Tuyen Tap Thi DH Hay

Nguyn Anh Tun Nm hc 2011-2012
1

TRNG THPT VIT YN S 2

TUYN TP
THI TH I HC MN HA

NM 2012

2

Li ni u:
Sau 12 nm hc tp, gi y ch cn mt k thi duy nht ang ch i cc em l k thi i hc. y s l k thi kh
khn nht trong sut 12 nm cc em ngi trn gh nh trng. K thi i hc chnh l mt bc ngot ln trong cuc
i ca mi hc sinh v th mi hc sinh cn phi chun b kin thc tht ton din v ni dung ca thi mang tnh
lin tc. C l trong cc mn, mn ha vn lun chim v tr quan trng v l vt cn ln trn bc ng tin ti
ging ng i hc.
V th ti ra cun sch TUYN TP CC THI TH I HC CAO NG .
Hy vng y s l ti liu b ch cho cc em hc tp tham d cc k thi trc nghim mn Ha hc.
Chc cc em hc tt v vt qua cc k thi sp ti vi kt qu tt nht!

3
CHIN THUT CHN NGU NHIN TRONG BI THI TRC NGHIM HA HC
Cc bn v cc em hc sinh thn mn, t trc ti nay, phng n chn ngu nhin thng c xem l
gii php cui cng trong bi thi trc nghim trc nhng cu hi hc ba, nhng bi ton kh gii quyt, . Vic
ging dy cho cc em v cc chin lc v chin thut chn ngu nhin cng b xem l mt phng php tiu cc,
phn s phm. Tuy nhin, nu nh ng trn quan im cng nh mc tiu ca k thi H l tuyn chn, phn loi
c nhng hc sinh c kin thc v t duy tt, th r rng mt hc sinh c c mt chin thut la chn ngu
nhin hp l v c hiu qu khng ch phn nh c s may mn m cn th hin s sng to, tr thng minh,
kh nng ng bin v t duy tt ca hc sinh . Bi vit ny ca ti xin c khi qut mt s kinh nghim trong
vic ra mt chin lc chn ngu nhin hp l v hiu qu. Hy vng bi vit s nhn c nhiu phn hi tch cc
v gip ch c nhiu cho cc bn hc sinh trong k thi sp ti, ng thi cng cung cp nhng gi nho nh cho
cc bn gio vin cng tc ra thi trc nghim trong thi gian ti c nhiu ci thin tch cc hn.
I.L do chn ngu nhin
1, Th nht l v mt thi gian.
Thi gian lm bi lun l mt cu hi khin cc bn hc sinh phi trn tr khi i mt vi bi thi trc nghim.
Thc t l khi bin son thi, chc chn hi ng ra thi cn nhc n vn thi gian, 90 cho 50 cu hi
khng phi l qu eo hp v nu nh thc s c kin thc, phng php v bn lnh t duy tt, cc em c th hon
thnh bi thi trong vng 20-30. Tuy nhin, cng cn mt thc t l phong cch dy v hc trng ph thng hin
nay vn cha hon ton theo hng phc v k thi trc nghim, k nng lm bi ca cc em vn cn chm v nng v
hnh thc, cc bi kim tra trn lp a phn vn l t lun khin cho thi gian gii mt bi ton ngn gn cng c th
mt n 5 10. Do , c rt nhiu bn khng th hon thnh ht bi thi trong khong thi gian cho php. Trong
nhng hon cnh , chn ngu nhin l gii php ti u.
2, Th hai l do s phn b kin thc ca hc sinh
Thc t qu trnh n thi H ca cc em cho thy, c th n tp v nm chc c tt c cc ni dung kin
thc c 3 mn thi l iu khng h d dng. Vic la chn s hc phn no, mn no v b phn no, mn no cng
l mt phn trong chin thut n thi m mi hc sinh cn cn nhc cho ph hp vi nng lc ca mnh.
Ly mt v d n gin: Cng vi mc tiu l tng im 3 mn l 24, nhng mt hc sinh c th t mc tiu
l 8-8-8, hc sinh khc l 8-10-6, .. nhng mc tiu kh thc hin nht bao gi cng l 10-10-4, t c
im 8 cho mi mn thi l iu d thc hin, nhng c im 10, th mn hc no cng kh. c bit l vi cc th
sinh c thi mn Ton, vic t c im 10 trong cu hi cui cng bao gi cng l iu khng d thc hin.
Do , thay v dnh 2 - 3 thng cui tru b vi bt ng thc (m cha chc c im 10), ta
c th chp nhn im 8, im 9 trong mn Ton dnh thi gian cho 2 mn cn li.
Chin thut phn b kin thc v vy c th to ra cc l hng kin thc cho hc sinh: c bn ch kp hc v
nm chc ha hu c, c bn ch nm vng ha v c, bn khc ch tp trung hc lp 11, 12 m b qua kin thc ca
lp 10, . i vi cc hc sinh ny, chn ngu nhin cho cc phn kin thc b qua l gii php duy nht.
3. Th ba, chn sai do ngu nhin vn cha b tr im

My ngy gn y, c mt s thng tin trn cc bo v vic c tr im hay khng i vi cc cu tr li sai,
tuy nhin, cho n gi vn cha c mt s thay i chnh thc no t pha B GD T, thm na, vi mt bng
trnh hc sinh v p lc t pha x hi (c im m
???) s lm cho quyt nh ny kh i vo thc t.

4. Th t, chn ngu nhin khng c ngha xc sut ng l 25%

Nhiu ngi cho rng, chn ngu nhin chng qua l chn ba v xc sut ng ca bin php ny ch l 25%,
tuy nhin, thc t lm bi cho thy, hu nh khng c hc sinh no l hon ton khng c cht kin thc no i
vi mn thi, khi thi mnh chn. Mc d kin thc y c th l cha em gii quyt vn nhng vn c
th gii hn c p n ng ca vn , xc sut chn ngu nhin thng thng i vi cc thi trc nghim ca
Vit Nam hin nay thng ln hn 30%.
II.Chin thut chn ngu nhin

1, ra chin thut phn b kin thc ngay t giai on n thi

Ngay t trong giai on n thi, mi hc sinh cn phi xc nh r rng nhng im mnh, im yu ca mnh
c k hoch n tp, bi dng li kin thc. i khi, vi qu thi gian eo hp, vic b sung y , hon thin tt
c cc kin thc cho c 3 mn thi l iu khng th thc hin c. Khi , cc em cn cn nhc la chn cho mnh
nhng ni dung kin thc quan trng nht, d tip thu nht v c kh nng nm vng c nht, hay ri vo thi
nht n
tp.

Nhng ni dung cn b st cng cn c c lt qua c mt cht nim trong nhn thc, phc v cho
vic chn ngu nhin sau ny.
4
2, c k thi v gch chn nhng chi tit, nhng s liu quan trng

Mt sai lm cht ngi m th sinh mc phi trong qu trnh lm bi thi l: Nn bt u lm bi t cu s 1, ln
lt lt nhanh, quyt nh lm nhng cu cm thy d v chc chn, ng thi nh du trong thi nhng cu
cha lm c. Ln lt thc hin n cu trc nghim cui cng trong . Sau , quay tr li "gii quyt"
nhng cu tm thi b qua. Lu , khi thc hin vng hai cng cn khn trng. Nn lm nhng cu tng i
d hn, b li nhng cu qu kh gii quyt trong lt th ba, nu cn thi gian
y vn l mt li khuyn m cc thy c gio cng nh cc phng tin truyn thng vn thng dng
rao ging cho cc em khi lm bi, nhng n ch ph hp vi thi t lun, cn trong trc nghim, n l mt sai lm
cht ngi.
Nu bn bm ng h ri th c tht to v nhanh bi v cc p n ca 1 cu hi trc nghim, bn s
thy, thi gian ta kp c xong v ghi nhn c nhng thng tin cn thit cho 1 cu hi trung bnh l 15 -
20s/cu. iu c ngha l c trn vn 50 cu trong
1 thi trc nghim, s phi mt chng 12 - 15 pht v cha cn phi suy ngh hay lm g, ch
6 8 ln c i c li l ht gi.

Thc t l trong qu trnh lm bi, s tp trung cao ca th sinh s khin cho cc em nhanh chng qun i
cu hi m mnh c trc , do , mi ln b qua l mt ln qun, mi ln c li l li thy cu hi mi v
vic c i c li nh th s nhanh chng t chy ht thi gian lm bi ca cc em.
khc phc iu , vic cc em cn thc hin ngay l phi c tht k v dt khot thi, nhanh chng ghi
nhn v gch chn li nhng thng tin quan trng nhp tm v ghi nh ngay vo trong u, va trnh c sai st
trong qu trnh gii (b st d kin), va gip cc em nhanh chng nh li bi ton khi c li ln sau.
ng thi, ngay sau khi c , cc em cng nn ghi li nhng phn tch, nhn nh ca mnh ngay bn cnh
cu hi, tin xem li nhng ln sau (nu nh cha gii c ngay lc ). Tt nht l gii hn ngay cc p n c
kh nng ng nu c th.
3, Phn tch 4 p n gii hn cu tr li ng

Mt trong nhng nguyn tc khi ra thi trc nghim l phi c c cc p n gy nhiu nhng p n
a ra c gy nhiu c khng v gy nhiu n u, gy nhiu nh th no l cu hi khng d tr li cho
ngi ra v hin nay c khng nhiu cc thi p ng c yu cu .
cc nc tin tin, vic x hi ha gio dc mc cao n ni cc k thi chun quc gia v quc t khng
phi do cc c quan gio dc nh nc ra , m do cc cng ty hot ng gio dc t chc m kt qu ca n c c
x hi tha nhn v s dng nh gi cht lng hc sinh (SAT, TOEFL, .). Thc t l ra c mt thi
trc nghim hay, vi nhiu phng n gy nhiu tt, c th s dng nh gi chnh xc trnh ca hc sinh i
hi s u t tm hiu v nhiu mt: tm sinh l, qun tnh t duy, thi quen suy ngh, nhng li sai thng gp
ca hc sinh. Trong khi , Vit Nam, phn ln thi i hc li do cc nh nghin cu c hc hm, hc v cao ra
ch khng phi l nhng thy c gio trc tip ng lp nhng ngi thng xuyn tip xc v hiu r thi
quen suy ngh ca hc sinh. Cc thi kim tra trn lp ca cc thy c gio th nhiu khi li khng m bo v mt
kin thc.
Th nn mi c chuyn hc sinh lp 10 hc Vn vn cn c hi nhng cu nh: C
Tm t qu g chui ra?
A. Qu na B. Qu cam C. Qu th D. Qu bi

C th ni l p n gy nhiu ca ta hin nay cha thc s tt, nhiu tc gi ra thi cn kh ty tin trong
vic a p n nhiu, hoc l p n nhiu khng la ni hc sinh, khng nh trng vo li sai ca hc sinh, thm
ch mt s thi cn th hin s thiu trch nhim ca ngi ra .
Mt hc sinh kin thc Ha hc khng tht tt nhng t duy logic tt vn hon ton c th gii hn p n
nng cao xc sut chn ngu nhin c p n ng.
Vic phn tch p n l cc k quan trng, v c mt s bi ton khng th gii c n cng m ch c th
chn c p n ng nht, hoc c nhng bi ton m hc sinh ch nhn ra c phng php gii sau khi c p
n.
4, La chn phng php v gii quyt vn

Sau khi c k , ghi nhn cc thng tin quan trng v gii hn p n th vic tip theo l gii quyt bi
ton. Thc t l mt bi ton c th c nhiu phng php gii khc nhau, vic lm sao chn c cch gii nhanh,
gn v tit kim thi gian nht i hi nhiu yu t v cn c mt qu trnh rn luyn tch cc th mi c th t
c. Trong thi trc nghim, mt phng php gii hay cha chc c ghi nhn, do , cch ca mnh l cch
lm nhanh nht, tt nht l cc em hy la chn cho mnh cch lm m cc em nm chc nht, hiu r nht v
ngh ra nhanh nht vo thi im .
5, Sot li thi, lm li nhng cu hi cha hon thnh

5

Nu thi gian lm bi gn ht hoc gii nhiu ln khng ra th cn bnh tnh xem xt cc p n, ch
cc thng tin, cc phn tch t nhng ln trc, gii hn li cc p n kh nghi ri nhanh chng chn ngu nhin.
Tuyt i khng b qua bt k cu hi no trong thi!

III. Mt s v d minh ha

1. a mt hn hp kh N
2
v H
2
c t l 1:3 vo thp tng hp, sau phn ng thy th
tch kh i ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh
sau phn ng.

A.20%, 60%, 20%
B.22,22%, 66,67%, 11,11%
C.30%, 60%, 10%
D.33,33%, 50%, 16,67%

gii nhanh bi ton ny, ta c th da vo 2 kt qu quan trng:

- Trong phn ng c hiu sut nh hn 100%, nu t l cc cht tham gia phn ng bng ng h s cn bng
trong phng trnh phn ng, th sau phn ngphn cht d cng c t l ng vi h s cn bng trong phn ng. C
th trng hp ny l 1:3. Do A v B c kh nng l p n ng.
- Trong phn ng tng hp amoniac, th tch kh gim sau phn ng ng bng th tch kh
NH
3
sinh ra, do , trong trng hp ny, %NH
3
= 10% hn hp u hay l 1/9 =11,11% hn hp sau. Do B l
p n ng
2. Cho cc phn ng:

Cc cht A, D, E v G c th l:

Nhn xt: Tt c cc p n cho u c cng kt qu vi D, E, G. Do ta ch cn quan tm n A. tm A,
ta xt ring phn ng A D + G. V D v G chc chn l K v Cl
2
nn A phi khng cha O A l KCl
p n B

1. Hp cht no sau y c tnh axit mnh nht?
A. CCl
3
-COOH
B.CH
3
COOH
C. CBr
3
COOH
D. CF
3
COOH
Nhn xt: Cho d khng c khi nim g v mnh yu ca acid y, nhng cn c vo bin thin tnh cht
trong dy Halogen, c th d on p n ng l B hoc D

2. Hn hp X gm 2 axit no: A
1
v A
2
. t chy hon ton 0,3mol X thu c 11,2 lt kh
CO
2
(ktc). trung ha 0,3 mol X cn 500ml dung dch NaOH 1M. Cng thc cu to ca 2 axit l:
A. CH
3
COOH v C
2
H
5
COOH B. HCOOH v C
2
H
5
COOH
C. HCOOH v HOOC-COOH
6

D. CH
3
COOH v HOOC-CH
2
-COOH
Nhn xt: s nguyn t C trung bnh = nCO2/n(acid) = 5/3 mt trong 2 acid phi l HCOOH p n c th l
B hoc C
3. t chy mt axit no a chc Y ta thu c 0,6 mol CO
2
v 0,5 mol nc. Bit mch
cacbon l mch thng. Cho bit cng thc cu to ca Y
A. HOOC-COOH

B. HOOC-CH
2
-COOH
C. HOOC-C(CH
2
)
2
-COOH D. HOOC-(CH
2
)
4
-COOH
Nhn xt: cn c vo cc p n c th thy acid cho l acid 2 chc, no, do CTPT
l CnH2n-2O4

n
acid
= n
CO2
n
H2O
= 0,1 mol; s nguyn t C = n
CO2
/n
acid

D ng
4. C 2 cht hu c X v Y u cha cc nguyn t C, H, O. 2,25 gam cht X tc dng va
vi 50 ml dung dch KOH 1M. t chy hon ton 3 gam cht Y c 4,4 gam CO
2
v 1,8 gam H
2
O.
Bit cht X tc dng vi Na
2
CO
3
gii phng CO
2
. Cng thc phn t ca cht X l:
A. CH
3
COOH B. HOOC-CH
2
-OOH C. (COOH)
2
D. Kt qu khc
Nhn xt: n
H2O
= n
CO2

acid/ester no, n chc

A hoc D ng
5. Cng thc n gin nht ca mt axit hu c X l (CHO)
n
. Khi t chy 1 mol X ta thu c
di 6 mol CO
2
cng thc cu to ca X l:
A. HOOC-CH=CH-COOH B. CH
2
=CH-COOH
C. CH
3
COOH
D. Kt qu khc

Nhn xt: X phi c 6 C nn p n l D

6. Cho s chuyn ha sau:

Cc cht A, E, F l

Nhn xt: t phn ng ca A vi HCl, suy ra A l Fe
3
O
4
p n D ng
7. Tm cc cht A, B, C, D, E trong s sau:

Cc cht A, B, C, D, E l

Nhn xt: phn ng u tin, A ch c th l Cl
2
p n C hoc D xt tip cht B
7

C ng.
8. Ha tan hon ton 9,6 gam kim loi R trong H
2
SO
4
c un nng nh thu c dung dch X v 3,36
lt kh SO
2
( ktc). Xc nh kim loi R.
A. Fe B. Ca C. Cu D. Na
Nhn xt: B v D l 2 kim loi tc dng c vi H
2
O t c kh nng ng p n
l A hoc C dng 9,6 chia ra s chn C ng
9. Mt hn hp X gm 2 kim loi A, B c t l khi lng l 1:1 . Trong 44,8 gam hn hp X,
hiu s v s mol ca A v B l 0,05 mol. Mt khc khi lng nguyn t ca A ln hn B l 8 gam. Kim loi A v B
c th l:
A. Na v K B. Mg v Ca C. Fe v Cu D. Kt qu khc

Nhn xt: khng gii bi ton cng thy Fe v Cu c KLNT hn km nhau 8 n v C hoc D ng, v A > B D
ng
10. Ha tan 7,2 gam mt hn hp gm 2 mui sunfat ca 2 kim loi ha tr (II) v (III) vo nc
c dung dch X (Gi thit khng c phn ng ph khc). Thm vo dung dch X mt lng BaCl
2
va kt ta
ion SO
4
2-
th thu c kt ta BaSO
4
v dung dch Y. Khi in phn hon ton dung dch Y cho 2,4 gam kim loi.
Bit s mol ca mui kim loi ha tr (II) gp i s mol ca mui kim loi ha tr (III), bit t l s khi lng nguyn
t ca kim loi ha tr (III) v (II) l 7/8. Xc nh tn hai loi:
A. Ba v Fe B. Ca v Fe C. Fe v Al
D. Cu v Fe
Nhn xt: khng gii bi ton cng thy Fe v Cu c t l khi lng 7/8 D ng
11. Khi cho 17,4 gam hp kim Y gm st, ng, nhm phn ng ht vi H
2
SO
4
long d ta
c
dung dch A; 6,4 gam cht rn; 9,856 lt kh B 27,3
0
C v 1 atm. Phn trm khi lng mi kim loi trong hp
kim Y l:
A. Al: 30%; Fe: 50% v Cu: 20% B. Al: 30%; Fe: 32% v Cu: 38%
C. Al: 31,03%; Fe: 32,18% v Cu: 36,79% D. Al: 25%; Fe: 50% v Cu: 25%
Nhn xt: phn trm khi lng ca kim loi trong hn hp thng l nn chn p n C. (hoc B)

12. Ha tan hon ton mt t oxit Fe
x
O
y
. bng dung dch H
2
SO
4
c nng ta thu c 2,24 lt
SO
2
(o ktc), phn dung dch em c cn th thu c 120 gam mui khanCng thc Fe
x
O
y
l:
A. FeO B. Fe
2
O
3

C. Fe
3
O
4
D. B hoc C ng

Nhn xt: c SO
2
sinh ra oxit st cho phi c tnh kh A hoc C
13. Cho s chuyn ha sau:

Cc cht A, B, C, D, E v F l:

Nhn xt: B v C rt ging nhau B ng th C nhiu kh nng cng phi ng v ngc li c 2 u sai A
8
hoc D
14. Mt hc sinh pht biu: Tt c cc hp cht Hirocacbon no (l cc Hirocacbon m
phn t ca n khng c cha lin kt i C=C, lin kt ba CC hay vng thm) th khng th cho c phn ng
cng. Pht biu ny:
a) Khng ng hn
b) ng hon ton
c) ng nhin, v hp cht no th khng th cho c phn ng cng
d) (b) v (c)
Nhn xt: Mt mnh c tnh khng nh tuyt i th thng khng ng

p n ng l a.

Nhn xt: RCOOC
2
H
5
c gc C
2
H
5
= 29 > Na = 23 khi lng cht rn sinh ra phi nh hn loi p
n D. (Nu chn ngu nhin 3 p n cn li khi lng ester ban u th xc sut l 1/3 > 1/4)

Nhn xt: v Al v Fe u cng b th ng ha trong acid H
2
SO
4
v HNO
3
c ngui nn nhiu kh nng C ng
th D cng ng c 2 u sai. Mun phn bit 3 acid ny nhiu kh nng phi da vo sn phm oxi ha ch
cn A ng

Nhn xt: Tch nc ra anken loi ete A, to ra 3 anken khng th l ru bc 1 khng th l B, khng th
c mch C i xng cao loi C.

Nhn xt: Mnh A v mnh D i ngha nhau 1 trong 2 p n phi ng
(xc sut 50 50)

Nhn xt: A v C cng c 1 anehit, 1 ankin v etilen nhiu kh nng A ng th C cng ng c 2 u sai.
Chn ngu nhin B v D (xc sut 50)

Nhn xt: t t l CO
2
v H
2
O ru cn tm phi c cng thc dng C
3
H
8
O
x
loi p nB

9
Nhn xt: t 4 p n X l este, 4,4 gam X tc dng vi NaOH to ra 4,8 gam mui ca acid hu c Y gc
ru trong X nh hn 23 D ng

Nhn xt: C 3 p n A, B, C u l Al tc dng vi oxit, ch c p n B l tc dng vi acid B ng.

Nhn xt: C A, B, C u l kim loi kim v kim th, c bit l A v B rt ging nhau (cng l kim loi kim)
rt nhiu kh nng D ng, cng c th C ng nhng xc sut t hn

Nhn xt: M phi l kim loi nhiu ha tr hay nhiu s oxi ha p n
D
Nhn xt: khi lng mui < khi lng este gc ru c khi lng nh hn 23 C ng
Cu 5: (C - 07) t chy hon ton mt ru (ancol) X thu c CO
2
v H
2
O c t l s mol tng ng l
3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO
2
thu c ( cng iu kin). Cng thc phn t ca X l:
A. C
3
H
8
O
2
. B. C
3
H
8
O
3
. C. C
3
H
4
O. D. C
3
H
8
O.
Phn tch: Nhn thy
2
2
O
CO
n
T 1,5
n
= = =>ancol no,n chc, mch h (C
n
H
2n+2
O ) => p n D. Suy lun nh vy rt nhanh
khng cn tnh ton, dnh thi gian gii quyt cc bi ton khc.
Cu 6:(H-09) Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt
cht tan c nng 0,04M v 0,224 lt kh H
2
( ktc). Kim loi M lA. Na. B. Ca. C. Ba. D. K.
Phn tch: Da vo p n ta thy KL l ha tr II hoc ha tr I ,ta ln lt xt hai trng hp:
Nu l KL ha tr II: MO + H
2
O => M(OH)
2 ;
M + H
2
O => M(OH)
2
+ H
2
0,01 0,01 mol 0,01 0,01 0,01mol
2,9 = 0.01(M+16) + M*0,01 =>M =137 =>Ba
Cu 7 : (H-10) Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol
Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to
ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l
A. HCOOH v CH
3
OH B. CH
3
COOH v CH
3
OH C. HCOOH v C
3
H
7
OH D. CH
3
COOH v C
2
H
5
OH
Phn tch: : Gi s mol: RCOOH a ; ROH a ; RCOOR b
Theo gi thit: n
RCOONa
= a + b = 0,2 mol. M
RCOONa
= 82 R = 15. (CH
3
). X l CH
3
COOH
Loi p n: A v C. (a + b) < n
ROH
= a + b < a + b 0,1 < n
ROH
< 0,2
40,25 < M
ancol
< 80,5. Loi p n B => p n D
IV. Mt s tng kt kinh nghim
1, Thnh phn phn trm v khi lng trong hn hp thng l s l
2, Thnh phn phn trm v th tch hoc s mol trong hn hp kh thng l s chn
3, Nu c 2 p n i ngha vi nhau th mt trong 2 p n s c nhiu kh nng l
p n ng
4, Nu c 2 hoc 3 p n tng i ging nhau v mt ha hc th thng l cc p n u sai, p n c kh nng ng cao
s l cc p n cn li
V. i li nhn nh
Qua y, ta cng c th thy c vai tr cc k quan trng ca chin thut chn ngu nhin, khi i thi trc nghim, tt
nht l u tin thc hin sng lc p n chn ngu nhin trc, sau mi dng kin thc, phng php bi bn gii
quyt vn . C rt nhiu bi ton m nu khng s dng p n cho pha di th khng th gii c, hoc c nhiu khi
phi c p n di ta mi tm c ng phng php. Ngoi ra, thc hin sng lc p n cng l cch rt tt ta kim tra
li kt qu gii bng cc phng php bi bn khc.
Hy vng bi vit trn l thc s hu ch i vi cc em.

10
S GIO DC V O TO BC GIANG
TRNG THPT VIT YN 2

KIM TRA CHT LNG N THI I HC-S 1
MN HA HC
Thi gian lm bi: 90 pht

M thi 134
Cho bit khi lng nguyn t (theo u) ca cc nguyn t:
H = 1; Li = 7; Be =9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40;
Cr=52; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; I=127; Ba = 137.

Cu 1: Khi cho hn hp Fe
3
O
4
v Cu vo dung dch H
2
SO
4
long d thu c cht rn X v dung dch Y. Dy no
di y gm cc cht u tc dng c vi dung dch Y ?
A. Br
2,
NaNO
3
, KMnO
4
. B. NaOH, Na
2
SO
4,
Cl
2
.
C. KI, NH
3
, Cu. D. BaCl
2
, HCl, Cl
2
.
Cu 2: Cho cc cht sau: CH
3
COOCH
2
CH
2
Cl, ClH
3
N-CH
2
COOH, C
6
H
5
Cl(thm), HCOOC
6
H
5
(thm),
C
6
H
5
COOCH
3
(thm), HO-C
6
H
4
-CH
2
OH(thm), CH
3
CCl
3
, CH
3
COOC(Cl
2
)-CH
3
, HCOOC
6
H
4
Cl (thm) C bao nhiu
cht khi tc dng vi NaOH c d, nhit v p sut cao to ra sn phm c cha 2 mui?
A. 5 B. 4 C. 6 D. 7
Cu 3: X c CTPT C
3
H
12
N
2
O
3
. X tc dng vi dung dch NaOH (un nng nh) hoc HCl u c kh thot ra. Ly
16,50 gam X tc dng hon ton vi 400ml dung dch NaOH 1M. Sau phn ng c cn dung dch ri nung nng cht
rn n khi lng khng i th c m gam. Xc nh m?
A. 22,75 B. 19,9 C. 20,35 D. 21,20
Cu 4: Cho cc cp cht sau:
(1). Kh Br
2
v kh O
2
. (5). Dung dch AgNO
3
v dung dch Fe(NO
3
)
2
.
(2). Kh H
2
S

v dung dch FeCl
3
. (6). Dung dch KMnO
4
v kh SO
2
.
(3). Kh H
2
S v dung dch Pb(NO
3
)
2
. (7). Hg v S.
(4). CuS v dung dch HCl. (8). Kh Cl
2
v dung dch NaOH.
S cp cht xy ra phn ng ha hc nhit thng l
A. 8. B. 6. C. 7. D. 5.
Cu 5: Oxi ha 2m gam ancol no, n chc, bc 1 bng oxi khng kh trong iu kin thch hp th thu c 3m gam
hn hp X gm anehit, axit v nc. Xc inh cng thc ca ancol trn.
A. CH
3
OH hoc C
2
H
5
OH B. C
2
H
5
OH
C. CH
3
OH D. C
2
H
5
OH hoc C
3
H
7
OH
Cu 6: Hn hp A gm axit aipic v mt axit n chc X (X khng c phn ng trng gng). Ly 3,26 gam A tc
dng va vi 50ml dung dch NaOH 1M. % v khi lng ca X trong A l?
A. 29,375% B. 55,215% C. 64,946% D. 34,867%
Cu 7: Cho dung dch hn hp FeCl
3
, AlCl
3
, CuCl
2
, FeCl
2
, MgCl
2
(nng mi cht khong 0,1M). Sc H
2
S n d
vo X th xut hin kt ta Y. S cht c trong Y l?
A. 4 B. 2 C. 5 D. 3
Cu 8: Cho Na vo dung dch cha 2 mui MgSO
4
v CuSO
4
thu c kh X, dung dch Y v hn hp kt ta Z.
Nung kt ta Z c cht rn R. Cho X i qua R nung nng n phn ng hon ton thu c cht rn P. Cho P vo
dung dch HCl d. Nhn xt no ng ?
A. P hon ton khng tan trong HCl B. P tan ht trong HCl
C. P tan mt phn nhng khng to kh D. P tan mt phn trong HCl to kh
Cu 9: C 5 mu kim loi: Ba, Mg, Fe, Ag, Al. Nu ch dng dung dch H
2
SO
4
long (khng dng thm bt c cht
no khc k c qu tm v nc nguyn cht) c th nhn bit c nhng kim loi no?
A. C 5 kim loi B. Ba, Ag, Fe C. Ba v Ag D. Ba, Ag v Al
Cu 10: X mch h c CTPT C
6
H
10
tc dng vi HBr cho 3 sn phm monobrom l ng phn cu to ca nhau. S
ng phn cu to tha mn X l:
A. 3 B. 4 C. 1 D. 2
Cu 11: So snh tnh baz ca cc cht sau: (1).Natri axetat; (2).Natri phelonat; (3).Natri etylat; (4).Natri hiroxit
A. (2) < (1) < (4) < (3) B. (1) < (3) < (2) < (4) C. (1) < (2) < (3) < (4) D. (1) < (2) < (4) < (3)
Cu 12: Tin hnh este ha hn hp axit axetic v etilenglycol (s mol bng nhau) th thu c hn hp X gm 5
cht (trong c 2 este E
1
v E
2
,
2 1
E E
M M <
). Lng axit v ancol phn ng ln lt l 70% v 50% so vi
ban u. Tnh % v khi lng ca E
1
trong hn hp X?
11
A. 51,656% B. 23,934% C. 28,519% D. 25,574%
Cu 13: Cho 0,2 mol NO
2
hp th hon ton vo mt dung dch cha 0,2 mol NaOH thu c dung dch X. Hi dung
dch X c nhng cht tan g?
A. NaNO
3
+ NaOH B. NaNO
3
+ NaNO
2
+ NaOH
C. NaNO
3
+ NaNO
2
D. NaNO
2
+ NaOH
Cu 14: X phng ho mt este no n chc mch h X bng 0,6 mol MOH (M l kim loi kim) thu c dung dch
Y. C cn Y v t cht rn thu c trong kh O
2
d, n phn ng hon ton to ra 2,24 lt CO
2
(ktc), a gam H
2
O
v 31,8 gam mui. Gi tr ca a khng th l?
A. 7,2 gam. B. 9 gam. C. 5,4 gam D. 10,8 gam.
Cu 15: Tin hnh nhit phn hexan (gi s ch xy ra phn ng cracking ankan) th thu c hn hp X. Trong X c
cha ti a bao nhiu cht c CTPT khc nhau?
A. 6 B. 9 C. 8 D. 7
Cu 16: Cho cn bng ha hc: a A + b B pC + q D. 100
0
C, s mol cht D l x mol; 200
o
C, s mol cht D l y
mol.
Bit x > y, (a + b) > (p + q), cc cht trong cn bng trn u th kh. Kt lun no sau y ng:
A. Phn ng thun thu nhit v tng p sut B. Phn ng thun ta nhit v gim p sut
C. Phn ng thun thu nhit v gim p sut. D. Phn ng thun ta nhit v tng p sut
Cu 17: Ly x gam P
2
O
5
cho tc dng vi 338 ml dung dch NaOH 2M. Sau phn ng c cn dung dch thu c 3x
gam cht rn. Xc nh x?
A. 11,36 gam B. 17,04 gam C. 12,78 gam D. 14,20 gam
Cu 18: Cho 2-metylpropan-1,2-diol tc dng vi CuO un nng th thu c cht c CTPT no sau y?
A. C
4
H
8
O
2
B. C
4
H
6
O
2
C. C
4
H
8
O
3
D. C
4
H
6
O
3

Cu 19: Hn hp X gm C
3
H
8
, C
2
H
4
(OH)
2
v mt s ancol no, n chc, mch h (trong C
3
H
8
v C
2
H
4
(OH)
2
c s
mol bng nhau). t chy hon ton 5,444 gam X ri hp th ton b sn phm chy vo dung dch Ba(OH)
2
d thy
khi lng bnh tng ln 16,58 gam v xut hin m gam kt ta. Xc nh m?
A. 42,158 gam B. 43,931 C. 47,477 gam D. 45,704 gam
Cu 20: C cc dy ng ng ca: anken; anhit no n chc; este ca ancol tylic vi axit no n chc. Cc dy ng
ng trn c c im g chung?
A. u lm mt mu dung dch nc Brm
B. t chy lun cho
2 2
:
CO O H
n n = 1:1 v u cha 1 lin kt t trong phn t
C. t chy lun cho
2 2
:
CO O H
n n = 1:1
D. u cha 1 lin kt t trong phn t
Cu 21: Ly 2,32 gam Fe
3
O
4
cho tc dng hon ton vi dung dch HI d thu c dung dch X. C cn X c cht
rn Y. Cho Y tc dng vi dng dch AgNO
3
d c m gam kt ta. Xc nh m?
Cu 22: Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng ha hc sau:
X + 2YCl
3
XCl
2
+ 2YCl
2
; Y + XCl
2
YCl
2
+ X.
Pht biu ng l:
A. Ion Y
2+
c tnh oxi ha mnh hn ion X
2+
B. Kim loi X kh c ion Y
2+

C. Ion Y
3+
c tnh oxi ha mnh hn ion X
+2
D. Kim loi X c tnh kh mnh hn kim loi Y
Cu 23: Cho 6,48 gam hn hp Al v Mg tc dng va vi dung dch cha 0,87 mol HNO
3
to ra sn phm kh X
duy nht. Lm bay hi dung dch sau phn ng thu c m gam mui khan, m c th l
A. 46,935 B. 51,430 C. 56,592 D. 47,355
Cu 24: Cho cc cht: ancol metylic, etylenglycol, glyxerin, axit oxalic.
Nu ly cc cht trn vi khi lng bng nhau ln lt tc dng vi Na d th cht no thu c nhiu H
2
nht.
A. ancol metylic B. etylenglycol C. glyxerin D. axit oxalic
Cu 25: Thc hin cc th nghim sau:
1. Sc Cl
2
vo dung dch Ca(OH)
2
.
2. Sc F
2
vo nc.
3. Sc NO
2
vo dung dch NaOH.
4. Sc CO
2
vo nc javen.
5. Cho dung dch Na
2
S vo dung dch AlCl
3
.
6. Cho NaBr
(tinh th)
vo H
2
SO
4 (c nng)
.
S th nghim c phn ng oxi ho - kh xy ra l:
12
A. 5 B. 4. C. 6 D. 2
Cu 26: Cho 0,3 mol hn hp kh X gm HCHO v C
2
H
2
tc dng hon ton vi lng d dung dch AgNO
3
trong
NH
3
to ra 91,2 gam kt ta. Nu cho ton b lng X trn vo bnh ng dung dch brom trong CCl
4
th khi lng
brom phn ng ti a l
A. 128. B. 64 gam. C. 80 gam. D. 96 gam.
Cu 27: Trong cc cp kim loi sau: (1) Mg, Fe; (2) Fe, Cu; (3) Fe, Ag; cp kim loi khi tc dng vi dung dch
HNO
3
c th to ra dung dch cha ti a 3 mui (khng k trng hp to NH
4
NO
3
) l.
A. (1) v (2) v (3). B. (2) v (3). C. (1) v (2). D. (1).
Cu 28: Dng phn ng no sau y iu ch Fe(NO
3
)
2
?
A. Fe + HNO
3(d)
B. Fe(OH)
2
+ HNO
3
C. FeCl
2
+ HNO
3
D. Ba(NO
3
)
2
+ FeSO
4

Cu 29: in phn dung dch X (cha y mol Cu(NO
3
)
2
v 2y mol NaCl) bng in cc tr n khi khi lng catot
khng i th ngng v thu c dung dch Z. B qua tan ca kh trong nc. o pH ca X (pH
X
) v pH ca Z (pH
Z
),
nhn thy
A. pH
X
< pH
Z
= 7 B. pH
X
< 7 < pH
Z
C. pH
X
= pH
Z
= 7 D. pH
Z
< pH
X
= 7
Cu 30: Ly m gam kim loi M hoc
2
m
gam mui sunfua ca n tc dng vi dung dch HNO
3
c nng d th u
thot ra kh NO
2
(duy nht) vi th tch bng nhau trong cng iu kin. Xc nh cng thc ca mui sunfua trn?
A. FeS B. MgS C. Cu
2
S D. CuS
Cu 31: Cho 150 ml dung dch Ba(OH)
2
1M vo 250 ml dung dch Al
2
(SO
4
)
3
x(M) thu c 42,75 gam kt ta. Thm
tip 200 ml dung dch Ba(OH)
2
1M vo hn hp phn ng th lng kt ta thu c l 94,2375 gam. Gi tr ca x l
A. 0,3 B. 0,45 C. 0,25 D. 0,15
Cu 32: Este X to thnh t aminoaxit v ancol etylic. t chy hon ton 10,3 gam X thu c 17,6 gam kh CO
2
,
8,1 gam H
2
O v 1,12 lit N
2
(ktc). Aminoaxit to thnh X l
A. CH
3
-CH
2
-CH(NH
2
)-COOH B. H
2
N-CH
2
-COOC
2
H
5

C. H
2
N-CH(CH
3
)-COOC
2
H
5
D. H
2
N-CH
2
-COOH
Cu 33: Ly 22,35 gam hn hp mui clorua ca kim loi kim A v kim loi kim th B (A, B thuc 2 chu k lin
tip nhau trong bng HTTH) tc dng vi dung dch AgNO
3
d thu c 43,05 gam kt ta. A, B ln lt l?
A. K v Sr B. Rb v Ca C. Na v Ca D. K v Mg
Cu 34: Ly 4,6 gam Na cho tc dng va vi C
2
H
5
OH thu c cht rn X. Cho X vo 100 gam dung dch
NaHSO
4
18% thu c dung dch Y. C cn Y c m gam cht rn khan, xc nh m?
Cu 35: Tin hnh ln men gim 100ml dung dch C
2
H
5
OH 46
0
vi hiu sut 50% th thu c dung dch X. un
nng X (gii s ch xy ra phn ng este ha) n trng thi cn bng thu c 17,6 gam este. Tnh hng s cn bng
ca phn ng este ha? (bit ml g d
O H
/ 1
2
= , ml g d
OH H C
/ 8 , 0
5 2
= )
A. 17 B. 16 C. 18 D. 1
Cu 36: Hn hp X gm 2 este thm l ng phn ca nhau c cng thc C
8
H
8
O
2
. Ly 34 gam X th tc dng c
ti a vi 0,3 mol NaOH. S cp cht c th tha mn X l?
A. 8 B. 4 C. 2 D. 6
Cu 37: Cho cc dung dch sau (nng khong 1M): NaAlO
2
, C
6
H
5
NH
3
Cl, C
2
H
5
NH
2
, FeCl
3
, C
6
H
5
ONa, CH
3
COOH.
Ln lt trn ln tng cp dung dch vi nhau, s trng hp c phn ng xy ra l
A. 9 B. 8 C. 10 D. 7
Cu 38: Khuy k dung dch cha 13,6g AgNO
3
vi m gam bt Cu ri thm tip 100ml dung dch H
2
SO
4
long d vo.
un nng cho ti khi phn ng xy ra hon ton th thu c 9,28g kim loi v V lt kh NO (duy nht). Tnh m v V (th
tch kh o ktc):
A. 6,4 gam v 2,24 lt B. 10,88 gam 2,688 lt C. 3,2 gam 0,3584 lt D. 10,88 gam 1,792 lt
Cu 39: Cho 2 ng nghim ng cc dung dch sau: FeCl
3
, hn hp FeCl
2
v FeCl
3
. Dng thuc th no trong s cc
thuc th sau nhn bit 2 dung dch trn?
A. KI/H tinh bt B. Dung dch Br
2
hoc KMnO
4
/H
2
SO
4
(long)
C. Dung dch Br
2
D. KMnO
4
/H
2
SO
4
(long)
Cu 40: S ng phn este mch h, c cng thc phn t C
5
H
8
O
2
c ng phn hnh hc l:
A. 4 B. 2 C. 5 D. 3
Cu 41: Ly 10,44 gam hn hp Fe v Fe
x
O
y
tc dng vi dung dch H
2
SO
4
c nng d thu c 0,504 lt SO
2

(ktc). Xc nh cng thc ca Fe
x
O
y
A. FeO hoc Fe
3
O
4
B. Fe
2
O
3
C. Fe
3
O
4
hoc Fe
2
O
3
D. FeO
13
Cu 42: Cho cc cht: Metyl fomiat, stiren, anilin, vinyl axetat, poli vinyl clorua, axit acrylic. S cht c phn ng
cng vi dung dch Br
2
l?
A. 2 B. 5 C. 3 D. 4
Cu 43: Cho mt thanh Al vo dung dch cha 0,03 mol HCl v 0,03 mol RCl
2
. Phn ng hon ton thy khi lng
thanh Al tng 0,96 gam.Vy R l
A. Ni (59) B. Mn (55) C. Zn (65) D. Cu (64)
Cu 44: Cho dy gm cc cht Mg, Ag, O
3
, Cl
2
, Mg(HCO
3
)
2
, NaCl, C
2
H
5
-OH, CH
3
ONa s cht tc dng c vi
axit propionic trong iu kin thch hp l:
A. 5 B. 6 C. 7 D. 4
Cu 45: Mt lng FeCl
2
tc dng c ti a vi 9,48 gam KMnO
4
trong H
2
SO
4
long d th thu c dung dch X.
C cn X c m gam mui khan. Xc nh m?
Cu 46: C cc th nghim:
(1) Nh dung dch NaOH d vo dung dch hn hp KHCO
3
v CaCl
2
.
(2) un nng nc cng ton phn.
(3) un nng nc cng vnh cu.
(4) Nh dung dch Ba(OH)
2
nd vo dung dch KAl(SO
4
)
2
.12H
2
O.
(5) Cho dung dch Na
3
PO
4
vo nc cng vnh cu.
C ti a my th nghim thu c kt ta?
A. 3 B. 4 C. 5 D. 2
Cu 47: Cho phng trnh phn ng: Mg + HNO
3
Mg(NO
3
)
2
+ NO + N
2
O + H
2
O. Nu t khi ca hn hp NO v
N
2
O i vi H
2
l 19,2. T l s phn t b kh v b oxi ha l
A. 8: 15 B. 11: 28 C. 38: 15 D. 6: 11
Cu 48: Ho tan ht hn hp rn gm CaC
2
, Al
4
C
3
v Ca vo H
2
O thu c 3,36 lt hn hp kh X c t khi so vi
hiro bng 10. Dn X qua Ni un nng thu c hn hp kh Y. Tip tc cho Y qua bnh ng nc brom d th c
0,784 lt hn hp kh Z (t khi hi so vi He bng 6,5). Cc kh o iu kin tiu chun. Khi lng bnh brom tng
l
A. 2,09 gam B. 3,45gam C. 3,91 gam D. 1,35 gam
Cu 49: Cho khng kh (cha 20% O
2
v 80% N
2
v

th tch) vo bnh kn ri phng tia la in i qua (Gi s ch c
phn ng to O
3
) thy th tch khng kh gim 2%. Xc nh hiu sut phn ng iu ch O
3

A. 20% B. 10% C. 30% D. 2%
Cu 50: Cho hn hp cha ton b cc anken th kh iu kin thng tc dng vi H
2
O ( xt: H
+
) to ra hn hp
cha ti a bao nhiu ancol:
A. 5. B. 8. C. 6. D. 7.

----------- HT ----------

14
Trng THPT VIT YN 2 THI TH I HC LN 2 NM HC 2011-2012
MN HA HC
Thi gian: 90 pht
M : 125
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
O =16, H= 1; C = 12, Fe =56; Cu=64; Al=27; Mg=24; N =14; Cl =35,5; S =32; P=31; Ag =108; Zn =65;
K =39; Na=23; Ba =137; Sr =87,5, Ca = 40;Si = 28; Be = 9; Cr=52; Br =80; I = 127)

Cu 1 : X phng ha hon ton 1 este X a chc vi 100ml dung dch KOH 1M sau phn ng c cn dung dch thu
c 8,32 gam cht rn v ancol n chc Y. Nu t chy hon ton Y thu c 3,584 lit CO
2
(ktc) v 4,32
gam H
2
O cng thc cu to ca X l
A. C
2
H
5
OOC-C
2
H
4
-COOC
2
H
5
B. CH
3
COOCH
2
-CH
2
-OOCCH
3

C. C
2
H
5
OOC-CH
2
-COOC
2
H
5
D. CH
3
OOC-C
2
H
4
-COOCH
3

Cu 2 : Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Cu; Fe v Zn; Fe v Sn; Fe v Ni, Fe v
Mg. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hu trc l
A. 5 B. 3 C. 2 D. 4
Cu 3 : Mt loi nc cng cha cc ion: Ca
2+
, Mg
2+
, HCO
3
-
, Cl
-
, SO
4
2-
. Dy gm cc cht lm gim cng ca
nc l
A. Ca(OH)
2
, HCl, Na
2
CO
3
, K
2
CO
3
B. Ba(OH)
2
, Na
2
CO
3
, Na
3
PO
4
, NaOH
C. NaOH, K
2
CO
3
, Na
3
PO
4
, HCl D. HCl, Ca(OH)
2
, Na
2
CO
3
, Na
3
PO
4

Cu 4 : Hn hp X gm 1 ancol A v 2 sn phm hp nc ca propen. C t khi so vi hiro l 23. Cho m gam X
i qua ng ng CuO nung nng thy khi lng cht rn gim 3,2 gam v hn hp cht hu c Y. Cho ton
b Y tc dng vi AgNO
3
/ NH
3
d thu c gam 56,16gam Ag. Phn trm khi lng ca propan -1-ol l
A. 48,9% B. 16,3% C. 65,21% D. 39,13%
Cu 5 : Mt hn hp gm etylenglicol v ancol etylic phn ng vi Na d thu c 5,6 lt kh (ktc). Mt khc nu
cng cho hn hp trn tc dng vi Cu(OH)
2
th ha tan c 4,9 gam Cu(OH)
2
. Phn trm khi lng ca
etylenglicol v ancol etylic ln lt l
A. 69% v 31% B. 85,58% v 14,42 % C. 31% v 69% D. 14,42 % v 85,58%
Cu 6 : C 4 dung dch trong sut, mi dung dch ch cha mt loi cation v mt loi anion. Cc loi ion trong c 4
dung dch gm Ba
2+
, Mg
2+
, Pb
2+
, Na
+
, SO
4

2-
, Cl
-
, CO
3
2-
, NO
3
-
. l 4 dung dch g?
A. BaCl
2
, MgSO
4
, Na
2
CO
3
, Pb(NO
3
)
2
. B. BaCO
3
,MgSO
4
,NaCl,Pb(NO
3
)
2
.
C. BaCl
2
, PbSO
4
, MgCl
2
, Na
2
CO
3
D. Mg(NO
3
)
2
, BaCl
2
, Na
2
CO
3
, PbSO
4

Cu 7 : Dn kh H
2
qua cht rn X nung nng thy khi lng ca X gim. Nu Cho X phn ng vi dung dch HCl
thu c dung dch A. Cho t t dung dch NaOH thy c kt ta dng keo, nu tip tc cho dung dch NaOH
th thy kt ta tan dn. X l
A. ZnO B. Al
2
O
3
C. CuO D. Fe
2
O
3

Cu 8 : Pht biu no sau y ng
1). Photpho trng c cu trc tinh th phn t
2). Nung hn hp qung photphorit, ct trng v than iu ch photpho trong cng nghip
3) Axit H
3
PO
4
c tnh oxi ha mnh ging HNO
3

4) Amophot l hn hp cc mui NH4H2PO4 v (NH4)2HPO4
5) Hm lng dinh dng ca phn ln c nh gi qua hm lng P2O5 trong ln
6) Bn ln cho cy trng thng lm cho t b chua
7) Photpho ch th hin tnh kh
A. (1), (2), (4), (5) B. (1), (3), (4), (6)
C. (3), (4), (5), (7) D. (1), (3), (5), (7)
Cu 9 : Cho cc cht sau: hexan, Xiclo propan, benzen, stiren, toluen, axetilen, butaien, vinyl axetilen, etilen s cht
lm mt mu nc brom l
A. 5 B. 4 C. 6 D. 7
Cu 10 : t chy hon ton x mol axit hu c Y c 4x mol CO
2
. Mt khc, trung ho x mol Y cn va 2x
mol NaOH. Cng thc cu to thu gn ca Y l
A. C
2
H
5
COOH. B. HOOC- COOH. C. CH
3
COOH. D. HOOC -CH
2
-CH
2
COOH.
Cu 11 : Cho 9,2 gam hn hp kim loi Mg v Fe vo 210 ml dung dch CuSO
4
1M. Sau khi phn ng xy ra hon
ton thu c dung dch X v 15,68 gam kim loi. Phn trm khi lng ca Fe trong hn hp ban u l
A. 60,87% B. 24,35% C. 36,52% D. 70,43%
Cu 12 : Dy gm cc nguyn t c cu trc lp phng tm khi l
A. Li, Na, K, Ca B. Li, Na, Ba, K C. Na, Ba, Mg, Be D. Na, K, Ca, Ba
Cu 13 : Pht biu no sau y sai
Trong chu k theo chiu tng ca in tch ht nhn
A. Bn knh nguyn t kim loi gim dn, bn knh nguyn t phi kim tng dn
15
B. Tnh kim loi gim dn, tnh phi kim tng dn
C. Bn knh nguyn t kim loi gim dn, bn knh nguyn t phi kim gim dn
D. Nng lng ion ha th nht ca cc nguyn t nhm A tng dn
Cu 14 : Trong s cc polime cho di y, polime no khng phi l polime tng hp?
A. Poli(vinylclorua) (PVC) B. T capron
C. Polistiren (PS) D. T xenluloz triaxetat
Cu 15 : Nhn xt no khng ng
A. Amino axit l cht rn v hi ngt
B. Protein c phn ng mu biure vi Cu(OH)
2

C. Protein n gin l nhng protein c to thnh t cc gc -amino axit
D. Lin kt ca nhm CO vi nhm NH gia cc amino axit l lin kt peptit
Cu 16 : Cho bit th t t tri sang phi ca cc cp oxi ha - kh trong dy in ha (dy th in cc chun) nh
sau: Al
3+
/Al, Zn
2+
/Zn, Fe
2+
/Fe, Cu
2+
/Cu, Fe
3+
/Fe
2+
, Ag
+
/Ag.
Cc cp v cc ion u phn ng c vi ion Fe
2+
trong dung dch l
A. Al, Zn, Ag
+
B. Al
3+
, Zn
2+
, Ag
+
C. Al, Zn, Fe
3+
D. Al, Zn, Cu
Cu 17 : Chia m gam mt anehit X thnh 2 phn bng nhau
-Phn 1: t chy hon ton thu cc 3,36 lit CO
2
(ktc) v 2,7 gam H
2
O
-Phn 2: Cho Tc dng vi AgNO
3
/NH
3
d thu c Ag kim loi vi t l mol n
X
: n
Ag
= 1:4. Anehit X l
A. Ane hit khng no (1 lin kt ), n chc B. Anehit no n chc
C. Anehit fomic D. Anehit no 2 chc
Cu 18 : Ha tan hn hp cha 12,8 gam CuSO
4
v 2,235 gam KCl vo nc c dung dch X. Tin hnh in phn
dung dch X vi cng dng in 5A trong thi gian 16 pht 5 giy. Dung dch sau in phn cha nhng
cht no
A. CuSO
4
, H
2
SO
4
B. CuSO
4
, H
2
SO
4
, K
2
SO
4

C. CuSO
4
, H
2
SO
4
, KCl D. KCl, KOH, K
2
SO
4

Cu 19 : Mt cht hu c X mch h, khng phn nhnh, ch cha C, H, O. Cht X cha cc nhm chc c nguyn t
hiro linh ng v khi X tc dng vi Na d thu c s mol hiro bng s mol ca X. Cht X tc dng vi
CuO nung nng to ra anehit. Ly 13,5 gam X phn ng va vi Na
2
CO
3
thu c 16,8 gam mui v c
kh CO
2
bay ra. Cng thc cu to thu gn ca X l
A. HO-CH
2
-CH(OH)-CHO. B. HOOC-CH
2
-CH
2
-OH.
C. CH
3
-C(OH)
2
-CHO. D. HOOC-CH(OH)
-
CH
3
.
Cu 20 : Dy gm cc kim loi u tc dng vi nc nhit thng to ra cc mi trng kim l:
A. Fe, K, Ca B. Li, K, Ba C. Be, Na, Ca D. Zn, Na, Ba
Cu 21 : Cho 7,2 gam mt este n chc mch h tc dng ht vi dung dch NaOH un nng, thu c dung dch X.
Cho X tc dng vi lng d dung dch AgNO
3
trong NH
3
thu c 43,2 gam Ag. Tn gi ca este l:
A. anlyl fomat. B. vinyl axetat. C. etyl fomat. D. vinyl fomat
Cu 22 : Nung 31,8 gam hn hp X gm 2 mui cacbonat ha tr II (ha tr khng di) n khi lng khng i, cn
li 16,4 gam cht rn. Hp th hon ton b khi lng kh CO
2
sinh ra vo dung dch Y cha 0,1 mol
Ba(OH)
2
v 0,2 mol NaOH. Khi lng kt ta thu c sau phn ng l.
Cu 23 : Cho dy cc cht: HCl, SO
2
, F
2
, Fe
2+
, HCO
3
-
, Cl
2
, Al. S phn t v ion va th hin tnh kh va th hin
tnh oxi ha l
A. 3 B. 6 C. 5 D. 4
Cu 24 : Mt hn hp X gm hai cht hu c. Cho m gam hn hp X phn ng va vi 100 ml dung dch KOH
5M, sau phn ng thu c hn hp hai mui ca hai axit no n chc v mt ancol no n chc. Cho ton
b lng ancol ny tc dng vi Natri d, c 3,36 lt H
2
(ktc). Hai hp cht hu c trong X gm
A. 1 axit v 1 ancol. B. 2 axit C. 2 este. D. 1 axit v 1 este.
Cu 25 : Hn hp A gm CuO v MO theo t l mol tng ng l 1: 2 (M l kim loi ha tr khng i). Cho 1 lung
H
2
d i qua 2,4 gam A nung nng thu c hn hp cht rn B. ho tan ht B cn 40 ml dung dch
HNO
3
2,5M v thu c V lt kh NO duy nht (ktc). Hiu sut cc phn ng t 100%.
A. Ca v V = 0,56 lt B. Mg v V = 0,224 lit
C. Zn v V = 0,448 lit D. Pb v V = 0,336 lit
Cu 26 : Cho m gam hn hp X gm Fe v FeS tc dng ht vi dung dch HCl d thu c V lt kh (ktc). Mt khc
nu cho m gam hn hp X vo dung dch HNO
3
d, thu c dung dch Y ch cha mt mui nitrat duy nht
v 2V lt hn hp kh (ktc) gm NO v SO
2
. Phn trm v khi lng ca Fe trong X l
A. 52,1% B. 45,9% C. 54,1% D. 43,9%
Cu 27 : iu ch 25,8 kg metyl acrylat vi hiu sut 60% cn x kg axit acrylic v y kg metanol. Gi tr ca x v y l
A. x = 36,98, y = 13,76 B. x = 12,96, y = 5,76
C. x= 21,6, y = 9,6 D. x = 36, y = 16
Cu 28 : C V lit kh A gm H
2
v 2 anken l ng ng lin tip nhau, trong H
2
chim 60% v th tch. Dn hn
16
hp A qua bt Ni nung nng c hn hp kh B. t chy hon ton B thu c 19,8 gam CO
2
v 13,5 gam
H
2
O. Cng thc 2 anken l
A. C
5
H
10
v C
6
H
12
B. C
3
H
6
v C
4
H
8
C. C
2
H
4
vc C
3
H
6
D. C
4
H
8
v C
5
H
10

Cu 29 : t chy hon ton 15,84 gam hn hp 2 este CH
3
COOC
2
H
5
v C
2
H
5
COOCH
3
cho ton bc sn phm chy
qua dung dch nc vi trong thy khi lng bnh tng m gam. Gi tr ca m
Cu 30 : Pht biu khng ng l:
A. Dung dch Fructoz ho tan c Cu(OH)
2

B. Sn phm thu phn xenluloz (xc tc, H
+
, nhit ) c th tham gia phn ng trng gng
C. Dung dch Mantoz tc dng vi Cu(OH)
2
khi ung nng cho kt ta Cu
2
O
D. Thu phn (xc tc, H
+
, nhit ) Saccaroz cng nh Mantoz u cho cng mt monosaccarit
Cu 31 : in phn 100ml dung dch gm Fe
2
(SO
4
)
3
1,25M, CuCl
2
1,5M v NaCl 1,5M trong thi gian 83 pht 38
giy vi cng dng in 12,5 A thu c m gam kim loi catot v V lt kh (ktc) anot. Gi tr ca m
v V l
A. m = 14 gam v V = 6,16 lit B. m = 12,4 gam v V = 6,16 lit
C. m = 12,4gam v V = 5,04lit D. m = 9,6 gam v V = 5,04 lit
Cu 32 : C 500 ml dung dch X cha Na
+
, NH
4
+
, CO
3
2-
v SO
4
2-
. Ly 100 ml dung dch X cho tc dng vi lng d
dung dch HCl thu c 2,24 lt kh (ktc). Ly 100 ml dung dch X cho tc dng vi lng d dung dch
BaCl
2
thy c 43 gam kt ta. Ly 100 ml dung dch X cho tc dng vi lng d dung dch NaOH thu c
4,48 lt kh NH
3
(ktc). Tng khi lng mui c trong 500 ml dung dch X l
A. 23,8 gam B. 119 gam. C. 43,1 gam D. 86,2 gam
Cu 33 : X l 1 tetrapeptit cu to t aminoaxit A, Trong phn t ca A c 1 nhm NH
2
v 1 nhm -COOH, no mch
h. Trong A nit chim 15,73% v khi lng. Thy phn m g gam X trong mi trng axit th thu c
27,72 gam tripeptit, 32 g ipeptit v 13,35g A. Gi tr ca m
Cu 34 : Cho cc dn xut halogen (1) CH
3
CH
2
Cl. (2) CH
3
CH=CHCl. (3) C
6
H
5
CH
2
Cl. (4) C
6
H
5
Cl. Thu phn nhng
cht no s thu c ancol ?
A. (1), (2), (3). B. (1), (2), (4). C. (1), (3). D. (1), (2), (3), (4).
Cu 35 : Hp cht kh vi hiro ca nguyn t R c dng RH
3
trong R Chim 82,353% v khi lng. Trong hp
cht oxit cao nht ca R phn trm khi lng ca R l
A. 25,92% B. 30,435% C. 46,66% D. 43,66%
Cu 36 : Cho 0,1 mol aminoaxit X tc dng va vi 200ml dung dch HCl 1M thu c dung dch A. Cho dung
dch A tc dng va vi dung dch NaOH. Sau phn ng c cn dung dch thu c 22,9 gam mui khan.
Cng thc cu to thu gn ca X l
A. NH
2
-CH
2
-CH
2
-CH
2
-COOH B. NH
2
-CH
2
-CH
2
-COOH
C. (NH
2
)
2
-CH-COOH D. (NH
2
)
2
C
2
H
2
(COOH)
2

Cu 37 : Cho 61,28 gam hn hp kim loi gm Fe v Cu vo dung dch HNO
3
long thu c 13,44 lt (ddktc) kh NO
sn phm kh duy nht v 7,68 gam cht rn khng tan. Phn trm khi lng ca Cu trong hn hp ban u
l
A. 90,86% B. 54,3% C. 41,77% D. 45,7%
Cu 38 : t chy hon ton 0,1 mol mt axit cacboxylic n chc cn va V lt O
2
( ktc), cho ton b sn phm
vo bnh cha nc vi trong d thu c 30 gam kt ta v khi lng bnh nc vi tng 16,8 gam. Gi tr
ca V l
A. 4,48 B. 2,24 C. 6,72. D. 8,96
Cu 39 : Cho 9,6 gam Cu vo 200ml dung dch gm HNO
3
1M v H
2
SO
4
0,5M sau khi phn ng xy ra hon ton (sn
phm kh duy nht l NO), c cn dung dch sau phn ng th khi lng mui khan l
Cu 40 : Khi lng xenluloz v khi lng axit nitric cn ly sn xut ra 445,5 kg xenluloz trinitrat, bit hiu
xut phn ng t 75% l
A. 324 kg xenluloz v 126 kg HNO
3
B. 162 kg xenluloz v 378 kg HNO
3

C. 182,25 kg xenluloz v 212,625 kg HNO
3
D. 324 kg xenluloz v 378 kg HNO
3

Cu 41 : Cho cc cht sau: axit glutamic; valin, lysin, phenol, axit fomic, glyxin, alanin, trimetylamin, anilin. S cht
lm qu tm chuyn mu hng, mu xanh v khng i mu ln lt l
A. 2, 3, 4 B. 2, 3, 4 C. 3, 3, 3 D. 2, 2,5
Cu 42 : NH
3
c tng hp t N
2
v H
2
nhit 450-500
O
C, p sut p =200-300atm, xc tc Fe theo phn ng:
N
2
+ 3H
2
2NH
3

Nu tng nng N
2
v H
2
ln 2 ln th tc phn ng tng
A. 16 ln B. 4 ln C. 8 ln D. 2 ln
Cu 43 : Cho s phn ng sau:
Benzen --------> X --------> Y --------> Z
17
Z l hp cht hu c no sau y
A. C
6
H
5
ONa B. C
6
H
5
CO
3
H C. C
6
H
5
OH D. NaHCO
3

Cu 44 : Thc hin cc th nghim sau:
(1). Sc kh C
2
H
4
vo dung dch KMnO
4
. (2). Sc Cl
2
d vo dung dch NaOH

(3). Chiu sng vo hn hp kh (CH
4
; Cl
2
). (4). Sc kh H
2
S vo dung dch CuCl
2
.

(5). Sc kh CO
2
vo dung dch Ca(OH)
2
. (6). Sc kh SO
2
vo dung dch H
2
S.
S th nghim c phn ng oxi ho- kh xy ra l
A. 1,2,3,6. B. 2,3,6. C. 1,3,4,6. D. 1,2,4,6
Cu 45 : Protein A c khi lng phn t l 50000 vC. Thy phn 100 gam A thu c 33,998 gam alanin. S mt
xch alanin trong phn t A l
A. 562 B. 208 C. 382 D. 191
Cu 46 : Pht biu no sau y ng
A. Tnh oxi ha ca clo mnh hn Iot
B. Trong hp cht cc nguyn t halogen u c s oxi ha -1, +1, +3, +5, +7
C. Cc mui AgCl, AgBr, AgI, AgF khng tan trong nc
D. HF, HCl, HBr, HI c tnh kh gim dn
Cu 47 : Th t cc cht xp theo chiu tng dn lc axit l
A. CH
2
ClCH
2
COOH<CH
3
CHClCOOH<CH
3
COOH<HCOOH
B. HCOOH<CH
3
COOH<CH
2
ClCH
2
COOH<CH
3
CHClCOOH.
C. CH
3
COOH<HCOOH<CH
2
ClCH
2
COOH<CH
3
CHClCOOH.
D. HCOOH<CH
3
COOH<CH
3
CHClCOOH<CH
2
ClCH
2
COOH.
Cu 48 : Hn hp kh X gm SO
2
v O
2
c t khi i vi H
2
bng 24. Sau khi un nng hn hp trn vi cht xc tc thu c
hn hp kh Y gm SO
2
, O
2
v SO
3
c t khi i vi H
2
bng 30. Phn trm s mol ca SO
2
, trong hn hp Y l:
A. 12,5% B. 25% C. 50% D. 37,5%
Cu 49 : Cho 15,6 g este X (C
4
H
8
O
3
) tc dng va vi dung dch cha 0,15 mol NaOH th thu c 14,7g mui.
Cng thc cu to ng ca este l:
A. CH
3
COO - CH
2
CH
2
OH B. HCOO CH
2
CH
2
CHO
C. HO - CH
2
COO C
2
H
5
D. CH
3
CH (OH) COO CH
3

Cu 50 : Cho cc cht CH
3
COONH
4
, Na
2
CO
3
, Ba(OH)
2
, Al
2
O
3
, CH
3
COONa, C
6
H
5
ONa, Zn(OH)
2
, NH
4
Cl, KHCO
3
,
NH
4
HSO
4
, Al, (NH
4
)
2
CO
3
S cht va phn ng vi dung dch HCl v dung dch NaOH l
A. 5 B. 6 C. 7 D. 8
--------------------------------------------------------------------------Ht----------------------------------------------------------------

18
TRNG THPT VIT YN 2 THI TH I HC S 3
( thi c 4 trang) MN HO HC
Thi gian lm bi 90 pht - S cu trc nghim: 50 cu.

H, tn th sinh:.............................................................................
S bo danh: ...............................................................................
Cho: H = 1, C = 12, N = 14, O = 16, Na = 23, Mg = 24, Al = 27, Si = 28; P = 31; S = 32; Cl = 35,5; K = 39, Ca =
40, Cr = 52; Fe = 56, Cu = 64; Zn = 65, Br = 80; Ag = 108, Ba = 137.
Cu 1: Cho m gam hn hp Cu, Fe, Zn tc dng vi dung dch HNO
3
long, d thu c dung dch Z (gi thit NO l
sn phm kh duy nht). C cn dung dch Z thu c (m + 62) gam mui khan. Nung hn hp mui khan trn n
khi lng khng i thu c cht rn c khi lng l
A. (m + 8) gam. B. (m + 31) gam.
C. (m + 16) gam. D. (m + 4) gam.
Cu 2: Ion X
n+
c cu hnh electron l 1s
2
2s
2
2p
6
, X l nguyn t thuc nhm A trong bng tun hon cc nguyn t
ho hc. S nguyn t ha hc tha mn vi iu kin ca X l
A. 2. B. 3. C. 4. D. 5.
Cu 3: Cht X c cng thc phn t C
x
H
y
O
z
. Cho X tc dng vi NaOH thu c Y v Z. Bit Z khng tc dng c
vi Na v c s chuyn ha sau:

Z T Y ankan n gin nht.

Thnh phn phn trm theo khi lng ca cacbon trong X l
A. 40,00%. B.55,81%. C. 48,65%. D. 54,55%.
Cu 4: Ho tan m gam Al trong dung dch HNO
3
long (d), thu c dung dch X v 1,344 lt hn hp Y ( ktc)
gm N
2
v N
2
O. T khi ca Y so vi hiro l 18. Cho dung dch X tc dng vi dung dch NaOH d thu c 0,672
lt kh ( ktc) lm xanh qu tm m. Gi tr ca m l
A. 4,86. B. 6,75. C. 8,10. D. 7,02.
Cu 5: X phng ha hon ton cht bo X trong NaOH (d) un nng thu c 9,2 gam glixerol v 91,2 gam mt
mui natri ca axit bo. Tn ca X l
A. tristearin. B. triolein.
C. tripanmitin. D. trilinolein.
Cu 6: Cho 16,4 gam hn hp cc kim loi Cr, Fe tc dng vi lng d dung dch H
2
SO
4
long nng (trong iu
kin khng c khng kh), thu c dung dch X v 6,72 lt kh H
2
( ktc). Cho dung dch X tc dng vi dung dch
NaOH (trong iu kin c khng kh) c m gam kt ta. Gi tr ln nht ca m l
A. 31,7. B. 19,3. C. 21,0. D. 17,6.
Cu 7: Cho Fe
3
O
4
vo dung dch H
2
SO
4
long d thu c dung dch X. Hy cho bit trong cc ha cht sau: KMnO
4
,
Cl
2
, NaOH, CuSO
4
, Cu, KNO
3
, KI, dung dch X tc dng c vi bao nhiu cht ?
A. 4. B. 5. C. 7. D. 6.
Cu 8: Oxi ho hon ton 11,2 lt SO
2
(ktc) bng khng kh (d) nhit cao, c cht xc tc. Ho tan ton b sn
phm vo 210 gam dung dch H
2
SO
4
10% thu c dung dch X. Cc phn ng xy ra hon ton. Nng phn trm
khi lng ca dung dch X l
A. 16%. B. 24%. C. 28%. D. 32%.
Cu 9: Thc hin phn ng nhit phn V lt kh metan iu ch axetilen, thu c 11,2 lt hn hp X gm axetilen,
hiro v metan cha phn ng ht. Cho ton b X qua dung dch AgNO
3
(d) trong amoniac thu c 24,0 gam kt
ta. Cc th tch kh o ktc. Gi tr ca V l
A. 2,24. B. 6,72. C. 4,48. D. 3,36.
Cu 10: Hiro c nguyn t khi trung bnh l 1,008. Trong nc, hiro ch yu tn ti hai ng v l
1
1
H v
2
1
H. S
nguyn t ca ng v
2
1
H trong 1ml nc l
(cho s Avogaro bng 6,022.10
23
, khi lng ring ca nc l 1 g/ml).
A. 5,33.10
20
. B. 4,53.10
20
. C. 5,35.10
20
. D. 4,55.10
20
.
Cu 11: Hn hp X gm axit axetic v ancol etylic. Cho 14,52 gam hn hp X tc dng vi Na d thu c 3,024 lt
H
2
(ktc). Thm H
2
SO
4
c vo hn hp X v un nng thu c 8,80 gam este. Hiu sut ca phn ng este ha l
A. 75,36%. B. 80,00%. C. 83,33%. D. 66,67%.
Cu 12: Ion NO
3
oxi ho c Zn trong dung dch kim (OH

) to NH
3
, ZnO
2
2

v H
2
O.

Ha tan ht 6,5 gam Zn vo
200ml dung dch hn hp gm KNO
3
0,1M v NaOH 1,0M. Kt thc phn ng, thu c V lt hn hp kh ( ktc).
Gi tr ca V l
A. 0,448. B. 0,784. C. 0,896. D. 1,120.
Cu 13: Cho phng trnh ion sau: Al + NO
3
+ OH
+ H
2
O AlO
2
+ NH
3
Tng cc h s (cc s nguyn ti gin) ca cc cht tham gia v to thnh sau phn ng l
M thi 114
+ O
2

xt, t
o
+ NaOH
CaO, t
o
+ NaOH

19
A. 19. B. 29. C. 18. D. 28.
Cu 14: Mt hp cht hu c X ch cha C, H, O c phn t khi bng 90. Cho X tc dng ht vi Na thy s mol H
2

sinh ra bng s mol X tham gia phn ng. X khng tc dng vi NaOH. S ng phn cu to ca X l
A. 3. B. 6. C. 5. D. 4.
Cu 15: Cho 1,2 lt hn hp gm hiro v clo vo bnh thu tinh bng thch anh y kn v chiu sng bng nh sng
khuch tn. Sau mt thi gian ngng chiu sng, thu c mt hn hp kh cha 30% hiroclorua v th tch v lng
clo gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca hiro trong hn hp ban
u l
A. 88,25%. B. 30,75%. C. 81,25%. D. 66,25%.
Cu 16: Cho cc dung dch sau: Anilin, natri phenolat, natri axetat, metylamin. S dung dch lm xanh qu tm l
A. 1 B. 2 C. 3 D. 4
Cu 17: Cho cc cht sau: Clobenzen, axit oxalic, phenyl axetat, glyxin, benzyl clorua. S cht c th tc dng vi
NaOH (trong iu kin thch hp) theo t l mol n
X
: n
NaOH
= 1 : 2 l
A. 1 B. 2 C. 3 D. 4
Cu 18: Cho 18,4 gam hn hp Y gm ancol metylic, ancol anlylic v etylen glicol tc dng vi Na kim loi (d) thu
c V lt kh H
2
( ktc). Mt khc, t 18,4 gam hn hp Y, thu c 30,8 gam CO
2
v 18,0 gam H
2
O. Gi tr ca V
l
A. 2,24 B. 3,36 C. 4,48 D. 5,60
Cu 19: X l hp cht hu c cha C, H, O c 32,43% C (v khi lng), phn t khi ca X bng 74. Cho s
phn ng:
X Y

Cng thc phn t ca Y l
A. C
2
H
2
O
3
B. C
2
H
4
O
3
C. C
2
H
6
O
3
D. C
2
H
4
O
2

Cu 20: Ngm mt thanh st trong dung dch Fe
2
(SO
4)3
, sau khi phn ng xy ra hon ton thu c dung dch Y c
khi lng tng 5,6 gam so vi dung dch Fe
2
(SO
4)3
ban u. S mol KMnO
4
trong H
2
SO
4

long,

d phn ng ht vi
dung dch Y l
A. 0,04. B. 0,05. C. 0,06. D. 0,07.
Cu 21: Nung nng m gam hn hp X gm Al v Fe
2
O
3
ti phn ng hon ton, thu c cht rn Y. Nghin nh,
trn u v chia Y lm 2 phn:
- Phn 1: Cho tc dng vi dung dch NaOH n d thu c 0,672 lt H
2
(ktc) v cht rn Z. Ha tan cht rn Z
trong dung dch HCl d thu c 2,688 lt kh H
2
(ktc)
- Phn 2: Cho tc dng vi dung dch HCl d thu c 10,08 lt kh H
2
(ktc). Gi tr ca m l
A. 29,04 gam. B. 43,56 gam. C. 53,52 gam. D. 13,38 gam.
Cu 22: X l mt dn xut ca benzen c cng thc phn t l C
7
H
9
NO
2
. Cho 13,9 gam X tc dng va vi dung
dch NaOH, c cn dung dch thu c 14,4 gam mui khan Y. Y tc dng ht vi dung dch HCl d thu c cht
hu c Z. Khi lng phn t (theo vC) ca Z l
A. 161,5. B. 143,5. C. 144.

D.122.
Cu 23: Cho 124,0 gam canxi photphat tc dng vi 98,0 gam dung dch axit sunfuric 64,0%. Lm bay hi dung dch
thu c n cn kh c m gam mt hn hp rn. Bit cc phn ng xy ra hon ton.
Gi tr ca m l
A. 186,72. B. 188,72. C. 180,72. D. 190,68.
Cu 24: in phn 2 lt dung dch hn hp gm NaCl v CuSO
4
n khi H
2
O b in phn hai cc th dng li, ti
catot thu 1,28 gam kim loi v anot thu 0,336 lt kh ( ktc). Coi th tch dung dch khng i th pH ca dung dch
thu c bng
A. 12. B. 1. C. 13. D. 2.
Cu 25: Hiro ha etylbenzen thu c xicloankan X. Khi cho X tc dng vi clo (c chiu sng) thu c bao nhiu
dn xut monoclo ?
A. 4. B. 3. C. 5. D. 6.
Cu 26: Cho a gam Si tc dng vi dung dch KOH (d) thu c 8,96 lt kh ( ktc). Gi tr ca a l
A. 4,2.

B. 5,6. C. 7,0.

D. 8,4.
Cu 27: Hn hp E gm hai cht hu c X, Y mch h c cng chc ho hc. Khi t chy hon ton 21,8 gam hn
hp E thu c 24,64 lt CO
2
( ktc) v 19,8 gam H
2
O. Mt khc, cho 21,8 gam E tc dng vi dung dch NaOH va
, thu c 12 gam ancol n chc v m gam hn hp mui ca hai axit hu c n chc k tip nhau trong dy
ng ng. Gi tr ca m l
A. 17,8. B. 18,8. C. 15,8. D. 21,8.
Cu 28: Mt hn hp gm Al
2
(SO
4
)
3
v K
2
SO
4
, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong
hn hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl
2
d, hi khi lng kt ta thu c gp
bao nhiu ln khi lng hn hp ban u ?
A. 1,588 ln. B. 1,788 ln. C. 1,688 ln. D. 1,488 ln.
+ H
2

t
o
, xt
20
Cu 29: Cho cc nhn xt sau:
(1) Cht bo l trieste ca glixerol vi axit bo.
(2) T nilon-6,6 , t capron, t enang u iu ch bng phn ng trng ngng.
(3) Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
(4) Nitro benzen phn ng vi HNO
3
c (xc tc H
2
SO
4
c, un nng) to thnh m-initrobenzen.
(5) Anilin phn ng vi nc brom to thnh p-bromanilin.
S nhn xt ng l:
A. 3. B. 5. C. 2. D. 4.
Cu 30: X l hn hp hai anehit n chc mch h. 0,04 mol X c khi lng 1,98 gam tham gia phn ng ht vi
dung dch AgNO
3
/NH
3
d thu c 10,8 gam Ag. m gam X kt hp va vi 0,35 gam H
2
. Gi tr ca m l .
A.8,66 gam. B. 5,94 gam. C. 6,93 gam. D. 4,95 gam.
Cu 31: Cho s phn ng: Ca(OH)
2
+ H
3
PO
4
(d) X + H
2
O.
X l
A. Ca
3
(PO
4
)
2
. B. CaHPO
4
.
C. Ca(H
2
PO
4
)
2
. D. Ca
3
(PO
4
)
2
v CaHPO
4
.
Cu 32: Hn hp X gm mt ankan v mt anken. Cho 11,2 lt hn hp X lm mt mu va ht 500 ml dung dch Br
2

0,4M. Mt khc, t chy hon ton 5,6 lt hn hp X thu c 13,44 lt CO
2
(th tch cc kh o ktc). Cng thc
phn t ca X, Y l
A. C
2
H
6
v C
3
H
6
. B. C
2
H
6
v C
2
H
4
.
C. CH
4
v C
4
H
8
. D. C
3
H
8
v C
3
H
6
.
Cu 33: Khi cho hn hp Al v K vo nc thy hn hp tan ht, chng t
A. nc d. B. Al tan hon ton trong nc.
C. nc d v n
Al
> n
K.
D. nc d v n
K
> n
Al.

Cu 34: Cho 9,2 gam hn hp hai ancol no, n chc, mch h tc dng vi Na (d) sinh ra 2,24 lt H
2
(ktc). Mt
khc oxi ha hon ton hn hp hai ancol ny bng CuO nung nng, sn phm thu c cho phn ng vi lng d
AgNO
3
trong NH
3
, thu c 43,2 gam Ag. Khi lng ca ancol c khi lng mol nh hn l
A. 3,2 gam. B. 4,6 gam. C. 6 gam. D. 3 gam.
Cu 35: X c cng thc nguyn l (CH)
n
. Khi t chy 1 mol X c khng qu 5 mol CO
2
. Bit X phn ng vi
dung dch AgNO
3
trong NH
3
. S cht X tha mn tnh cht trn l
A. 1. B. 3. C. 4. D. 2.
Cu 36: Cho dung dch cc cht sau: Br
2
, NaOH, NaHCO
3
, CH
3
COOH. S dung dch phn ng vi c vi phenol
l
A. 2. B. 3. C. 4. D. 5.
Cu 37: Oxit Y ca mt nguyn t X ng vi ha tr II c thnh phn phn trm theo khi lng ca X l 42,86%. C
cc pht biu sau:
(I). Y l kh khng mu, khng mi, khng v, tan nhiu trong nc, l kh rt c.
(II). Y l oxit axit.
(III). nhit cao, Y c th kh c nhiu oxit kim loi.
(IV). Y c th iu ch trc tip t phn ng gia X nung v hi nc.
(V). T axit fomic c th iu ch c Y.
(VI). T Y, bng mt phn ng trc tip vi metanol (xt, t
o
), c th iu ch c axit axetic.
S pht biu ng l
A. 3. B. 5. C. 4 . D. 6.
Cu 38: Khi cho 7,15 gam hn hp kim loi gm Mg, Zn, Al vo dung dch H
2
SO
4
long (d) thu c 5,60 lt kh (
ktc). Khi lng mui clorua thu c khi cho 7,15 gam hn hp trn tc dng hon ton vi kh clo l
Cu 39: Pht biu no sau y khng ng ?
A. iu ch kh HBr bng cch cho NaBr (rn) tc dng vi axit H
2
SO
4
m c, un nng.
B. iu ch kh HF bng cch cho CaF
2
(rn) tc dng vi axit H
2
SO
4
m c, un nng.
C. Cho kh clo tc dng vi sa vi 30
O
C thu c clorua vi.
D. Flo c tnh oxi ho rt mnh, oxi ho mnh lit nc.
Cu 40: t chy a mol mt axit cacboxylic X thu c b mol CO
2
v c mol H
2
O (bit a = b - c). Khi cho a mol cht
X tc dng vi NaHCO
3
(d) thu c 2a mol kh. X thuc dy ng ng ca axit
A. no, n chc. B. no, hai chc.
C. c 1 ni i, n chc. D. c 1 ni i, hai chc.
Cu 41: t chy hon ton 1,72 gam hn hp X gm c anehit acrylic v mt anehit no n chc Y cn 2,296 lt
oxi ( ktc). Cho ton b sn phm chy hp th ht vo dung dch nc vi trong d c 8,50 gam kt ta. Cng
thc cu to ca Y l
A. CH
3
-CH=O. B. H-CH=O.
C. C
2
H
5
CH=O. D. C
3
H
7
-CH=O.
21
Cu 42: Khi dng kh CO kh Fe
2
O
3
thu c hn hp rn X. Ho tan X bng dung dch HCl d thy c 4,48 lt
kh thot ra ( ktc). Dung dch thu c sau phn ng tc dng vi NaOH d (khng c mt khng kh) thu c 45
gam kt ta trng xanh. Th tch kh CO ( ktc) cn dng l
A. 6,72 lt. B. 8,96 lt. C. 10,08 lt. D. 13,44 lt.
Cu 43: Cho glixerol tc dng vi hn hp 3 axit C
17
H
35
COOH, C
17
H
33
COOH v C
15
H
31
COOH.
S loi trieste c to thnh cha ng thi c 3 gc axit trn c th l
A. 2. B. 4. C. 6. D. 3.
Cu 44: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca st v crom ?
A. St v crom u b th ng ha trong dung dch HNO
3
c ngui.
B. St v crom u phn ng vi lu hunh nhit cao theo cng t l v s mol.
C. St l kim loi c tnh kh yu hn crom .
D. St v crom u tan trong dung dch long khi un nng ca axit HCl v H
2
SO
4
to mui st(II) v mui crom(II)
khi khng c khng kh.
Cu 45: Hp cht A
1
c cng thc phn t C
3
H
6
O
2
tha mn s :

3 3 2 4
dd AgNO /NH dd H SO NaOH
A A A A
1 2 3 4

Cng thc cu to ca A
1
l
A. HCOOCH
2
CH
3
. B. CH
3
OCOCH
3
.
C. CH
3
CH
2
COOH . D. HOCH
2
CH
2
CHO.
Cu 46: Hai dung dch CH
3
COONa v NaOH c cng pH, nng mol/l ca cc dung dch tng ng l x v y.
Quan h gia x v y l
A. x = y. B. x < y. C. x > y. D. x = 0,1y.
Cu 47: Hp cht hu c X c cng thc phn t chung l C
x
H
y
O
2
(x > 2), bit cht X l hp cht no, mch h. Pht
biu no sau y khng ng ?
A. y = 2x + 2 ; X l ancol no hai chc.
B. y = 2x - 4 ; X l anehit no hai chc.
C. y = 2x - 2 ; X l anehit no hai chc.
D. y = 2x ; X l axit hoc este no n chc.
Cu 48: Cho a mol cht bo X cng hp ti a vi 5a mol Br
2
. t a mol X c b mol H
2
O v V lt CO
2
.Biu
thc lin h gia V, a v b l
A. V = 22,4.(4a - b). B. V = 22,4.(b + 5a).
C. V = 22,4.(b + 6a). D. V = 22,4.(b + 7a).
Cu 49: Cho 45,0 gam hn hp bt Fe v Fe
3
O
4
vo V lt dung dch HCl 1M, khuy u cc phn ng xy ra hon
ton, thy thot ra 4,48 lt kh (ktc) v 5,0 gam kim loi khng tan (cho bit th t t tri sang phi ca cc cp oxi
ha-kh trong dy in ha nh sau: Fe
2+
/Fe ; H
+
/H
2
; Fe
3+
/Fe
2+
).
Gi tr ca V l
A. 1,4 lt B. 0,4 lt C. 0,6 lt D. 1,2 lt
Cu 50: Cho cc cht sau: C
2
H
5
NH
2
, C
6
H
5
NH
2
, NH
3
, C
2
H
5
NH
3
Cl, C
6
H
5
NH
3
Cl, NH
4
Cl. S cp cht phn ng c
vi nhau l
A. 3. B. 2. C. 4. D. 1.

--------------------------------Ht--------------------------------

22
S GIO DC & O TO BC GIANG THI TH I HC , CAO NG NM 2012 S 4
TRNG THPT VIT YN 2 Mn: HO HC
( thi c 04 trang) Thi gian lm bi: 90 pht, khng k thi gian pht

H, tn th sinh: .......................................................................
S bo danh: ............................................................................
Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe
= 56; Cu = 64; Zn = 65; Br = 80; Ag = 108
.

Cu 1: Hp cht X l dn xut ca benzen c CTPT C
8
H
10
O
2
. X tc dng vi NaOH theo t l mol 1: 1. Mt khc cho
X tc dng vi Na th s mol H
2
thu c ng bng s mol ca X phn ng. Nu tch mt phn t H
2
O t X th
to ra sn phm c kh nng trng hp to polime. S CTCT ph hp ca X l:
A. 7. B. 6. C. 2. D. 9.
Cu 2: Cho dung dch Ca(OH)
2
d vo 100 ml dd Mg(HCO
3
)
2
0,15M phn ng xong c m g kt ta Gi tr m l:
A. 0,87. B. 2,37. C. 3,87. D. 2,76.
Cu 3: Cho cc cp dung dch sau:
(1) NaAlO
2
v AlCl
3
; (2) NaOH v NaHCO
3
; (3) BaCl
2
v NaHCO
3
;
(4) NH
4
Cl v NaAlO
2
; (5) Ba(AlO
2
)
2
v Na
2
SO
4
; (6) Na
2
CO
3
v AlCl
3

(7) Ba(HCO
3
)
2
v NaOH. (8) CH
3
COONH
4
v HCl (9) KHSO
4
v NaHCO
3

S cp trong c phn ng xy ra l:
A. 8 B. 7 C. 6 D. 9
Cu 4: Nguyn t ca nguyn t X c electron phn lp ngoi cng l 3p. Nguyn t ca nguyn t Y c electron
phn lp ngoi cng l 3s. Tng s electron trn hai phn lp ngoi cng ca X v Y l 7. Bit rng X v Y d dng
phn ng vi nhau. S hiu nguyn t ca X v Y tng ng l
A. 13 v 15 B. 18 v 11 C. 17 v 12 D. 11 v 16
Cu 5: Cho 22,72 gam hn hp gm Fe, FeO, Fe
2
O
3
v Fe
3
O
4
phn ng ht vi dd HNO
3
long d thu c V lt kh
NO (duy nht ktc) v dung dch X. C cn dung dch X thu c 77,44 gam mui khan. Gi tr ca V l
A. 2,24. B. 2,688. C. 4,48. D. 5,6.
Cu 6: Trong cc mnh sau, c bao nhiu mnh ng:
(I). HI l cht c tnh kh, c th kh c H
2
SO
4
n H
2
S.
(II). Nguyn tc iu ch Cl
2
l kh ion Cl
-
bng cc cht nh KMnO
4
, MnO
2
, KClO
3

(III). iu ch oxi c th tin hnh in phn cc dung dch axit, baz, mui nh H
2
SO
4
, HCl, Na
2
SO
4
,
BaCl
2

(IV). Lu hunh t phng v n t l hai dng ng hnh ca nhau.
(V). HF va c tnh kh mnh, va c kh nng n mn thu tinh.
(VI). nhit cao, N
2
c th ng vai tr l cht kh hoc cht oxi ha.
(VII). Dung dch Na
2
SO
3
c th lm mt mu nc brom.
A. 3 B. 4 C. 5 D. 6
Cu 7: Dung dch Y c cha cc ion: NH
4
+
, NO
3
-
, SO
4
2-
. Cho dd Y tc dng vi lng d dd Ba(OH)
2
, un nng thu
c 11,65 gam kt ta v 4,48 lt kh (ktc). Nu cho m gam dung dch Y cho tc dng vi mt lng bt Cu d v
H
2
SO
4
long d sinh ra V lt NO (sn phm kh duy nht, o ktc). Gi tr ca V l
A. 1,87 B. 2,24 C. 1,49 D. 3,36
Cu 8: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H
2
SO
4

c, nng thu c dung dch X v 3,248 lt
kh SO
2

(sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l
A. 52,2. B. 48,4. C. 58,0. D. 54,0.
Cu 9: a mol cht bo X cng hp ti a vi 5a mol Br
2
. t a mol X c b mol H
2
O v V lt CO
2
.Biu thc gia
V vi a, b l:
A. V = 22,4.(4a - b). B. V = 22,4.(b + 3a). C. V = 22,4.(b + 6a). D. V = 22,4.(b + 7a).
Cu 10: Cc cht sau: Na
2
O, H
2
O, NH
3
, MgCl
2
, CO
2
, KOH, HCl. S cht c lin kt cng ha tr l
A. 3 B. 5 C. 4 D. 6
Cu 11: Dy cc cht u c th to ra axit axetic bng mt phn ng l
A. C
2
H
5
OH, CH
3
CHO, C
4
H
10
, HCOOCH
3
B. CH
3
CH
2
Cl, CH
3
OH, CH
3
CHO, CH
3
COOC
2
H
5

C. CH
3
OH, C
2
H
5
OH, CH
3
CHO, HCOOCH
3
D. CH
3
OH, C
2
H
5
OH, C
4
H
10
, CH
3
CCl
3
Cu 12: Ch ra s cu ng trong cc cu sau:
(1) Phenol, axit axetic, CO
2
u phn ng c vi NaOH.
(2) Phenol, ancol etylic khng phn ng vi NaHCO
3
(3) CO
2
, v axit axetic phn ng c vi natriphenolat v dd natri etylat
(4) Phenol, ancol etylic, v CO
2
khng phn ng vi dd natri axetat
M 101
23
(5) HCl phn ng vi dd natri axetat, natri p-crezolat
A. 3 B. 2 C. 5 D. 4
Cu 13: Thc hin phn ng crackinh m gam isobutan, thu c hn hp X gm cc hirocacbon. Dn hn hp X
qua qua bnh nc brom c ha tan 6,4 gam brom. Nc brom mt mu ht, c 4,704 lt hn hp kh Y ( ktc) gm
cc hirocacbon thot ra. T khi hi ca Y so vi hiro bng 117 / 7. Tr s ca m l
A. 8,7. B. 10,44. C. 5,8. D. 6,96.
Cu 14: t chy hon ton 2,76 gam hn hp X gm C
x
H
y
COOH, C
x
H
y
COOCH
3
, CH
3
OH thu c 2,688 lt CO
-
2
(ktc) v 1,8 gam H
2
O. Mt khc cho 2,76 gam X phn ng va vi 30 ml dung dch NaOH 1M thu c 0,96
gam CH
3
OH. Cng thc ca C
x
H
y
COOH l
A. C
3
H
5
COOH B. C
2
H
5
COOH C. C
2
H
3
COOH D. CH
3
COOH
Cu 15: C cc cht : Fe, dung dch FeCl
2,
dung dch HCl c, ngui; dung dch Fe(NO
3
)
2
; dung dch FeCl
3
, dung
dch AgNO
3
. Cho tng cp cht phn ng vi nhau th s cp c phn ng thuc loi phn ng oxi ha kh l :
A. 5 B. 4 C. 7 D. 6
Cu 16: mt cht hu c A n chc cha cc nguyn t ( C,H,O ) v khng c kh nng trng bc. A tc dng va
vi 96g dd KOH 11,66%. Sau khi phn ng c cn dd thu c 23g cht rn Y v 86,6g nc. t chy hon ton
Y thu c sn phm gm 15,68 lt CO
2
( ktc ) v 7,2g nc v mt lng K
2
CO
3
. CTCT ca A l:
A. CH
3
-COO-C
6
H
5
B. HCOO-C
6
H
4
-CH
3
C. CH
3
-C
6
H
4
-COOH D. HCOO-C
6
H
5

Cu 17: Dung dch A cha: 0,15 mol Ca
2+
; 0,6 mol Cl
-
; 0,1 mol Mg
2+
; a mol HCO
3
-
; 0,4 mol Ba
2+
. C cn dung
dch A c cht rn B. Nung B trong khng kh n khi lng khng i thu c m gam cht rn khan. Gi tr ca
m l:
A. 90,1. B. 105,5. C. 102,2. D. 127,2.
Cu 18: Thu phn hon ton 62,5 g dung dch X 17,1 % trong mi trng axit va uc dung dch Y, Cho
AgNO
3
d vo Y, un nh c 13,5 g kt ta. Bit X l mt cacbohydrat. X l:
A. C
5
H
10
O
5
B. C
6
H
12
O
6
C. C
4
H
8
O
4
D. C
12
H
22
O
11

Cu 19: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt
kh O
2

( ktc), thu c 6,38 gam CO
2
. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol
l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C
3
H
6
O
2

v C
4
H
8
O
2
. B. C
2
H
4
O
2

v C
5
H
10
O
2
. C. C
3
H
4
O
2

v C
4
H
6
O
2
. D. C
2
H
4
O
2

v
C
3
H
6
O
2
.
Cu 20: Cho cc phn ng ho hc sau
(1) Al
2
O
3
+ dung dch NaOH (2) Al
4
C
3
+ H
2
O
(3) dung dch NaAlO
2
+ CO
2
(4) dung dch AlCl
3
+ dung dch Na
2
CO
3

(5) dung dch AlCl
3
+ dung dch NH
3
(6) Al + dung dch NaOH
S phn ng c s to thnh Al(OH)
3
l
A. 4 B. 3 C. 2 D. 5
Cu 21: Khi nhit phn: NH
4
NO
3
, NH
4
NO
2
, NH
4
HCO
3
, CaCO
3
, KMnO
4
, NaNO
3
, Fe(NO
3
)
2
. S phn ng thuc phn
ng oxi ho - kh l
A. 4. B. 3. C. 6. D. 5.
Cu 22: Chia 156,8 gam hn hp L gm FeO, Fe
3
O
4
, Fe
2
O
3
thnh hai phn bng nhau. Cho phn th nht tc dng ht
vi dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va vi dung dch M l hn hp HCl,
H
2
SO
4
long thu c 167,9 gam mui khan. S mol ca HCl trong dung dch M l
A. 1,75 mol B. 1,80 mol C. 1,50 mol D. 1,00 mol
Cu 23: Mt hn hp X gm Na, Al v Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi H
2
O d th thu c
V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H
2
SO
4
long d th thu c 0,25V lt kh (cc kh
o cng iu kin). Thnh phn % theo khi lng ca Fe trong hn hp X l
A. 14,4% B. 33,43% C. 20,07% D. 34,8%.
Cu 24: Trong cc ho cht Cu, C, S, Na
2
SO
3
, FeS
2
, FeSO
4,
O
2
, H
2
SO
4
c. Cho tng cp cht phn ng vi nhau th
s cp cht c phn ng to ra kh SO
2
l
A. 6 B. 8 C. 7 D. 9
Cu 25: Trong cc phn ng sau y, c bao nhiu phn ng iu ch c mui st (III).
(I). Cho Fe
2
O
3
tc dng vi dung dch HI.
(II). Sc kh H
2
S vo dung dch mui FeCl
3

(III). Cho Fe d vo dung dch HNO
3
c, nng.
(IV). Cho Fe
2
(SO
4
)
3
tc dng vi dung dch K
2
CO
3
.
(V). Sc kh Cl
2
vo dung dch Fe(NO
3
)
2

(VI). Cho Fe(OH)
2
tc dng vi HNO
3
long.
(VII). Cho FeSO
4
long vo dung dch HNO
3
long.
(VIII). Cho qung pirit vo dung dch HCl c, nng. A . 2 B. 3
C. 4 D. 5
24
Cu 26: Khi cho Fe2O3 v Cu vo dung dch H2SO4 long, d c cht rn X v dung dch Y. Dy gm cc cht u
tc dng c Y l
A. Cl
2
, K
2
Cr
2
O
7
, HNO
3
, Na
2
SO
4
. B. Cl
2
, KMnO
4
, NaOH, BaCl
2
.
C. KI, NH
3
, H
2
S, NH
4
Cl. D. BaCl
2
, HCl, KNO
3
, NH
3
.
Cu 27: Hn hp X c C
2
H
5
OH, C
2
H
5
COOH, CH
3
CHO (trong C
2
H
5
OH chim 50% theo s mol). t chy m gam
hn hp X thu c 3,06 gam H
2
O v 3,136 lt CO
2
(ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng
bc thy c p gam Ag kt ta. Gi tr ca p l
A. 9,72. B. 8,64. C. 10,8. D. 2,16.
Cu 28: Cho cc phn ng sau :
(1) CO
2
+ H
2
O + C
6
H
5
ONa (2) C
6
H
5
OH + NaOH
(3) CH
3
COOH + Cu(OH)
2
(4) C
3
H
5
(OH)
3
+ Cu(OH)
2

(5) C
6
H
5
NH
3
Cl + AgNO
3
(6) CO
2
+ H
2
O + CH
3
COONa
(7) CH
3
COOH + C
6
H
5
OH (8) C
6
H
5
OH + HCHO
Cc phn ng c tin hnh trong iu kin thch hp. Dy gm cc phn ng c th xy ra l
A. (2), (3), (4), (5), (7), (8) B. (1), (2), (4), (5), (6), (7)
C. (1), (2), (3), (4), (7), (8) D. (1), (2), (3), (4), (5), (8)
Cu 29: C cc th nghim sau:
(I) Sc kh H
2
S vo dung dch FeCl
2
. (II) Sc kh SO
2

vo dung dch KMnO
4
.
(III) Sc kh CO
2

vo nc Gia-ven. (IV) Nhng l nhm vo dung dch H
2
SO
4

c, ngui.
(V) Nh dung dch AgNO
3
vo dung dch NaF. (VI) Nhng thanh Zn vo dung dch CrCl
3
.
S th nghim xy ra phn ng ho hc l
A. 5. B. 3. C. 2. D. 4.
Cu 30: un nng 2V lt hi anehit X vi 3V lt H
2
(xc tc Ni) n khi phn ng xy ra hon ton ch thu c hn
hp kh Y c th tch 3V lt (cc th tch o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z phn
ng vi Na (d) sinh ra V lt kh H
2
(cc th tch o cng iu kin nhit , p sut). Cht X l anehit
A. khng no (cha mt ni i C=C), hai chc B. no, hai chc
C. no, n chc D. khng no (cha mt ni i C=C), n chc
Cu 31: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai
phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H
2

( ktc). t chy hon ton phn hai,
sinh ra 26,4 gam CO
2
. Cng thc cu to thu gn ca Z trong hn hp X l
A. HOOC-(CH
2
)
2
-COOH B. HOOC-(CH
2
)
3
-COOH
C. HOOC-COOH D. HOOC-CH
2
-COOH
Cu 32: Ho tan hon ton 24,4 gam hn hp gm FeCl
2
v NaCl (c t l s mol 1 : 2) vo nc (d) c dung
dch X. Cho dung dch AgNO
3
(d) vo X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m
l
A. 57,4. B. 10,8. C. 28,7. D. 68,2.
Cu 33: Cho hn hp X gm hai ancol n chc A v B un nng vi H
2
SO
4
c 140
0
C c 3 ete. Ly ngu nhin
mt ete em t chy hon ton th thu c 0,5 mol CO
2
v 0,6 mol H
2
O. S cp CTCT ca ancol A v B tha mn
X l:
A. 6 B. 3 C. 4 D. 2
Cu 34: Sc 2,016 lt kh CO
2
( ktc) vo 100 ml dung dch NaOH 1M c dung dch A. Rt thm 200 ml dd gm
BaCl
2
0,15M v Ba(OH)
2
xM thu c 5,91 gam kt ta. Tip tc nung nng th thu tip m gam kt tana. Gi tr ca
x v m l:
A. 0,1M v 3,94gam B. 0,05M v 1,97 gam C. 0,05M v 3,94 gam D. 0,1M v 1,97
gam
Cu 35: Cho 31,9 gam hn hp Al
2
O
3
, ZnO, FeO, CaO tc dng ht vi CO d, un nng thu c 28,7 gam hn hp
X. Cho X tc dng vi dung dch HCl d thu c V lt kh H
2
(ktc). V c gi tr l:
A. 5,6 lt B. 11,2 lt C. 6,72 lt D. 4,48 lt
Cu 36: Cho hp cht hu c n chc mch h X. Khi X b t chy ch thu c CO
2
v H
2
O. Trong X cha
53,33% oxi v khi lng. S cht X tha mn iu kin trn l:
A. 2 B. 1 C. 3 D. 4
Cu 37: C cc phn ng sau:
(1): poli(vinylclorua) +Cl
2

0
t

(2) Cao su thin nhin + HCl

0
t

(3). Cao su BuNa S + Br
2

0
t

(4) poli(vinylaxetat) + H
2
O

0
t OH

(5) Amiloz + H
2
O

+ 0
t H

25
Phn ng gi nguyn mch polime l
A. (1), (2),(5) B. (1), (2), (3) C. (1), (2), (3), (4) D. (1),(2),(3),(4),(5)
Cu 38: Thu phn hon ton 150 g hn hp cc ipeptit c 159 g cc aminoaxit. Bit rng cc ipeptit c to bi cc
aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc dng vi HCl d th lng
mui thu c l:
Cu 39: in phn 500 ml dung dch NaCl 0,40M (in cc tr, mng ngn xp) vi cng dng in l 9,65A;
trong thi gian 16 pht 40 giy. Dung dch sau in phn ho tan c ti a bao nhiu gam bt nhm ?
A. 1,35 B. 10,80 C. 5,40 D. 2,70
Cu 40: Cho cc cht: NaOH, HF, HBr, CH
3
COOH, C
2
H
5
OH, C
12
H
22
O
11
(saccaroz), HCOONa, NaCl, NH
4
NO
3
.
Tng s cht thuc cht in li v cht in li mnh l :
A. 7 v 6 B. 8 v 6 C. 8 v 5 D. 7 v 5
Cu 41: Ho tan hon ton 2,40 gam FeS
2
trong dung dch H
2
SO
4
c, nng (d). Ton b kh thu c cho li vo
dung dch brom d. Khi lng brom (theo gam) tham gia phn ng l
A. 8,80 B. 12,00 C. 17,60 D. 24,00
Cu 42: Ho tan 20,8 gam hn hp bt gm Fe, FeS, FeS
2
, S bng dung dch HNO
3
c nng d thu c 53,76 lt
NO
2
(sn phm kh duy nht, kC. v dung dch A. Cho dung dch A tc dng vi dung dch NaOH d, lc ly ton
b kt ta nung trong khng kh n khi lng khng i th khi lng cht rn thu c l:
A. 16 gam B. 9 gam C. 8,2 gam D. 10,7 gam
Cu 43: Ho tan 7,68 g hn hp Fe
2
O
3
v Cu trong dung dch HCl khi axit ht ngi ta thy cn li 3,2 gam Cu d.
Khi lng ca Fe
2
O
3
ban u l
Cu 44: Hp cht hu c X c cng thc phn t C
9
H
16
O
4
, Khi thy phn trong mi trng kim thu c mt mui
m t mui ny iu ch trc tip c axit dng sn xut t nilon-6,6. S cng thc cu to tho mn l
A. 1 B. 2 C. 3 D. 4
Cu 45: Hn hp gm Al, Al
2
O
3
, Cu, Zn. Ho tan hon ton trong dung dch HNO
3
long c dung dch A. Cho A
tc dng vi dung dch NH
3
d thu c kt ta B. Nung B ti khi lng khng i c cht rn E. Thnh phn ca
E l
A. Al
2
O
3
, CuO, ZnO. B. Al
2
O
3
, CuO. C. Al
2
O
3
, ZnO. D. Al
2
O
3
.
Cu 46: Cho cc cht sau: Ancol etylic, Anhit Axetic, phenol, Toluen, Etilen, Stiren, Axit axetic, Etyl axetat,
Anehit acrylic. S cht lm mt mu dung dch nc brm l:
A. 5 B. 3 C. 2 D. 6
Cu 47: Pht biu no sa y ng ?
(1) Protit l loi hp cht cao phn t thin nhin c cu trc phc tp
(2) Protit ch c trong c th ngi v ng vt
(3) C th ngi v ng vt khng th tng hp c protit t nhng cht v c, m ch tng hp c t aminoaxit
(4) Protit bn i vi nhit, i vi axit v baz kim
A. (1), (3) B. (1), (2) C. (2), (3) D. (3), (4)
Cu 48: Cho cht Y c cng thc C
4
H
6
O
2
, khi tc dng vi dung dch NaOH thu c sn phm c kh nng tham gia
phn ng trng gng. S ng phn cu to ca Y tho mn l:
A. 4 B. 2 C. 3 D. 5
Cu 49: Oxit Y ca mt nguyn t X ng vi ha tr II c thnh phn % theo khi lng ca X l 42,86%. Hy cho
bit trong cc mnh sau, c bao nhiu mnh ng khi ni v X:
(I). Y tan nhiu trong nc.
(II). Lin kt X vi O trong Y l lin kt ba.
(III). Y c th iu ch trc tip t phn ng gia X v hi nc nng.
(IV). T axit fomic c th iu ch c Y.
(V). T Y, bng mt phn ng trc tip c th iu ch c axit etanoic.
(VI). Y l kh khng mu, khng mi, khng v, c tc dng iu ha khng kh.
A. 3 B. 4 C. 5 D. 6
Cu 50: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ha hon ton 0,2
mol hn hp X c khi lng m gam bng CuO nhit thch hp thu c hn hp sn phm Y. Cho ton b Y
phn ng hon ton vi lng d dung dch AgNO
3
trong NH
3
, thu c 54,0 gam Ag. Gi tr ca m l
A. 13,5. B. 8,5. C. 8,1. D. 15,3.

---------- Ht --------

26
S GD - T BC GIANG
Trng THPT VIT YN 2
M 123
(c 4 tr ang)

THI TH H LN 5 NM 2012
M n: Ho hc
Thi gian: 90 pht (khng kthi gian giao )
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t : H = 1 ; Li = 7 ; N = 14; C = 12; O = 16; Na = 23; Mg =
24; Al = 27; S = 32; Cl = 35,5; Ca = 40; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.
I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40)
Cu 1: Nhn xt no sau y khng ng?
A. lm gim nhit nng chy ca Al
2
O
3
, khi in phn nng chy Al
2
O
3
ngi ta cho thm 3NaF.AlF
3
vo.
B. Cu, Fe, Ni l nhm kim loi c th iu ch c theo c 3 phng php: thu luyn, nhit luyn, in phn.
C. S khc nhau v bn cht gia n mn ho hc v n mn in ho l cch dch chuyn electron t kim loi n
mn sang mi trng.
D. Khi in phn dung dch NaCl c mng ngn ta thu c kh H
2
Ant

Cu 2: t chy hon ton m gam hn hp gm hai este X
1
, X
2
l ng phn ca nhau cn dng 19,6 gam O
2
, thu
c 11,76 lt CO
2
(ktc) v 9,45 gam H
2
O. Mt khc nu cho m gam hn hp trn tc dng vi 200 ml dung dch
NaOH 1M ri c cn dung dch thu c sau phn ng th cn li 13,95 gam cht rn khan. Bit gc axit ca X
2
c s
nguyn t cacbon nhiu hn gc axit ca X
1
. T l mol ca X
1
v X
2
trong hn hp trn ln lt l.
A. 2 : 3 B. 3 : 4 C. 4 : 3 D. 3 : 2
Cu 3: Cho 6,9 gam hn hp X gm 2 ancol no, n chc (Y v Z) tc dng vi Na d thu c 1,68 lt H
2
(ktc).
Cn khi oxi ho 6,9 gam hn hp X bi CuO d, nung nng thu c hn hp T gm 2 sn phm hu c tng ng
vi Y v Z. Cho T tc dng vi lng d dung dch AgNO
3
trong NH
3
th thu c 43,2 gam Ag. Cng thc hai ancol
trong axit l:
A. CH
3
CH
2
OH v CH
3
CH
2
CH
3
OH B. CH
3
OH v CH
3
CH(OH)CH
3

C. CH
3
OH v CH
3
CH(CH
3
)CH
2
OH D. CH
3
OH v CH
3
CH(OH)CH
2
CH
3
Cu 4: Cho m gam hn hp X gm Ba v Al ( trong Al chim 37,156% v khi lng) tc dng vi H
2
O d thu
c V lt H
2
(ktc). Mt khc nu cho m gam hn hp X trn tc dng vi dung dch NaOH d th thu c 12,32 lt
H
2
(ktc). Gi tr ca m v V ln lt l:
A. 21,8 v 8,96 B. 19,1 v 8,96 C. 21,8 v 10,08 D. 19,1 v 10,08
Cu 5: Cho s phn ng:
Triolein
+ NaOH
( X )
+ HCl
(Y )
+ H2
( Z.) Z c tn gi l:
A. Axit panmitic B. Glixerol C.axit oleic D. axit stearic
Cu 6: Cho cc dung dch Na
2
CO
3
, NaOH, AlCl
3
, HCl, NaHSO
4
. Nu trn cc dung dch vi nhau tng i mt th c
nhiu nht bao nhiu phn ng c sn phm l cht kh?
A. 2 B. 4 C. 3 D. 1
Cu 7: Cho tng cht C, Fe, BaCl
2
, , Fe
3
O
4
, FeCO
3
, FeS, H
2
S, HI, AgNO
3
, HCl, Na
2
SO
3
, FeSO
4
ln lt tc dng vi
H
2
SO
4
c, nng. S phn ng thuc loi phn ng oxi ha - kh l:
A. 7 B. 6 C. 9 D. 8
Cu 8: Nhm cc vt liu c iu ch t polime to ra do phn ng trng hp l
A. T lapsan, t axetat, thu tinh plexiglas, poli(vinyl) clorua, polietilen
B. Cao su, t capron , thu tinh plexiglas, poli(vinyl) clorua, t nitron
C. T nilon-6,6, poli(metyl metacrylat) , thu tinh plexiglas, t nitron
D. Cao su, t lapsan, thu tinh plexiglas, poli(vinyl) clorua, t nitron
Cu 9: Pht biu no sau y khng ng?
A.Dung dch m c ca Na
2
SiO
3
v K
2
SiO
3
c gi l thy tinh lng
B. m chy magi c th c dp tt bng ct kh
C. CF
2
Cl
2
b cm s dng do khi thi ra kh quyn th ph hu tng ozon
D. Trong phng th nghim, N
2
c iu ch bng cch nung nng dung dch NH
4
NO
2
bo ho.
Cu 10: Thu phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala,
32gam Ala-Ala v 27,72 gam Ala-Ala-Ala .Gi tr m l
A. 81,54 B. 88,2 C. 111,74 D. 90,6
Cu 11: Dung dch X c cha: 0,07 mol K
+
, 0,02 mol SO
4
2-
v x mol OH
-
. Dung dch Y c cha ClO
4
-
, NO
-
3
v y mol
H
+
; tng s mol ClO
4
-
v NO
-
3
l 0,04. trn X v Y thu c 100ml dung dch Z. Dung dch Z c pH (b qua s in
li nc) l:
A. 1 B. 2 C. 12 D. 13
Cu 12: Th nghim trnh by khng ng l?
A.Cho t t dung dch Ca(OH)
2
vo dung dch H
2
SO
3
thy xut hin kt ta trng, tip tc cho dung dch
Ca(OH)
2
n d kt ta li tan ra
B. Cho dung dch CH
3
COOH tc dng va vi dung dch NaOH, tip tc nh vo y vi git qu tm thy
dung dch c mu xanh
27
C. Nh rt t t dung dch HCl long vo dung dch Na
2
CO
3
ng thi khy u khng thy kh thot ra. Nh
tip vo y vi git dung dch Ba(OH)
2
c thy c kt ta xut hin.
D. Nh dung dch Na
2
CO
3
vo dung dch FeCl
3
thy dung dch thu c c kt ta nu v kh thot ra
Cu 13: Cho hn hp X gm C
2
H
5
OH, C
2
H
5
COOH, CH
3
CHO, trong C
2
H
5
OH chim 50% v s mol. Khi t chy
hon ton m gam hn hp X thu c 3,06 gam H
2
O v 3,136 lt CO
2
(ktc). Mt khc khi cho m gam hn hp X tc
dng vi lng d dung dch AgNO
3
trong NH
3
thu c x gam bc. Gi tr ca x l
A. 2,16 B. 8,64 C. 4,32 D. 1,08
Cu 14: Thy phn hp cht:
H
2
N-CH(CH
3
)-CO-NH-CH
2
-CO-NH-CH
2
-CH
2
-CO-NH-CH(C
6
H
5
)-CO-NH-CH(CH
3
)-COOH th thu c nhiu nht
bao nhiu -amino axit?
A. 3 B. 5 C. 2 D. 4
Cu 15: Ion M
3+
c cu hnh electron phn lp ngoi cng l 3d
3
. Hy chn pht biu khng ng?
A. Hirxit ca M
3+
c tnh lng tnh B. M c cu hnh electron l
1s
2
2s
2
2p
6
3s
2
3p
6
3d
6
C. Dung dch cha M
3+
va c tnh oxi ha va c tnh kh. D. M thuc chu k 4 nhm VIB
Cu 16: C th pha ch mt dung dch ng thi c cc ion
A. Na
+
, NO
-
3
, H
+
, SO
4
2-
B. HCO
3
-
, K
+
, HSO
4
-
, OH
-
C. H
+
, Fe
2+
, Cl
-
, NO
-
3
D. HSO
4
-
, Ba
2+
, HCO
3
-
,NH
4
+

Cu 17: Cho hn hp X gm hai cht hu c tc dng va vi 50ml dung dch NaOH 0,4M, thu c mt mui v
168 ml hi mt ancol(ktc). Mt khc t chy hon ton hn hp trn, ri hp th ht sn phm chy vo bnh ng
dung dch Ba(OH)
2
d, khi lng bnh tng 3,41 gam. Cng thc ca hai cht hu c trong X l
A. CH
3
COOH v CH
3
COOC
2
H
5
B. C
2
H
5
COOH v C
2
H
5
COOCH
3

C. HCOOH v HCOOC
2
H
5
D. HCOOH v HCOOC
3
H
7

Cu 18: Khi ho tan SO
2
vo nc c cn bng sau:
SO
2
+ H
2
O HSO
3
-
+ H
+

Nhn xt no sau y l ng?
A. Khi thm dung dch H
2
SO
4
vo th cn bng chuyn dch theo chiu thun.
B. Khi thm dung dch Na
2
CO
3
vo th cn bng chuyn dch theo chiu thun.
C. Khi un nng th khng chuyn dch cn bng ha hc.
D. Khi thm dung dch K
2
SO
3
vo th cn bng chuyn dch theo chiu nghch.
Cu 19: Hn hp X gm hai axit cacboxylic A, B n chc, hn km nhau mt nguyn t cacbon. Cho 12,9 gam X
tc dng ht vi 300 ml dung dch NaHCO
3
1M, c cn dung dch thu c n khi lng khng i cn li 21,05
gam cht rn khan. Cho 12,9 gam hn hp X trn tc dng vi lng d dung dch AgNO
3
trong NH
3
, kt thc phn
ng thu c m gam kt ta bc. Cng thc cu to thu gn ca A, B v gi tr m l:
A. HCOOH, CH
3
COOH v 32,4 B. CH
3
COOH, C
2
H
5
COOH v 32,4
C. CH
3
COOH, C
2
H
5
COOH v 21,6 D. HCOOH, CH
3
COOH v 21,6
Cu 20: Cho s phn ng:
CH
3
OH
+ CO,t0,xt
(X)
+ CH3 C CH
(Y)
+ NaOH
(Z) propan-2-ol
Cng thc cu to thu gn ca X v Z ln lt l:
A. CH
3
COOH v CH
3
COCH
3
B.C
2
H
5
OH v C
2
H
5
CHO
C. C
2
H
5
OH v CH
3
CH(OH)CH
3
D. CH
3
COOH v CH
3
COOCH=CHCH
3

Cu 21: Mt dung dch c cha HCO
3
-
; 0,2 mol Ca
2+
; 0,8 mol Na
+
; 0,1 mol Mg
2+
; 0.8 mol Cl
-
. C cn dung dch
n khi lng khng i th lng mui thu c l:
Cu 22: Mt hirocacbon thm X c cng thc n gin nht l C
4
H
5
v khng tc dng vi nc brm. S ng
phn cu to ca X l:
A. 1 B. 6 C. 4 D. 5
Cu 23: trong cc cht sau: CH
3
OH, NaOH, HCl, glyxin, NaCl, HNO
2
c bao nhiu cht c phn ng vi alanin?
A. 4 B. 3 C. 2 D. 5
Cu 24: Cho xiclopropan vo nc brm thu c cht hu c X. Cho X vo dung dch NaOH un nng(d) to ra
sn phm hu c Y. Y tc dng vi CuO, t nng thu c hp cht a chc Z. Khi em n mol Z tham gia phn ng
trng bc th s mol Ag ti a thu c l
A. 2n mol B. 6n mol C. n mol D. 4n mol
Cu 25: Ho tan hn hp cha ng thi 0,15 mol mi kim loi Fe v Cu trong 675 ml dung dch AgNO
3
1M. Khi
lng cht rn thu c khi kt thc phn ng l:
A. 64,8 B. 75,3 C. 70,2 D. 72,9
Cu 26: Nhn nh no sau y l khng ng?
A. Vinyl axetat khng phi l sn phm ca phn ng este ho B. Phn ng cng axit axetic vo etilen thu c
este.
C. Hir ho hon ton triolein thu c tristearin. D. Sn phm ca phn ng gia axit v ancol l
este.
28
Cu 27: Cho cc cht sau tc dng vi nhau trong dung dch
a. KI + FeCl
3
----> b. HI + FeO -> c. KI + O
3
+ H
2
O ->
d. KI + H
2
O
2
-> e. Pb(NO
3
)
2
+ KI -> f. Cl
2
+ KI -> g. KI + K
2
Cr
2
O
7
+ H
2
SO
4
long
->
Nhng phn ng ho hc to ra sn phm I
2
l:
A. a, c, d, f, g B. a, c, d, e, f C. a, f, g D. a, b,c, d, e,
g, f
Cu 28: Cation M
3+
c cu hnh electron ngoi cng l 2p
6
. Khi cho dung dch MCl
3
vo cc ng nghim ng lng
d cc dung dch: Na
2
CO
3
, NaOH, NH
3
, Na
2
SO
4
. S ng nghim sau phn ng c kt ta hirxit l
A. 4 B. 2 C. 3 D. 1
Cu 29: Mt loi kh than cha ng thi N
2
, CO v H
2
. t chy 4,48 lt (ktc) hn hp kh ny bng lng O
2
va
ri dn sn phm chy vo nc vi trong (d) thy tch ra 10 gam kt ta, thu c dung dch X v c 0,56 lt
N
2
(ktc) thot ra. Khi lng dung dch X thay i so vi khi lng dung dch nc vi trong ban u l
A. gim 8,65 gam B. gim 4,25 gam C. tng 6 gam D. tng 7,25
gam
Cu 30: Cho m gam anilin tc dng vi 150 ml dung dch HCl 1M thu c hn hp X c cha 0,05 mol anilin. Hn
hp X ny tc dng va vi V ml dung dch NaOH 1M. Gi tr ca m v V ln lt l:
A. 18,6 v 150 B. 18,6 v 300 C. 9,3 v 150 D. 9,3 v 300
Cu 31: t chy hon ton 1 mol hp cht hu c X mch h, n chc c cha oxi cn 4 mol oxi v ch thu c
CO
2
v hi nc c th tch bng nhau ( o cng iu kin nhit v p sut). S cng thc cu to tho mn ca
X l
A. 4 B. 1 C. 3 D. 2
Cu 32: Cho 0,5 gam hn hp X gm Li, Na, K vo nc thu c 2 lt dung dch c pH = 12. Trn 8 gam hn hp X
v 5,4 gam bt Al ri cho vo nc n phn ng hon ton c V lt kh thot ra(ktc).Gi tr ca V l:
A. 11,648 B. 8,064 C. 10,304 D. 8,160
Cu 33: Cho hn hp cht rn gm CaC
2
, Al
4
C
3
v Ca vo nc thu c hn hp X gm 3 kh, trong c hai kh
cng s mol. Ly 8,96 lt hn hp X (ktc) chia lm hai phn bng nhau. Phn 1 cho vo dung dch AgNO
3
trong NH
3

d, sau phn ng hon ton thy tch ra 24 gam kt ta. Phn 2 cho i qua Ni, un nng thu c hn hp kh Y. Th
tch O
2
va (ktc) cn dng t chy hon ton Y l
A. 5,6 lt B. 8,4 lt C. 8,96 lt D. 16,8 lt
Cu 34: C cc cht kh: NO
2
, Cl
2
, CO
2
, SO
2
, SO
3
, HCl. Nhng cht kh khi tc dng vi dung dch NaOH xy ra
phn ng oxi ho- kh l:
A. NO
2
v Cl
2
B. NO
2
, Cl
2
, CO
2
, SO
2
C. CO
2
, SO
2
, SO
3
D. CO
2
, SO
2
, SO
3
,
HCl
Cu 35: Cho 20 gam kim loi R tc dng vi N
2
un nng thu c cht rn X. Cho X vo nc d thu c 8,96 lt
(ktc) hn hp kh c t khi so vi H
2
bng 4,75. Vy R l
A. Mg B. Ca C. Ba D. Al
Cu 36: Hp th hon ton 0,07 mol CO
2
vo 250 ml dung dch NaOH 0,32 M thu c dung dch G. Thm 250 ml
dung dch gm BaCl
2
0,16M v Ba(OH)
2
nng xM vo dung dch G thu c 7,88 gam kt ta. Gi tr ca x l
A. 0,03 B. 0,06 C. 0,04 D. 0,02
Cu 37: Cho hn hp gm 9,6 gam Cu v 5,6 gam Fe vo dung dch HNO
3
long. Khy u v phn ng xy ra hon
ton, thy c 3,136 lt kh NO l sn phm kh duy nht thot ra( ktc) v cn li m gam cht khng tan. Gi tr ca
m l
A. 2,24 B. 2,56 C. 1,92 D. 2,8
Cu 38: Cho dy cc cht: axetanehit, axit fomic, metyl fomat, anehit oxalic, mantoz, glucoz, saccaroz,
fructoz. S cht trong dy c kh nng tham gia phn ng trng bc l
A. 6 B. 7 C. 8 D. 5
Cu 39: Cho cc cp cht sau y tc dng vi nhau: O
2
+ Cl
2
(1) , H
2
S + SO
2
(2), CuS +dd HCl (3), tinh th NaNO
3
+
dd H
2
SO
4
c, nng (4)HI + dd H
2
SO
4
c, nng (5),Cl
2
+ dd CrCl
2
(6). Cc cp cht khng xy ra phn ng l
A. (1),(3),(6) B. (1),(3),(5),(6) C. (1), (3) D. (2),(3),(4)
Cu 40: Pht biu no sau y ng?
A Glucoz, mantoz, fructoz, fomanhit l nhng cacbohirat c phn ng trng bc
B. Nhm cc cht: Val, Glu, Lys u lm i mu qu tm m
C. Tnh baz ca cc cht: NaOH, C
2
H
5
ONa, CH
3
-NH
2
, NH
3
gim dn t tri sang phi.
D. Etilen b oxi ho bi brm.
II. PHN RING (10 CU)
Th sinh ch c lm mt trong hai phn (Phn A hoc B)
A.Theo chng trnh chun (T cu 41 n cu 50)
Cu 41: Cho 1,5 gam hircacbon X tc dng vi lng d dung dch AgNO
3
trong NH
3
, thu c 7,92 gam kt ta
vng nht. Mt khc 1,68 lt kh X( ktc) c th lm mt mu c ti a V lt dung dch Br
2
1M. Gi tr ca V l
A. 0,25 B. 0,3 C. 0,2 D. 0,15
29
Cu 42: t chy hon ton m gam hn hp X gm hai anhit cn 17,6 gam O
2
thu c 10.08 lt CO
2
(ktc) v 8,1
gam H
2
O. Mt khc cho m gam X tc dng vi dung dch AgNO
3
/NH
3
d thu c khi lng kt ta bc l
A. 108 gam B. 86,4 gam C. 54 gam D. 27 gam
Cu 43: Nh t t cho n ht 400 ml dung dch HCl 1M vo 200 ml dung dch cha ng thi Na
2
CO
3
1M v
NaHCO
3
1M, kt thc phn ng thu c V lt CO
2
(ktc). Gi tr ca V l
A. 6,72 B. 2,24 C. 4,48 D. 8,96
Cu 44: Thc hin phn ng x phng ho gia 0,1 mol mt este n chc X vi 200 ml dung dch NaOH 1M thu
c 8,8 gam ancol v dung dch cha 12,2 gam cht tan. Este X c tn gi l
A. vinyl fomat B. benzyl benzoat C. isoamyl axetat D. isopropyl axetat
Cu 45: Cho dy cht: NaHSO
4
, Na
2
CO
3
, CrO, Al
2
O
3
, Zn(OH)
2
, (NH
4
)
2
SO
3
. S cht trong dy l cht lng tnh l
A. 3 B. 4 C. 2 D. 5
Cu 46: Khi in phn mt dung dch vi in cc tr, khng mng ngn th dung dch sau in phn c pH tng so
vi dung dch trc khi in phn. Vy dung dch em in phn l
A. dung dch NaCl B. dung dch CuSO
4
C. dung dch H
2
SO
4
D. dung dch HNO
3

Cu 47: Cho 8,9 gam alanin tc dng va vi dung dch NaOH thu c dung dch X. em dung dch X tc dng
vi dung dch HCl d, thu c dung dch Y. C cn cn thn dung dch Y(trong qu trnh c cn khng xy ra phn
ng ho hc) thu c khi lng cht rn khan l
Cu 48: Thu phn hon ton 34,2 gam sacaroz, thu ly ton b sn phm hu c ri em tc dng vi Cu(OH)
2
d
trong mi trng kim cho ti phn ng hon ton thu c khi lng kt ta Cu
2
O l
Cu 49: Cho s phn ng:
Fe +H
2
O, t
0
(X) + H
2
SO
4
long (Y) + KI (Z ) + H
2
SO
4
c (Y)
X v Z ln lt l
A. FeO v Fe
2
(SO
4
)
3
B. Fe
2
(SO
4
)
3
v FeSO
4
C. FeO v FeSO
4
D. Fe
3
O
4
v FeSO
4

Cu 50: Trong cng nghip luyn mu, thu c mt lng ln sn phm ph l SO
2
. thu hi S trong SO
2
ngi ta
cn s dng thm ho cht l
A. O
2
hoc H
2
S B. dung dch Ca(OH)
2
C. nc Clo D. dung dch KMnO
4

B. Theo chng trnh nng cao (T cu 51 n cu 60)
Cu 51: Chia 31,2 gam hn hp X gm Cr, Zn, Ni, Al thnh hai phn bng nhau. Ho tan ht phn 1 trong mt lng
d dung dch HCl long, nng thu c 7,28 lt H
2
(ktc). Cho phn 2 tc dng vi kh Cl
2
(d) t nng thu c
42,225 gam mui clorua. Phn trm khi lng ca Cr trong hn hp X l
A. 26,04 % B. 66,67% C. 33,33% D. 39,07%
Cu 52: Ch dng thm Cu(OH)
2
c th phn bit c tt c cc dung dch ring bit sau trong dy no sau y?
A. Saccaroz, glixerol, anehit axetic, ancol etylic B. Glucoz, mantoz, glixerol, anehit axetic
C. Glucoz, glixerol, lng trng trng, ancol etylic D. Lng trng trng, glucoz, fructoz, glixerol
Cu 53: C 5 dung dich ring bit : a)HCl, b) CuSO
4,
c) Fe
2
(SO
4
)
3
, d) HCl c ln CuCl
2
, e) ZnSO
4
. Nhng vo mi
dung dch mt thanh st nguyn cht . S trng hp xut hin s n mn in ho l
A. 0 B. 3 C. 2 D. 1
Cu 54: Cho dung dch axit axetic c nng x % tc dng va vi dung dch NaOH c nng 20% thu c
mui c nng 10,25%. Gi tr ca x l A. 10 B. 15 C. 18,67 D. 20
Cu 55: Ho tan hon ton m gam Na vo 1 lt dung dch HCl a M, thu c dung dch G v a mol kh thot ra. Dy
gm cc cht u tc dng c vi dung dch G l
A. Al, NH
4
NO
3
, Na
2
SO
3
B. Sn, Na
2
CO
3
, NH
4
H
2
PO
4
C. Zn, Al
2
O
3
, NaHSO
3
D. Ni, Br
2
, Ca(HCO
3
)
2
Cu 56: Khi tch nc ni phn t 3- metylpentan-2-ol thu c anken X c cp ng phn hnh hc. Cho X vo
dung dch KMnO
4
long, nng, c mt H
2
SO
4
long thu c cc sn phm hu c l
A.CH
3
COOH v C
2
H
5
COOH B. C
2
H
5
OH v CH
3
COCH
3

C.CH
3
COOH v CH
3
COCH
3
D. CH
3
COOH v CH
3
COC
2
H
5

Cu 57: in phn vi in cc tr 500ml dung dch CuSO
4
n khi thu c 1,12 lt kh (ktc) anot th dng li.
Ngm mt l st vo dung dch sau in phn n khi phn ng hon ton th thy l st tng 0,8 gam. Nng mol
ca dung dch CuSO
4
ban u lA. 3,6M B. 1,5M C. 0,4M D. 1,8M
Cu 58: Cho 32,25 gam mt mui c cng thc phn t l CH
7
O
4
NS tc dng ht vi 750 ml dung dch NaOH 1M
un nng thy thot ra cht kh lm xanh qu tm m v thu c dung dch X ch cha cc cht v c. C cn dung
dch X thu c bao nhiu gam cht rn khan?A. 45,5 B. 35,5 C. 30,0 D. 50,0
Cu 59: Hp cht X c to ra t ancol n chc v amino axit cha mt chc axit v mt chc amin. X c cng
thc phn t trng vi cng thc n gin nht. t chy hon ton 0,89 gam X cn va 1,2 gam O
2
v to ra
1,32 gam CO
2
, 0,63 gam H
2
O. Khi cho 0,89 gam X tc dng vi 200 ml dung dch NaOH 1M ri c cn th khi lng
cht rn khan thu c lA. 1,37 gam B. 8,57 gam C. 8,75 gam D. 0,97 gam
Cu 60: Cho dy cht: Cu(OH)
2
, Ni(OH)
2
, Fe(OH)
2
, AgCl, Zn(OH)
2
. S cht trong dy tan c trong dung dch NH
3

l
A. 5 B. 2 C. 4 D. 3
30
S GIO DC V O TO BC GIANG
TRNG THPT VIT YN 2

KIM TRA CHT LNG N THI I HC LN 5
MN HA HC
Thi gian lm bi:90 pht

M thi 132

Cho bit khi lng nguyn t (theo u) ca cc nguyn t:
H = 1; Li = 7; Be =9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40;
Cr=52; Fe = 56; Cu = 64; Zn = 65; As = 75; Br = 80; Rb = 85,5; Ag = 108; I=127; Ba = 137.

Cu 1: Cho cn bng: A
(dung dch)
+ 3B
(dung dch)
3C
(dung dch)
+ D+
Cn bng s thay i nh th no khi pha long dung dch?
A. Dch chuyn theo chiu nghch B. Ty thuc vo pha long bao nhiu ln
C. Dch chuyn theo chiu thun D. Khng dch chuyn
Cu 2: t chy hon ton hn hp Q gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch
Ca(OH)
2
0,02M thu c kt kt ta v khi lng dung dch tng 3,78 gam so vi ban u. Cho dung dch Ba(OH)
2

va vo dung dch thu thm kt ta. Tng kt ta 2 ln l 18,85 gam. Bit rng s mol ca X bng 60% tng s mol
ca X v Y c trong hn hp Q. Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l:
A. C
2
H
2
v C
4
H
6
B. C
4
H
6
v C
2
H
2
C. C
2
H
2
v C
3
H
4
D. C
3
H
4
v C
2
H
6

Cu 3: Ha tan a mol Fe vo dung dch long cha 1,2a mol H
2
SO
4
thu c dung dch X, sc O
2
vo X phn ng
xy ra hon ton thu c dung dch Y. Khi cho Y tc dng vi Cu v dung dch KMnO
4
th:
A. Y ha tan c Cu v lm mt mu KMnO
4

B. Y ha tan c Cu v khng lm mt mu KMnO
4

C. Y khng ha tan c Cu v lm mt mu KMnO
4

D. Y khng ha tan c Cu v khng lm mt mu KMnO
4

Cu 4: Cho cc este: vinyl axetat, vinyl benzoat, etyl axetat, isoamyl axetat, phenyl axetat, anlyl axetat, s este c th
iu ch trc tip bng phn ng ca axit v ancol tng ng (c H
2
SO
4
c lm xc tc) l:
A. 5 B. 3 C. 2 D. 4
Cu 5: Nhn xt no sau y khng ng?
A. T poliamit km bn trong cc mi trng axit v baz.
B. Khi cho fomanehit d tc dng vi phenol, c baz xc tc thu c nha novolac.
C. Saccaroz khng to kt ta khi cho vo dung dch AgNO
3
trong NH
3
.
D. T xenluloz axetat thuc loi t ha hc.
Cu 6: Tch nc hon ton 1,08 gam hn hp hai ancol thu c hn hp hai anken ng ng k tip. t chy
hon ton 2 anken trn trong 2,24 lt O
2
d, lm lnh hn hp sau phn ng ngng t ht hi nc thu c 1,568
lit kh (th tch cc kh o ktc). Cng thc ca hai anken l:
A. C
4
H
8
v C
5
H
10
B. C
3
H
6
v C
4
H
8
C. C
5
H
10
v C
6
H
12
D. C
2
H
4
v C
3
H
6

Cu 7: Ha hi 3,35 gam X gm CH
3
COOH, HCOOC
2
H
5
, CH
3
COOCH
3
, CH
3
COOC
2
H
5
thu c 1,68 lt hi X (
136,5
0
C v p sut 1 atm). t chy hon ton 3,35 gam hn hp X trn th thu c m gam H
2
O. Gi tr ca m l
Cu 8: Cho phn ng: Al + HNO
3
Al(NO
3
)
3
+ N
2
O + N
2
+ H
2
O.Nu t l s mol N
2
O

:N
2
ln lt l 2:3 th h s
cn bng ti gin ca HNO
3
l:
A. 138 B. 148 C. 168 D. 76
Cu 9: Trong cng nghip m Zn ln Fe ngi ta lm nh sau:
A. Anot lm bng Fe, catot lm bng Zn v nhng trong dung dch FeSO
4
.
B. Catot lm bng Zn, anot lm bng Fe v nhng trong dung dch ZnSO
4
.
C. Anot lm bng Zn, catot lm bng Fe v nhng trong dung dch ZnSO
4
.
D. Nhng thanh Fe vo Zn nng chy.
1. Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc.
2. Khi nhng thanh Fe vo dung dch hn hp CuSO
4
v H
2
SO
4
th c bn Fe b n mn in ho.
3. Trong thc t loi b NH
3
thot ra trong phng th nghim ta phun kh Cl
2
vo phng
4. Khi cho mt t CaCl
2
vo nc cng tm thi s thu c nc cng ton phn.
5. Nguyn tc sn xut gang l kh qung st oxit bng than cc trong l cao.
6. Sc H
2
S vo dung dch hn hp FeCl
3
v CuCl
2
thu c 2 loi kt ta.
7. Dung dch FeCl
3
khng lm mt mu dung dch KMnO
4
trong H
2
SO
4
long
S nhn xt ng l:
A. 4. B. 5. C. 3. D. 6.
Cu 11: Dy gm cc cht sp xp theo chiu tng dn ca tnh axit l
A. C
6
H
5
OH < CH
2
=CH-COOH < CH
3
COOH < HCOOH.
31
B. C
6
H
5
OH < HCOOH < CH
3
COOH < CH
2
=CH-COOH.
C. C
6
H
5
OH < CH
3
COOH < HCOOH < CH
2
=CH-COOH.
D. C
6
H
5
OH < CH
3
COOH < CH
2
=CH-COOH < HCOOH.
Cu 12: Hn hp X gm axit propionic, axit fomic,axit axetic v axit oxalic. Khi cho m gam X tc dng vi NaHCO
3

(d) th thu c 13,44 lt kh CO
2
. Mt khc, t chy hon ton m gam X cn 10,08 lt kh O
2
, thu c 16,8 lt kh
CO
2
v y mol H
2
O. Bit th tch cc kh o ktc. Gi tr ca y l :
A. 0,7 B. 0,6 C. 0,5 D. 0,4
Cu 13: Ly 3,93 gam hn hp X gm Fe
2
(SO
4
)
3
v M
2
SO
4
(M l kim loi kim) tc dng vi dung dch BaCl
2
d thu
c 6,99 gam kt ta. Xc nh thnh phn % v khi lng ca M
2
SO
4
trong hn hp X
A. 32,52 B. 25,19 C. 10,84 D. 8,40
Cu 14: in phn 2 lt dung dch hn hp gm NaCl v CuSO
4
n khi H
2
O b in phn hai cc th dng li, ti
catt thu 1,28 gam kim loi v ant thu 0,336 lt kh ( ktc). Xem th tch dung dch khng i th pH ca dung dch
thu c bng?
A. 2,3 B. 2 C. 12 D. 3
Cu 15: Cho cc cht: Al, Zn, NaHCO
3
, Al
2
O
3
, ZnO, Zn(OH)
2
, Cr
2
O
3
, Ba, Na
2
O, K, MgO, Fe. S cht c th b ha tan trong
c dung dch NaOH v dung dch KHSO
4
l:
A. 11 B. 10 C. 8 D. 9
Cu 16: Cho m gam NaOH vo 300ml NaAlO
2
0,5M c dung dch X. Cho t t dung dch cha 500ml HCl 1,0M
vo dung dch X, thu c dung dch Y v 7,8 gam cht kt ta. Sc CO
2
vo dung dch Y thy xut hin kt ta. Gi
tr ca m l:
Cu 17: Oxi ho hn hp 1 ancol n chc v 1 anehit n chc thu c 1 axit hu c duy nht (Hiu sut phn
ng l 100%). Cho lng axit ny tc dng ht vi m gam dung dch NaOH 2% v Na
2
CO
3
13,25% thu c dung
dch ch cha mui ca axit hu c c nng 21,87%. Tn gi ca anehit ban u l:
A. axetanehit B. fomanehit C. Butanal D. Propionanehit
Cu 18: Cho cc d kin thc nghim:
(1) Cho dung dch NaOH d vo dung dch Ca(HCO
3
)
2
; (2) Cho Ba vo dung dch Ba(HCO
3
)
2
;
(3) cho Ba vo dung dch H
2
SO
4
long; (4) Cho H
2
S vo dung dch FeSO
4
;
(5) Cho SO
2
n d vo dung dch H
2
S (6) Cho NaHCO
3
vo dung dch BaCl
2
;
(7) Sc d NH
3
vo Zn(OH)
2
; (8) dung dch NaAlO
2
d vo dung dch HCl
S trng hp xut hin kt ta khi kt thc th nghim l ?
A. 8 B. 5 C. 6 D. 4
Cu 19: X phng ha 265,2 kg cht bo c ch s axit bng 7 cn 56,84 kg dung dch NaOH 15%. Khi lng
glixerol thu c l
A. 4,62 kg B. 4,6 kg C. 5,52 kg D. 5,98 kg
Cu 20: Cho s sau:
(CH
3
)
2
CH-CH
2
CH
2
Cl
) t ( ol tan e / KOH
0
A
HCl
B
) t ( ol tan e / KOH
0
C
HCl
D
) t ( O H , NaOH
0
2
E
E c cng thc cu to l
A. (CH
3
)
2
CH-CH
2
CH
2
OH B. (CH
3
)
2
C=CHCH
3
. C. (CH
3
)
2
CH-CH(OH)CH
3
. D. (CH
3
)
2
C(OH)-CH
2
CH
3
.
Cu 21: Cho 33,35 gam hn hp A gm Fe
3
O
4
, Fe(NO
3
)
3
, Cu tc dng hon ton vi dung dch cha 0,414 mol
H
2
SO
4
(long) th thu c kh NO duy nht v dung dch B ch cha 2 mui. C cn B thu c bao nhiu gam mui
khan?
A. 64,400 hoc 61,520 B. 65,976 hoc 61,520 C. 73,122 hoc 64,400 D. 65,976 hoc 75,922
Cu 22: X l hn hp AlBr
3
v MBr
2
. Ly 0,1 mol X nng 24,303 gam tc dng vi dung dch AgNO
3
d thu c
52,64 gam kt ta. Xc nh % v khi lng AlBr
3
trong X?
A. 47,10% B. 58,23% C. 41,77% D. 51,63
Cu 23: Trong cc phn ng sau, xy ra trong dung dch :
1. Na
2
CO
3
+ H
2
SO
4
2. Na
2
CO
3
+ FeCl
3
3. Na
2
CO
3
+ CaCl
2

4. NaHCO
3
+ Ba(OH)
2
5. (NH
4
)
2
SO
4
+ Ba(OH)
2
6. Na
2
S + AlCl
3

Cc phn ng c to ng thi c kt ta v kh bay ra l:
A. 1, 3, 6 B. 2, 5, 6 C. 2, 3, 5 D. 2, 4, 6
Cu 24: Trong cc dung dch sau: (1) saccaroz, (2) 3-monoclopropan1,2-iol (3-MCPD), (3) etilenglycol, (4)
ipeptit, (5) axit fomic, (6) tetrapeptit, (7) propan-1,3-iol. S dung dich c th ha tan Cu(OH)
2
l
A. 4 B. 6 C. 3 D. 5
Cu 25: Cho dung dch Ba(HCO
3
)
2
ln lt vo cc dung dch: CaCl
2
, Ca(NO
3
)
2
, NaOH, Na
2
CO
3
, KHSO
4
, Na
2
SO
4
,
Ca(OH)
2
, H
2
SO
4
, HCl. S trng hp c to ra kt ta l
A. 5. B. 6. C. 7. D. 4.
Cu 26: Cc cht u khng b thu phn trong dung dch H
2
SO
4
long, nng l
A. poli (vinyl axetat); polietilen, cao su buna B. t capron; nilon-6,6, polietylen
32
C. nilon-6,6; poli(etylen-terephtalat); polistiren D. polietilen; cao su buna; polistiren
Cu 27: Cho hn hp Mg, Al v Fe vo dung dch AgNO
3
, n phn ng hon ton thu c cht rn X v dung dch
Y. Cho dung dch Y tc dng vi NaOH d thu c kt ta Z. Nung Z trong khng kh ti khi lng khng i thu
c hn hp cht rn T cha 3 cht rn khc nhau. Vy trong dung dch Y cha cc cation:
A. Mg
2+
, Fe
3+
, Ag
+
. B. Mg
2+
, Al
3+
, Fe
3+
, Ag
+
.
C. Mg
2+
, Al
3+
, Fe
2+
, Fe
3+
. D. Mg
2+
, Al
3+
, Fe
2+
, Fe
3+
, Ag
+
.
Cu 28: t chy hon ton 1 lng cao su buna-N vi lng khng kh va , thy to 1 hn hp kh nhit
trn 127
o
C m CO
2
chim 14,1% v th tch.T l s mt xch butaien v vinyl xyanua trong polime ny l? (bit
khng kh chim 20% O
2
v 80% N
2
v th tch)
A. 3:4 B. 2:3 C. 2:1 D. 1:2
Cu 29: Cho cc phn ng:
(1) O
3
+ dung dch KI; (2) F
2
+ H
2
O; (3) MnO
2
+ HCl (t
o
);
(4) H
2
S + dung dch Cl
2
d; (5) Cl
2
+ NH
3
d; (6) CuO + NH
3
(t
o
);
(7) KMnO
4
(t
o
); (8) H
2
S + SO
2
; (9) NH
4
Cl + NaNO
2
(t
o
); (10) NH
3
+ O
2
(Pt, 800
o
C).
S phn ng to ra n cht l
A. 6 B. 8 C. 9 D. 7
Cu 30: Ly 5,2 gam hn hp FeS
2
v Cu
2
S tc dng hon ton vi dung dch HNO
3
th thu c dung dch ch cha
2 mui v 12,208 lt hn hp NO
2
v SO
2
(ktc). Xc nh % v khi lng ca FeS
2
trong hn hp ban u
A. 71,53% hoc 81,39% B. 93,23% hoc 71,53% C. 69,23% hoc 81,39% D. 69,23% hoc 93,23%
Cu 31: Trong hn hp CH
3
OH v C
2
H
5
OH c cc loi lin kt hir sau:

Loi lin kt hir bn nht v km bn nht ln lt l:
A. (I) v (II) B. (II) v (II) C. (IV) v (III) D. (III) v (IV)
Cu 32: Ly 3,51 gam hn hp Al, Zn tc dng vi dung dch HNO
3
d th thu c 1,344 lt (ktc) kh X l sn
phm kh duy nht. Xc nh X?
A. NO
2
B. N
2
C. NO D. N
2
O
Cu 33: Theo danh php IUPAC ancol (CH
3
)
2
C=CHCH
2
OH c tn gi l:
A. 3-metylbut-2-en-1-ol. B. pent-2-en-1ol.
C. ancol iso-pent-2-en-1-ylic. D. 2-metylbut-2-en-4-ol.
Cu 34: Tin hnh in phn 100 ml dung dch Fe(NO
3
)
3
1M v Cu(NO
3
)
3
1M trong bnh in phn vi in cc tr,
I=19,3A, sau mt thi gian ly catot ra cn li thy n nng thm 3,584 gam (gi thit rng ton b kim loi sinh ra
u bm vo catot). Tnh thi gian in phn?
A. 1060 giy B. 960 giy C. 560 giy D. 500 giy
Cu 35: Ly 200ml dung dch NaOH 1,6M v KOH 1M tc dng ht vi dung dch H
3
PO
4
thu c dung dch X.
Chia X thnh 2 phn bng nhau
- Phn 1 : C cn thu c 17,12 gam hn hp mui khan
- Phn 2 : Cho tc dng vi dung dch CaCl
2
d thu c m gam kt ta. Xc nh m? (Bit mui photphat v
hidrophotphat ca Canxi u khng tan)
Cu 36: Nhit phn hon ton hn hp A gm Fe(NO
3
)
3
v Cu(NO
3
)
2
thu c hn hp kh X v cht rn Y. Hp th
ht X vo nc c dung dch Z, kh hon ton Y bng CO d c cht rn T. T tan va ht trong dung dch Z (to
kh NO duy nht). % v khi lng Cu(NO
3
)
2
trong A c th l?
A. 36,81% B. 60,84% C. 27,98% D. 43,72%
Cu 37: Dy no sau y c sp xp tng dn theo th t nhit si:
A. C
2
H
5
OH, C
2
H
5
Cl, CH
3
COOH, C
6
H
5
OH. B. C
2
H
5
Cl, C
2
H
5
OH, CH
3
COOH, C
6
H
5
OH.
C. C
2
H
5
Cl, C
2
H
5
OH, C
6
H
5
OH, CH
3
COOH. D. C
2
H
5
Cl, C
6
H
5
OH , C
2
H
5
OH, CH
3
COOH
Cu 38: Cho cc qu trnh ha hc :
1. Sc kh H
2
S vo dung dch FeCl
3
2. Dung dch AlCl
3
tc dng vi dung dch Na
2
S
3. Hidrat ha C
2
H
4
4. Nhit phn CaOCl
2

5. KF tc dng vi H
2
SO
4
c, nng 6. in phn dung dch NaCl
7. Al
4
C
3
tc dng vi dung dch HCl 8. n mn gang, thp trong khng kh m
C bao nhiu qu trnh xy ra phn ng oxi ha kh?
A. 5 B. 7 C. 6 D. 4
Cu 39: Hai hp cht X, Y c cng cng thc phn t C
4
H
7
ClO
2
tc dng vi dung dch NaOH thu c cc sn
phm sau:
33
X + NaOH mui hu c X
1
+ C
2
H
5
OH + NaCl
Y + NaOH mui hu c X
2
+ C
2
H
4
(OH)
2
+ NaCl
Cng thc cu to c th ca X, Y ln lt l:
A. CH
3
-CHCl-COOC
2
H
5
v CH
3
COOCHCl-CH
3
B. ClCH
2
-COOC
2
H
5
v CH
3
COOCH
2
CH
2
Cl
C. ClCH
2
-COOC
2
H
5
v CH
3
COOCHCl-CH
3
D. CH
3
COOCHCl-CH
2
Cl v CH
3
COOCH
2
CH
2
Cl
Cu 40: Aminoaxit X c 1 nhm NH
2
. Cho 0,01 mol aminoaxit X tc dng va vi 200ml dung dch NaOH 0,1M.
Mt khc 0,03 mol X tc dng vi 40g dung dch NaOH 7,05% c cn dung dch thu c 6,15 gam cht rn. Cng
thc ca X l
A. (H
2
N)
2
C
3
H
5
COOH B. H
2
NC
4
H
7
(COOH)
2
C. H
2
NC
2
H
3
(COOH)
2
. D. H
2
NC
3
H
5
(COOH)
2
.
Cu 41: Cho m gam hn hp A gm Al
4
C
3
v CaC
2
vo nc d thu c dung dch X; a gam kt ta Y v kh hn
hp kh Z. Lc b kt ta. t chy hon ton kh Z ri dn sn phm chy vo dung dch X thu c thm a gam kt
ta na. Hi trong hn hp X, Al
4
C
3
v CaC
2
c trn vi t l mol th no
A. 1: 1 B. 1:3 C. 1:2 D. 2:1
Cu 42: Cho 20 g hn hp 3 amin no n chc l ng ng lin tip ca nhau, tc dng va vi dung dch HCl,
c cn dung dch thu c 31,68g hn hp mui. Nu 3 amin trn c trn vi t l s mol 1:10:5 theo th t phn t
khi tng dn th cng thc ca 3 amin l:
A. C
4
H
9
NH
2
, C
5
H
11
NH
2
, C
6
H
13
NH
2
. B. CH
3
NH
2
, C
2
H
5
NH
2
, C
3
H
7
NH
2
.
C. C
2
H
5
NH
2
, C
3
H
7
NH
2
, C
4
H
9
NH
2
. D. C
3
H
7
NH
2
, C
4
H
9
NH
2
, C
5
H
11
NH
2
.
Cu 43: thu c 120 gam axit axetic cn ln men bao nhiu lt ancol etylic 35
0

. Bit rng khi lng ring ancol
etylic nguyn cht l 0,8 g/ml v hiu sut qu trnh ln men dm l 75%.
A. 0,438 lt B. 0,635 lt C. 0,0537 lt D. 0,246 lt
Cu 44: Cho cc dung dch sau:
(1): dung dch C
6
H
5
NH
2
; (2): dung dch CH
3
NH
2
; (3): dung dch H
2
N-CH
2
COOH;
(4): dung dch C
6
H
5
ONa; (5): dung dch Na
2
CO
3
; (6): dung dch NH
4
Cl.
Nhng dung dch lm xanh qu tm l:
A. (1); (2); (4); (5). B. (3); (4); (6). C. (2); (4); (5). D. (2); (5).
Cu 45: C bao nhiu nguyn t tha mn iu kin trong mi nguyn t ca nguyn t ( trng thi c bn) c
tng s e trn cc phn lp s l 8?
A. 6 B. 7 C. 15 D. 17
Cu 46: Hn hp X gm C
2
H
2
v H
2
c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn
hp Y gm C
2
H
4
, C
2
H
6
, C
2
H
2
v H
2
. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 19 gam v thot ra 4,48 lt
hn hp kh (ktc) c t khi so vi H
2
l 8,5. Th tch O
2
(ktc) cn t chy hon ton hn hp Y l
A. 22,4 lt. B. 26,88 lt. C. 58,24 lt. D. 53,76 lt.
Cu 47: Cho hn hp X gm C
3
H
7
COOH, C
4
H
8
(NH
2
)
2
, HO-CH
2
- CH=CH-CH
2
OH. t chy hon ton m gam hn
hp X, sn phm chy hp th hon ton vo dung dch Ca(OH)
2
thy to ra 20g kt ta v dung dch Y. un nng
dung dch Y thy xut hin kt ta. C cn dung dch Y ri nung cht rn thu c n khi lng khng i thu c
5,6 gam cht rn. Gi tr ca m l
A. 8,2 B. 5,4 C. 8,8 D. 7,2
Cu 48: Cho hn hp bt cha 0,01 mol Al v x mol Fe vo 200 ml dung dch hn hp AgNO
3
0,2M v Cu(NO
3
)
2

0,1M. n phn ng hon ton thu c dung dch A v 6,16 gam kim loi. Gi tr ca x l:
A. 0,035 mol. B. 0,05 mol. C. 0,03 mol. D. 0,025 mol.
Cu 49: Mt ancol 2 chc phn t khng cha nguyn t C bc 3. un nng nh m gam hi ancol trn vi CuO d
n khi phn ng xy ra hon ton thy khi lng cht rn trong bnh gim 2,24 gam ng thi thu c hn hp kh
v hi c t khi so vi H
2
l 18. m c gi tr l:
A. 5,32 gam B. 1,54 C. 7,84 gam D. 12,88 gam
Cu 50: a mt hn hp kh N
2
v H
2
c t l 1: 3 vo thp tng hp, sau phn ng thy th tch kh i ra gim 1/10
so vi ban u. Hiu sut ca phn ng tng hp NH
3
l
A. 25%. B. 20%. C. 15%. D. 10%.

----------- HT ----------

34
TRNG THPT VIT YN 2 K THI KHO ST CHT LNG LP 12 LN 6
NM HC :2011- 2012
Mn thi: HO HC KHI A,B
thi c 5 trang, gm 50 cu trc nghim

M 357
H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Br = 80; P = 31; Na = 23; Mg = 24; Al = 27; K = 39; Ca = 40; Cr =
52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207; Ni = 59.

I. PHN CHUNG CHO TT C TH SINH (40 cu t cu 1 n cu 40)
Cu 1: Oxi ha hon ton hn hp X gm HCHO v CH
3
CHO bng O
2
(c xc tc) thu c hn hp Y gm 2 axit
tng ng. T khi hi ca Y so vi X l T. Hi T bin thin trong khong no?
A. 1,36 < T < 1,53. B. 1,53 < T < 1,64. C. 1,12 < T < 1,36. D. 1,36 < T < 1,64.
Cu 2: Cho V lt Cl
2
(ktc) tc dng vi dung dch NaOH long, ngui, d thu c m
1
gam tng khi lng 2 mui.
Cho V lt Cl
2
(ktc) tc dng vi dung dch NaOH c, nng, d thu c m
2
gam tng khi lng 2 mui. T l m
1
:
m
2
bngA. 1 : 2.B. 2 : 1. C. 1 : 1. D. 1 : 1,5.
Cu 3: Mt hn hp X gm 1 axit no n chc v mt axit no, 2 chc. t chy hon ton a gam hn hp X thu c
0,24 mol CO
2
v 0,2 mol H
2
O. Mt khc, cho a gam hn hp X tc dng vi NaHCO
3
d thu c 3,136 lt CO
2

(ktc). Xc nh cng thc ca 2 axit.
A. CH
3
COOH v HOOC-CH
2
-COOH B. HCOOH v HOOC-COOH
C. HCOOH v HOOC-(CH
2
)
4
-COOH D. CH
3
COOH v HOOC-COOH
Cu 4:Hp cht hu c X c cng thc phn t C
3
H
9
O
2
N. Bit X tc dng vi NaOH v HCl. S cng thc cu to
tha mn lA. 4 B. 3 C. 1 D. 2
Cu 5: Cho s sau : C
4
H
7
ClO
2
+ NaOH mui X + Y + NaCl. Bit rng c X, Y u tc dng vi Cu(OH)
2
.
Vy cng thc cu to ca cht c cng thc phn t C
4
H
7
ClO
2
l :
A. Cl-CH
2
-COOCH=CH
2
B. CH
3
COO-CHCl-CH
3

C. HCOOCH
2
-CH
2
-CH
2
Cl D. HCOO-CH
2
-CHCl-CH
3

Cu 6:Cho phng trnh phn ng: FeS
2
+ Cu
2
S + HNO
3
0
t
Fe
2
(SO
4
)
3
+ CuSO
4
+ NO + H
2
O
Tng cc h s ca phng trnh vi cc s nguyn ti gin c lp theo phng trnh trn l:
A. 100 B. 108 C. 118 D. 150
Cu 7: Cho 8(g) bt Cu vo 200ml dung dch AgNO
3
, sau 1 thi gian phn ng lc c dung dch A v 9,52(g) cht
rn. Cho tip 8 (g) bt Pb vo dung dch A, phn ng xong lc tch c dung dch B ch cha 1 mui duy nht v
6,705(g) cht rn. Nng mol/l ca AgNO
3
ban u l:
A. 0,20M. B. 0,25M. C. 0,35M. D. 0,1M.
Cu 8: Oxi ha anehit X n chc bng O
2
(xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y
gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri
c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch
AgNO
3
trong NH
3
d, un nng th thu c khi lng Ag l
Cu 9: Cao su Buna-N c iu ch nh loi phn ng no sau y?
A. trng hp. B. trng ngng. C. cng hp. D. ng trng hp.
Cu 10: Ha tan Fe
3
O
4
trong lng d dung dch H
2
SO
4
long thu c dung dch X. Dung dch X tc dng c vi
bao nhiu cht trong s cc cht sau: Cu, NaOH, Br
2
, AgNO
3
, KMnO
4
, MgSO
4
, Mg(NO
3
)
2
, Al?
A. 5. B. 6. C. 4. D. 7.
Cu 11: Ha tan 2,8 gam BaCl
2
.4H
2
O vo nc thu c 500ml dung dch X. Ly 1/10 dung dch X em in phn
vi in cc tr (c mng ngn) trong 16 pht 5 giy vi cng dng in mt chiu bng 0,1A. Tnh %BaCl
2
b
in phn.A. 50%. B. 70%. C. 60%. D. 45%.
Cu 12: C bao nhiu nguyn t m trong cu hnh electron nguyn t c phn lp ngoi cng l 4s
2
?
A. 1. B. 9. C. 8. D. 3.
Cu 13: Chia 7,8 gam hn hp ancol etylic v ancol ng ng R-OH thnh 2 phn bng nhau. Phn 1 cho tc dng
vi Na d thu c 1,12 lt H
2
(ktc). Phn 2 tc dng vi dung dch cha 30 gam CH
3
COOH (c mt H
2
SO
4
c).
Tnh khi lng este thu c, bit hiu sut cc phn ng este ha u l 80%.
Cu 14: xc nh ru ca mt loi ancol etylic (k hiu l X) ngi ta ly 10 ml X cho tc dng ht vi Na d
thu c 2,564 lt H
2
(ktc). Tnh ru ca X bit khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml.
35
A. 92,5
o
. B. 87,5
o
. C. 91,0
o
. D. 85,7
o
.
Cu 15: Hn hp X gm 2 axit no. t chy hon ton a mol hn hp X thu c a mol H
2
O. Mt khc, cho a mol
hn hp X tc dng vi NaHCO
3
thu c 1,4 a mol CO
2
. % khi lng ca axit c khi lng mol nh hn trong X.
A. 26,4% B. 27,3% C. 43,4% D. 35,8%
Cu 16: Cho 4,6 gam ru X tc dng vi Na d thu c 1,12 lt H
2
. Cho 9,0 gam axit hu c Y tc dng vi Na d
thu c 1,68 lt H
2
. un nng hn hp gm 4,6 gam ru X v 9 gam axit Y ( xt H
2
SO
4
c,t
0
) thu c 6,6 gam
este E. t chy hon ton E thu c CO
2
v nc theo t l mol l 1: 1. Xc nh hiu sut phn ng to thnh este.
Cc kh o ktc. A. 50% B. 60% C. 75% D. 80%
Cu 17: Cho V lt kh NO
2
(ktc) hp th vo mt lng va dung dch NaOH, sau em c cn th thu c hn
hp cht rn khan cha 2 mui. Nung cht rn ny ti ch cn mt mui duy nht thy cn li 13,8 gam. Gi tr ca V
lA. 4,48 lt. B. 1,12 lt. C. 5,60 lt. D. 2,24 lt.
Cu 18: Cho m gam hn hp X gm Fe
2
O
3
, CuO, MgO, FeO v Fe
3
O
4
vo dung dch H
2
SO
4
c nng thu c 3,36
lt kh SO
2
(ktc). Mt khc nung m gam hn hp X vi kh CO d thu c cht rn Y v hn hp kh Z. Cho Z vo
dung dch Ca(OH)
2
d thu c 35 gam kt ta. Cho cht rn Y vo dung dch HNO
3
c, nng, d thu c V lt kh
NO
2
(ktc) l sn phm kh duy nht. Gi tr ca V l
A. 11,2. B. 22,4. C. 44,8. D. 33,6.
Cu 19: Cho cc trng hp sau:
(1) O
3
tc dng vi dung dch KI. (5) KClO
3
tc dng vi dung dch HCl c, un nng.
(2) Axit HF tc dng vi SiO
2
. (6) un nng dung dch bo ha gm NH
4
Cl v NaNO
2
.
(3) MnO
2
tc dng vi dung dch HCl c, un nng. (7) Cho kh NH
3
qua CuO nung nng.
(4) Kh SO
2
tc dng vi nc Cl
2
. S trng hp to ra n cht l
A. 6. B. 3. C. 4. D. 5.
Cu 20: Trong cc cht cho sau y: xenluloz, ct, canxi cacbua, ancol etylic, cao su, tinh bt, natri clorua, st kim
loi, oxi, du m; cht no l nguyn liu t nhin?
A. xenluloz, ancol etylic, tinh bt, natri clorua, oxi, du m.
B. xenluloz, ct, cao su, tinh bt, natri clorua, oxi, du m.
C. xenluloz, ct, canxi cacbua, tinh bt, st kim loi, oxi, du m.
D. xenluloz, cao su, ancol etylic, tinh bt, st kim loi, oxi, du m.
Cu 21: Chia hn hp X gm ancol etylic v axit axetic (trong s mol ancol nhiu hn s mol axit) thnh 2 phn
bng nhau. Phn 1 cho tc dng ht vi Na d thu c 5,6 lt H
2
(ktc). Phn 2 un nng vi mt t H
2
SO
4
c (chp
nhn phn ng este ha l hon ton) th thu c 8,8 gam este.
S mol ancol v axit trong X ln lt lA. 0,6 v 0,5. B. 0,2 v 0,3. C. 0,4 v 0,1. D. 0,8 v 0,2.
Cu 22: kim loi R htr khng i vo 100 ml dd HCl 1,5M c 2,24 lt H
2
(ktc) v dd X. Tnh m
kt ta
thu c
khi cho dd AgNO
3
d vo dd X.A. 21,525 g B. 26,925 g C. 24,225 g D. 27,325 g.
Cu 23: Cho cc dung dch khng mu: HCOOH, CH
3
COOH, glucoz, glixerol, C
2
H
5
OH, CH
3
CHO. Nu dng thuc
th l Cu(OH)
2
/OH
-
th nhn bit c ti a bao nhiu cht trong s cc cht trn?
A. 4. B. 3. C. 5. D. 6.
Cu 24:Hp cht E to t ion X
n+
v Y
-
. C X
n+
, Y
-
u c cu hnh e l 1s
2
2s
2
2p
6
.
So snh bn knh ca X, Y, X
n+
v Y
-
.
A. X
n+
< Y < Y
-
< X. B. X
n+
< Y < X < Y
-

C. X
n+
< Y
-
< Y < X. D. Y < Y
-
< X
n+
< X
Cu 25: Oxi ho 6 gam ru X bng oxi (xt Cu,t
0
) thu c 8,4 gam hn hp cht lng Y. Cho hn hp Y tc dng
vi Ag
2
O d trong NH
3
, un nng thu c ti a bao nhiu gam Ag ?
A. 16,2 g B. 32,4 g C. 64,8 g D. 54 g
Cu 26: X l dung dch AlCl
3
, Y l dung dch NaOH 2 M. Thm 150 ml dung dch Y vo cc cha 100ml dung dch
X, khuy u n phn ng hon ton thy trong cc c 7,8 gam kt ta. Thm tip vo cc 100 ml dung dch Y,
khuy u n phn ng hon ton thy trong cc c 10,92 gam kt ta. Nng mol/l ca dung dch X bng
A. 2,0 M. B. 3,2 M. C. 1,6 M. D. 1,0 M.
Cu 27: Cho 15,84 gam este no, n chc, mch h tc dng ht vi 30ml dung dch MOH 20% (d=1,2g/ml) vi M l
kim loi kim. Sau phn ng hon ton, c cn dung dch thu c cht rn X. t chy hon ton X thu c hn
hp kh v hi gm CO
2
, H
2
O v 9,54 gam M
2
CO
3
. Kim loi M v cng thc cu to ca este ban u l
A. Na v HCOO-C
2
H
5
. B. Na v CH
3
COOC
2
H
5
.
C. K v HCOO-CH
3
. D. K v CH
3
COOCH
3
.
Cu 28: Ha tan hon ton 12,9 gam hn hp Cu, Zn bng dung dch H
2
SO
4
c, nng thu c sn phm kh l
3,136 lt SO
2
(ktc) v 0,64 gam lu hunh. % khi lng mi kim loi trong hn hp ban u l
A. 50,15% Cu; 49,85% Zn. B. 49,61% Cu; 50,39% Zn.
C. 51,08% Cu; 48,92% Zn. D. 45,54% Cu; 54 46% Zn.
Cu 29: Hp cht X c vng benzen v c CTPT l C
x
H
y
N. Khi cho X tc dng vi HCl thu c mui Y c cng
thc dng RNH
2
Cl. Trong cc phn t X, % khi lng ca N l 11,57%; Hy cho bit X c bao nhiu cng thc cu
to?A. 32 B. 18 C. 5 D. 34
Cu 30: Cho cc cht sau y phn ng vi nhau:
36
(1) CH
3
COONa + CO
2
+ H
2
O; (2) (CH
3
COO)
2
Ca + Na
2
CO
3
; (3) CH
3
COOH + NaHSO
4
;
(4) CH
3
COOH + CaCO
3
; (5) C
17
H
35
COONa + Ca(HCO
3
)
2
; (6) C
6
H
5
ONa + CO
2
+ H
2
O;
(7) CH
3
COONH
4
+ Ca(OH)
2
. Cc phn ng khng xy ra l
A. 1, 3. B. 1, 3, 5. C. 1, 3, 4. D. 1, 3, 6.
Cu 31: : Cho dung dch KOH d vo dung dch FeCl
2
thu c 13,5 g kt ta. Nu thay dung dch KOH bng dung
dch AgNO
3
d th thu c bao nhiu g kt ta ?A. 43,05 g B. 59,25 g C. 53,85 g D. 48,45 g.
Cu 32: Cho 500ml dung dch FeCl
2
1M tc dng vi 200 ml dung dch KMnO
4
1M c axit ha bng dung dch
H
2
SO
4
long d. Khi phn ng xy ra hon ton thu c dung dch Y v V lt kh iu kin tiu chun. Gi s Clo
khng phn ng vi nc.Gi tr ca V l A. 11,2. B. 5,6. C. 14,93. D. 33,6.
Cu 33: Cho bit phn ng no sau y khng xy ra nhit thng?
A. Ca(OH)
2
+ 2NH
4
Cl CaCl
2
+ 2H
2
O + 2NH
3 |
.
B. Mg(HCO
3
)
2
+ 2Ca(OH)
2
Mg(OH)
2 +
+ 2CaCO
3 +
+ 2H
2
O.
C. CaCl
2
+ 2 NaHCO
3
CaCO
3 +
+ 2NaCl + 2HCl.
D. Ca(HCO
3
)
2
+ Ca(OH)
2
2CaCO
3 +
+ 2H
2
O.
Cu 34: ng vi cng thc phn t C
3
H
6
O
2
c bao nhiu ng phn mch h c th tc dng c vi Na v bao
nhiu ng phn mch h khng th tc dng c vi Na?
A. 2 v 5. B. 3 v 4. C. 4 v 3. D. 5 v 2.
Cu 35: Mt hn hp gm ankaien X v O
2
ly d (O
2
chim 90% th tch) c np y vo mt bnh kn
p sut 2 atm. Bt tia la in t chy ht X ri a bnh v nhit ban u cho hi nc ngng t ht th p sut
gim 0,5 atm. Cng thc phn t ca X lA. C
4
H
6
. B. C
5
H
8
. C. C
3
H
4
. D. C
6
H
10
.
Cu 36: X l mt -amino axit cha 1 nhm COOH v 1 nhm NH
2
. Cho 8,9 gam X tc dng vi 200 ml dung
dch HCl 1 M thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn dng 300 ml dung dch
NaOH 1 M. Cng thc ng ca X l;
A. CH
3
C(CH
3
)(NH
2
)COOH. B. CH
3
CH(NH
2
)COOH.
C. CH
3
CH(CH
3
)CH(NH
2
)COOH. D. CH
3
CH
2
CH(NH
2
)COOH.
Cu 37: un 20,4 gam mt cht hu c X n chc vi 300 ml dung dch NaOH 1 M thu c mui Y v hp cht
hu c Z n chc. Cho Z tc dng vi Na d thu c 2,24 lt kh H
2
(ktc). Oxi ha Z thu c hp cht Z khng
phn ng vi dung dch AgNO
3
/NH
3
. Nung Y vi NaOH rn thu c kh T c t khi hi so vi O
2
l 0,5. Cng thc
cu to ca X l
A. CH
3
COOCH(CH
3
)
2
.B. CH
3
COOCH
2
CH
2
CH
3
.C. CH
3
COOCH(CH
3
)CH
2
CH
3
. D. C
2
H
5
COOCH(CH
3
)
2
.
Cu 38: Cho phn ng ha hc sau: aMgO + bP
2
O
5
(X)
Bit rng trong (X) Mg chim 21,62% v khi lng v cng thc phn t trng vi cng thc n gin nht. Cng
thc phn t ca X lA. Mg
2
P
2
O
7
. B. Mg
3
(PO
3
)
2
. C. Mg
2
P
4
O
7
. D. Mg
3
(PO
4
)
2
.
Cu 39: Cho phng trnh phn ng: X + H
2
SO
4
Fe
2
(SO
4
)
3
+ SO
2
+ H
2
O
C th c bao nhiu hp cht l X cha 2 nguyn t ?
A. 2 B. 3 C. 4 D. 5
Cu 40: Dung dch X cha 0,025 mol CO
2
3
; 0,1 mol Na
+
; 0,3 mol Cl
-
, cn li l ion NH
+
4
. Cho 270 ml dung dch
Ba(OH)
2
0,2 M vo dung dch X v un nng nh. Hi tng khi lng dung dch X v dung dch Ba(OH)
2
gim bao
nhiu gam? Gi s nc bay hi khng ng k.
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (phn A hoc B)
A.Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Trn 19,2 gam Fe
2
O
3
vi 5,4 gam Al ri tin hnh phn ng nhit nhm (khng c mt khng kh v ch xy
ra phn ng kh Fe
2
O
3
thnh Fe). Hn hp sau phn ng (sau khi lm ngui) tc dng hon ton vi dung dch HCl
d thu c 5,04 lt kh (ktc). Hiu sut phn ng nhit nhm l
A. 75%. B. 57,5%. C. 60%. D. 62,5%.
Cu 42: Mt hn hp X gm CH
3
OH, CH
2
=CHCH
2
OH, CH
3
CH
2
OH, C
3
H
5
(OH)
3
.Cho 25,4 gam hn hp X tc dng
vi Na d thu c 5,6 lt H
2
(ktc). Mt khc em t chy hon ton 25,4 gam hn hp X thu c m gam CO
2
v
27 gam H
2
O. Gi tr ca m lA. 61,6 gam. B. 52,8 gam. C. 44 gam. D. 55 gam.
Cu 43: x phng ha 10 kg cht bo (RCOO)
3
C
3
H
5
ngi ta un cht bo vi dung dch cha 1,37 kg NaOH.
Lng NaOH d c trung ha bi 500 ml dung dch HCl 1 M. Khi lng glixerol v x phng nguyn cht thu
c ln lt l
A. 1,035 kg v 11,225 kg. B. 1,050 kg v 10,315 kg.C. 1,035 kg v 10,315 kg. D. 1,050 kg v 11,225 kg.
Cu 44:Cho 200ml dung dch A cha CuSO
4
(d = 1,25g/ml). Sau khi in phn A, khi lng ca dung dch gim i
8(g). Mt khc, lm kt ta ht lng CuSO
4
cn li cha b in phn phi dng ht 1,12(lt) H
2
S ( ktc). Nng
C% ca dung dch CuSO
4
trc khi in phn l:
A. 9,6% B. 50% C. 20% D. 30%
37
Cu 45: Xenluloz iaxetat c dng sn xut phim nh hoc t axetat. Cng thc n gin nht ca xenluloz
iaxetat lA. C
10
H
13
O
5
. B. C
12
H
14
O
7
. C. C
10
H
14
O
7
. D. C
12
H
14
O
5
.
Cu 46: Hy chn cc pht biu ng v phenol (C
6
H
5
OH) trong cc pht biu sau:
(1) phenol c tnh axit nhng yu hn axit cacbonic; (2) dung dch phenol lm i mu qu tm sang ;
(3) phenol c tnh axit mnh hn etanol; (4) phenol tan tt trong nc lnh do to c lin kt hiro vi nc;
(5) axit picric (2, 4, 6 trinitrophenol) c tnh axt mnh hn phenol;
(6) phenol tan tt trong dung dch NaOH;
A. 1, 2, 3, 6. B. 1, 2, 4, 6. C. 1, 3, 5, 6. D. 1, 2, 5, 6.
Cu 47:Cho phng trnh phn ng: Fe (NO
3
)
2
+ H
2
SO
4
Fe
2
(SO
4
)
3
+ HNO
3
+ NO + H
2
O
Tng cc h s ca phng trnh vi cc s nguyn ti gin c lp theo phng trnh trn l:
A. 40 B. 42 C . 34 D. 36
Cu 48: C 6 gi bt mu en CuO, MnO
2
, Ag
2
O, CuS, FeS, PbS. Nu ch c dung dch HCl c th nhn bit c
bao nhiu gi bt? A. 6. B. 3. C. 4. D. 5.
Cu 49 X c cng thc phn t l C
9
H
12
O. X tc dng vi NaOH. X tc dng vi dd brom cho kt ta Y c cng thc
phn t l C
9
H
9
OBr
3
. Hy cho bit X c bao nhiu cng thc cu to tha mn ?
A. 3 B. 2 C. 4 D. 5
Cu 50: Tng s ht mang in trong anion XY
2
3
bng 82. S ht proton trong ht nhn X nhiu hn s ht proton
trong ht nhn Y l 8 ht. S hiu nguyn t ca X, Y ln lt l
A. 14, 8. B. 15, 7. C. 16, 8. D. 17, 9.
B.Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51:Khi x phng ha hon ton 1,26 g mt cht bo cn 45 ml dung dch KOH 0,1M. Ch s x phng ha ca
cht bo lA. 300 B. 150 C. 200 D. 250
Cu 52:Cho th in cc chun ca cc kim loi: E
0
Ni
2+
/Ni = - 0,26V; E
0
Cu
2+
/Cu = + 0,34V
Gi tr sut in ng chun E
0
ca pin in ha Ni-Cu l:
A. + 0,08V B. +0,60V C. 0,08V D. 0,60V
Cu 53: Cho este X c cng thc phn t C
4
H
6
O
2
phn ng vi NaOH theo s sau:
X + NaOH mui Y + anehit Z
Cho bit phn t khi ca Y nh hn 70. Cng thc cu to ng ca X l
A. CH
3
COOCH=CH
2
.B. HCOOCH=CHCH
3
.C. HCOOCH
2
CH =CH
2
. D. CH
2
=CHCOOCH
3
.
Cu 54:Nguyn t Urani ( Z= 92) c cu hnh e nh sau: U [Rn] 5f
3
6d
1
7s
2
. Vi Rn l mt kh him c cu to lp v
bn vng v cc e u ghp i. trng thi c bn Urani c bao nhiu e c thn?
A. 4 B. 5 C. 6 D. 3
Cu 55: Cho 0,1 mol cht X c cng thc phn t l C
2
H
8
O
3
N
2
(M = 108) tc dng vi dung dch cha 0,2 mol NaOH
un nng thu c kh X lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam cht rn
khan. Gi tr ca m lA. 5,7 gam. B. 12,5 gam. C. 15 gam. D. 21,8 gam.
Cu 56: Cht no sau y c nhit nng chy cao nht?
A. CH
3
CH
2
CH(NH
2
)-COOH B. CH
3
CH(NH
2
)-COOCH
3

C. H
2
N-CH
2
-COOC
2
H
5
D.CH
3
COOCH
2
CH
2
CH
2
NH
2

Cu 57: Phn ng gia glucoz v CH
3
OH/HCl un nng thu c sn phm l:
A.
O
OH
OCH
3
OH
OH
CH
2
OH
B.
O
OCH
3
OH
OH
OH
HOH
2
C
C.
O
OH
OH
OH
OCH
3
CH
2
OH
D.
O
OH
OH
OH
OH
CH
2
OCH
3

Cu 58: Cho cc polime sau : cao su buna ; polistiren ; amiloz ; amilopectin ; xenluloz ; t capron ; nha bakelt .
C bao nhiu polime c cu trc mch thng ?
A. 4 B. 5 C. 6 D. 7
Cu 59:K
2
S H
2
S S SO
2
H
2
SO
4
H
2
S . trong s trn, c ti a my phn ng oxi ha-kh?
A. 6 B. 8 C. 9 D. 10
Cu 60:Sc kh H
2
S cho ti d vo 100 ml dung dch hn hp gm FeCl
3
0,2M v CuCl
2
0,2M; phn ng xong thu
c a gam kt ta. Gi tr ca a l:
A. 3,68 gam. B. 4 gam. C. 2,24 gam. D. 1,92 gam.
----------- HT ----------
Th sinh khng c s dng Bng tun hon

38

TRNG THPT VIT YN 2

K THI TH I HC- CAO NG LN 7
Thi gian lm bi: 90 pht;
S cu trc nghim: 50 cu
CHNH THC

M thi 890
Cho bit nguyn t khi : H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Br = 80; P = 31; Na = 23; Mg = 24; Al
= 27; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207; Ni = 59.
I. Phn chung cho tt c th sinh : (40 cu, t cu 1 n cu 40)
Cu 1: Cc cht X, Y, Z c cng CTPT C
2
H
x
O
2
N. X tc dng c c vi HCl v Na
2
O. Y tc dng c vi nguyn
t hydro mi sinh to ra Y
1
. Y
1
tc dng vi H
2
SO
4
to ra mui Y
2
. Y
2
tc dng vi NaOH ti to li Y
1
. Z tc dng
vi NaOH to ra mt mui v kh NH
3
. CTCT ng ca X, Y, Z ln lt l :
A. X (CH
2
NH
2
COOH), Y (CH
3
CH
2
NO
2
), Z (CH
3
COONH
4
)
B. X (CH
3
COONH
4
), Y (HCOOCH
2
NH
2
), Z (CH
2
NH
2
COOH)
C. X (HCOOCH
2
NH
2
), Y (CH
3
COONH
4
), Z (CH
2
NH
2
COOH)
D. X (CH
3
COONH
4
), Y (CH
2
NH
2
COOH), Z (HCOOCH
2
NH
2
)
Cu 2: Nung nng tng cp cht trong bnh kn: (1) Fe + S (r), (2) Fe
2
O
3
+ CO (k), (3) Au + O
2
(k), (4) Cu +
Zn(NO
3
)
2
(r), (5) Cu + KNO
3
(r) , (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l :
A. (2), (3), (4) B. (2), (5), (6) C. (1), (4), (5) D. (1), (3), (6)
Cu 3: Khi thy phn mt octapetit X mch h, c cng thc cu to l Gly-Phe-Tyr-Lys-Gly-Phe-Tyr-Ala th thu
c bao nhiu tripeptit c cha Gly?
A. 4. B. 3. C. 5. D. 6.
Cu 4: Dng thuc th no sau y phn bit cc hidrocacbon thm: benzen, toluen v stiren ?
A. Dung dch HNO
3
B. Brom khan C. Dung dch brom D. Dung dch KMnO
4

Cu 5: Phn ng no sau y chng t Fe
2+
c tnh kh yu hn so vi Cu. :
A. Fe+Cu
2+
Fe
2+
+Cu B. 2Fe
3+
+Cu 2Fe
2+
+Cu
2+

C. Fe
2+
+Cu Cu
2+
+Fe D. Cu
2+
+2Fe
2+
2Fe
3+
+Cu
Cu 6: t chy hon ton m gam hn hp X gm hai ancol ng ng k tip, cho sn phm chy qua bnh cha
dung dch Ca(OH)
2
d thy khi lng bnh tng 19,1 gam v c 25 gam kt ta. Nu oxi ha ht m gam X bng CuO
d, ly sn phm thu c cho tc dng vi dung dch AgNO
3
/ NH
3
d, un nng c x gam Ag. Tnh gi tr ca x?
( hiu sut phn ng 100%)
A. 64,8g B. 86,4g C. 75,6g D. 43,2g
Cu 7: Ha tan m gam Fe
3
O
4
trong 425 ml dung dch HCl 2,0 M , sc mt lng xi vo dung dch thu c, nhn
c mt dung dch X. X lm mt mu 100 ml dung dch Br
2
0,25 M. Gi tr ca m :
A. 11,6 g B. 46,4 g C. 32,8 g D. 23,2 g
Cu 8: Cho dung dch Ba(HCO
3
)
2
ln lt vo cc dung dch: CaCl
2
, Ca(NO
3
)
2
, NaOH, Na
2
CO
3
, KHSO
4
, Na
2
SO
4
,
Ca(OH)
2
, H
2
SO
4
, HCl. S trng hp c to ra kt ta l
A. 5. B. 4. C. 7. D. 6.
Cu 9: Thi t t n d kh X vo dung dch Ba(OH)
2
thy c kt ta, sau kt ta tan. Kh X c th l:
A. SO
2
hay H
2
S B. H
2
S hay NO
2
C. CO
2
hay SO
2
D. CO
2
hay NO
2

Cu 10: Vi cc cht: butan, buta-1,3-dien, propilen, but-2-in, axetilen, metylaxetilen, isobutan, xiclopropan,
isobutilen , anlen. Chn pht biu ng v cc cht trn:
A. C 8 cht lm mt mu nc brom.
B. C 3 cht tc dng dung dch AgNO
3
/NH
3
to kt ta mu vng nht.
C. C 8 cht lm mt mu tm ca dung dch KMnO
4

D. C 7 cht tham gia phn ng cng hidro.
Cu 11: Cho x mol Fe tan ht trong dung dch cha y mol HNO
3
( t l x : y = 16 : 61) ta thu c mt sn phm kh
Y duy nht v dung dch Z ch cha mui st. S mol electron m x mol Fe nhng khi tham gia phn ng l :
A. 0,75y mol B. y mol C. 2x mol D. 3x mol
Cu 12: Dy cc gm cc polime tng hp l:
A. Polipropilen; poli(vinylclorua); visco; nilon-6. B. Polietilen; polistiren; nilon-6; poli(vinylclorua).
C. Poli(vinyl clorua); polietilen; t axetat; polistiren. D. Nilon-6; polietilen; protin; polistiren.
Cu 13: Ha tan m gam hh X gm CuCl
2
v FeCl
3
trong nc c dung dch Y . Chia Y 2 phn bng nhau. Phn 1 :
cho kh H
2
S d vo c 1,28 g kt ta. Phn 2 : cho Na
2
S d vo c 3,04 g kt ta. Gi tr ca m l :
A. 10,2 g B. 9,2 g C. 8,4 g D. 14,6 g
Cu 14: X l dung dch AlCl
3
Y l dung dch NaOH 2M .Cho 150ml dung dch Y vo cc cha 100 ml dung dch X,
khuy u n khi phn ng hon ton thy trong cc c 7,8 g kt ta. Nu thm tip vo cc 100 ml dung dch Y kt
thc phn ng c 10,92 g kt ta. Nng mol ca dung dch X l :
A. 1,0 M B. 3,2 M C. 1,6 M D. 2,0 M
Cu 15: Cho 1,54 g hn hp gm HCOOH ; C
6
H
5
OH ; HOOC-COOH tc dng vi 0,6 g Na, sinh ra 224 ml kh H
2

(ktc). Khi lng hn hp mui thu c sau phn ng l:
39
A. 1,632g B. 2,12g C. 1,98g D. 1,83g
Cu 16: Phn ng in phn dung dch CuCl
2
(vi in cc tr) v phn ng n mn in ha xy ra khi nhng hp
kim Fe-Cu vo dung dch H
2
SO
4
long, c c im l:
A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi.
B. Phn ng cc dng u l s oxi ha Cl
-
.
C. Phn ng xy ra lun km theo s pht sinh dng in.
D. u sinh ra Cu cc m.
Cu 17: Cht hu c M c mt nhm amino, mt chc este. Hm lng oxi trong M l 35,96 %. X phng ha a gam
cht M c ancol. Cho ton b hi ancol i qua CuO d, t
o
thu andehit Z. Cho Z phn ng vi dung dch
AgNO
3
/NH
3
d, thu c 16,2 gam Ag. Gi tr ca a l: ( hiu sut phn ng 100%)
Cu 18: Nhng cht no sau y va l mt mu dung dch brom, va lm mt mu dung dch thuc tm (nhit
thng hoc khi un nng): pentan, xiclopropan, butaien, toluen, ancol alylic, anehit axetic.
A. butaien, toluen, ancol alylic. B. xiclopropan, butaien, toluen.
C. xiclopropan, butaien, ancol alylic. D. butaien, ancol alylic, anehit axetic.
Cu 19: Hn hp kh M gm Cl
2
v O
2
. M phn ng va ht vi mt hn hp Y gm 4,32g Mg v 7,29g Al sau khi
phn ng hon ton c 33,345g hn hp cc mui v oxit. Tnh % th tch kh O
2
trong hn hp M :
A. 33,33% B. 45,87% C. 78,98% D. 44,44%
Cu 20: Ha tan hon tan m gam hn hp X gm Mg v Al trong dung dch HCl thu c 2,688 lt kh . Cng cho
lng hn hp X trn vo dung dch HNO
3
d,un nng, sau phn ng c 537,6 ml mt cht kh Y l sn phm kh
duy nht (th tch kh o ktc). Cng thc phn t ca Y l :
A. N
2
B. NO
2
C. NO D. N
2
O
Cu 21: Cho Fe
3
O
4
vo dung dch H
2
SO
4
long d thu c dung dch X. Hy cho bit trong cc ha cht sau:
KMnO
4
, Cl
2
, NaOH, CuSO
4
, Cu, KNO
3
, KI, th dung dch X tc dng c vi bao nhiu cht ?
A. 4 B. 6 C. 7 D. 5
Cu 22: Thu phn triglixerit X trong NaOH ngi ta thu c hn hp hai mui gm natrioleat v natristearat theo
t l mol ln lt l: 1 : 2. Khi t chy a mol X thu c b mol CO
2
v c mol H
2
O. Lin h gia a, b, c l:
A. b-c =4a B. b-c =2a C. b-c =3a D. b= c-a
Cu 23: Cu hnh electron cc nguyn t ca cc nguyn t X, Y, Z, T ln lt l : [Ne]3s
2
3p
5
; [Ar]3d
10
4s
2
4p
4
;
[He]2s
2
2p
5
; [Ne]3s
2
3p
4
. Th t tng dn tnh phi kim ca cc nguyn t tng dn t tri sang phi l :
A. Y, T, Z, X B. T, Y, X, Z C. Y , X, T, Z D. X, Y, Z ,T
Cu 24: Dy gm cc cht, ion va c tnh oxi ha va c tnh kh l :
A. O
3
, Fe
2+
, FeCl
2
, CrO
3
B. NO
2
, Fe
2+,
Cl
2
, FeCl
3
, SO
2
3

C. FeO, H
2
S, Cu, HNO
3
D. HCl, Na
2
S, NO
2
, Fe
3+

Cu 25: ha tan ht mt ming km trong dung dch axit clohidric 20
0
C cn 27 pht. Nt thc hin th nghim
40
0
C th thi gian phn ng l 3 pht. Nu thc hin th nghim 55
0
C th thi gian phn ng l:
A. 37,64 giy B. 44,36 giy C. 44,08 giy D. 34,64 giy
Cu 26: Cho s phn ng sau:
0
2 2
0
H d O ,xt CuO,t
Ni ,t
X Y Z ax i t i sobut i ri c .
Bit X, Y, Z l cc hp cht hu c khc nhau v X cha no. Cng thc cu to ca X l cht no sau y?
A. (CH
3
)
3
CCHO.B. CH
3
-H(CH
3
)CH
2
OH.C. (CH
3
)
2
C=CHCHO. D. CH
2
=C(CH
3
)CHO.
Cu 27: Cho 4,48 lt kh CO
2
(ktc) vo 200 ml dung dch X gm Na
2
CO
3
1,0 M v KOH 1,5 M. Sau khi phn ng
hon ton c dung dch Y. Cho dung dch Ba(NO
3
)
2
d vo Y c m gam kt ta. Tnh m ?
A. 98,50 g B. 59,10 g C. 78,80 g D. 68,95 g
Cu 28: t chy hon ton mt amin no, h, bc mt X bng oxi va , sau phn ng c hn hp Y gm kh v
hi,trong V
2
CO
: V
2
H O
= 1 : 2 . Cho 1,8g X tc dng vi dung dch HCl d. Sau phn ng lm bay hi dung dch
c m gam mui khan.Gi tr ca m l :
A. 3,99g B. 5,085g C. 3,26g D. 2,895g
Cu 29: Hn hp X gm CH
2
=CH-CH
2
OH v CH
3
CH
2
OH. Cho a gam hn hp X tc dng vi Na thu c 2,24 lt
H
2
(ktc). Mt khc, a gam hn hp X lm mt mu va ht 100 gam dung dch Br
2
20%. Vy gi tr ca a tng ng
l:A. 12,7 gam B. 11,7 gam C. 9,7 gam D. 10,7 gam
Cu 30: Cho mt hn hp X cha NH
3
, C
6
H
5
NH
2
v C
6
H
5
OH. Hn hp X tc dng va vi 0,02 mol NaOH hoc
0,01 mol HCl. Nu cho hn hp phn ng ht vi Br
2
th cn

va vi 0,075 mol Br
2
. Lng cc cht NH
3
,

C
6
H
5
NH
2

v C
6
H
5
OH trong hn hp X ln lt l
A. 0,005 mol; 0,005 mol v 0,02 mol. B. 0,01 mol; 0,005 mol v 0,02 mol.
C. 0,005 mol; 0,02 mol v 0,005 mol. D. 0,01 mol; 0,05 mol v 0,02 mol.
Cu 31: Hn hp X gm hai este no, n chc, mch h hn nhau mt nhm metylen (CH
2
). t chy hon ton 0,01
mol X c 1,008 lt kh CO
2
(ktc). un 19,2g X vi 270 ml dung dch NaOH 1,0 M, sau phn ng c cn dung dch
thu c 19,2g cht rn. Cng thc cu to hai este l :
40
A. CH
3
COOC
2
H
5
; C
2
H
5
COOC
2
H
5
B. H-COOC
3
H
7
; CH
3
COOC
3
H
7

C. CH
3
COOC
2
H
5
; CH
3
COOC
3
H
7
D. C
2
H
5
COOC
2
H
5
; C
2
H
5
COOC
2
H
5

Cu 32: Cho phng trnh ha hc ca cc phn ng sau : (1) Cr
2
O
3
+ NaNO
3

0
t
....
(2) (NH
4
)
2
Cr
2
O
7

0
t
..... (3) NH
4
Cl (bh) + NaNO
2
(bh)
0
t
.....
(4) AgNO
3

0
t
..... (5) CuO + NH
3
(kh)
0
t
...........
(6) Cu(NO
3
)
2

0
t
..... (7) CrO
3
+ NH
3
(kh)
0
t
.........
C bao nhiu phn ng sn phm sinh ra cho kh N
2
?
A. 5 B. 6 C. 4 D. 3
Cu 33: Ho tan hon ton a gam hn hp : NaI v NaBr vo nc thu c dung dch X. Cho Br
2
d vo X c
dung dch Y. C cn Y thu c b gam cht rn khan. Tip tc ho tan b gam cht rn khan trn vo nc c dung
dch Z. Cho Cl
2
d vo Z c dung dch T. C cn T thu c c gam cht rn khan. Bit cc phn ng xy ra hon
ton v 2b = a + c. Phn trm khi lng ca NaBr trong hn hp ban u l:
A. 7,3% B. 4,5% C. 3,7% D. 6,7%
Cu 34: C 5 dung dch ring bit: HCl, CuSO
4
, Fe
2
(SO
4
)
3
, HCl c ln CuSO
4
, AgNO
3
. Nhng vo mi dung dch
mt thanh Fe nguyn cht. S trng hp xut hin n mn in ha l:
A. 4 B. 1 C. 2 D. 3
Cu 35: un este E (C
6
H
12
O
2
) vi dung dch NaOH ta c mt ancol X. X khng b oxi ho bi CuO. E c tn l:
A. tert-butyl axetat.B. n-butyl axetatC. isopropyl axetat D. isopropyl propionat
Cu 36: Cc cht kh sau: SO
2
, NO
2
, Cl
2
, N
2
O, CO
2
.Cc cht kh khi tc dng vi dung dch NaOH ( nhit
thng) lun to ra 2 mui l:
A. NO
2
, SO
2
, CO
2
B. Cl
2
, NO
2
C. SO
2
, CO
2
D. CO
2
, Cl
2
, N
2
O
Cu 37: Hn hp X gm glucoz v tinh bt c chia i. Phn th nht c khuy trong nc, lc v cho nc
lc phn ng vi dung dch AgNO
3
(d)/NH
3
thy tch ra 2,16 gam Ag. Phn th hai c un nng vi dung dch
H
2
SO
4
long, trung ho hn hp thu c bng dung dch NaOH ri cho sn phm tc dng vi dung dch
AgNO
3
(d)/NH
3
thy tch ra 6,48 gam Ag. Gi s cc phn ng hon ton. Tnh % khi lng ca glucoz v tinh bt
trong X ?A. 64,29% ; 35,71% B. 35,29% ; 64,71% C. 35,71% ; 64,29% D. 64,71% ; 35,29%
Cu 38: Tng s ht electron trong cc ion : HXY
2
3
v XY
2
4
ln lt l : 42 v 50. Hai nguyn t X, Y ln lt l :

A. P, O B. N, P C. S, O D. Si, O
Cu 39: Cho 8,4 gam Fe vo dung dch HNO
3
long. Sau khi phn ng xy ra hon ton thu c 2,688 lt NO (sn
phm kh duy nht, ktc) v dung dch X. Khi lng Fe(NO
3
)
3
trong dung dch X l :
Cu 40: C cc pht biu sau:
(1) Lu hunh, photpho, C
2
H
5
OH u bc chy khi tip xc vi CrO
3
.
(2) Ion Fe
3+
c cu hnh electron vit gn l [Ar]3d
5
.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O.
Cc pht biu ng l:
A. (1), (2), (4) B. (2), (3), (4). C. (1), (3), (4). D. (1), (2), (3).
II. Phn ring : Th sinh ch c lm mt trong hai phn (phn I hay phn II)
Phn I : Theo chng trnh chun : ( 10 cu, t cu 41 n cu 50 )
Cu 41: Trong mt loi nc thi c cha hm lng cao cc ion Hg
2+
, Pb
2+
, Fe
3+
, Cu
2+
, Zn
2+
, Al
3+
. loi b lng
ln cc ion trn cn dng ha cht thch hp no sau y ?
A. NH
3
B. Ca(OH)
2
C. NaOH D. KOH
Cu 42: Cho cc cht tham gia phn ng :
1. S + F
2

0
t
. 2. SO
2
+ H
2
S (d) 3. SO
2
+ O
2
(d)
0
, t xt

4. S + H
2
SO
4
(c, nng) 5. H
2
S + Cl
2
(d) +H
2
O 6. S + CrO
3
.
S phn ng trong S b oxi ha ln mc oxi ha +6 l :
A. 5 B. 3 C. 4 D. 2
Cu 43: Cho 0,15 mol hn hp X gm hai aminoaxit : R(NH
2
)(COOH)
2
v R(NH
2
)
2
(COOH) vo 200 ml dung dch
HCl 1,0 M, thu c dung dch Y. Y tc dng va ht vi 400 ml dung dch NaOH 1,0 M. S mol ca
R(NH
2
)(COOH)
2
trong 0,15 mol X l :A. 0,1 mol B. 0,125 mol . C. 0,075 mol D. 0,05 mol
Cu 44: in phn 200 ml dung dch gm AgNO
3
0,1M v Cu(NO
3
)
2
0,2 M vi in cc tr, cng dng in I =
5 A, trong thi gian 19 pht 18 giy. Khi lng dung dch sau in phn gim m gam. Tnh m, bit hiu sut in
phn 80 % , b qua s bay hi ca nc.A. 3,92g B. 3,056 g C. 6,76g D. 3,44g
Cu 45: Trong cc polime sau : (1) poli(metyl metacrylat) ; (2) t capron ; (3) nilon 6,6 ; (4) poli(etylen-terephtalat) ;
(5) poli(vinylclorua) ; (6) poli(vinyl axetat). Cc polime c th tng hp bng phn ng trng hp l :
A. (1), (2) , (4), (6) B. (2), (3), (4) . C. (1), (2), (3), (5) D. (1), (2) ,(5), (6)
41
Cu 46: t chy hon ton mt lng hn hp kh X gm mt ankan v mt anken cn dng va 0,7 mol O
2
, thu
c 0,4 mol CO
2
. Cng thc ca ankan l :A. CH
4
. B. C
2
H
6
C. C
3
H
8
D. C
4
H
10

Cu 47: Mt hp cht X l dn xut ca benzen trong phn t c 4 lin kt . t chy hon ton a mol X sau phn
ng c s mol CO
2
b hn 8,2a mol. Mt khc a mol X tc dng va a mol NaOH. Cho 1 mol X tc dng vi Na
d sau phn ng c 1 mol kh H
2
. Cng thc cu to ph hp ca X l :
A. HOCH
2
C
6
H
4
CHOB. HOCH
2
C
6
H
4
COOHC. C
6
H
4
(OH)
2
D. HOC
6
H
4
COOH
Cu 48: Hn hp X gm andehyt Y, axit cacboxylic Z, este T. t chy hon ton 0,2 mol X cn 0,625 mol O
2
, thu
c 0,525 mol CO
2
v 0,525 mol nc. Cho Y trong 0,2 mol X tc dng vi dung dch AgNO
3
d trong NH
3
, un
nng sau phn ng c m gam Ag ( hiu sut phn ng 100%). Gi tr ln nht ca m l:
A. 32,4g B. 10,8g C. 16,2g D. 21,6g
Cu 49: Phn ng no sau y khng ng?
A. p-Cl-C
6
H
4
-CH=CH-CH
2
Cl + NaOH (long)
0
t
p-Cl-C
6
H
4
CH=CH-CH
2
OH + NaCl
B. CH
3
CH=CHCHO + Br
2
+ H
2
O CH
3
CH=CHCOOH + 2HBr
C. 3CH
2
=CH-CH
2
OH + 2KMnO
4
+ 4H
2
O 3CH
2
OH-CHOH-CH
2
OH + 2KOH + 2MnO
2

D. CH
2
=CH-CH
2
Cl + H
2
O
0
t
CH
2
=CH-CH
2
OH + HCl
Cu 50: Phn ng no sau y khng ng ?
A. 2CrO
3
+ 2NH
3
0
t
Cr
2
O
3
+ N
2
+ 43H
2
O B. (NH
4
)
2
Cr
2
O
7

0
t
Cr
2
O
3
+ N
2
+ 4H
2
O
C. Fe
2
O
3
+ 6HI 2FeI
3
+ 3 H
2
O D. 3CuO + 2 NH
3

0
t
3Cu + N
2
+ 3 H
2
O
Phn II : Theo chng trnh nng cao : ( 10 cu, t cu 51 n cu 60 )
Cu 51: Ba cht hu c mch h : X, Y, Z c cng cng thc phn t C
3
H
6
O v c cc tnh cht sau:
-X, Y u phn ng vi dung dch brom trong nc
-Z ch tc dng vi brom khi c mt CH
3
COOH.
-X c nhit si cao hn Z. Cc cht X, Y, Z ln lt l :
A. CH
2
=CH-O-CH
3
, CH
3
COCH
3
, CH
3
CH
2
CHO B. CH
3
CH
2
CH
2
OH, CH
2
=CH-O-CH
3
, CH
3
CH
2
CHO
C. CH
2
=CHCH
2
OH, CH
3
CH
2
CHO, CH
3
OCH
3
D. CH
3
CH
2
CH
2
OH, CH
3
COCH
3
, CH
3
CH
2
CHO
Cu 52: t chy hon ton 0,25 mol hn hp X gm aminoaxit H
2
NR(COOH)
x
v mt axit no, h ,n chc, thu
c 0,6 mol CO
2
v 0,675 mol nc. Mt khc, 0,2 mol X phn ng va vi dung dch cha a mol HCl. Gi tr
ca a l :A. 0,2 mol B. 0,25 mol C. 0,12 mol D. 0,1 mol
Cu 53: Cho cn bng sau : N
2
+ 3H
2

0
, , t P xt
2NH
3
, H= -92,0 KJ.
Nu nng mol cc kh N
2
, H
2
gim 3 ln th ti cn bng mi nng mol ca NH
3
s bin i bao nhiu ln ?
A. Tng 3 ln B. Gim 9 ln C. Tng 27 ln D. Gim 3 ln
2 4
KI+H SO Zn NaOH
2 2 7
K Cr O X Y Z . Cc cht X, Y, Z ln lt l :
A. Cr
2
(SO
4
)
3
, CrSO
4
,Cr(OH)
2
B. CrI
3
, CrI
2
, Na[Cr(OH)
4
]
C. Cr
2
(SO
4
)
3
, CrSO
4
, Na[Cr(OH)
4
] D. Cr
2
(SO
4
)
3
, CrSO
4
,Cr(OH)
3

Cu 55: Cho cc cht sau: ietylete, vinyl axetat, saccarozo, tinh bt, vinyl clorua, nilon-6,6. S cht trong dy b thy
phn trong mi trng kim lang l :A. 5 B. 2 C. 3 D. 4
Cu 56: Trn mt th tch hydro vi mt th tch anken c hn hp X. T khi ca X so vi hydro l 7,5. Cho X
qua ng c Ni nung nng, thu c hn hp kh Y, t khi ca Y so vi hydro l 9,375. Phn trm khi lng ca
ankan trong Y l:A. 40% B. 25% C. 20% D. 60%
Cu 57: Cht X khng tc dng vi Na, tham gia phn ng trng bc v cng hp vi brom theo t l mol : 1 : 1.
Cng thc cu to ca X l :
A. HCOOCH
2
CHOB. CH
2
=CH-O-CH
3
C. HO-CH
2
CH=CHCHO D. H-COOCH=CH
2

Cu 58: Pht biu no sau y ng ?
A. Cc dung dch peptit u ha tan Cu(OH)
2
to dung dch mu tm.
B. Enzim mantaza xc tc cho phn ng thy phn mantoz thnh glucoz.
C. Khi thy phn hon ton protein n gin s cho hn hp cc aminoaxit.
D. Andehyt axetic lm mt mu dung dch brom trong CCl
4
.
Cu 59: Cho sut in ng chun E
0
ca cc pin in ha : E
0
X-Y
= 1,10V; E
0
X-Z
= 0,78V; E
0
T-Z
= 0,56V (X, Y, Z, T
u l kim loi).Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l:
A. T, Z, X, Y B. Z, T, X, Y C. X, T, Z, Y D. Y, Z, T, X
Cu 60: Khi iu ch kh Cl
2
trong phng th nghim, c thot ra kh clo. Dng ha cht no sau y loi b hon ton
kh clo thot ra ?
A. Dung dch NaOH B. Dung dch NH
3
C. Dung dch KMnO
4
D. Dung dch Na
2
CO
3

-----------------------------------
----------- HT---------

42
TRNG THPT VIT YN 2
------------------
THI TH I HC LN 8
NM HC 2011 - 2012
MN: HA HC
(50 cu trc nghim)

M thi
165
H, tn th sinh:..........................................................................
S bo danh:...............................................................................

I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40)
Cu 1: Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl
2
0,3M v Ba(HCO
3
)
2
0,8M
thu c 2,8 lt H
2
( ktc) v m gam kt ta. Gi tr ca m l:
A. 43,34 B. 49,25 C. 31,52 D. 39,4
Cu 2: Hn hp X gm hiro, propen, propanal, ancol alylic (CH
2
=CH-CH
2
OH). t 1 mol hn hp X thu c
40,32 lt CO
2
(ktc). un X vi bt Ni mt thi gian thu c hn hp Y c
Y
X
d = 1,25. Nu ly 0,1 mol hn hp Y
th tc dng va vi V lt dung dch Br
2
0,2M. Gi tr ca V l:
A. 0,1 lt B. 0,2 lt C. 0,25 lit D. 0,3 mol
Cu 3: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l:
A. Ca, Sr, Ba B. Na, K, Ba C. Na, K, Mg D. Mg, Ca, Ba
Cu 4: Dy no sau y gm cc ion X
+
, Y
2+
,Z
-
,T
2-
v nguyn t M u c cu hnh e l 1s
2
2s
2
2p
6
3s
2
3p
6
?
A. K
+
, Ca
2+
, Cl
-
, S
2-
, Ar. B. K
+
, Ca
2+
, F
-
, O
2-
, Ne.
C. Na
+
, Ca
2+
, Cl
-
, O
2-
, Ar. D. K
+
, Mg
2+
, Br
-
, S
2-
, Ar.
Cu 5: Nhng mt l st nh vo dung dch cha lng d mt trong nhng cht sau: FeCl
3
, AlCl
3
, CuSO
4
, Pb(NO
3
)
2
,
NaCl, HCl, HNO
3
long, H
2
SO
4
c nng, NH
4
NO
3
. S trng hp phn ng to mui Fe(II) l:
A. 4 B. 3 C. 6 D. 5
Cu 6: phn ng ht a mol kim loi M cn 1,25a mol H
2
SO
4
v sinh ra kh X (sn phm kh duy nht). Ha tan
ht 19,2 gam kim loi M vo dung dch H
2
SO
4
to ra 4,48 lt kh X (sn phm kh duy nht, ktc). Kim loi M l:
A. Fe. B. Cu. C. Mg. D. Al.
Cu 7: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO
3
th
thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht
rn khan T. Xc nh s mol HNO
3
phn ng.
A. 0,28 B. 0,36 C. 0,32 D. 0,34
Cu 8: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi
trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca
X l:
A. CH
4
B. C
4
H
8
C. C
4
H
10
D. C
3
H
6

Cu 9: Hn hp X cha K
2
O, NH
4
Cl, KHCO
3
v BaCl
2
c s mol bng nhau. Cho X vo nc d, un nng, dung
dch thu c cha cht tan l:
A. KCl, BaCl
2
B. KCl, KOH C. KCl, KHCO
3
, BaCl
2
D. KCl
Cu 10: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va v
un nng, sau thm tip dung dch AgNO
3
n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc phn
ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l:
A. 4,0 gam. B. 2,71 gam. C. 4,71 gam D. 6,0 gam.
Cu 11: Nung nng hon ton 27,3 gam hn hp NaNO
3
, Cu(NO
3
)
2
. Hn hp kh thot ra c dn vo nc d th
thy c 1,12 lt kh (ktc) khng b hp th (lng O
2
ha tan khng ng k). Khi lng Cu(NO
3
)
2
trong hn hp
ban u l:
Cu 12: Trn 3 dung dch Ba(OH)
2
0,1M, NaOH 0,2M, KOH 0,3 M vi nhng th tch bng nhau thu c dung dch
A . Ly 300ml dung dch A cho phn ng vi V lt dung dch B gm HCl 0,2M v HNO
3
0,29M, thu c dung dch
C c pH =12. Gi tr ca V l:
A. 0,134 lt B. 0,414 lt C. 0,424 lt D. 0,214 lt
Cu 13: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam
dung dch Y tc dng vi lng d Na thu c 2,8 lt H
2
(ktc). S nguyn t H c trong cng thc phn t ancol X l:
A. 10 B. 6 C. 8 D. 4
Cu 14: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO
3
)
2
. Thm m (gam) bt st vo dung dch X, sau khi
phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,628m (gam) v ch to kh NO (sn phm
kh duy nht ca N
+5
). Gi tr ca m l:
43
A. 1,92. B. 9,28. C. 14,88. D. 20,00.
Cu 15: Trong t nhin clo c hai ng v c s khi l 35 v 37. Khi lng trung bnh nguyn t ca clo l 35,5.
Vy % v khi lng ca
37
Cl trong axit pecloric HClO
4
l (Cho s khi
1
H,
16
O):
A. 9,204 B. 9,25 C. 9,45 D. 9,404
Cu 16: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t
gim dn l:
A. I > II > III > IV. B. IV > III > I > II. C. II > III > I > IV. D. IV > I > III > II.
Cu 17: Xt ba nguyn t c cu hnh electron ln lt l:
X: 1s
2
2s
2
2p
6
3s
1
; Y: 1s
2
2s
2
2p
6
3s
2
; Z: 1s
2
2s
2
2p
6
3s
2
3p
1
.
Hiroxit ca X, Y, Z xp theo th t tng dn tnh baz l:
A. XOH < Y(OH)
2
< Z(OH)
3
B. Z(OH)
2
< Y(OH)
3
< XOH
C. Y(OH)
2
< Z(OH)
3
< XOH D. Z(OH)
3
< Y(OH)
2
< XOH
Cu 18: Cho m gam hp cht hu c X c cng thc phn t l C
3
H
6
O
2
tc dng hon ton vi 200 ml dung dch
KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Cng thc cu to ca X v gi tr ca
m l:
A. C
2
H
5
COOH v 8,88 gam. B. CH
3
COOCH
3
v 6,66 gam.
C. HCOOCH
2
CH
3
v 8,88 gam. D. C
2
H
5
COOH v 6,66 gam.
Cu 19: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l
s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn
cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l:
A. 19,455. B. 68,1. C. 17,025. D. 78,4
Cu 20: Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca
hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H
2
(ktc). X gm :
A. Hai este. B. Mt este mt ancol.
C. Mt este v mt axit. D. Mt axit mt ancol.
Cu 21: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O
2
(iu kin chun).
Dn sn phm chy qua bnh ng dung dch Ca(OH)
2
d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca
m l:
A. 10,0 B. 12,0 C. 15,0 D. 20,5
Cu 22: Khi nhit phn hon ton 100 gam mi cht sau: KClO
3
(xc tc MnO
2
), KMnO
4
, KNO
3
v AgNO
3
. Cht to
ra lng O
2
t nht l:
A. KMnO
4
B. KNO
3
C. AgNO
3
D. KClO
3

Cu 23: C bao nhiu ng phn cu to, mch h c cng thc phn t C
5
H
8
tc dng vi H
2
d (xc tc thch hp)
thu c sn phm isopentan ?
A. 4. B. 2. C. 6. D. 3.
Cu 24: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t
nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l:
A. 5 B. 4 C. 6 D. 7
Cu 25: Chn cu ng trong cc cu sau:
A. Ancol a chc ha tan Cu(OH)
2
to thnh dung dch mu xanh.
B. Phng php chung iu ch ancol no, n chc bc 1 l cho an ken cng nc.
C. un nng ancol metylic vi H
2
SO
4
c 170
o
C thu c ete.
D. Khi oxi ha ancol no, n chc th thu c anehit.
Cu 26: Nung nng m gam hn hp gm Al v CuO trong iu kin khng c khng kh. Cho cht rn sau phn ng
vo dung dch NaOH (d) thu c 672 ml kh H
2
v cht rn X. Ho tan ht X trong dung dch HNO
3
long (d) thy
c 448 ml kh NO (cc phn ng xy ra hon ton v cc th tch kh o ktc). Gi tr m l:
A. 2,94 B. 3,48 C. 34,80 D. 29,40
Cu 27: Mt hp cht X c khi lng phn t bng 103. Cho 51,50 gam X phn ng ht vi 500 ml dung dch
NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit v ancol (c khi lng phn t ln hn khi
lng phn t O
2
). C cn Y thu m gam cht rn. Gi tr m l:
A. 52,50 B. 24,25 C. 26,25 D. 48,50
Cu 28: Cho Ba kim loi ln lt vo cc dung dch sau: NaHCO
3
, CuSO
4
, (NH
4
)
2
CO
3
, NaNO
3
, MgCl
2
. S dung dch
to kt ta l:
A. 5 B. 4 C. 2 D. 3
Cu 29: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6).
Th t tng dn lc baz ca cc cht l:
A. (3) < (2) < (4) < (1) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6)
C. (3) < (1) < (4) < (2) < (5) < (6) D. (2) < (3) < (4) < (1) < (5) < (6)
Cu 30: Hp th hon ton 4,48 lt CO
2
(ktc) vo 200ml dung dch cha Na
2
CO
3
0,5M v NaOH 0,75M thu c
dung dch X. Cho dung dch BaCl
2
d vo dung dch X thu c kt ta c khi lng l:
44
Cu 31: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht
lm mt mu dung dch KMnO
4
nhit thng l:
A. 4. B. 5. C. 7. D. 6.
Cu 32: Hn hp X gm HCOOH v CH
3
COOH trn theo t l mol 1 : 1. Cho 10,6 gam hn hp X tc dng vi 11,5
gam C
2
H
5
OH (c H
2
SO
4
c lm xc tc) thu c m gam este (hiu sut phn ng este ha t 80%). Gi tr ca m
l:
A. 16,2. B. 14,08. C. 17,6. D. 12,96.
Cu 33: iu no sau y khng ng?
A. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin dng
khi thi tc dng.
B. T visco, t axetat l t tng hp.
C. Nilon-6,6 v t capron l poliamit
D. T tm, bng, len l polime thin nhin.
Cu 34: Tm nhn xt ng:
A. Khi thay i bt k 1 trong 3 yu t: p sut, nhit hay nng ca mt h cn bng ho hc th h s
chuyn dch sang mt trng thi cn bng mi.
B. Trong bnh kn tn ti cn bng 2NO
2(nu)
N
2
O
4
. Nu ngm bnh trn vo nc thy mu nu trong
bnh nht dn. iu chng t chiu nghch ca phn ng l chiu thu nhit.
C. Trong bnh kn, phn ng 2SO
2
+ O
2
2SO
3
trng thi cn bng. Thm SO
2
vo , trng thi cn
bng mi, ch c SO
3
l c nng cao hn so vi trng thi cn bng c.
D. Khi thm cht xc tc, hiu sut phn ng tng hp NH
3
: N
2
+ 3H
2
NH
3
s tng.
1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh.
2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng H
2
SO
4
long.
3) Sc hiro sunfua vo dung dch FeCl
3
s thy xut hin vn c mu vng.
4) Dung dch H
2
S lu trong khng kh s c vn c mu vng.
5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho
Cc nhn xt ng l :
A. 1, 3, 4. B. 1, 2, 4, 5. C. 1, 2, 3, 4. D. 2, 4, 5.
Cu 36: Cho cc cht v ion sau: Cl
-
, Na, NH
3
, HCl, O
2-
, Fe
2+
, SO
2
, Cl
2
. Cc cht v ion ch th hin c tnh kh
trong cc phn ng oxi ha kh l:
A. Cl
-
, Na, O
2-
B. Cl
-
, Na, O
2-
, NH
3
, Fe
2+

C. Na, O
2-
, NH
3
, HCl D. Na, O
2-
, HCl, NH
3
, Fe
2+

Cu 37: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO
2
(ktc) v 2,304 gam H
2
O. Nu cho 15
gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn khan.
Vy cng thc ca ancol to nn este trn c th l:
A. CH
2
=CH-OH B. CH
3
OH C. CH
3
CH
2
OH D. CH
2
=CH-CH
2
OH
Cu 38: S nguyn t m nguyn t ca n ( trng thi c bn) c tng s electron trn cc phn lp s bng 7 l:
A. 9. B. 3. C. 5. D. 1.
Cu 39: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat,
mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l:
A. 6 B. 7 C. 8 D. 5
Cu 40: Cho cc cht: FeCO
3
, Fe(NO
3
)
2
, Fe
2
(SO
4
)
3
, FeSO
4
, FeS, FeS
2
, CuS. S lng cht c th c kh thot ra khi
cho vo dung dch HCl v un nng nh l:
A. 7. B. 4. C. 5. D. 6.
II. PHN RING [10 cu]
Th sinh ch c lm mt trong hai phn (Phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Chia 38,1 gam FeCl
2
thnh 2 phn, phn 2 c khi lng gp 3 ln phn 1. em phn 1 phn ng ht vi
dung dch KMnO
4
d, trong mi trng H
2
SO
4
long, d, thu ly kh thot ra. em ton b kh ny phn ng ht vi
phn 2, c cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l?
A. 29,640. B. 28,575. C. 24,375. D. 33,900.
Cu 42: Pht biu no sau y l ng ?
A. Phn t cc amino axit ch c 1 nhm amino.
B. Trong peptit mch h to ra t n phn t H
2
NRCOOH, s lin kt peptit l (n1)
C. Dung dch cc amino axit u khng lm i mu qu tm.
D. Phn t ipeptit mch h c 2 lin kt peptit.
Cu 43: C cc dung dch ring r sau: AlCl
3
, NaCl, MgCl
2
, H
2
SO
4
. Ch dng thm mt dung dch no sau y
nhn bit c 4 dung dch trn?
A. NaOH. B. qu tm. C. AgNO
3
. D. BaCl
2
.
45
Cu 44: Cho 35,48 gam hn hp X gm Cu v FeCO
3
vo dung dch HNO
3
long, un nng v khuy u. Sau khi
cc phn ng xy ra hon ton thu c NO; 0,03 mol kh CO
2
; dung dch Y v 21,44 gam kim loi. C cn dung dch
Y thu c khi lng cht rn khan l:
A. 38,82 g B. 36,24 g C. 36,42 g D. 38,28 g
Cu 45: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro
gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l:
A. 1 B. 2 C. 3 D. 4
Cu 46: Ha tan hon ton 80 gam hn hp X gm CuSO
4
, FeSO
4
v Fe
2
(SO
4
)
3
trong S chim 22,5% v khi lng trong
nc c dung dch X. Thm NaOH d vo X, lc kt ta em nung trong khng kh n khi lng khng i thu c
cht rn Y, thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng ca Z l:
A. 30 gam B. 40 gam C. 26 gam D. 36 gam
Cu 47: Cho m gam hn hp X gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d)
nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H
2
l 13,75). Cho ton b Y phn
ng vi mt lng d AgNO
3
trong dung dch NH
3
un nng, sinh ra 64,8 gam Ag. (Cc phn ng u xy ra hon
ton). Gi tr ca m l:A. 7,4 B. 8,8 C. 9,2 D. 7,8
Cu 48: Cho dy cc cht: C
2
H
2
, HCHO, HCOOH, CH
3
CHO, (CH
3
)
2
CO, C
12
H
22
O
11
(mantoz). S cht trong dy
tham gia c phn ng trng gng l:A. 6 B. 4 C. 5 D. 3
Cu 49: hirat ha 2-metylbutan-2-ol thu c sn phm chnh l anken no sau y?
A. 3-metyl but-1-en B. Pent-1-en C. 2-metyl but-1-en D. 2-metyl but-2-en
Cu 50: Nung hn hp SO
2
, O
2
c s mol bng nhau trong mt bnh kn c th tch khng i vi cht xc tc thch
hp. Sau mt thi gian, a bnh v nht ban u thy p sut trong bnh gim 10% so vi p sut ban u. Hiu
sut ca phn ng xy ra bng:A. 40% B. 50% C. 20% D. 75%
B. Theo chng trnh Nng cao (t cu 51 n cu 60)
Cu 51: Khi nung butan vi xc tc thch hp thu c hn hp T gm CH
4
, C
3
H
6
, C
2
H
4
, C
2
H
6
, C
4
H
8
, H
2
v C
4
H
10
d.
t chy hon ton hn hp T thu c 8,96 lt CO
2
(o ktc) v 9,0 gam H
2
O. Mt khc, hn hp T lm mt mu
va ht 12 gam Br
2
trong dung dch nc brom. Hiu sut phn ng nung butan l:
A. 75%. B. 65%. C. 50%. D. 45%.
Cu 52: A l hp cht hu c mch vng cha C, H, N trong N chim 15,054% theo khi lng. A tc dng vi
HCl to ra mui c dng RNH
3
Cl. Cho 9,3g A tc dng ht vi nc brom d thu c a g kt ta. Gi tr ca a l:
A. 30 gam B. 33 gam C. 44 gam D. 36 gam
Cu 53: Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO
3
2M trong
NH
3
. Sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l:
A. C
4
H
5
CHO B. C
3
H
5
CHO C. C
4
H
3
CHO D. C
3
H
3
CHO.
Cu 54: Trn 10,8g bt Al vi 34,8g bt Fe
3
O
4
ri tin hnh phn ng nhit nhm trong iu kin khng c khng
kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H
2
SO
4
long (d) thu c 10,752 lt kh H
2
(ktc).
Hiu sut ca phn ng nhit nhm l:
A. 70% B. 90% C. 80% D. 60%
Cu 55: Th nh 6,85 gam Ba (c ct nh) vo 20 gam dung dch H
2
SO
4
9,80%. Sau khi kt thc phn ng thu
c dung dch X. Nng cht tan c trong dung dch X l:
A. 23,22% B. 23,12% C. 22,16% D. 31,96%
Cu 56: Cho dung dch NH
3
d vo dung dch X cha hn hp MgCl
2
, ZnCl
2
, FeCl
3
, FeCl
2
thu c kt ta Y. Nung
kt ta Y trong khng kh ta c cht rn Z. Cho lung kh CO d i qua A nung nng (cc phn ng xy ra hon
ton) thu c cht rn T. Trong T c cha:
A. Fe
2
O
3
, MgO, ZnO B. Fe, Mg, Zn C. Fe, MgO D. Fe, MgO, ZnO
Cu 57: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl
amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l:
A. 6. B. 5. C. 4. D. 3.
Cu 58: Trong phng th nghim, kh hiro halogenua c iu ch t phn ng:
NaX
rn
+ H
2
SO
4 c

0
t
HX| + NaHSO
4

Phng php trn c dng iu ch hiro halogenua no?
A. HBr B. HCl C. HCl v HBr D. HI
Cu 59: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)
2

l:A. 4 B. 1 C. 3 D. 2
Cu 60: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amoni axit no mch h, c mt
nhm COOH v mt nhm NH
2
. t chy hon ton 0,1 mol X bng O
2
va thu c sn phm gm CO
2
, H
2
O
v N
2
c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng
cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn?

46
TRNG THPT VIT YN 2 THI TH I HC LN 9
Nm hc: 2011 - 2012
Mn thi: HA HC (M : 155)
Cho d kin nguyn t khi sau: H = 1; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P
= 31; S = 32; Cl = 35,5; Br = 80; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Rb =
85; Sr = 88; Ag = 108; I = 127; Cs = 133; Ba = 137; Pb = 207.

I. PHN CHUNG CHO TT C TH SINH (40 cu)

Cu 1. Cho hn hp gm Fe v Cu tc dng vi cc ha cht sau: (1) dung dch HCl; (2) kh oxi, t
0
; (3) dung dch
NaOH; (4) dung dch H
2
SO
4
c, ngui; (5) dung dch FeCl
3
. S ha cht ch tc dng vi 1 trong 2 kim loi l:
A. 3 B. 5 C. 2 D. 4
Cu 2. Cho cc cht sau: Cu, FeS
2
, Na
2
SO
3
, S, NaCl, Cu
2
O, KBr v Fe
3
O
4
tc dng vi dung dch H
2
SO
4
c, nng. S trng hp xy ra phn ng oxi ha - kh l:
A. 5 B. 4 C. 7 D. 6
Cu 3. Hn hp X gm hai kim loi kim th Y v Z thuc hai chu k k tip nhau (M
Y
< M
Z
). Cho m gam hn
hp X vo nc d thy thot ra V lt kh H
2
. Mt khc, cho m gam hn hp X vo dung dch HCl d, sau phn ng
hon ton thy thot ra 3V lt H
2
(Th tch cc kh o cng iu kin). % khi lng ca Y trong hn hp X l:
A. 54,5% B. 33,3% C. 66,7% D. 45,5%
Cu 4. Cho phenol tc dng vi cc ha cht sau: (1) NaOH; (2) HNO
3
c/xt H
2
SO
4
c; (3) Br
2
(nc);
(4) HCl c; (5) HCHO (xt H
+
, t
0
); (6) NaHCO
3
. S ha cht phn ng vi phenol l:
A. 4 B. 5 C. 6 D. 3
Cu 5. Thuc th no sau y dng phn bit Fe, FeO v FeS.
A. dung dch HCl long, nng B. dung dch H
2
SO
4
c, nng
C. dung dch NaOH c, nng D. dung dch HNO
3
long, nng
Cu 6. Amin X c cha vng benzen v c cng thc phn t l C
8
H
11
N. X c phn ng th H trong vng
benzen vi Br
2
(dd). Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH
3
Cl. X c bao nhiu cng
thc cu to?A. 7 B. 9 C. 8 D. 6
Cu 7. Dn 7,1 gam hn hp hi ca 2 ancol no, n chc k tip nhau trong dy ng ng qua CuO d, un
nng. Sau phn ng hon ton thu c 10,3 gam hn hp hi Y. Dn hn hp hi Y vo dung dch AgNO
3
d
trong NH
3
, un nng, sau phn ng hon ton thu c Ag c khi lng l:
Cu 8. Dy cht no sau y c th s dng iu ch trc tip axetanehit?
A. metanol, etilen, axetilen. B. etanol, etilen, axetilen. C. etanol, butan, etilen. D. glucoz, etilen, vinyl axetat. Cu
9. Hn hp X gm ankin Y v H
2
c t l mol l 1 : 2. Dn 13,44 lt hn hp X (ktc) qua Ni, nung nng thu c
hn hp Z c t khi so vi H
2
l 11. Dn hn hp Z qua dung dch Br
2
d, sau phn ng hon ton thy c 32
gam Br
2
phn ng. Cng thc ca ankin Y l:
A. C
2
H
2
. B. C
4
H
6
. C. C
3
H
4
. D. C
5
H
8
.
Cu 10. Dy cc cht no sau y l cc hp cht ion?
A. AlCl
3
, HCl, NaOH. B. HNO
3
, CaCl
2
, NH
4
Cl. C. KNO
3
, NaF, H
2
O. D. NaCl, CaO, NH
4
Cl.
Cu 11. Cho cc cht sau: (1) etyl amin, (2) imetyl amin, (3) p-Metyl anilin, (4) benzyl amin. S sp xp no ng
vi tnhbaz ca cc cht ?
A. (4) > (2) > (3) > (1). B. (1) > (2) > (4) > (3). C. (2) > (1) > (3) > (4).D. (2) > (1) > (4) > (3).
Cu 12. Nh t t dung dch H
2
SO
4
long vo dung dch X cha 0,1 mol Na
2
CO
3
v 0,2 mol NaHCO
3
, thu c
dung dch Yv 4,48 lt kh CO
2
(ktc). Tnh khi lng kt ta thu c khi cho dung dch Ba(OH)
2
d vo dung
dch Y? A. 66,30 gam B. 54,65 gam C. 46,60 gam D. 19,70 gam
Cu 13. Dy cc dung dch no sau y, khi in phn (in cc tr, mng ngn) c s tng pH ca dung dch ?
A. KCl, KOH, HNO
3
. B. CuSO
4
, HCl, NaNO
3
. C. NaOH, KNO
3
,KCl. D. NaOH, BaCl
2
, HCl.
Cu 14. Ancol X no a chc mch h (c s nhm -OH t hn s nguyn t cacbon). t chy hon ton 0,1 mol X
cn dng 12,32 lt kh O
2
(ktc). Mt khc, dung dch cha X ha tan c Cu(OH)
2
nhit thng to dung
dch xanh lam. X c bao nhiu cng thc cu to?
A. 6 B. 4 C. 3 D. 5
Cu 15. Ho tan hon ton mt lng bt Fe trong 200,0 gam dung dch HNO
3
nng 63%, un nng thu c
kh NO
2
(sn phm kh duy nht). Trong dung dch sau phn ng, nng % ca HNO
3
l 36,92%. Th tch kh
NO
2
(o 27
0
C v 1,12 atm) thot ra l:
A. 9,92 lt. B. 9,15 lt. C. 9,89 lt. D. 9,74 lt
47
Cu 16. Cho cc th nghim sau:
(1) Sc kh CO
2
vo dung dch natri aluminat. (2) Cho dung dch NH
3
d vo dung dch AlCl
3
.
(3) Sc kh H
2
S vo dung dch AgNO
3
. (4) Dung dch NaOH d vo dung dch AlCl
3
.
(5) Dung dch NaOH d vo dung dch Ba(HCO
3
)
2
.
Nhng trng hp thu c kt ta sau phn ng l:
A. (2), (3), (5). B. (1), (2), (5). C. (1), (2), (3), (5). D. (2), (3), (4), (5).
Cu 17. Cho dy cc dung dch sau: NaHSO
4
, NH
4
Cl, CuSO
4
, K
2
CO
3
, ClH
3
N-CH
2
-COOH, NaCl v AlCl
3
. S
dung dch c pH < 7 l:A. 6. B. 4. C. 5. D. 3.
Cu 18. Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe
3
O
4
v Fe
2
O
3
trong 400 ml dung dch HNO
3
3M (d) un nng, thu c dung dch Y v V lt kh NO (ktc). NO l sn phm kh duy nht ca NO
3
-
. Cho 350
ml dung dch NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l:
A. 3,36 lt. B. 5,04 lt. C. 5,60 lt. D. 4,48 lt.
Cu 19. Cho cc pht biu sau:
(1) Thu phn hon ton este no, n chc mch h trong dung dch kim thu c mui v ancol. (2) Phn ng este
ho gia axit cacboxylic vi ancol (xt H
2
SO
4
c) l phn ng thun nghch.
(3) Trong phn ng este ho gia axit axetic v etanol (xt H
2
SO
4
c), nguyn t O ca phn t H
2
O c ngun gc
t axit. (4) t chy hon ton este no mch h lun thu c CO
2
v H
2
O c s mol bng nhau.
(5) Cc axit bo u l cc axit cacboxylic n chc v c s nguyn t cacbon chn.
S pht biu ng l:
A. 5 B. 4 C. 3 D. 2
A. etyl butanoat. B. propyl propanoat. C. sec-butyl axetat. D. butyl axetat.
Cu 20. Cho s sau:
buta-1,3-ien X Y Z T (C
6
H
12
O
2
)
T l hp cht n chc.T l :
A. etyl butanoat. B. propyl propanoat. C. sec-butyl axetat. D. butyl axetat.
Cu 21. Tnh khi lng ca glucoz cn dng trong qu trnh ln men to thnh 5 lt ancol etylic 46 l (bit hiu
sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml).
A. 4,0 kg B. 3,0 kg C. 5,0 kg D. 4,5 kg
Cu 22. Cht hu c X tc dng va vi dung dch NaOH, thu c 14,2 gam mui sunfat v thy thot ra 4,48
lt kh Y (ktc). Y c cha C, H v N. T khi ca Y so vi H
2
l 22,5. Phn t khi ca X l:
A. 152. B. 125. C. 188. D. 232.
Cu 23. Axit Malic (2-hiroxi butanioic) c trong qu to. Cho m gam axit Malic tc dng vi Na d thu c V
1
lt kh H
2
. Mt khc, cho m gam axit Malic tc dng vi NaHCO
3
d thu c V
2
lt kh CO
2
(Th tch cc kh o
cng iu kin). Mi quan h gia V
1
v V
2
l:
A. V
1
= 0,5V
2
.B. V
1
= V
2
. C. V
1
= 0,75V
2
. D. V
1
= 1,5V
2
.
Cu 24. Cho 16 gam hn hp X gm Fe, Cu, Zn tc dng vi oxi thu c 19,2 gam cht rn Y. Ha tan hon ton
Y trongdung dch H
2
SO
4
c, nng d thy thot ra V lt kh SO
2
(ktc). SO
2
l sn phm kh duy nht ca
H
2
SO
4
. C cn dung dch thu c 49,6 gam hn hp mui khan. Gi tr ca V l:
A. 2,80 lt. B. 4,48 lt. C. 3,92 lt. D. 3,36 lt.
Cu 25. trung ha m gam dung dch axit cacboxylic n chc X nng 8,64% cn dng m gam dung dch
NaOH nng C%. Sau phn ng thu c dung dch cha cht tan c nng 5,64%. Cng thc ca X v gi tr ca
C tng ng l:
A. CH
3
-COOH v 5,76. B. HCOOH v 7,5. C. CH
3
-CH
2
-COOH v 4,6. D. CH
2
=CH-COOH v 4,8.
Cu 26. Thy phn hon ton a gam ipeptit Glu-Ala trong dung dch NaOH d, un nng thu c 45,3 gam hn
hp mui. Gi tr ca a l:A. 34,5 gam. B. 33,3 gam. C. 35,4 gam. D. 32,7 gam.
Cu 27. Cho cc vt liu polime sau: (1) nha bakelit, (2) nilon-6,6, (3) cao su lu ha, (4) t visco, (5)
polietilen, (6) nha PVC. S vt liu c thnh phn chnh l cc polime tng hp l:
A. 4 B. 6 C. 3 D. 5
Cu 28. Cho m gam Zn vo dung dch cha 0,1 mol AgNO
3
v 0,15 mol Cu(NO
3
)
2
, sau mt thi gian thu c
26,9 gam kt ta v dung dch X cha 2 mui. Tch ly kt ta, thm tip 5,6 gam bt st vo dung dch X, sau khi
cc phn ng hon ton thu c 6 gam kt ta. Gi tr ca m l:
Cu 29. Cho phn ng oxi ha - kh sau: K
2
Cr
2
O
7
+ FeSO
4
+ KHSO
4
K
2
SO
4
+ Cr
2
(SO
4
)
3
+ Fe
2
(SO
4
)
3
+
H
2
O. Tng i s cc h s cht (nguyn, ti gin) trong phng trnh phn ng l:
A. 40 B. 37 C. 34 D. 39
Cu 30. Hy cho bit pht biu no sau y khng ng?
A. Trong dy cc axit: HF, HCl, HBr. HBr c tnh axit mnh nht.
B. Ozon c tnh oxi ha v kh nng hot ng hn O
2
.
HBr(1:1) 40
0
C NaOH,t
0

H
2
/Ni,t
0

+M/H
2
SO
4
,t
0

48
C. Kh nng phn ng ca Cl
2
km hn ca O
2
.
D. Tnh kh ca H
2
S ln hn ca nc.
Cu 31. Cht hu c X c cng thc phn t l C
4
H
9
O
2
N. Cho 5,15 gam X tc dng dung dch NaOH (ly d
25% so vi lng phn ng) un nng. Sau phn ng hon ton, c cn dung dch thu c 6,05 gam cht rn khan.
Cng thc ca X l:
A. H
2
N-CH
2
COO-C
2
H
5
. B. H
2
N-C
3
H
6
COOH. C. C
2
H
3
COONH
3
-CH
3
. D. H
2
N-C
2
H
4
COO-CH
3
.
Cu 32. Hiro ha hon ton anehit X (xt Ni, t
0
) thu c ancol Y. Mt khc, oxi ha X thu c axit cacboxylic
Z. Thc hin phn ng este ha gia Y v Z (xt H
2
SO
4
c) thu c este M c cng thc phn t l C
6
H
10
O
2
.
Cng thc ca X l:
A. CH
2
=CH-CH=O. B. O=CH-CH
2
-CH=O. C. CH
3
-CH
2
-CH=O. D. CH
2
=CH-CH
2
-CH=O.
Cu 33. Cho cc pht biu sau:
(1) Trong dung dch, tng nng cc ion dng bng nng cc ion m. (2) Dy cc cht: CaCO
3
, HBr v NaOH
u l cc cht in ly mnh.
(3) Trong 3 dung dch cng pH l HCOOH, HCl v H
2
SO
4
, dung dch c nng ln nht l HCOOH. (4) Phn ng
axit-baz xy ra theo chiu to ra cht c tnh axit v baz yu hn.
(5) Phn ng trao i ion trong dung dch khng km theo s thay i s oxi ha.
S pht biu ng l:
A. 3 B. 4 C. 2 D. 5
Cu 34. Cho cc phn ng sau:
(1) MnO
2
+ HCl
c
Kh X+.
(2) NH
4
NO
2
Kh Y +.
(3) Na
2
SO
3
+ H
2
SO
4
Kh Z +.
(4) Cu + HNO
3

c
Kh T +.
(5) Al
4
C
3
+ H
2
O Kh Q +.
Nhng kh tc dng c vi dung dch NaOH l:A. X, Y, Z. B. X, Z, T. C. X, T, Q. D. Y, Z, Q
Cu 35. Cho a gam P
2
O
5
vo dung dch cha a gam NaOH, thu c dung dch X. Cht tan c trong dung dch X l:
A. NaH
2
PO
4
v Na
2
HPO
4
B. NaH
2
PO
4
v H
3
PO
4
C. Na
2
HPO
4
v Na
3
PO
4
D. Na
3
PO
4
v NaOH
Cu 36. Cho bt nhm d vo axit X long, un nng thu c kh Y khng mu, nh hn khng kh v dung dch
Z. Cho dung dch NaOH n d vo dung dch Z, un nng. Sau phn ng hon ton, thy thot ra kh T (khng
mu, i mu qu (tm m sang xanh). Axit X v kh Y l:
A. H
2
SO
4
v H
2
S. B. HNO
3
v N
2
. C. HCl v H
2
. D. HNO
3
v N
2
O.
Cu 37. Hp th ht V lt kh CO
2
vo dung dch cha 0,39 mol Ca(OH)
2
thu c a gam kt ta. Tch ly kt
ta, sau thm tip 0,4V lt kh CO
2
na, thu thm 0,2a gam kt ta. Th tch cc kh o ktc. Gi tr ca V l:
A. 7,84 lt. B. 5,60 lt. C. 8,40 lt. D. 6,72 lt.
Cu 38. Cht hu c X n chc, mch h c cng thc phn t l C
4
H
6
O
2
. Cho 12,9 gam X vo 200 ml dung
dch NaOH 1M, un nng. Sau phn ng hon ton c cn dung dch thu c 16,1 gam cht rn khan. Cng thc ca
X l:
A. CH
2
=CH-COO-CH
3
.B. H-COO-CH
2
-CH=CH
2
. C. CH
3
-COO-CH=CH
2
. D. CH
2
=C(CH
3)
-COOH.
Cu 39. Hn hp tecmit c dng hn gn cc ng ray c thnh phn l:
A. Cr v Fe
3
O
4
. B. C v Fe
2
O
3
. C. Al v Fe
2
O
3
. D. Al v Cr
2
O
3
.
Cu 40. Hirocacbon mch h X tc dng vi HCl theo t mol 1 : 1 thu c dn xut Y duy nht. Trong phn t
Y, clo
chim 38,38% v khi lng. Tn gi ca X l:
A. etilen. B. -butilen. C. -butilen. D. 2,3-imetyl but-2-en.

II. PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn
A. Phn theo chng trnh chun:
Cu 41. Dn kh NH
3
qua CrO
3
nung nng. Hin tng quan st c l:
A. Cht rn chuyn t mu sang mu lc. B. Cht rn chuyn t mu xanh sang mu vng.
C. Cht rn chuyn t mu da cam sang mu lc. D. Cht rn chuyn t mu vng sang da cam.
Cu 42. Cho cc cp oxi ho/kh sau: M
2+
/M, X
2+
/X, Y
2+
/Y. Bit tnh oxi ho ca cc ion tng dn theo th t:
M
2+
, Y
2+
, X
2+
tnh kh cc kim loi gim dn theo th t M, Y, X. Trong cc phn ng ho hc sau, phn ng no
khng xy ra?
A. M + YCl
2
B. X + YCl
2
C. Y + XCl
2
D. M + XCl
2
Cu 43. Cht hu c X tc dng vi AgNO
3
trong NH
3
, un nng thu c Ag. Mt khc, hiro ha hon ton X
thu c 2,3-imetyl butan-1-ol. X c bao nhiu cng thc cu to?A. 5 B. 3 C. 4 D. 6
t
0

t
0

t
0

t
0

49
Cu 44. C cc dung dch sau: (1) glucoz; (2) mantoz; (3) saccaroz; (4) axit axetic; (5) glixerol; (6) axetanehit.
S dung dch ha tan Cu(OH)
2
nhit thng? A. 6 B. 3 C. 5 D. 4
Cu 45. Cht hu c X c cha vng benzen v c cng thc phn t l C
x
H
y
O. Tng s lin kt xichma c trong
phn t X l 16. X c bao nhiu cng thc cu to?
A. 6 B. 7 C. 4 D. 5
Cu 46. Hy cho bit dng qu tm c th phn bit c dy cc dung dch no sau y ?
A. glyxin, H
2
NCH
2
COOCH
3
, H
2
NCH
2
COONa B. glyxin, H
2
NCH
2
COONa, H
2
NCH
2
CH
2
COONa
C. glyxin, H
2
NCH
2
COONa, axit glutamic D. ClH
3
NCH
2
COOH, axit glutamic, glyxin.
Cu 47. t chy hon ton a mol axit cacboxylic X no, mch h thu c a mol H
2
O. Mt khc, cho a mol X tc
dng vi NaHCO
3
d thu c 2a mol CO
2
. Tng s nguyn t c trong phn t X l:
A. 6 B. 8 C. 7 D. 5
Cu 48. Cho -aminoaxit X tc dng vi ancol n chc Y trong HCl khan thu c cht hu c Z c cng thc
phn t l C
5
H
12
O
2
NCl. Cho Z tc dng va vi 100 ml dung dch NaOH 2M, un nng thu c 16,95 gam
mui. Cng thc ca X l:
A. H
2
N-CH
2
-CH
2
-COOH.B. CH
3
-CH(NH
2
)-COOH. C. CH
3
-CH
2
-CH(NH
2
)-COOH. D. H
2
N-CH
2
-COOH.
Cu 49. Cho cn bng ha hc sau: N
2
(k) + 3H
2
(k) 2NH
3
(k), H
0
p
= -92 kJ/mol. Khi tng nhit th:
A. cn bng chuyn dch v pha nghch, t khi ca hn hp phn ng gim.
B. cn bng chuyn dch v pha nghch, t khi ca hn hp phn ng tng. C. cn bng chuyn dch v pha thun, t
khi ca hn hp phn ng gim. D. cn bng chuyn dch v pha thun, t khi ca hn hp phn ng tng.
Cu 50. Cho m gam hn hp X gm Cu v Fe
2
O
3
vo dung dch HCl, sau phn ng hon ton thu c dung dch Y
cha hai cht tan v cn li 0,2m gam cht rn cha tan. Tch b phn cha tan, cho dung dch AgNO
3
d vo
dung dch Y thu c
86,16 gam kt ta. Gi tr ca m l:
B. Phn theo chng trnh nng cao:
Cu 51. Cht hu c X n chc (c cha cc nguyn t C, H, O) v cha vng benzen. X tc dng vi Na thu c
kh H
2
.t chy hon ton 1 mol X thu c di 8 mol CO
2
. X c bao nhiu cng thc cu to?
A. 7 B. 6 C. 5 D. 4
Cu 52. Peptit X c CTCT l : H
2
NCH
2
CONH-CH(CH
3
)CONH-CH(COOH)CH
2
CH
2
CH
2
CH
2
NH
2
. Tn gi ca X
l :A. Glyxin Alanin Lysin B. Glyxyl Alanyl Lysin C. Glyxyl Alanyl Glutamin D. Alanyl Glyxyl Lysin
Cu 53. Hiro ha hon ton anehit X thu c ancol Y. t chy hon ton Y thu c CO
2
v H
2
O theo t l
mol 2 : 3. Mt khc, cho a mol X tc dng vi AgNO
3
d trong NH
3
un nng thu c 4a mol Ag. Tng s
nguyn t c trong phn t X l:A. 6 B. 4 C. 8 D. 7
Cu 54. Cho hn hp gm m gam bt Cu v 23,2 gam Fe
3
O
4
vo dung dch H
2
SO
4
long d thy tan hon
ton thu c dung dch X. oxi ha ht Fe
2+
trong dung dch X cn dng 90 ml dung dch KMnO
4
0,4M. Gi tr
ca m l:
Cu 55. Cho cn bng sau: H
2
(k) + I
2
(k) 2HI (k) (1). Tong bnh kn dung tch khng i, ti nhit T,
ban u ly s mol H
2
gp i s mol I
2
. Ti thi im cn bng, s mol ca HI gp i s mol ca I
2
. Hng s cn
bng K
c
ca cn bng (1) l:
A. 4,00 B. 1,33 C. 1,67 D. 2,67
Cu 56. Cho 0,2 mol axit cacboxylic n chc X vo 200 ml dung dch NaOH 0,8M, thu c dung dch c cha
15,52 gam cht tan. Cng thc ca axit cacboxylic X l:
A. CH
3
COOH B. C
2
H
5
COOH C. C
2
H
3
COOH D. HCOOH
Cu 57. Hy cho bit c th s dng qu tm phn bit dy cc dung dch no sau y?
A. NaOH, NaClO, HCl v NaCl B. NH
4
Cl, NaCl, AlCl
3
v HCl
C. Na2CO3, NaOH, NaCl v HCl D. NaNO3, NaOH, HNO3 v Ba(NO3)2
Cu 58. Cho bit phn ng trong pin in ho l: X + Y
2+
X
2+
+ Y. Sc in ng chun ca pin l 1,1V.
Bit E
0
ca
cp Y
2+
/Y l +0,34V. Vy E
0
ca cp X
2+
/X l:
A. +0,76V B. -0,76V C. +1,43V D. -1,43V
Cu 59. Hy cho bit kim loi no sau y khng tan trong dung dch H2SO4 long?
A. Fe B. Ni C. Zn D. Pb
Cu 60. Kiu lin kt gia cc gc glucoz trong amiloz l:
A. -1,6-glicozit B. -1,2-glicozit C. -1,4-glicozit D. -1,4-glicozit

50
TRNG THPT VIT YN 2
( thi c 05 trang)
THI TH I HC, NM 2011 -2012
Mn thi: HO HC 12 - KHI A, B - LN 10
H, tn th sinh:.........................................................................S bo danh:.........
Cu 1: Cho CO phn ng vi CuO mt thi gian to hn hp kh A v hn hp rn B . Cho A phn ng vi mt dung
dch cha 0,025mol Ca(OH)
2
to 2(g) kt ta . Ly cht rn B phn ng vi dung dch HNO
3
c, nng d to V(lt)
kh (ktc) mu nu . Gi tr ca V l:
A. 1,344 lt hoc 0,672 lt B. 1,120 lt hoc 0,672 lt
C. 1,344 lt hoc 0,896 lt. D. 1,120 lt hoc 0,896 lt
Cu 2: Cho p sau Fe
3
O
4
+ HNO
3
Fe(NO
3
)
3
+ NO
2
+ NO + H
2
O
Nu t l s mol gia NO v NO
2
l 1 : 2 th h s cn bng ca HNO
3
trong phng trnh ho hc l
A. 30 B. 48 C. 38 D. 66
Cu 3: Cho cn bng sau: 3A
(k)
2B
(k)
+ D
(r)
. Khi tng nhit ca p, t khi hi ca hn hp kh so vi H
2
tng
ln. Khng nh no sau y ng?
A. P thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu p nghch.
B. P thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu p thun.
C. P thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu p thun.
D. P thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu p nghch.
Cu 4: Cho cng thc cht A l C
3
H
5
Br
3
. Khi A tc dng vi dd NaOH d to ra mt hp cht tp chc ca ancol bc
1 v anehit. CTCT ca A l
A. CH
3
-CHBr-CHBr
2
.B. CH
2
Br-CH
2
-CHBr
2
.C. CH
2
Br-CHBr-CH
2
Br. D. CH
3
-CBr
2
-CH
2
Br.
Cu 5: Trn u 6,102 gam hn hp Al, Fe
3
O
4
v CuO (cc cht c cng s mol) ri tin hnh p nhit nhm thu
c hn hp X. Cho X tc dng vi dd HNO
3
d c V ml ( ktc) hn hp kh NO
2
v NO theo t l mol tng
ng l 1:1. Gi tr ca V lA. 806,4 B. 604,8 C. 403,2 D. 645,12
Cu 6: Hp cht thm X, c CTPT C
8
H
8
O
2
va c kh nng tc dng vi Na, va c kh nng tc dng vi NaOH v
lm qu tm chuyn mu hng. S ng phn cu to ca X lA. 4. B. 5. C. 6. D. 3.
Cu 7: P no sau y sai?
A. 3Na[Al(OH)
4
] + AlCl
3
4Al(OH)
3
+ 3NaCl
B. 3Na
2
CO
3
+ 2FeCl
3
+ 3H
2
O 2Fe(OH)
3
+ 6NaCl + 3CO
2

C. Ag
2
S + 10HNO
3
2AgNO
3
+ H
2
SO
4
+ 8NO
2
+ 4H
2
O
D. C
2
H
5
ONa + H
2
O C
2
H
5
OH + NaOH
Cu 8: Hy la chn cc ho cht cn thit trong phng th nghim iu ch kh sunfur?
A. Na
2
SO
3
v dd H
2
SO
4
c B. CaSO
3
v dd H
2
SO
4
c
C. CaSO
4
v dd H
2
SO
4
long D. CaSO
4
v dd H
2
SO
4
c
Cu 9: Cacbon p vi tt c cc cht trong dy no sau y ?
A. Fe
2
O
3
, Al
2
O
3
, CO
2
,HNO
3
B. CO, Al
2
O
3
, HNO
3
(c), H
2
SO
4
(c)
C. Fe
2
O
3
, CO
2
, H
2
, HNO
3
(c) D. CO, Al
2
O
3
, K
2
O, Ca
Cu 10: Cho 15 gam fomon 37,5% tc dng vi lng d AgNO
3
/NH
3
thy xut hin m gam kt ta . Gi tr ca m l
A. 108,0. B. 81,0. C. 42,8 D. 40,5
Cu 11: Cht A c CTPT C
11
H
20
O
4
. A tc dng vi NaOH to ra mui ca axit hu c B mch thng v 2 ancol l
etanol v propan-2-ol. CTCT ca A l
A. C
2
H
5
OOC[CH
2
]
4
OOCCH
2
-CH
2
-CH
3
. B. C
2
H
5
OOC[CH
2
]
4
COOCH
2
-CH
2
-CH
3
.
C. C
2
H
5
OOC[CH
2
]
4
COOCH(CH
3
)
2
. D. C
2
H
5
OOC[CH
2
]
4
OOCCH(CH
3
)
2
.
Cu 12: Trng thi lai ha ca cc nguyn t cacbon trong cc phn t: CO
2
; C
2
H
6
; C
2
H
2
v C
2
H
4
ln lt l
A. sp; sp
3
; sp; sp
2
. B. sp
2
; sp
3
; sp; sp
2
. C. sp; sp
2
; sp; sp
3
. D. sp; sp
3
; sp
2
; sp.
Cu 13: Pht biu no di y khng ng?
A. Nguyn t c cu thnh t cc ht c bn l proton, ntron v electron.
B. V nguyn t c cu thnh bi cc ht electron.
C. Ht nhn nguyn t c cu thnh t cc ht proton v ntron.
D. Vi mi nguyn t, khi lng nguyn t bng s khi.
Cu 14: Trong 1 kg go cha 81% tinh bt, c s mt xch C
6
H
10
O
5
- l
A. 12,044.10
24
. B. 6,020.10
24
. C. 16,20.10
24
. D. 3,012.10
24
.
Cu 15: Dng thuc th no sau y phn bit bn cht rn: NaCl, CaCO
3
, Na
2
CO
3
v BaSO
4

A. Nc B. Qu tm C. Nhit phn D. Nc v CO
2

Cu 16: Cho cc ion:HSO

4
, NO
3
, C
6
H
5
O
-
,
-
OCO-CH
2
-NH
+
3
, CH
3
NH
+
3
, Cu
2+
, Ba
2+
, Al(OH)
4
, HCO
3
. Tng s ion
c vai tr axit v tng s ion c vai tr lng tnh l
A. 3 v 2 B. 2 v 1 C. 1v 2 D. 2 v 2
Cu 17: Chia 4,58g hn hp gm ba kim loi Zn, Mg, Al thnh hai phn bng nhau:
51
- Phn 1 tan hon ton trong dd HCl gii phng 1,456l H
2
(ktc) v to ra m(g) hn hp mui clorua
- Phn 2 b oxi ha hon ton thu c m(g) hn hp ba oxit.
Gi tr ca m v m ln lt l:
A. 6,905 v 4,37 B. 6,905 v 3,33 C. 7,035 v 3,33 D. 7,035 v 4,37
Cu 18: chun mt dd Fe
2+
axit ho phi dng 50 ml dd K
2
Cr
2
O
7
0,02M. chun cng lng dd Fe
2+

trn bng dd KMnO
4
th th tch dd KMnO
4
0,02M cn dng l
A. 25 ml B. 60 ml C. 120 ml D. 30 ml
Cu 19: Hp cht A to bi ion M
2+
v ion X
2
2
. Tng s ht c bn to nn hp cht A l 241 trong , tng s ht
mang in nhiu hn ht khng mang in l 47. Tng s ht mang in ca ion M
2+
nhiu hn ca ion X
2
2
l 76 ht.
V tr ca M trong bng tun hon l
A. 20, chu k 4, nhm IIA B. 12, chu k 3, nhm IIA
C. 56, chu k 6, nhm IIA D. 38, chu k 5, nhm IIA
Cu 20: Cho cc ion sau: Cl
-
; S
2-
; Ca
2+
; K
+
. Th t tng dn bn knh ca cc ion trn l
A. Ca
2+
; K
+
; S
2-
; Cl
-
B. Cl
-
; S
2-
; Ca
2+
; K
+
. C. S
2-
; Cl
-
; K
+
; Ca
2+
D. .Ca
2+
; K
+
; Cl
-
; S
2-
.
Cu 21: Khi thu phn 0,01 mol este E to bi axit hu c n chc X v ancol Y th dng ng 1,68 gam KOH, cn
khi thu phn 6,35 gam E th cn 3,0 gam NaOH v thu c 7,05 gam mui. CTPT ca este l
A. C
14
H
18
O
6
. B. C
9
H
12
O
6
. C. C
12
H
20
O
6
. D. C
12
H
14
O
6
.
Cu 22: t chy hon ton 2,76 gam hn hp X gm C
x
H
y
COOH; C
x
H
y
COOCH
3
v CH
3
OH thu c 2,688 lt CO
2

( ktc) v 1,8 gam H
2
O. Mt khc, cho 2,76 gam hn hp X p va vi 30 ml dd NaOH 1M, thu c 0,96 gam
CH
3
OH. Cng thc ca C
x
H
y
COOH l
A. C
2
H
3
COOH. B. CH
3
COOH. C. C
3
H
5
COOH. D. C
2
H
5
COOH.
Cu 23: S ng phn (k c ng phn cis trans) ng vi CTPT C
3
H
5
Br bng
A. 2. B. 4. C. 3. D. 5.
Cu 24: Khi trn nhng th tch bng nhau ca dd A c pH = 13 v dd B c pH = 2 th thu c dd c pH bng
A. 12,95 B. 12,65 C. 1,05 D. 1,35
Cu 25: Hn hp Z gm hai este X, Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng
(M
X
< M
Y
). t chy hon ton m gam Z cn dng 6,16 lt kh O
2
( ktc), thu c 5,6 lt kh CO
2
( ktc) v 4,5
gam H
2
O. Cng thc este X v gi tr m tng ng l
A. (HCOO)
2
C
2
H
4
v 6,6. B. HCOOC
2
H
5
v 9,5
C. HCOOCH
3
v 6,7. D. CH
3
COOCH
3
v 6,7.
Cu 26: Cho 10,8 gam hn hp A gm Mg v Fe tc dng vi 500 ml dd AgNO
3
0,8M, sau khi p xy ra hon ton
thu c dd B v 46 gam cht rn D . Thnh phn % khi lng ca mt kim loi trong hn hp A l
A. 51,85% B. 22,32% C. 77,78% D. 25,93%
Cu 27: X l dd H
2
SO
4
0,02M, Y l dd NaOH 0,035M. Khi trn ln dd X vi dd Y ta thu c dd Z c th tch bng
tng th tch hai dd mang trn v c pH = 2. T l th tch gia dd Y v dd X l
A. 2:1 B. 1:2 C. 3:2 D. 2:3
Cu 28: trung ho 28,8 gam hn hp gm axit axetic, ancol propylic v p-crezol cn 150 ml dd NaOH 2M. Mt
khc ho tan hon ton 28,8 gam hn hp trn trong hexan ri cho Na d vo th thu c 4,48 lt H
2
( ktc). Lng
p-crezol hn hp bng
A. 0,1 mol. B. 0,2 mol. C. 0,3 mol D. 0,4 mol
Cu 29: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dd A. Nu cho brom d vo dd A, sau
p hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc kh clo d vo dd A, p hon ton,
c cn dd thy khi lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l
A. 47,8% B. 64,3% C. 35,9% D. 39,1%
Cu 30: Tinh th NaCl kt tinh theo kiu mng lp phng tm mt. S ion clo tip gip vi mi ion natri l
A. 4. B. 12. C. 8. D. 6.
Cu 31: t chy hon ton 200 ml hp cht hu c X (cha C, H, O) vi 1200 ml kh O
2
(ly d). Sau p th tch
cn 1700 ml, sau khi i qua H
2
SO
4
c cn 900 ml v sau khi qua KOH cn 300 ml. Xc nh CTPT ca X, bit cc
kh c o cng iu kin.
A. C
4
H
8
O
2
. B. C
4
H
8
O. C. C
3
H
6
O
2
. D. C
3
H
8
O.
Cu 32: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton. Sn phm ca
p tc dng vi dung dich HCl d thu c kh A . Tnh th tch dd CuSO
4
10% (d = 1,1g/ml) ti thiu cn dng
hp th ht kh A?
A. 750,25lm B. 872,73ml C. 1018,18ml D. 525,25ml
Cu 33: Cho isopren p vi Br
2
theo t l 1:1. S sn phn thuc loi dn xut ibrom thu c (khng xt ng phn
hnh hc) l
A. 3. B. 4. C. 2. D. 1.
Cu 34: C bao nhiu ng phn l dn xut ca benzen c CTPT C
7
H
6
O
2
?
A. 4. B. 5. C. 2. D. 3.
52
Cu 35: Cho m gam Cu tc dng vi 100ml dd hn hp HNO
3
0,9M v H
2
SO
4
0,2M thu c 0,672 lt kh NO ktc
l sn phm duy nht v dd X c pH = x. Gi tr ca m v x l
A. 2,88 v 1,5. B. 1,92 v 1,5. C. 1,92 v 1,0 D. 2,88 v 1,0
A. M ng vt ch yu cu thnh t cc este ca cc axit bo no, tn ti th rn.
B. Du thc vt ch yu cu thnh t cc este ca cc axit bo khng no, tn ti th lng.
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn.
D. Cht bo nh hn nc v khng tan trong nc
Cu 37: Polime no di dy c cu to khng iu ho?
A.
-H
2
C - C - C - CH
2
- CH
2
- C - C- CH
2
-
CH
3
CH
3
Cl
Cl
CH
3
CH
3
Cl
Cl
B.
-H
2
C - C - CH
2
- C - CH
2
- C - CH
2
-C-
CH
3
H
CH
3
H
CH
3
H
CH
3
H

C.
-H
2
C - C = C - CH
2
- CH
2
- C = C- CH
2
-
Cl
H
Cl
H
D.
-H
2
C - C - CH
2
- C - C H
2
- C -
H H
OOCCH
3
H
OOCCH
3
OOCCH
3

Cu 38: C 6 ng nghim, mi ng nghim cha mt trong cc dd sau: glixerol; glucoz; lng trng trng; axit fomic;
natri hiroxit; axit axetic . phn bit 6 dd ny c th dng mt loi thuc th l
A. Qi tm. B. CuSO
4
. C. AgNO
3
/NH
3
. D. Br
2
.
Cu 39: t chy hon ton 0,336 lt kh ( ktc) mt ankaien lin hp X. Sn phm chy c hp th hon ton
vo 40 ml dd Ba(OH)
2
1,5M thu c 8,865 gam kt ta . CTPT ca X l
A. C
3
H
4
hoc C
5
H
8
B. C
4
H
6
. C. C
3
H
4
. D. C
5
H
8
.
Cu 40: Khi trng ngng 7,5 gam axit amino axetic vi hiu sut 80%, ngoi amino axit cn d, thu c m gam
polime v 1,44 gam H
2
O. Gi tr ca m l
A. 5,56. B. 6,00. C. 4,25. D. 4,56.
Cu 41: Thm t t 300ml dd HCl 1M vo 200ml dd hn hp gm Na
2
CO
3
1M v NaHCO
3
0,5M c dd A v gii
phng V lt kh CO
2
ktc . Cho thm nc vi vo dd A ti d thu c m gam kt ta trng. Gi tr ca m v V l
A. 15gam v 3,36lt B. 10gam v 3,36lt C. 10gam v 2,24lt D. 15gam v 2,24lt
Cu 42: So snh tnh baz ca cc cht sau: (a) C
6
H
5
NH
2
; (b) CH
3
-NH
2
; (c) CH
3
-C
6
H
4
-NH
2
; (d) O
2
N-C
6
H
4
-NH
2

A. a> b > c > d B. a > b > d > c C. b > c > a > d D. b > c > d > a
Cu 43: ng vi CTPT C
3
H
6
O c bao nhiu hp cht mch h bn khi tc dng vi H
2
(Ni, t
0
) sinh ra ancol?
A. 4. B. 1. C. 2. D. 3.
Cu 44: Tn gi cho peptit
H
2
N-CH-CO-NH-CH
2
-CO-NH-CH-COOH
CH
3
CH
3

A. alanylglyxylalanyl. B. glixylalanylglyxin. C. glixylalanylglyxin. D. alanylglixylalanin.
Cu 45: Cho cc cht: tinh bt, benzen, cht bo, protein. S cht khi t chy ht trong khng kh to ra hn hp
chy gm CO
2
, H
2
O, N
2
lA. 4. B. 5. C. 6. D. 3.
Cu 46: un nng 132,35 gam axit axetic vi 200 gam ancol isoamylic ((CH
3
)
2
CH-CH
2
CH
2
-OH) c H
2
SO
4
lm xc
tc thu c isoamyl axetat (du chui). Tnh lng du chui thu c, bit hiu sut p t 68%.
A. 97,5 gam. B. 195,0 gam. C. 292,5 gam. D. 159,0 gam
Cu 47: Trong s cc cht l propan, etyl clorua, axeton, v etyl axetat, th cht tan tt nht trong nc l
A. propan. B. etyl clorua C. etyl axetat D. axeton
Cu 48: Hn hp X gm CO v NO c t khi hi so vi H
2
l 14,5. V(l) hn hp X tc dng va vi 1,6g O
2
c
hn hp Y. Cho Y sc vo 200 ml dd NaOH 2M c 200ml dd A . S cht tan trong dd A v nng ca mt cht
trong dd A lA. 4 v 0,20M B. 4 v 0,25M C. 3 v 0,25M D. 3 v 0,20M
Cu 49: Nhng cu sau y, cu no sai ?
A. Cc nguyn t lin kt vi nhau thnh phn t chuyn sang trng thi c nng lng thp hn.
B. Phn t NH
4
NO
3
cha cc lin kt ion, lin kt cng ho tr.
C. Trong nhm A, cc nguyn t c xp theo chiu s hiu nguyn t tng dn.
D. Nguyn t ca cc nguyn t cng chu k c s electron bng nhau.
Cu 50: Hin tng ca th nghim no di y c m t khng ng?
A. Cho Br
2
vo dung dich phenol xut hin kt ta mu trng.
B. Cho qu tm vo dd phenol, qu chuyn mu .
C. Cho phenol vo dd NaOH, ban u phn lp, sau to dd ng nht.
D. Thi kh CO
2
qua dd natri phenolat xut hin vn c mu trng.

53
TRNG THPT VIT YN 2

THI TH I HC LN TH 11
NM HC 2011-2012
MN : HA HC - KHI A, B
H, tn th sinh:..........................................................................
S bo danh:...............................................................................
M thi 132

I. Phn chung cho tt c cc th sinh: 40 cu
Cu 1: Hp cht A c cng thc phn t C
4
H
6
Cl
2
O
2
. Cho 0,1 mol A tc dng va vi dung dch c cha 0,3 mol
NaOH, thu c dung dch hn hp trong c hai cht hu c gm ancol etylic v cht hu c X, c cn dung dch
sau phn ng thu c m gam cht rn khan. Khi lng m l:
Cu 2: Nhn nh no sau y khng ng?
A. Axeton khng lm mt mu dung dch KMnO
4
iu kin thng.
B. Cc xeton khi cho phn ng vi H
2
u sinh ra ancol bc 2.
C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton.
D. Cc hp cht c cha nhm >C=O u phn ng vi dung dch Br
2
.
Cu 3: Cho 70g hn hp phenol v cumen tc dung vi dung dch NaOH 16% va , sau phn ng thy tch ra hai
lp cht lng phn cch, chit thy lp pha trn c th tch l 80 ml v c khi lng ring 0,86g/cm
3
. % theo khi
lng ca cumen trong hn hp l:
A. 26,86% B. 98,29% C. 73,14% D. 56,8%
Cu 4: Cho 27,3 gam hn hp A gm hai este no, n chc tc dng va vi dung dch KOH, thu c 30,8 gam
hn hp hai mui ca 2 axit k tip v 16,1 gam mt ancol. Khi lng ca este c khi lng phn t nh c trong
hn hp A l
A. 21 gam. B. 22 gam. C. 17,6 gam. D. 18,5 gam.
Cu 5: Ch dng qu tm c th nhn bit c ti a bao nhiu dung dch trong cc dung dch sau: NaCl, NaHCO
3
,
Na
2
CO
3
, NaHSO
4
, NaNO
3
, NaOH.
A. 3 B. 2 C. 4 D. 6
Cu 6: Cho 13,62 gam trinitrotoluen (TNT) vo mt bnh ng bng thp c dung tch khng i 500ml (khng c
khng kh) ri gy n. Sau phn ng nhit bnh l 1800
0
C, p sut trong bnh l P atm, bit rng sn phm kh trong
bnh sau n l hn hp CO, N
2
, H
2
. P c gi tr l:
A. 224,38 B. 203,98 C. 152,98 D. 81,6
Cu 7: trung ho dung dch cha 0,9045 gam 1 axit hu c A cn 54,5 ml dung dch NaOH 0,2 M. Trong dung
dch ancol B 94% (theo khi lng) t s mol ancol : nc l 86:14. Cng thc ca A v B l:
A. C
4
H
8
(COOH)
2
, C
2
H
5
OH B. C
6
H
4
(COOH)
2
, CH
3
OH
C. C
4
H
8
(COOH)
2
, CH
3
OH D. C
6
H
4
(COOH)
2
, C
2
H
5
OH.
Cu 8: Cc cht kh sau: SO
2
, NO
2
, Cl
2
, N
2
O, H
2
S, CO
2
. Cc cht kh khi tc dng vi dung dch NaOH ( nhit
thng) lun to ra 2 mui l:
A. NO
2
, SO
2
, CO
2
B. CO
2
, Cl
2
, N
2
O C. SO
2
, CO
2
, H
2
S D. Cl
2
, NO
2

Cu 9: Hp cht hu c X c cng thc phn t C
6
H
10
O
2
, cho 9,12 gam X tc dng vi dung dch NaOH va thu
c dung dch Y, cho dung dch Y tc dng vi dung dch AgNO
3
d trong NH
3
un nng thu c 34,56 gam Ag.
S ng phn cu to ca X l:
A. 4. B. 5 C. 2. D. 3.
Cu 10: Cho 11,36 gam hn hp gm Fe, FeO, Fe
2
O
3
, Fe
3
O
4
phn ng ht vi dung dch HNO
3
long d thu c
1,344 lt kh NO sn phm kh duy nht ( ktc) v dung dch X. Dung dch X c th ho tan c ti a 11,2 gam Fe.
S mol ca HNO
3
c trong dung dch ban u l:
Cu 11: Cho cc cht v dung dch sau: toluen, stiren, etilen, xiclopropan, isopren, vinyl axetat, etyl acrylat, ivinyl
oxalat, foocmon, axeton, dung dch glucoz, dung dch Fructoz, dung dch mantoz, dung dch saccaroz. S cht v
dung dch c th lm mt mu dung dch Br
2
l:
A. 11. B. 10 C. 8 D. 9
Cu 12: Ha tan 14g hn hp Cu, Fe
3
O
4
vo dung dch HCl, sau phn ng cn d 2,16g hn hp cht rn v dung
dch X. Cho X tc dng vi AgNO
3
d thu c bao nhiu gam kt ta:
A. 45,92 B. 12,96 C. 58,88 D. 47,4
Cu 13: Ho tan ht m gam Al
2
(SO
4
)
3
vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu c
2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc phn ng
xy ra hon ton, gi tr ca m l:
A. 18,81 B. 15,39 C. 20,52 D. 19,665
(1). O
3
+ dung dch KI (6). F
2
+ H
2
O
o
t

54
(2). MnO
2
+ HCl c
o
t
(7). H
2
S + dung dch Cl
2

(3). KClO
3
+ HCl c
o
t
(8). HF + SiO
2

(4). NH
4
HCO
3
o
t
(9). NH
4
Cl + NaNO
2
o
t

(5). NH
3(kh)
+ CuO
o
t
(10). Cu
2
S + Cu
2
O
S trng hp to ra n cht l:
A. 5. B. 6. C. 7. D. 8.
Cu 15: Ha tan 15,84 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl
d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c 6,048 lt
kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l:
A. 7,2. B. 11,52. C. 3,33. D. 13,68.
Cu 16: X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m (gam) hn hp cha X v Y c t l s mol ca
X v Y tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn
dung dch T thu c 56,4 gam cht rn khan. Gi tr ca m l:
A. 45,6 B. 40,27. C. 39,12. D. 38,68.
Cu 17: C cc nhn xt sau:
1- Cht bo thuc loi cht este.
2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng.
3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
4- Nitro benzen phn ng vi HNO
3
c (xc tc H
2
SO
4
c) to thnh m-initrobenzen.
5- phenyl amoni clorua phn ng vi nc brom d to thnh (2,4,6-tribromphenyl) amoni clorua.
Nhng cu ng l:
A. 1, 3, 4. B. 2, 3, 4. C. Tt c. D. 1, 2, 4, 5.
Cu 18: Mt loi phn Supephotphat kp c cha 72,68% mui canxi ihirophotphat cn li gm cc cht khng
cha pht pho. dinh dng ca loi phn ln ny l:
A. 60,68% B. 37,94% C. 30,34% D. 44,1%
A. Cht bo nh hn nc v khng tan trong nc
B. M ng vt ch yu cu thnh t gc axit bo, no, tn ti trng thi rn
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn
D. Nhc im ca cht git ra tng hp l gy nhim cho mi trng
Cu 20: Cho cc cht sau: FeBr
3
, FeCl
2
, Fe
3
O
4
,

AlBr
3
, MgI
2
, KBr, NaCl, CaF
2
,

CaC
2
. Axit H
2
SO
4
c nng c th oxi
ha bao nhiu cht?
A. 3 B. 6 C. 5 D. 7
Cu 21: Cho ankan X tc dng vi clo (as) thu c 26,5 gam hn hp cc dn xut clo (mono v iclo). Kh HCl bay
ra c hp th hon ton bng nc sau trung ha bng dd NaOH thy tn ht 500 ml dd NaOH 1M. Xc nh CT
ca X?
A. C
2
H
6
B. C
4
H
10
C. C
3
H
8
D. CH
4

Cu 22: Cho cc cht: xiclobutan, metylxiclopropan, 1,2-imetylxiclopropan, -butilen, but-1-in, trans but-2-en,
butaien, vinyl axetilen, isobutilen, anlen. C bao nhiu cht trong s cc cht trn khi tc dng vi hiro c th to ra
butan.
A. 8 B. 9 C. 7 D. 6
Cu 23: Khi iu ch Na trong cng nghip ngi ta dng hn hp gm 2 phn NaCl v 3 phn CaCl
2
v khi lng
vi mc ch:
A. To ra nhiu cht in ly hn
B. Tng nng ion Cl
-

C. Gim nhit nng chy
D. To ra hn hp c khi lng ring nh ni ln trn Na nng chy

Na
2
O
2
+ H
2
O
Cl
2
+ KOH
Fe
3
O
4
+ H
2
SO
4
(loang)
t
o
c
CH
3
-CH=CH
2
+ Br
2
(dd)
CH
2
=CH
2
+ H
2
O
C
2
H
5
OH + HBr (bk)
CH
3
-CHO + H
2
t
o
c
H
Mg(NO
3
)
2

Trong cc phn ng trn c bao nhiu phn ng l oxh-kh, bao nhiu phn ng ni phn t:
A. 7 4 B. 6 4 C. 5 4 D. 6 2
Cu 25: Sb cha 2 ng v chnh
121
Sb v
123
Sb, khi lng nguyn t trung bnh ca Sb l 121,75. % khi lng ca ng
v
121
Sb trong Sb
2
O
3
(M
O
=16) l:
A. 52,2 B. 62,5 C. 26,1 D. 51,89
55
Cu 26: Cho H (Z=1), N (Z=7), O (Z=8). Trong phn t HNO
3
, tng s cp electron lp ngoi cng khng tham gia
lin kt ca 5 nguyn t l:
A. 8. B. 9. C. 7. D. 6.
Cu 27: Mt loi cao su buna-N c phn trm khi lng ca nit l 19,72%. T l mt xch butaien v vinyl xianua
l:
A. 1 : 2 B. 2 : 1 C. 1 : 3 D. 3 : 1
Cu 28: Cho cc cn bng sau:
(1) 2NH
3(k)
N
2(k)
+ 3H
2(k)
A H > 0 (2) 2SO
2(k)
+ O
2(k)
2SO
3(k)
A H < 0
(3) CaCO
3(r)
CaO
(r)
+ CO
2(k)
A H > 0 (4) H
2(k)
+ I
2(k)
2HI
(k)
A H < 0
Trong cc cn bng trn cn bng no s chuyn dch theo chiu thun khi tng nhit v gim p sut:
A. 1, 3. B. 2, 4. C. 1, 2, 3 ,4. D. 1, 4.
Cu 29: Cho cc dung dung dch sau: (1): natri cacbonat; (2): st (III) clorrua; (3): axit sunfuaric long; (4): axit
axetic; (5): natri phenolat; (6): phenyl amoni clorua; (7): imetyl amoni clorua. Dung dch metylamin tc dng c
vi dung dch:
A. 3, 4, 6, 7 B. 2, 3, 4, 6 C. 2, 3, 4, 5 D. 1, 2, 4, 5
Cu 30: Cho mt ipeptit Y c cng thc phn t C
6
H
12
N
2
O
3
. S ng phn peptit ca Y (ch cha gc -amino axit)
mch h l:
A. 5. B. 4. C. 7. D. 6.
Cu 31: Cho dung dch mui X vo cc dung dch Na
2
CO
3
; dung dch Na
2
S u thy c kt ta v c kh bay ln. Vy X l :
A. AlCl
3
B. FeCl
3
C. FeCl
2
D. CuCl
2
.
Cu 32: C cc pht biu sau y:
(1) Amiloz c cu trc mch phn nhnh. (2) Mantoz b kh ha bi dd AgNO
3
trong NH
3
.
(3) Xenluloz c cu trc mch phn nhnh. (4) Saccaroz lm mt mu nc brom.
(5) Fructoz c phn ng trng bc. (6) Glucoz tc dng c vi dung dch thuc tm.
(7) Trong dung dch, glucoz tn ti ch yu dng mch vng v mt phn nh dng mch h.
S pht biu ng l:
A. 6. B. 4. C. 5. D. 3.
Cu 33: Gi thit trong tinh th cc nguyn t st l nhng hnh cu chim 74% th tch tinh th, phn cn li l cc
khe rng gia cc qu cu, cho nguyn t khi ca Fe l 55,85 20
0
C khi lng ring ca Fe l 7,87g/cm
3
. Bn knh
nguyn t gn ng ca Fe l:
A. 1,28 A
0
. B. 1,41A
0
. C. 1,67 A
0
. D. 1,97 A
0
.
Cu 34: Cho 7,8 gam hn hp X gm 2 ancol n chc, bc I qua CuO d, nung nng (phn ng hon ton) sau phn
ng thy khi lng cht rn gim 3,2 gam. Cho hn hp sn phm tc dng vi AgNO
3
d trong NH
3
, un nng thu
c m gam Ag. Gi tr ca m l:
A. 64,8 B. 43,2 C. 21,6 D. 86,4
Cu 35: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch Y. Nu cho brom d vo
dung dch Y, sau phn ng hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc kh clo d
vo dung dch Y, phn ng hon ton, c cn dung dch thy khi lng mui khan gim 22,625 gam. Thnh phn %
khi lng ca mt cht trong hn hp X l:
A. 35,9% B. 47,8% C. 33,99% D. 64,3%
Cu 36: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp kh X
gm CO
2
, CO v H
2
. Hp th X vo dung dch Ba(OH)
2
d thu c 35,46 gam kt ta v c V lt kh Y thot ra. Cho
Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l:
Cu 37: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O
2
(iu kin chun).
Dn sn phm chy qua bnh ng dung dch Ca(OH)
2
d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca
m l
A. 10,0 B. 12,0 C. 15,0 D. 20,5
Cu 38: C cc pht biu sau:
(1) Lu hunh, photpho, C
2
H
5
OH u bc chy khi tip xc vi CrO
3
.
(2) Ion Fe
3+
c cu hnh electron vit gn l [Ar]3d
5
.
(3) Bt nhm t bc chy khi tip xc vi kh clo.
(4) Phn chua c cng thc l Na
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O.
Cc pht biu ng l:
A. (1), (2), (4) B. (1), (2). C. (1), (2), (3). D. (3), (4).
Cu 39: in phn c mng ngn vi in cc tr 250 ml dung dch hn hp CuSO
4
aM v NaCl 1,5M, vi cng
dng in 5A trong 96,5 pht. Dung dch to thnh b gim so vi ban u l 17,15g. Gi tr ca a l
A. 0,5 M. B. 0,4 M. C. 0,474M. D. 0,6M.
56
Cu 40: Nung hn hp gm 11,2 gam Fe; 6,4 gam Cu v 19,5 gam Zn vi mt lng d lu hunh n khi phn ng
hon ton. Sn phm ca phn ng tc dng vi dung dch HCl d thu c kh B. Th tch dung dch Pb(NO
3
)
2
20%
(d = 1,1 g/ml) ti thiu cn dng hp th ht kh B l
A. 752,27 ml B. 902,73 ml C. 1053,18 ml D. 910,25 ml
II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II )
Phn I: Theo chng trnh Chun
Cu 41: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz,
anehit axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l
A. 6 B. 8 C. 7 D. 5
Cu 42: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch NaOH
1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO
2
( ktc) v 14,76 gam H
2
O. % s mol
ca axit linoleic trong m gam hn hp X l:
A. 31,25% B. 30% C. 62,5% D. 60%
Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l:
A. Na, K, Ba B. Ca, Sr, Ba C. Mg, Ca, Ba D. Na, K, Mg
Cu 44: Xt phn ng: CO(kh) + H
2
O (kh) CO
2
(kh) + H
2
(kh). Trong iu kin ng nhit, khi tng p sut ca
h th tc phn ng nghch nh th no?
A. Gim. B. Tng. C. C th tng hoc gim D. Khng i.
Cu 45: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl
3
, thm tip H
2
O
2
d, ri
cho dung dch BaCl
2
vo l:
A. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng.
B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam.
C. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng.
D. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng.
Cu 46: Hn hp X gm hai anken c t khi so vi H
2
bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam H
2
.
Cho Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0
o
C thy p
sut trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch ca bnh khng i.
Hiu sut phn ng hiro ho l
A. 40%. B. 50%. C. 75%. D. 77,77%.
Cu 47: X c cng thc C
4
H
14
O
3
N
2
. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh
iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l:
A. 5 B. 3 C. 4 D. 2
Cu 48: C hai th nghim sau:
Th nghim 1: Cho 6g ancol no h n chc X tc dng vi m gam Na, sau phn ng thu c 0,075 gam H
2
.
Th nghim 2: Cho 6g ancol no h n chc X tc dng vi 2m gam Na, sau phn ng thu khng ti 0,1gam H
2
.
X c cng thc l:
A. CH
3
OH. B. C
2
H
5
OH. C. C
3
H
7
OH. D. C
4
H
9
OH.
Cu 49: Ha tan m gam hh X gm CuCl
2
v FeCl
3
trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau.
Phn 1 : cho kh H
2
S d vo c 1,28g kt ta. Phn 2 : cho Na
2
S d vo c 3,04g kt ta. Gi tr ca m l :
A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g
Cu 50: xc nh hm lng ca FeCO
3
trong qung xierit, ngi ta lm nh sau: Cn 0,600 gam mu qung, ch
ho n theo mt quy trnh hp l, thu c dd FeSO
4
trong mi trng H
2
SO
4
long. Chun dung dch thu c
bng dung dch chun KMnO
4
0,025M th dng va ht 25,2 ml dung dch chun.Thnh phn phn trm theo khi
lng ca FeCO
3
trong qung l:
A. 12,18% B. 60,9% C. 24,26% D. 36,54%
Phn II: Theo chng trnh nng cao
Cu 51: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CONH
trong 2 phn t l 5) vi t l s mol n
X
: n
Y
= 1: 2. Khi thy phn hon ton m gam M thu c 12 gam glixin v 5,34
gam alanin. m c gi tr l :
A. 14,46g B. 110,28g C. 16,548 D. 15,86g
Anehit no, mch h X
1

+
o
t Ni H , /
2
X
2

O H
2
X
3

xt p t
o
, ,
Cao su buna.
Anehit no mch h X
4

+
o
t Ni H , /
2
X
5

2 2
, H O H
X
3

xt p t
o
, ,
Cao su buna.
Hy cho bit: khi cho X
1
v X
4
vi khi lng bng nhau tc dng hon ton vi dung dch AgNO
3
trong NH
3
un
nng, cht no to ra lng Ag nhiu hn ?
A. bng nhau. B. X
1
.
C. X
4
. D. khng xc nh c.
Cu 53: Cho dung dch CH
3
COONa 0,1M (K
b
Ca CH
3
COO
-
l 5,71.10
-10
). Nng mol/l ca H
+
trong dung dch
bng:
57
A. 1,2.10
-9
mol/l B. 1.32.10
-9
mol/l C. 1,15.10
-9
mol/l D. 2,25.10
-10
mol/l
Cu 54: Cho dung dch AgNO
3
vo dung dch X c kt ta to thnh, lc ly kt ta cho vo dung dch NH
3
thy kt
ta tan.

Vy X
A. ch c th l NaCl. B. ch c th l Na
3
PO
4
.
C. l NaCl hay NaBr. D. l NaCl, NaBr hay NaI.
Cu 55: X l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi K
2
CO
3
c
mt khng kh th chuyn thnh cht Y c mu vng (d tan trong nc). Cho cht Y tc dng vi H
2
SO
4
long to
thnh cht Z c mu da cam. Cht Z tc dng vi HCl c thy to thnh cht kh mu vng lc. X, Y, Z ln lt l
A. Cr
2
O
3
, K
2
CrO
4
, K
2
Cr
2
O
7
. B. CrO, K
2
CrO
4
, K
2
Cr
2
O
7
.
C. CrO, K
2
Cr
2
O
7
, K
2
CrO
4
. D. CrO
3
, K
2
Cr
2
O
7
, K
2
CrO
4
.
Cu 56: Ha tan 1,0 gam qung crom trong axit, oxi ha Cr
3+
thnh Cr
2
O
7
2-
. Sau khi phn hy ht lng d cht
oxi ha, pha long dd thnh 100 ml. Ly 20 ml dd ny cho vo 25 ml dd FeSO
4
trong H
2
SO
4
. Chun lng d
FeSO
4
ht 7,50 ml dd chun K
2
Cr
2
O
7
0,0150M. Bit rng 25 ml FeSO
4
tng ng vi 35 ml dd chun K
2
Cr
2
O
7
.
Thnh phn % ca crom trong qung l:
A. 10,725% B. 13,65%. C. 35,1%. D. 26%.
Cu 57: Hn hp X c C
2
H
5
OH, C
2
H
5
COOH, CH
3
CHO (trong C
2
H
5
OH chim 50% theo s mol). t chy m gam
hn hp X thu c 2,88 gam H
2
O v 2,912 lt CO
2
(ktc). Mt khc 9 gam hn hp X thc hin phn ng trng bc
thy c p gam Ag kt ta. Gi tr ca p l
A. 12,96. B. 4,32. C. 8,64. D. 5,4.
Cu 58: Cho s : Propilen

+
+ H O H ,
2
A

+
o
t CuO,
B

+HCN
D. D l:
A. CH
3
CH
2
CH
2
OH B. CH
3
CH
2
CH(OH)CN
C. CH
3
C(OH)(CH
3
)CN D. CH
3
CH(OH)CH
3
.
Cu 59: Ha tan hon ton hn hp gm mt kim loi ha tr 1 v oxit kim loi ha tr 2 vo nc d. Sau khi phn
ng xong c 500 ml dd X ch cha mt cht tan duy nht v 4,48 lt kh H
2
. Tnh nng mol ca dung dch X:
A. 0,2M B. 0,4 M C. 0,3M D. 0,25 M
Cu 60: T khi ca mt hn hp kh ( gm 2 hidrocacbon mch h) so vi hidro l 17. iu kin tiu chun, trong bng
ti, 400 ml hn hp tc dng va vi 71,4 cm
3
dung dch brom 0,2 M. Sau phn ng th tch kh cn li l 240 cm
3
. Cng
thc phn t ca 2 hidrocacbon l:
A. C
2
H
2
v C
3
H
8
B. CH
4
v C
4
H
6
C. C
2
H
6
v C
3
H
6
D. C
2
H
6
v C
3
H
4

----------- HT ----------

58
TRNG THPT VIT YN 2

THI KHO ST CHT LNG LP 12 LN 12, NM 2012
Mn: HA HC
(Thi gian lm bi: 90 pht; 50 cu trc nghim)

H v tn .................................................................. S bo danh ..........................
M thi 132

Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Al = 27; N =
14; Ca = 40; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Zn = 65; K = 39; Mn = 55; Ag = 108; Br = 80.

A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40)
Cu 1: Cho 2 h cn bng sau trong hai bnh kn:
C
(r)
+ H
2
O
(k)

CO
(k)
+ H
2 (k)
; H A = 131 kJ v CO
(k)
+ H
2
O
(k)

CO
2

(k)
+ H
2 (k)
; H A = - 41 kJ
C bao nhiu iu kin trong cc iu kin sau y lm cc cn bng trn dch chuyn ngc chiu nhau?
(1) Tng nhit . (2) Thm lng hi nc vo. (3) Thm kh H
2
vo.
(4) Tng p sut. (5) Dng cht xc tc. (6) Thm lng CO vo.
A. 3. B. 4. C. 1. D. 2.
Cu 2: Ch dng Cu(OH)
2
/OH
-
c th nhn bit c cc dung dch ng ring bit tng cht trong nhm no sau
y?
A. Anbumin, axit acrylic, axit axetic, etanal, glucoz. B. Etylen glicol, glucoz, tripeptit, ancol etylic,
glixerol.
C. Glucoz, fructoz, glixerol, axit axetic, metanol. D. Glucoz, glixerol, axit axetic, etanal, anbumin.
Cu 3: Ha tan 64 gam hn hp mui gm CuSO
4
, FeSO
4
, Fe
2
(SO
4
)
3
, MgSO
4
trong lu hunh chim 25% v khi
lng vo nc c dung dch X. Cho X tc dng vi dung dch Ba(OH)
2
va thu c m gam kt ta. Gi tr ca m
l
A. 149,5. B. 116,5. C. 50,0. D. 233,0.
Cu 4: Cho 12,6 gam hn hp Mg v Al c t l mol tng ng l 3:2 tc dng vi dung dch HNO
3
long, d thu
c dung dch X v 2,24 lt (ktc) hn hp hai kh khng mu, khng ha nu trong khng kh c t khi hi so vi
H
2
bng 18. S mol HNO
3
tham gia phn ng l
Cu 5: Cho anehit X mch h c cng thc phn t l C
x
H
y
(CHO)
z
. Cho 0,15 mol X phn ng vi lng d dung
dch AgNO
3
trong NH
3
th thu c 64,8 gam Ag. Cho 0,125a mol X phn ng vi H
2
d (xc tc Ni, un nng) th
th tch H
2
phn ng l 8,4a lt (ktc). Mi lin h x, y l
A. 2x y 2 = 0. B. 2x y 4 = 0. C. 2x y + 2 = 0. D. 2x y + 4 = 0.
Cu 6: Cho m gam mt o amino axit X (l dn xut ca benzen, ch cha 1 nhm -NH
2
trong phn t) tc dng va
vi 40 ml dung dch HCl 1M, dung dch thu c sau phn ng tc dng va vi 100 ml dung dch NaOH
0,8M. Mt khc, nu em 5m gam aminoaxit ni trn tc dng va vi dung dch KOH ri c cn s thu c 40,6
gam mui khan. S cng thc cu to tha mn ca X l
A. 5. B. 2. C. 3. D. 4.
Cu 7: Nhn xt no sau y khng ng v glucoz?
A. Ln men glucoz ch thu c C
2
H
5
OH v CO
2
.
B. Vng 6 cnh ca glucoz c c l do phn ng cng ca nhm -OH C
5
vo lin kt C=O ca nhm chc
anehit.
C. Glucoz c th to este cha 5 gc CH
3
COO trong phn t khi tham gia phn ng vi anhirit axetic c mt
piriin.
D. Glucoz tc dng c vi H
2
(xc tc Ni, un nng), Cu(OH)
2
, dung dch AgNO
3
trong NH
3
.
Cu 8: Este X tc dng vi NaOH theo t l mol 1:2 thu c mt mui v mt ancol c s mol bng nhau v bng s
mol X phn ng. Cho 11,6 gam X phn ng va vi 200 ml dung dch NaOH 1M thu c 6,2 gam ancol. Cng
thc phn t ca X l
A. C
5
H
6
O
4
. B. C
4
H
8
O
2
. C. C
4
H
4
O
4
. D. C
3
H
6
O
2
.
Cu 9: Cho X (Z = 24), Y (Z = 26).
3
X
+
,
2
Y
+
c cu hnh electron ln lt l
A. [Ne]3d
4
, [Ne]3d
4
4s
2
. B. [Ne]3d
3
, [Ne]3d
6
. C. [Ar]3d
3
, [Ar]3d
6
. D. [Ar]3d
3
, [Ar]3d
5
.
Cu 10: Nung nng hn hp X gm 0,1 mol axetilen; 0,2 mol xiclopropan; 0,1 mol etilen v 0,6 mol hiro vi xc tc
Ni, sau mt thi gian thu c hn hp Y c t khi so vi H
2
bng 12,5. Cho hn hp Y tc dng vi brom d trong
CCl
4
thy c ti a a gam brom phn ng. Gi tr ca a l
A. 32. B. 24. C. 8. D. 16.
Cu 11: Cho m gam cht bo to bi axit panmitic v axit oleic tc dng ht vi dung dch NaOH va thu c
dung dch X cha 129 gam hn hp 2 mui. Bit 1/2 dung dch X lm mt mu va vi 0,075 mol Br
2
trong CCl
4
.
Gi tr ca m l
A. 64,35. B. 132,90. C. 128,70. D. 124,80.
59
Cu 12: Geranial (3,7-imetyl oct-2,6-ien-1-al) c trong tinh du s c tc dng st trng, gim mt mi, chng cng
thng, ... phn ng cng hon ton vi 28,5 gam geranial cn ti a bao nhiu gam brom trong CCl
4
?
A. 60 gam. B. 30 gam. C. 90 gam. D. 120 gam.
Cu 13: Cho t t dung dch cha 0,2 mol HCl vo dung dch cha m gam hn hp X gm Na
2
CO
3
, KHCO
3
th thy c
0,1 mol kh CO
2
thot ra. Cho dung dch Ca(OH)
2
d vo m/2 gam hn hp X nh trn thy c 15 gam kt ta. Gi tr
ca m l
A. 31,20. B. 30,60. C. 39,40. D. 19,70.
Cu 14: Nhn xt no sau y khng ng v kim loi kim?
A. Cu hnh electron lp ngoi cng ca kim loi kim l ns
1
vi n nguyn v 1 n 7 < s .
B. Kim loi kim kh H
2
O d dng nhit thng gii phng H
2
.
C. Kim loi kim c cu trc mng tinh th lp phng tm khi nn chng c nhit nng chy, nhit si
thp.
D. Khi cho kim loi kim vo dung dch HCl th kim loi kim phn ng vi dung mi H
2
O trc, vi axit sau.
Cu 15: Trong cc cht sau: amoniac, hiroflorua, metylamin, ancol etylic, axit axetic, axeton, axetanehit, glixerol,
etylclorua, tristearin. C bao nhiu cht trong cc cht trn m gia cc phn t ca n c th c lin kt hiro?
A. 6. B. 5. C. 4. D. 8.
Cu 16: Thnh phn % khi lng ca nit trong hp cht hu c C
x
H
y
N l 16,092%. S ng phn amin bc 2 tha
mn iu kin trn l
A. 8. B. 4. C. 9. D. 6.
Cu 17: Trong nhng cht sau: C
2
H
2
, C
2
H
6
, CH
3
OH, HCHO, C
3
H
6
, CH
3
COOH c bao nhiu cht c sinh ra t CH
4

bng mt phn ng ?
A. 1. B. 3. C. 2. D. 4.
Cu 18: Thc hin phn ng nhit nhm (trong iu kin khng c khng kh, hiu sut 100%) vi 9,66 gam hn hp
X gm Al v mt oxit st, thu c hn hp rn Y. Ha tan Y bng dung dch NaOH d, sau khi cc phn ng xy ra
hon ton thu c dung dch Z, cht khng tan T v 0,03 mol kh. Sc CO
2
n d vo dung dch Z, lc ly kt ta
nung n khi lng khng i c 5,1 gam mt cht rn. Cng thc ca oxit st v khi lng ca n trong hn hp
X trn l
A. Fe
3
O
4
v 2,76 gam. B. Fe
3
O
4
v 6,96 gam. C. FeO v 7,20 gam. D. Fe
2
O
3
v 8,00 gam.
Cu 19: ipeptit X, pentapeptit Y u mch h v cng c to ra t 1 amino axit no, mch h trong phn t c 1
nhm -NH
2
v 1 nhm -COOH. Cho 16 gam X tc dng ht vi dung dch HCl d, lm kh cn thn dung dch sau
phn ng thu c 25,1 gam cht rn. Vy khi t chy hon ton 0,2 mol Y th cn t nht bao nhiu mol O
2
nu sn
phm chy thu c gm CO
2
, H
2
O, N
2
?
Cu 20: S phn ng n gin nht iu ch nha novolac (dng sn xut bt p, sn) nh sau:
+ nCH
2
=O
n
n
n
CH
2
OH
OH OH
CH
2
OH
H
+
, 75
0
C
- nH
2
O

nha novolac
thu c 10,6 kg nha novolac th cn dng x kg phenol v y kg dung dch fomalin 40% (hiu sut qu trnh
iu ch l 80%). Gi tr ca x v y ln lt l
A. 10,2 v 9,375. B. 9,4 v 3,75. C. 11,75 v 3,75. D. 11,75 v 9,375.
Cu 21: t chy hon ton hn hp 2 ancol thuc cng mt dy ng ng thu c CO
2
, hi H
2
O c t l th tch
tng ng l 2 : 2,75 ( cng iu kin nhit , p sut). Hai ancol c cng thc chung l
A. C
n
H
2n+2-x
(OH)
x
(3 s xs n). B. C
n
H
2n+1
OH (vi n > 1) hoc C
n
H
2n
(OH)
2
(vi n > 2).
C. C
n
H
2n
(OH)
2
(vi n > 2). D. C
n
H
2n+1
OH (vi n > 1).
Cu 22: Tin hnh cc th nghim sau:
(1) t Mg trong kh CO
2
. (2) t Ag
2
S bng O
2
. (3) Cho O
3
vo dung dch KI.
(4) Cho F
2
vo H
2
O. (5) Cho dung dch KI vo dung dch FeCl
3
d nhit thng.
S th nghim to ra sn phm c n cht l
A. 4. B. 5. C. 3. D. 2.
Cu 23: Khi oxi ha ht 7,25 gam mt anehit n chc X th thu c 9,25 gam axit tng ng. Vy X l
A. propenal. B. propanal. C. butanal. D. etanal.
Cu 24: Hai hp cht hu c mch h c cng thc phn t ln lt l C
2
H
8
O
3
N
2
v C
3
H
7
O
2
N u tc dng vi dung
dch NaOH un nng, cho hai amin n chc bc 1 thot ra. Nhn xt no sau y ng v hai hp cht hu c trn?
A. Chng u tc dng vi dung dch brom. B. Chng u l cht lng tnh.
C. Phn t ca chng u c lin kt ion. D. Chng u tc dng vi H
2
(xc tc Ni, un nng).
Cu 25: Thp khng g c thnh phn khi lng 74% Fe, 18% Cr, 8% Ni c dng ch to dng c y t, dng c
nh bp. Khi lng qung pirit cha 60% FeS
2
dng sn xut gang t iu ch 1,12 tn thp khng g trn l
bao nhiu? (bit hiu sut c qu trnh sn xut l 80%, cc kim loi cn thit khc c sn).
A. 1,776 tn. B. 3,700 tn. C. 1,332 tn. D. 2,368 tn.
60
Cu 26: Dung dch cha mui X khng lm qu ha , dung dch cha mui Y lm qu ha . Trn 2 dung dch
trn vi nhau thy sn phm c kt ta v c kh bay ra. Vy X, Y ln lt l
A. Ba(HSO
4
)
2
v Na
2
CO
3
. B. K
2
SO
4
v Ba(HCO
3
)
2
.
C. BaCl
2
v Na
2
CO
3
. D. Ba(HCO
3
)
2
v NaHSO
4
.
Cu 27: t chy hon ton hn hp X gm CH
2
O, CH
2
O
2
, C
2
H
2
O
2
u c cu to mch h v c s mol bng nhau
thu c CO
2
, H
2
O. Hp th ht sn phm chy bng nc vi trong d, sau phn ng thy khi lng dung dch gim
17 gam so vi khi lng nc vi trong ban u. Cho lng hn hp X nh trn tc dng vi lng d dung dch
AgNO
3
trong NH
3
th thu c ti a m gam Ag. Gi tr ca m l
A. 86,4. B. 108,0. C. 64,8. D. 54,0.
Cu 28: Pht biu no sau y khng ng ?
A. Cht git ra tng hp ra tri cc vt bn bm trn vi, da,do lm gim sc cng b mt ca cc cht bn.
B. Cht git ra tng hp c th git ra c trong nc cng.
C. Thnh phn chnh ca cht git ra tng hp thng l natri lauryl sunfat hoc natri oecylbenzensunfonat.
D. Thnh phn chnh ca cht git ra tng hp l hn hp mui natri hoc mui kali ca axit bo.
Cu 29: Cho 18,4 gam hn hp X gm Cu, Cu
2
S, CuS, Fe, FeS, S tc dng ht vi HNO
3
c nng, d thu c V lt
kh NO
2
(cht kh duy nht thot ra, sn phm kh duy nht, ktc) v dung dch Y. Cho Y tc dng vi dung dch
BaCl
2
d thu c 46,6 gam kt ta, cn khi cho Y tc dng vi dung dch NH
3
d th thu c 10,7 gam kt ta. Gi
tr ca V l
A. 16,80. B. 24,64. C. 38,08. D. 11,20.
Cu 30: Ha tan ht 4,4 gam hn hp X gm kim loi M, Fe
3
O
4
v Fe
2
O
3
c t l mol tng ng 2:1:1 bng dung dch
HCl ch thu c dung dch Y m trong ch cha 2 mui clorua c khi lng 8,25 gam. Vy M l
A. Cu. B. Mg. C. Fe. D. Al.
Cu 31: Cho 2 cc nc cha cc ion: Cc 1: Ca
2+
, Mg
2+
,
3
HCO
. Cc 2: Ca
2+
,
3
HCO
, Cl
, Mg
2+
.
kh hon ton tnh cng ca nc c 2 cc ngi ta
A. cho vo 2 cc dung dch NaOH d. B. un si mt hi lu 2 cc.
C. cho vo 2 cc mt lng d dung dch Na
2
CO
3
. D. cho vo 2 cc dung dch NaHSO
4
.
Cu 32: Cho 100 ml dung dch cha hn hp Ba(OH)
2
1M v KOH 2M vo 100 ml dung dch cha hn hp NaHCO
3

2M v NH
4
HCO
3
1M. Sau khi phn ng xy ra hon ton, un nng hn hp sau phn ng cho kh thot ra ht th
khi lng dung dch sau phn ng gim bao nhiu gam so vi tng khi lng hai dung dch tham gia phn ng?
(bit nc bay hi khng ng k).
Cu 33: Cho 100 ml dung dch cha NaOH 1M, KOH 1M v Ba(OH)
2
0,9M vo 100 ml dung dch AlCl
3
xM th thu
c 7,8 gam kt ta. Vy nu cho 150 ml dung dch NaOH 1M vo 100 ml dung dch AlCl
3
xM th khi lng kt
ta thu c v gi tr ca x l (bit cc phn ng xy ra hon ton)
A. 11,70 gam v 1,6. B. 9,36 gam v 2,4. C. 3,90 gam v 1,2. D. 7,80 gam v 1,0.
Cu 34: t chy mt hp cht hu c X n chc, mch h ch thu c CO
2
, H
2
O c s mol bng nhau v s mol
O
2
cn dng gp 4 ln s mol ca X phn ng. X lm mt mu Br
2
trong dung mi nc v cng H
2
d (xc tc Ni,
un nng) cho ancol. S cng thc cu to tha mn ca X l
A. 1. B. 4. C. 2. D. 3.
Cu 35: ng thau c tnh cng hn ng, dng ch to cc chi tit my, cc thit b trong cng nghip ng tu bin.
ng thau l hp kim ca ng vi
A. Ni (25%). B. Sn (55%). C. Zn (45%). D. Au (5%).
Cu 36: Cho cc l mt nhn ng ring bit dung dch ca tng cht sau: KHSO
4
, Na
2
CO
3
, AlCl
3
, FeCl
3
, NaCl,
Ca(NO
3
)
2
. Ch dng cht ch th phenolphtalein th c th phn bit c bao nhiu dung dch?
A. 5. B. 3. C. 6. D. 1.
Cu 37: Ha tan 72 gam hn hp gm Fe
2
(SO
4
)
3
v CuSO
4
c t l mol tng ng l 2:1 vo bnh ng 0,1 mol
H
2
SO
4
long th thu c dung dch X. Tin hnh in phn dung dch X (vi in cc tr) vi cng dng in
10A trong thi gian 1 gi 4 pht 20 giy. Khi lng dung dch sau in phn gim bao nhiu gam so vi dung dch
trc in phn? (gi s trong qu trnh in phn nc bay hi khng ng k)
Cu 38: Cho 18,3 gam hn hp X gm hai hp cht hu c n chc l dn xut ca benzen c cng cng thc phn
t C
7
H
6
O
2
tc dng ht vi dung dch AgNO
3
trong NH
3
thu c 10,8 gam Ag. Vy khi cho 9,15 gam X ni trn tc
dng vi 300 ml dung dch NaOH 1M, ri c cn dung dch sau phn ng s thu c bao nhiu gam cht rn khan ?
Cu 39: Cho a mol Fe vo dung dch cha b mol HNO
3
long thu c dung dch X v kh NO (sn phm kh duy
nht). iu kin dung dch X ha tan c Cu l
A. b > 4a. B. 3b > 8a. C. 3b s 8a. D. b s 4a.
Cu 40: 4,2 gam st trong khng kh mt thi gian thu c 5,32 gam hn hp X gm st v cc oxit ca n.
ha tan ht X cn 200 ml dung dch HNO
3
xM, thy sinh ra 0,448 lt kh NO (ktc, sn phm kh duy nht) v dung
dch Y. Vy gi tr ca x l
61
A. 1,3. B. 1,2. C. 1,1. D. 1,5.

B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II)
Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50)
Cu 41: iu ch metyl axetat t CH
4
(cc cht v c, xc tc cn thit v phng tin c ) cn t nht bao nhiu
phn ng?
A. 3. B. 2. C. 5. D. 4.
Cu 42: Nhng nhn xt no trong cc nhn xt sau l ng?
(1) Metyl-, imetyl-, trimetyl- v etylamin l nhng cht kh mi khai kh chu, c.
(2) Cc amin ng ng ca metylamin c tan trong nc gim dn theo chiu tng ca khi lng phn t.
(3) Anilin c tnh baz v lm xanh qu tm m.
(4) Lc baz ca cc amin lun ln hn lc baz ca amoniac.
A. (1), (2). B. (2), (3), (4). C. (1), (2), (3). D. (1), (2), (4).
Cu 43: Trong cc th nghim sau, th nghim no khng to ra NaHCO
3
?
A. Sc CO
2
vo dung dch natriphenolat. B. Sc CO
2
vo dung dch Na
2
CO
3
.
C. Sc CO
2
vo dung dch bo ha cha NaCl v NH
3
. D. Cho dung dch NaOH vo Ba(HCO
3
)
2
.
Cu 44: Ancol etylic (d = 0,8 gam/ml) c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu
trnh 80%. Hp th ton b lng CO
2
sinh ra khi ln men tinh bt vo 4 lt dung dch Ca(OH)
2
1M th thu c 320
gam kt ta, lc b kt ta, un nng dung dch thu c thy xut hin thm kt ta. Th tch ancol etylic 46
0
thu
c l
A. 0,40 lt. B. 0,48 lt. C. 0,60 lt. D. 0,75 lt.
Cu 45: Nhm cht no sau y c th c dng lm sch mui n c ln cc tp cht: CaBr
2
, MgSO
4
, CaCl
2
,
MgCl
2
m sau khi lm sch th NaCl c khi lng khng thay i so vi khi lng c trong hn hp ban u?
A. HCl, BaCl
2
, Na
2
CO
3
, NaOH. B. Cl
2
, BaCl
2
, (NH
4
)
2
CO
3
, HCl.
C. Cl
2
, Ba(NO
3
)
2
, Na
2
CO
3
, HCl. D. Cl
2
, BaCl
2
, Na
2
CO
3
, HCl.
Cu 46: Hn hp X gm olefin Y v hiro c t khi so vi He l 3,2. Dn X i qua bt Ni nung nng cho n khi
phn ng xy ra hon ton thu c hn hp Z c t khi so vi H
2
l 8. Vy cng thc phn t ca Y l
A. C
5
H
10
. B. C
2
H
4
. C. C
4
H
8
. D. C
3
H
6
.
Cu 47: Oxi ha khng hon ton mt ancol n chc X bng O
2
va vi cht xc tc thch hp thu c sn
phm ch gm hai cht v hn hp sn phm c t khi hi so vi H
2
bng 23. Vy X l
A. etanol. B. propan-1-ol. C. propan-2-ol. D. butan-1-ol.
Cu 48: Cho s chuyn ha sau:
Ca
3
(PO
4
)
2
2
0 0
SiO C Ca HCl
1200 C t
X Y Z T
+ + + +

2
+O d

X, Y, X, T ln lt l
A. CaC
2
, C
2
H
2
, C
2
H
4
, CO
2
. B. PH
3
, Ca
3
P
2
, CaCl
2
, Cl
2
.
C. CaSiO
3
, CaC
2
, C
2
H
2
, CO
2
. D. P, Ca
3
P
2
, PH
3
, P
2
O
5
.
Cu 49: Kh 46,4 gam Fe
3
O
4
bng CO trong mt thi gian thu c 43,52 gam hn hp cht rn X. Cho X tan hon
ton trong H
2
SO
4
c nng, d thy thot ra V lt SO
2
(ktc, sn phm kh duy nht). Gi tr ca V l
A. 6,272. B. 2,240. C. 4,302. D. 1,792.
Cu 50: Hp cht M
2
SO
4
.Al
2
(SO
4
)
3
.24H
2
O c gi l phn chua khi M
+
l
A. K
+
hoc NH
4
+
. B. Na
+
. C. K
+
. D. NH
4
+
.

Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60)
Cu 51: Khi tch nc ca glixerol iu kin thch hp thu c hp cht hu c X c cng thc C
3
H
4
O. Nhn xt
no sau y khng ng v X?
A. C phn ng vi brom trong dung mi nc. B. Cng HCl theo quy tc cng Maccopnhicop.
C. C phn ng trng hp. D. C phn ng trng bc.
Cu 52: Nhng dng c bng Ag s chuyn thnh mu en trong khng kh c H
2
S l do Ag tc dng vi
A. H
2
S. B. H
2
S v H
2
O. C. H
2
S v O
2
. D. H
2
S v N
2
.
Cu 53: Cho 48,24 gam hn hp Cu, Fe
3
O
4
vo dung dch H
2
SO
4
long d, sau phn ng cn li 3,84 gam kim loi
khng tan. Cho tip NaNO
3
d vo hn hp sau phn ng s thu c ti a V lt kh NO (ktc, sn phm kh duy
nht). Gi tr ca V l
A. 4,256. B. 0,896. C. 3,360. D. 4,480.
Cu 54: Oxi ha hon ton m gam p-xilen (p-imetylbenzen) bng dung dch KMnO
4
un nng, va thu c
dung dch X v cht rn Y. Cho cht rn Y phn ng ht vi dung dch HCl c, d thy thot ra x mol Cl
2
. S mol
HCl phn ng va vi cc cht c trong dung dch X l
A. 0,25x mol. B. 2x mol. C. 0,5x mol. D. x mol.
(1) FeCO
3
+ H
2
SO
4

c

0
t
kh X + kh Y + (4) FeS + H
2
SO
4

long
kh G +
62
(2) NaHCO
3
+ KHSO
4
kh X + (5) NH
4
NO
2
0
t
kh H +
(3) Cu + HNO
3(c)

0
t
kh Z + (6) AgNO
3

0
t
kh Z + kh I +
Trong cc cht kh sinh ra cc phn ng trn, s cht kh tc dng vi dung dch NaOH l
A. 4. B. 5. C. 6. D. 7.
Cu 56: Policaproamit (nilon-6) c th iu ch c t axit c -aminocaproic hoc caprolactam. c 8,475 kg
nilon-6 (vi hiu sut cc qu trnh iu ch u l 75%) th khi lng ca axit c -aminocaproic s dng nhiu hn
khi lng caprolactam l
A. 1,80 kg. B. 3,60 kg. C. 1,35 kg. D. 2,40 kg.
Cu 57: C bao nhiu cht trong cc cht sau: S, P, NH
3
, C, C
2
H
5
OH, H
2
O, NaOH kh c CrO
3
thnh Cr
2
O
3
?
A. 7. B. 5. C. 6. D. 4.
Cu 58: t chy hon ton V lt mt hirocacbon mch h X cn 7V lt O
2
v sinh ra 5V lt CO
2
( cng iu kin nhit
, p sut). X cng H
2
d (xc tc Ni, un nng) sinh ra hirocacbon no, mch nhnh. S cng thc cu to tha mn
ca X l
A. 1. B. 4. C. 2. D. 3.
Cu 59: Cho s chuyn ha sau:
X Y
Z
+ H
2
- H
2
O
pol i butai en
gl ucoz C
2
H
5
OH
HCHO

Vy Y l
A. butan-1,4-iol. B. butan-2,3-iol. C. butan-2,3-iol. D. but-3-en-1-ol.
Cu 60: Cho
0
Ag
Ag
E 0,8V
+
= ,
0
pin( Ni Cu)
E 0, 6V
= ,
0
pin (Cu Ag)
E 0, 46V
= . Vy
2
0
Ni
Ni
E
+
(V) c gi tr l
A. 0,94. B. 0,66. C. 0,26. D. 1,56.
-----------------------------------------------
----------- HT ----------

63

S GIO DC O TO BC GIANG
Trng THPT VIT YN 2

THI KHO ST CHT LNG KHI 12 LN 13
NM HC 2011-2012
MN HO HC 12 (Khi A)
(50 cu trc nghim)
H, tn th sinh:........................................................................
S bo danh:...............................................................................

HC SINH CHN MT P N NG THEO YU CU CA BI V T VO PHIU TR LI TRC
NGHIM

Cu 1: Mt hn hp gm Al
2
(SO
4
)
3
v K
2
SO
4
, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn
hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl
2
d, hi khi lng kt ta thu c gp bao
nhiu ln khi lng hn hp ban u?
A. 1,588 ln B. 1,788 ln C. 1,488 ln D. 1,688 ln
Cu 2: Trong s cc polime sau:
[- NH-(CH
2
)
6
- NH-CO - (CH
2
)
4
- CO-]
n
(1); [-NH-(CH
2
)
5
-CO -]
n
(2) ;
[-NH-(CH
2
)
6
- CO-]
n
(3) ; [C
6
H
7
O
2
(OOCCH
3
)
3
]
n
(4) ;
(-CH
2
-CH
2
-)
n
(5) ; (-CH
2
-CH=CH-CH
2
-)
n
(6)
S lng Polime c dng sn xut t l:A. 4 B. 3 C. 6 D. 5
Cu 3: Mt s hin tng sau:
(1) Thm (d) NaOH vo dung dch K
2
Cr
2
O
7
th dung dch chuyn t mu da cam sang mu vng
(2) Thm (d) NaOH v Cl
2
vo dung dch CrCl
2
th dung dch t mu xanh chuyn thnh mu vng.
(3) Thm t t dung dch NaOH vo dung dch CrCl
3
thy xut hin kt ta vng nu tan li trong NaOH (d)
(4) Thm t t dung dch HCl vo dung dch Na[Cr(OH)
4
] thy xut hin kt ta lc xm, sau tan li.
S ng:A. 3 B. 1 C. 2 D. 4
Cu 4: Nung nng AgNO
3
c cht rn X v kh Y. Dn kh Y vo cc nc c dung dch Z. Cho ton b X vo
Z thy X tan mt phn v thot ra kh NO duy nht. Gi thit cc phn ng xy ra hon ton. Phn trm khi lng
ca X khng tan trong Z lA. 20%. B. 30%. C. 25%. D. 40%.
Cu 5: Hn hp X c hai hirocacbon l ng ng lin tip, M
x
= 31,6. Ly 6,32g X li vo 200g dung dch xc tc
thy thot ra 2,688 lt kh kh KTC c M = 33 thu c dung dch Z. Bit dung dch Z cha anehit vi nng
C%. Gi tr ca C l:A. 1,208 B. 1,409. C. 1,305 D. 1,043
Cu 6: Hn hp Z gm 2 axit cacboxylic no, n chc k tip nhau trong dy ng ng. t chy hon ton hn hp
Z thu c khi lng H
2
O t hn khi lng CO
2
l 5,46 gam. Nu ly 1/2 lng hn hp Z trn cho tc dng vi
dung dch NaOH va th sau phn ng thu c 3,9 gam hn hp mui khan. Cng thc ca axit c khi lng mol
phn t nh trong Z:A. CH
3
COOH B. HCOOH C. C
2
H
5
COOH D. C
3
H
7
COOH
1- Cht bo thuc loi cht este.
2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng.
3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng.
4- Nitro benzen phn ng vi HNO
3
c (xc tc H
2
SO
4
c) to thnh m-initrobenzen.
5- Anilin phn ng vi nc brom d to thnh p-bromanilin.
S nhn xt ng l:
A. 4. B. 5. C. 2. D. 3.
Cu 8: Cho mt lng bt CaCO
3
tc dng hon ton vi dung dch HCl 32,85%. Sau phn ng thu c dung dch X
trong nng HCl cn li l 24,20%. Thm vo X mt lng bt MgCO
3
khuy u cho phn ng xy ra hon
ton thu c dung dch Y trong nng HCl cn l 21,10%. Nng phn trm MgCl
2
trong dung dch Y l
A. 3,54%. B. 10,35%. C. 12,35%. D. 8,54%.
Cu 9: Chia 14,8g hn hp X cha ancol metylic v ancol anlylic thnh hai phn: Phn 1 cho tc dng vi Na d thu
c 2,52 lt kh H
2
(ktc). Phn 2 tc dng va vi 50 ml dung dch Br
2
1M. Xc nh phn trm theo khi lng
ancol metylic trong hn hp X?
A. 45% B. 66,67% C. 21,62% D. 45,68%
Cu 10: Dung dich A c cc cht: Ca(HCO
3
)
2
, NaOH, KNO
3
.
Dung dch B c cc cht: MgSO
4
, KCl, Al(NO
3
)
3
.
Dung dch C cha cc cht : Na
2
CO
3
, Ba(OH)
2
, NaNO
3
.
Dung dch D c cc cht: NaOH, Ba(OH)
2
, NaCl.
Dung dch E c cc cht: AgNO
3
, BaCl
2
, KNO
3
.
M 209
64
Dung dch F c cc cht: Fe(NO
3
)
2
, HCl, NaCl.
S dung dch khng tn ti trong thc t l:
A. 5 B. 2 C. 4 D. 3
Cu 11: Cho cc s phn ng sau :
a) 6X
xt
Y b) X + O
2

xt
Z c) E + H
2
O
xt
G
d) E + Z
xt
F e) F + H
2
O
H
+
Z + G.
iu khng nh no sau y ng
A. Cc cht X, Y, Z, E, F, G u c cng s C trong phn t.
B. Ch c X v E l hirocacbon
C. Cc cht X, Y, Z, E, F, G u phn ng c vi dung dch AgNO
3
trong NH
3
.
D. Cc cht X, Y, Z, E, F, G u c nhm chc CHO trong phn t.
A. Phn ng c kim loi tham gia l phn ng oxi ho - kh.
B. Mt cht c tnh oxi ho gp mt cht c tnh kh, c th xy ra phn ng oxi ho - kh.
C. Phi kim l cht oxi ho trong phn ng vi kim loi v hiro.
D. Mt cht hoc ch c tnh oxi ho hoc ch c tnh kh.
Cu 13: Ho tan ht hn hp FeS
2
, FeCO
3
bng dung dch HNO
3
c, nng c dung dch X v 4,48 lt (ktc) hn
hp kh Y c t khi so vi hiro bng 22,75. Hp th ton b kh Y vo 300 ml dung dch NaOH 1M c dung dch
Z. Tng khi lng cc cht tan trong Z l:
A. 18,85g. B. 32,20g. C. 16,85g. D. 20,00g.
Cu 14: Dy cc cht no sau y tc dng c vi dung dch AgNO
3
/NH
3
?
A. Glixerol, axetilen, olein, saccaroz. B. Fructoz, anehit fomic, axit fomic, but-2-in
C. Glucoz, anehit fomic, axit fomic, saccaroz. D. Glucoz, fructoz, anehit fomic, vinylaxetilen.
Cu 15: X l tetrapeptit Ala Gly Val Ala; Y l tripeptit Val Gly Val. un nng m gam hn hp cha X v Y
(trong t l mol ca X v Y tng ng l 1 : 3) vi dung dch NaOH va . Phn ng hon ton thu c dung
dch Z, c cn dung dch Z thu c 25,328 gam cht rn khan. Gi tr ca m l
Cu 16: Cho 2 mol axi t axeti c v 3 mol ancol etyl i c vo bnh cu cho phn ng sau xy ra:
CH
3
COOH + C
2
H
5
OH
CH
3
COOC
2
H
5
+ H
2
O
Khi phn ng t t i tr ng th i cn bng, trong hn h p c 1,2 mol este. nhi t , hng s cn bng ca phn
ng c gi trl A. 1,0. B. 3,2. C. 1,2. D. 2,8
Cu 17: Hai hp cht hu c A, B mch h (ch cha C, H, O) n chc, u tc dng vi NaOH, khng tc dng vi
Na. t chy hon ton m gam hn hp X (gm A v B) cn 8,4 lt O
2
(ktc) thu c 6,72 lt CO
2
(ktc) v 5,4g
H
2
O. Cho bit M
A
<M
B
v chng khc nhau 28u. Xc nh s cu to ca este A?
A. 1 B. 4 C. 3 D. 2
Cu 18: t chy hon ton 1,1g hn hp F gm metan, etin, propen thu c 3,52g CO
2
. Mt khc, khi cho 448 ml
hn hp kh F (ktc) i qua dung dch nc brom d th ch c 4g brom phn ng. Phn trm th tch etin trong hn
hp F l:A. 40% B. 60% C. 25% D. 50%
Cu 19: Khi vt bng gang, thp b n mn in ho trong khng kh m, nhn nh no sau y ng?
A. Tinh th cacbon l cc m, xy ra qu trnh oxi ho. B. Tinh th st l cc dng, xy ra qu trnh kh.
C. Tinh th st l cc m, xy ra qu trnh oxi ho. D. Tinh th cacbon l cc dng, xy ra qu trnh oxi ho.
Cu 20: Cho s : X
Na NaCl
X

Cht X trong s l :
A. Na
2
SO
4
B. NaOH C. Na
2
O D. Na
2
CO
3

Cu 21: Trong n c, hi ro ch yu tn t i 2 ng vl
1
1
H v
2
1
H. Bi t nguy n t khi trung bnh ca hi ro trong H
2
O
nguy n cht l 1,008. S nguy n t ca ng v
2
1
H trong 1ml n c l
A. 5,35.10
20
B. 3,53.10
20
C. 5,33.10
20
D. 4,55.10
20

Cu 22: Mt dung dch c cha H
2
SO
4
v 0,543 gam mui natri ca mt axit cha oxi ca clo (mui X). Cho thm
vo dung dch ny mt lng KI cho n khi iot ngng sinh ra th thu c 3,05 gam I
2
. Phn trm khi lng Clo
trong mui X lA. 40%. B. 39,23%. C. 33,45%. D. 48,56%.
65
Cu 23: Cht A c cng thc: C
x
H
y
O
z
, cho A tc dng vi NaOH thu c (B) v (C)~. (C) khng tc dng vi Na
v: (C)
2
O
xt
+
(D)
Na +
(B)
0
hhCaO,NaOH
t
+
ankan n gin nht. Thnh phn % theo khi lng ca cacbon
trong A l:A. 57,4% B. 60%. C. 55,8% D. 54,6%
Cu 24: Cho 11,6 gam mui FeCO
3
tc dng va vi dung dch HNO
3
, c hn hp kh CO
2
, NO v dung dch
X. Khi thm dung dch HCl (d) vo dung dch X, th dung dch thu c ho tan ti a bao nhiu gam bt ng kim
loi, bit rng c kh NO bay ra.A. 32 gam. B. 3,2 gam. C. 64 gam. D. 6,4 gam
A. Phn ng ca cht bo vi NaOH l phn ng x phng ha
B. Etyl acrylat, triolein, tristearin u l este
C. Phn ng ca glixerol vi axit bo c H
2
SO
4
c xc tc (t
o
) l phn ng este ha
D. Cht bo lng l cc triglixerit cha gc axit no trong phn t
Cu 26: Cho dung dch cha 1,22 gam cht hu c X l ng ng ca phenol tc dng vi nc brom (d) thu c
3,59 gam hp cht Y cha 3 nguyn t brom trong phn t (H=100%). Cng thc phn t ca X l
A. C
10
H
14
O. B. C
7
H
8
O. C. C
8
H
10
O. D. C
9
H
12
O.
Cu 27: in phn vi in cc tr dung dch cha 0,2 mol AgNO
3
vi cng dng in 3,86 A, trong thi gian t
giy thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 16,8 gam bt Fe vo X thy thot ra kh NO
(sn phm kh duy nht) v sau cc phn ng hon ton thu c 22,7 gam cht rn. Gi tr ca t l
A. 3000 giy B. 2500 giy C. 2685 giy D. 5000 giy
Cu 28: Nh t t 3V
1
ml dung dch Ba(OH)
2
(dung dch X) vo V
1
ml dung dch Al
2
(SO
4
)
3
(dung dch Y) th phn
ng va v ta thu c kt ta ln nht l m gam. Nu trn V
2
ml dung dch X trn vo V
1
ml dung dch Y th
kt ta thu c c khi lng bng 0,9m gam. So snh t l V
2
/V
1
thy
A. V
2
/V
1
= 0,9 hoc V
2
/V
1
= 1,183 B. V
2
/V
1
= 2,7 hoc V
2
/V
1
= 3,55
C. V
2
/V
1
= 2,5 hoc V
2
/V
1
= 3,55 D. V
2
/V
1
= 1,7 hoc V
2
/V
1
= 3,75
Cu 29: Cho mt lng ancol E i vo bnh ng Na (d), sau khi phn ng xy ra hon ton thy khi lng bnh
tng thm 6,3 gam v c 1,568 lt kh H
2
(ktc) thot ra. Cng thc ancol E l
A. C
2
H
4
(OH)
2
B. C
3
H
5
(OH)
3
C. C
2
H
5
OH D. C
3
H
7
OH
Cu 30: Cho m gam hn h p FeS, FeS
2
tl s mol 1:1 vo dung dch HNO
3
d, t
0
chtho t ra hn h p khcha 0,4
mol NO
2
, 0,2 mol NO (l sn phm kh duy nht). Tnh m?
Cu 31: Cho cc cht Cu, FeO, Fe
3
O
4
, C, FeCO
3
, Fe(OH)
2
, Fe tc dng ln lt vi H
2
SO
4
c, nng u gii phng
kh SO
2
. S cht m khi tc dng vi 1 mol H
2
SO
4
u gii phng ra 1/4 mol SO
2
l:
A. 4 B. 3 C. 5 D. 6
Cu 32: Thi hi nc qua than nng thu c hn hp kh A kh (H
2
, CO, CO
2
). Cho A qua Ca(OH)
2
cn li hn
hp kh B kh (H
2
, CO). Mt lng kh B tc dng va ht vi 8,96g CuO thy to thnh 1,26 g nc. Thnh phn %
theo th tch ca CO
2
trong A l:
A. 33,33% B. 11,11% C. 20,00% D. 30,12%.
Cu 33: T m gam tinh bt iu ch c 575 ml ancol etyl i c 10
0
(khi l ng ring ca ancol nguyn cht l 0,8
gam/ml ) v i hi u sut c qu trnh l 75%. Gi trca m l :
A. 60,75g B. 75,9375g C. 108g D. 135g
Cu 34: Cho hn hp A gm 3 kim loi X, Y, Z c ha tr ln lt l III, II, I v t l mol l 1:2:3, trong s mol ca
X bng x mol. Ha tan hon ton A bng dung dch c cha y (gam) HNO
3
(ly d 25%). Sau phn ng thu c V lt
kh NO
2
v NO (l sn phm kh duy nht v ktc). Biu thc tnh y theo x v V.
A. 1, 5.(9 ).63
22, 4
V
y x = + B. 1, 5.(10 ).63
22, 4
V
y x = +
C. 1, 25.(9 ).63
22, 4
V
y x = + D. 1, 25.(10 ).63
22, 4
V
y x = +
Cu 35: un nng hn hp hai ancol n chc, mch h A, B (M
A
<M
B
) vi H
2
SO
4
c ( 140
0
C) to thnh hn hp 3
ete. t chy 10,8g mt ete trong s 3 ete trn thu c 26,4g CO
2
v 10,8g H
2
O. Xc nh phn trm khi lng oxi
trong cht B? A. 27,59% B. 50% C. 34,78% D. 26,67%
Cu 36: Lng tiu th than ca mt nh my nhit in trong mt nm l 2,5 triu tn than, than cha 3% lu hunh.
Gi s ton b lng lu hunh chuyn thnh SO
2
th mi pht nh my in thi vo kh quyn bao nhiu kg SO
2
?
A. 356,5 kg B. 285,4 kg C. 190,0 kg D. 147,2 kg
Cu 37: Trong tinh bt, cc mt xch-glucoz lin kt vi nhau bng
A. lin kt -1,4-glicozit v -1,6-glicozit B. lin kt -1,6-glicozit v -1,4-glicozit
C. lin kt -1,4-glicozit v -1,4-glicozit D. lin kt -1,4-glicozit v -1,2-glicozit
66
Cu 38: Tm pht biu sai trong cc pht biu sau:
A. Phenol l cht rn kt tinh iu kin thng
B. Etylamin d tan trong H
2
O
C. Nhit si ca ankanol cao hn so vi ankanal c phn t khi tng ng.
D. Metylamin l cht lng c mi khai, tng t nh amoniac.
Cu 39: 20
0
C mt phn ng c hs nh t =3 kt thc sau 2 gi . Phn ng sau 25 pht t i nhi t :
A. 55
0
C B. 78
0
C C. 34,38
0
C D. 45,67
0
C
Cu 40: Chia hn hp X gm hai axit n chc, k tip nhau trong dy ng ng ra hai phn bng nhau. Phn I phn
ng va vi 500 ml dung dch NaOH 1M. Phn II phn ng vi lng d dung dch AgNO
3
/NH
3
to ra 43,2 gam
Ag. Phn trm khi lng ca axit c khi lng mol phn t nh trong X l
A. 18,4%. B. 33,82%. C. 35,55%. D. 36,22%
Cu 41: Ho tan 10 gam hn hp Cu
2
S v CuS bng 200 ml dung dch KMnO
4
0,75M trong mi trng axit H
2
SO
4
.
Sau khi un si ui ht kh SO
2
sinh ra, lng KMnO
4
cn d phn ng va ht vi 175 ml dung dch FeSO
4
1M.
Khi lng CuS trong hn hp ban u l:A. 5 gam. B. 4,8 gam. C. 9,6 gam. D. 6 gam.
Cu 42: Hp cht hu c A c cng thc phn t C
3
H
9
NO
2
. Cho A tc dng vi dung dch NaOH thu c mui B v
kh C lm xanh qu tm m. Nung B vi vi ti xt thu c mt hirocacbon c khi lng phn t nh nht. Phn
trm theo khi lng cacbon trong cht C lA. 38,71% B. 53,33% C. 26,67% D. 33,33%
Cu 43: Hp th va hn hp etilen v propilen vo dung dch KMnO
4
31,6% thu c dung dch X v kt ta Y.
Trong dung dch X nng % ca etilenglicol l 6,906%. Nng % ca propan1,2iol trong dung dch X l :
A. 15,86% B. 14,99% C. 15,12% D. 12,88%
Cu 44: Trong cc th nghim sau:
(1) Cho SiO
2
tc dng vi axit HF. (2) Cho kh SO
2
tc dng vi kh H
2
S.
(3) Cho kh NH
3
tc dng vi CuO un nng. (4) Cho CaOCl
2
tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O
3
tc dng vi Ag.
(7) Cho dung dch NH
4
Cl tc dng vi dung dch NaNO
2
un nng.
S th nghim to ra n cht l:A. 4. B. 5. C. 7. D. 6.
Cu 45: Thc hin phn ng nhit nhm 26,8 gam hn hp bt nhm v st (III) oxit c hn hp G. Ho tan G
trong dung dch NaOH d, thot ra 6,72 lt kh H
2
(cc phn ng xy ra hon ton, th tch kh o ktc). Khi lng
nhm c trong hn hp ban u bngA. 5,4 gam. B. 10,8 gam. C. 8,1 gam. D. 11,2 gam
Cu 46: Khi thy phn C
4
H
6
O
2
trong mi trng axit ta thu c hn hp hai cht u c phn ng trng gng. Vy
CTCT ca C
4
H
6
O
2
l mt trong cc cu to no sau y?
A.
CH
3
C
O
O CH CH
2
B.
CH
3
C
O
O CH CH
2

C.
CH
2
CH C
O
O CH
3
D.
H
C
O
O CH CH CH
3

Cu 47: Dung dch A cha c c i on: SO
4
2-
, 0,2 mol Ca
2+
, 0,1 mol NH
4
+
v 0,2 mol NO
3
-
. Tng khi lng cc mui
khan c trong dung dch A l :
Cu 48: Cho 1,2 lt hn hp gm hiro v clo vo bnh thu tinh y kn v chiu sng bng nh sng khuch tn. Sau
mt thi gian ngng chiu sng th thu c mt hn hp kh cha 30% hiroclorua v th tch v hm lng ca clo
gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca hiro trong hn hp ban u
bng
A. 88,25% B. 81,25% C. 30,75% D. 66,25%
Cu 49: Nguy n t ca nguy n t X c tng s el ectron trong c c phn l p p l 7. Nguy n t ca nguy n t Y c tng
s h t mang i n nhi u hn tng s h t mang i n ca X l 8. Tng s proton ca h p cht t o bi X v Y l :
A. 64 B. 30 C. 82 D. 28
Cu 50: Cho 7,02g hn hp Al, Fe, Cu vo bnh A cha dd HCl d, cn li cht rn B. L ng khtho t ra dn qua ng
cha CuO nng, d, thy khi l ng ng gim 2,72g. Thm vo A lng NaNO
3
d to 0,896 lit NO (ktc). Phn trm
v khi lng Fe trong hn hp ban u l:
A. 28,7% B. 20,47% C. 40% D. 15,95%

------------ HT ----------

67
P N THI TH H
C
U
LN1 LN
2
LN3 LN4 LN5 LN
6
LN7 LN8 LN 9 LN10 LN11 LN12
LN13
1 A A C B D A A A C C D D
2 B C B C B A C C D B D D
3 B B B A D A A B A C B A
4 D B D C A B A A A B D A
5 B D C B D D D A A A C A
6 A B A A C A C C B A B A
7 D B A B D D B B A C D A
8 C C A C B C D C B A D C
9 B A C D B C D D C C D C
10 C D D B A A D D D B C D
11 C D A D A D A B D C B D
12 C D B C A B B A B A C A
13 B C A A A D A C D D A B
14 B A D C A B D D C D C D
15 C B D D B B C A C D B A
16 C B A A A D C B C A C D
17 C A C A A B A D C B A B
18 D A B D B C B D D B D B
19 B D B A A C D C B C C A
20 C D B A A D B C D D D D
21 C B D D C A D C C D A B
22 D C B B C B D C C A C B
23 A C D B D B D D C D C B
24 D C D B D D A A D B D C
25 D B B B D B C C D C D B
26 B B B B D D C B D C C D
27 A C D B A B B A A D C B
28 C D C D B C B B D A A D
29 A A C B B B C A A A B C
30 D C D C A D A C C C A B
31 C B B C A C B B D D A C
32 A D B D C C B D A B D D
33 D B D A B A C B B A A C
34 A D C B A A C B B B A C
35 D C A D B D A C A D B C
36 A A C C B C B A B C C C
37 C A B C B B A D D A C A
38 B D C A B A A B A B C A
39 A C A D C B C B C A B B
40 B C D D D D B B B D A C
41 A B D D B A A D A C D A
42 C C A A B C B B B C B A
43 D A A C C A C A A D A D
44 B B D C C C A C C D B C
45 A A A D A C C D D A C B
46 C B C A A D C C C B B C
47 B A C A C C C D B D B B
48 D A A D B A C B B B D D
49 D C C B D A A D A D D A
50 A D D A B C A C B B C
51 C C A B A B
52 C B B B B C
53 C B C A B A
54 A A C C A D
55 C B A B A A
56 D A C A A A
57 D B A A A B
58 A B B B C D
59 B B D D B A
60 C C D D D C

Tuyen Tap Thi DH Hay

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Tuyen Tap Thi DH Hay

Uploaded by

Copyright:

Available Formats

Nguyn Anh Tun Nm hc 2011-2012

oxi ho c Zn trong dung dch kim (OH

ln lt l : 42 v 50. Hai nguyn t X, Y ln lt l :

You might also like