthe presence of dry ether iii) methyl chloride is treated with KCN or b) How do you convert the following. i) Prop-1-ene to 1-fluoropropane ii) Chlorobenzene to 2-chlorotoluene iii) Ethanol to propanenitrile 28. a) Write the equations of the following reactions: i) Friedal-crafts alkylation of anisole ii)Nitration of anisole iil) Bromination of anisole in ethanoic acid medium. pe = 26) siven atomic number of Fe =26] or by Write the preparation of Phenol from i) From aryl halide ii) From diazonium salt iit) From cumene. SECTION -D IV. CASED BASED QUESTIONS (2x4=8) 29. A student ina laboratory was tasked with synthesizing an organic compound from a series of reactions. Initially, they started witha primary alcohol (ethanol) and treated it with sodium fo produce an alkoxide, They then performed a nucleophilic substitution reaction using an alky! halide nd an ether was formed, The student was also asked to test the compound's reactivity with Bromine water and Sodium, After reacting with bromine water, a color change from brown to colorless was ‘and when the compound was treated with sodium, hydrogen gas was liberated. | observed, i) Whats the organic compound formed after the nucleophilic substitution reaction? ii) Why did the reaction with bromine water results in the disappearance of the brown color ii) Why did the student observe the evolution of hydrogen gas when the compound was treated with sodium? iv) What would happen ifthe same reaction were carried out with a phenol instead of an alcohol” 30. A group of students was asked to set up an experiment to study the electrolysis of water. They used two electrodes, connected toa 12 V battery, and immersed them in water containing a small amount of sulphuricacid as an electrolyte. Upon completing the circuit, the students observed gas bubbles forming at both the cathode and anode. After several minutes, they carefully collected the gases and identified that the gas formed at the cathode was hydrogen and the gas formed at the anode was, oxygen. i) Write the half-reactions occurring atthe cathode and anode during the electrolysis of water ii). Explain why the volume of hydrogen gas collected atthe cathode was double that of oxygen gas collected at the anode. een {) What isthe role of sulfuricacidin this electrolysis experiment? Ifthe students increased the voltage applied to the electrolytic cell, what would happen to the rat gas production at both electrodes? wv)SECTION: E V. Very short answer type questions: (3x5015) 31.a) A 4% solution (W/w) of sucrose (M=342g/mol) in water has a freezing point of 271.15%. Calculate the freezing point of 5% glucose (M=180g/mol) in water | Gi ng point of pure water | 273.15K) | 'b) A solution prepared from 1.25 g of oil of wintergreen (methyl salicylate) in 90.0g of benzene has « boiling point of 80.31°C. Determine the molar mass of this compound (Boiling point of pure benzene £80.10°C and Ks for benzene = 2.53°%C kg/mol} or ©)Benzene and toluene forms ideal solution over the entire range of composition. ‘The vapour pressure ‘of pure benzene and toluene at 300K are 50.71mm Hg and 32.06mm Hig respectively, Calculate the mole fraction of benzene in vapour phase if 80g of benzene is mixed with 100g of toluene. 4) 195g of CHzFCOOH is dissolved in 500g of water. The depression in the freezing point of water observed is 1.0°C. Calculate the Van't Hoff factor and dissociation constant of fluoroacetic acid / 32. a) Conductivity of 2x10 M methanoic acid is 8 x 10-5 Scm-*, Calculate its molar conductivity and degree of dissociation if 1°, for methanoic acid is 404 S cm? mol! 'b) What can be inferred from the magnetic moment values of the following complex species? EXAMPLE a Mat j Ka[Mn(CN)e] 22 _ ——— ~ [Fe(H20)q2* = z = Ko[MnCly 5.9 a ae J Or ©) Draw the structure of optical isomerism of i) [Cr(C204)s]° ii) (Ptcla(en)2]** fii) [Cr(NHs)2Cla(en)]* 33. a) An aromatic compound A on treatment with CHCls/KOH gives two compounds B and C give the same product D when distilled with zinc dust. Oxidation of D gives E having molecular formula C:H«02 The sodium salt of E on heating with sodalime gives F which may also be obtained by distilling A with zine dust, Identify A to F. or b) Amongall the isomers of molecular formula CaHsBr identify, 4) The one isomer which is optically active ii) The one isomer which is highly reactive towards Sy? iii) Two isomer which give the same product on dehydrohalogenation with alcoholic KOH Draw the structure for the following compounds iv) 2-chlorocyclopent-1-ene-1-carboxylic acid v) 1-bromo-2,2-dimethylpropaneTeton _Exontmerions-2 Nie: V Abana SN Ean ON peer Ghamve: xi- Binee Guertsrar [Answer kel IAbuesecrs CHemssrar eee dha to_highe hypeation 4 TeBoarsira ANAS (a) gill AB) | Loo cutis) 5811304 4] 5) | Bilane 1 o) Poa 116) Jot propane 81) | Resonance. cftabilizakion 6 phanoxide ion 131 0)| Boh Aon Row Gret ond Ris te Cot Ep of A il) Bot Aart A. ova Conest ond Ris the Get Bp >i WLC) | BOR A is Correct but Ris Dneorve ct 1 0)! Bott A ad Rate Gmetad Rin te a a 10 : Daa ss moe -oridic. ffan phanct effanol. dua | Gescranco. _gStobilization fe phonaxde ion fon. @r) 2tPanol => CHs cryoHt + Lass Gf) wan molauula > CHa ctisoH's Deperotonation -+cH3 cts 6fli) Lototikiy Cm) ‘a ince) x th. nuuebeos es weet a pon logan ia) & Pea TToRNULA ! Loatty co) « Hass. os ehent in hg rae Cor.) i) tha sae Point & a dulion x Sesccos Rat “of, Ra pum @fohent due to fa Priore Clute paticlon This phan oman on wn aa statin — poled deprawion . & = — N—& no-%- mela oh en Can] > Contarbalion ef Linc icon Leo] > Lelor Concortrration Capper ion —Oel’) Trareition clamarh form _Complx Compeurds use 1) Spat opi 4 high effective nuclaan ‘i) Petotante of Vacant _d- Gxbitol iii) Abeioble Ox- Brat » 2 (or) it) Transition rrelals how -Ueniable Oxidation Grown of to Ay Cfrrail erasay btn thin (n-Dd 2 ma Onbitol os « ef 10: Unstone 2%. Ein) Cerda isomthn tl apa of who fe figanh axa btn £4: Ceotwisde Ile cond sl andsib ae ae ea = 8-4ag cL ew Hecord ean 2» es al ty Ayu |r] YD follows firut Oreort vine [=> Rata ot C riky? gap 52> grt? ae il in] Ziasaliration ef a pe ae Teto73-158 = oe oi — Holst mass of Catia = s4o-08 +(x 35-45) =110.98 g/mol! eee Ces Qh 9-6 = 0-0 308mol _iQT __ 410-0861 ¥ 800-15. TOs gf Cotls = nxmolext mass 2 .0:0308X 10-98 _ | Zn2t 4 de7 —+ Zn Ae + Je” —» Fe_ 3 564 = Ox96500 6 G=it pebepecdpan cba SBS 00 seit ita psa ee 65:8q = odx26500¢ P= 9680 i 2) 65:3x9650 =) 3 -065g // axresoo Con) sting — chosen. elactitinl ergy 4d arr fer on cet Goures , ive, fate 0nebebiolutic tal. “ha Gyan O30 Opp to Rose Ocewsiy? using —dlincasee PbS, + Dio —» Pbos 4 Pb 4 OHsS0y SS ley) WH). a more Qftable dia 40 uh +4 Chang , vy Achlauiy a. Qables rable gps Corfiqurtalion il) coalill Aanants how a decunre in ‘ionie ius ua increasing boric numba, dua ‘40 Bro elachiocp folic ion bah And icin a ia ay ra nL Wil) Zine dx bet tn du) uneale metallic ee ere ard — choconiuun + “ bord to filed d cet posal + Ga) b1t) Pretronue Gongiqualion fantfanoida ae +R Af Qpubs hall { ii) el agi Bd2"! 692 Actinoids =i) fa Re 58 Subs hot eee iliac) byte odtst zat ti) Oxidotion Qstata antfoncids > faxinooiby Sbitit 0+ Ox. chtate Adinoids Bia 0. Ganlen Alaxialiy of Ox. dals 7) Atomic and ionic Jadius : Fontfanoids =\)Exhibst fantfancid Conkottion ii) Qroduod — doeroaxe. Aidinoids => i) Exhibit 2Aktinoid Conbaction ii) Gredst move pronounced —dacxcass iv) Chamiso) Geactwity > Fartfarids => Reactive lass tfan Adlinoids Actincide =» move Seackive Ran. fanifancids .ah) Fes [added al Aina CN” in ABlrong Ligord elackion fain up hybyidisation nd? 4p? eg ge 31 1 a> Pk HS i J ill [iviCiisl ca poumayralic duo 40 dpincd 2% tom te waok Lagord Co)” utile Chi Gog] ws . Hromgrdic bomaura fe. Sire fed Lisgud (C0) fpr fe d- elithors to pam up WM Alama of komt > Linkage 250marisn i T labile Giger a” Spor fot an atfach +0 _, ta Gonbol — matal ion ough too diff, done atom} Ex: Tiyrale Lgard — Cson~) ail il ae to Peputa + Zo Cg CH=CH BE cta= CH -crt MND Cac cu as Prepyre ii] Bemore 40 biphnf <6) Bi 599 8 aan + ONaBy ; iil oO Cla a Aa. koe oy * : Serayl Aleohe | ooTb)') Rou) in fub-4- ere fi) Result inp vasiom —bachide - 0 rig it) Result an “Corde f cor.) BA) cHs-cHachy ten Bride, cH3-cta ~cH| Ss SECTION? HI Ge Basen Guession —SSSa2S Cali) The Organic Compourd ormad aftr the yuuclecphili Boabatifution Geactn ee lis, i) Tha dicoppotanca 4, Glow, it indicat, the. Peasanto. Unsoluxalion (oloubh 6 triple bord ) an caxily Oidita, function! Group in ta offen ‘il) The exeluion 1 hydoiogn gan "whan ha Gimp. eas with Aedium frdicaty ta | Paonia of an acidic hy , mostly Broly ‘ dua fo pasenca of Abchol 1 o ‘ Alou acidit offen. WY) Risult in formalin of Eediure phanaide — Sil) Caiods 3 ceo 460" pra + OOH” she 2+ H20 por tHH? tde™ it) Tha blue jas di Pepotion! 16 no. o mols ee ote fata Ge, Collected pe, fa Cateds ax Gbublé tha Atlume 4, __| ©, gas __Colleckd at fe Catfede il) Chulfsie “acid Caso) acts os on elotholy te | Usiry ty —_powvides ions CH? £ So,?°) that “unGosa He dlochrie ardent, oh Re | SE a wie. ae Sh ges preduction at bot electrodes & (would — cincroase . SECTION -E Wes)@) Ubulily = 0. aotlsue = Bx jnnn =0-122 i Wooly Cin Kg) ~ W/iooo 342. us e Aly 2 O15. 18 - 11:1 = dk ee TT)ust su010 banzang = 0-1 mm H ae ae qe “ae: BR. 06 rom if Podial Aapou prasusa Of banzona ; Po= Xb x Pr® = O-Heb x D0-t1 =Oa-65 mm Ha Petia Nbpoun prasua Of Toluane ; Pe = Xox Pre = O-5iyx 52-06 = 16-48 mm Ha Hole foachion of Benire in Abpoun phase yi Pb oy Cube = 9-Saq 20:6 // Pose SH-bs4ib-ut Gl Lblecuke bight ef CHa FCooH = O44a+i94 52 =T1qlmo | ott, = des ogas = 0.506. Mo! kg"! Alp = i-kg om AY + 1x186X0-506 publ PFO as 5) mod) OB ielobl 1 86x 0-506 ae; i=il+a ('O6t= 1 +0 Cla Ftooti == cHsE coo + HI ee = Cig? cd = 0-506: (o0-061)* = 0506+ 000318 | =0-00188 U-ii) [ce (vie) cta Cen] * " en { Me a t en \ NH SS 1 CO ei Bde lS \ Z| nu, cl H ped Bade) OH oH ce Ga : Roirron - Terrain flere Pia oer ote (8) Zo dust le dust ZENaoH oy Oe Ee qi ion gai) au A Phono | a B > 0-Hydeoeybsrzaldahyde iE C > P-Huyduoxybarmaldahyde D> Benmlddryde £ — Banzoie arid s £ —> Benzone | Cor) ___b)i) CHa -cH» -CH-CH ay =\3-bsiomobutane ii) CHscla ctactia ey =} 4+ bsomobutane