Cálculo da constante de equilíbrio para a reação 1

A B C D
Temp (K) Cp(CO2; J/molK)= 27.437 4.2315E-02 -1.9555E-05 3.9968E-09
50 Cp(NH3; J/molK)= 33.573 -1.2581E-02 8.8906E-05 -7.1783E-08
75 Cp(NH2COONH4; J/molK)= 57.394 8.05409E-02 2.42885E-04 -2.75919E-07
100
125 Cálculo da variação dos coeficientes de Cp
150
175 alfa(0)= -37.189 alfa(1)= 6.3388E-02
200
225 alfa(3)= -1.3635E-07 alfa(4)= 4.4953E-11
250
275 Cálculo do delta H padrão da reação na temperatura T0
300
325 Reação (1), entrando com amônia e dióxido de carbono gasoso, formando carbam
350
375 Delta H0 kJ/mol (NH3)= -46.2
400 Delta H0 kJ/mol (NH2COONH4)= -645.05 Delta H0 da reação(J/m
425 Delta H0 kJ/mol (CO2)= -393.5
450
475 Delta G0 kJ/mol (NH3)= -16.6
500 Delta G0 kJ/mol (NH2COONH4)= -448.062 Delta G0 da reação(J/m
525 Delta G0 kJ/mol (CO2)= -394.4
550
575 Temp (K) lnk(1) Keq(1)
600 50 255.1514106 6.4692E+110
625 75 165.0825582 4.94816E+71
650 100 117.3200308 8.94215E+50
675 125 87.13579086 6.95974E+37
700 150 66.06456188 4.91445E+28
725 175 50.38534985 7.62218E+21
750 200 38.19160928 3.85838E+16
775 225 28.39863177 2.15461E+12
800 250 20.34025293 681804100
825 275 13.582738 792333.7624
850 300 7.830338206 2515.780082
875 325 2.873694826 17.70230445
900 350 -1.440066 0.236912122
925 375 -5.22552855 0.005377517
950 400 -8.57051674 0.000189615
975 425 -11.5436557 9.697371E-06
1000 450 -14.1994804 6.81152E-07
1025 475 -16.581977 6.288382E-08
1050 500 -18.7270944 7.36082E-09
1075 525 -20.664561 1.060462E-09
1100 550 -22.4192223 1.834237E-10
1125 575 -24.0120431 3.729943E-11
1150 600 -25.4608671 8.759633E-12
1175 625 -26.7810019 2.339692E-12
1200 650 -27.9856745 7.014165E-13
1225 675 -29.0863894 2.333144E-13
1250 700 -30.0932136 8.524784E-14
1275 725 -31.0150049 3.391209E-14
1300 750 -31.8595971 1.457313E-14
1325 775 -32.6339508 6.718236E-15
1350 800 -33.3442768 3.301905E-15
1375 825 -33.9961395 1.720538E-15
1400 850 -34.5945414 9.457614E-16
1425 875 -35.143995 5.459551E-16
1450 900 -35.6485831 3.296227E-16
1475 925 -36.1120092 2.073737E-16
1500 950 -36.5376417 1.354889E-16
975 -36.9285503 9.165041E-17
1000 -37.2875381 6.400707E-17
1025 -37.6171691 4.603319E-17
1050 -37.919792 3.401289E-17
1075 -38.1975606 2.576382E-17
1100 -38.4524521 1.996697E-17
1125 -38.6862829 1.580377E-17
1150 -38.9007221 1.275355E-17
1175 -39.0973041 1.047747E-17
1200 -39.2774389 8.750342E-18
1225 -39.4424222 7.419484E-18
1250 -39.5934434 6.37949E-18
1275 -39.7315936 5.556331E-18
1300 -39.8578717 4.897182E-18
1325 -39.9731911 4.363788E-18
1350 -40.0783846 3.928066E-18
1375 -40.1742096 3.569131E-18
1400 -40.2613522 3.271274E-18
1425 -40.3404315 3.022548E-18
1450 -40.4120028 2.81378E-18
1475 -40.4765609 2.637867E-18
1500 -40.5345434 2.489267E-18
o1
E
-2.9872E-13 Cp(NH2COONH4; J/molK)=
1.8569E-11 Cp(NH2CONH2; J/molK)=
8.17923E-11 Cp(H2O(L); J/molK)=

alfa(2)= 8.4628E-05

T0= 298

ormando carbamato de amônio gasoso

H0 da reação(J/mol) -159150

G0 da reação(J/mol) -20462

Lnk0T0 k0T0
8.2588922 3861.8135104
 Cálculo da constante de equilíbrio para a reação 2
A B C D E
57.394 8.05409E-02 2.42885E-04 -2.75919E-07 8.17923E-11
35.19258 0.079627 0.000473 -1.21E-06 1.26E-09
92.053 -0.04 -0.000211 5.35E-07 0

Cálculo da variação dos coeficientes de Cp

alfa(0)= 69.85158 alfa(1)= -0.0409139 alfa(2)=

alfa(3)= -3.99081E-07 alfa(4)= 1.178208E-09 R(J/mol*K)=

T0(K)
Cálculo do delta H padrão da reação na temperatura T0

Delta H0 kJ/mol (H2O)= -286 Delta H0 da reação(J/mol)

Delta H0 kJ/mol (NH2COONH4)= -645.053
Delta H0 kJ/mol (NH2CONH2)= -333.6
Delta G0 da reação(J/mol)
Delta G0 kJ/mol (H2O)= -237
Delta G0 kJ/mol (NH2COONH4)= -448.062
Delta G0 kJ/mol (NH2CONH2)= -197.15008

Temp (K) lnk(2)

50 139.1038264782
75 61.0947727219
100 27.766341387
125 11.0900850618
150 2.1398493798
175 -2.7359562276
200 -5.276974685
225 -6.401720299
250 -6.632169979
275 -6.2815012415
300 -5.545357041
325 -4.5495953242
350 -3.3767822481
375 -2.0816144559
400 -0.7002627774
425 0.7437724634
450 2.235884767
475 3.7678640905
500 5.3362092918
525 6.9409659792
550 8.5849127373
575 10.2729828531
600 12.0118480098
 625 13.8096151098
650 15.675603223
675 17.6201780035
700 19.6546277923
725 21.7910702758
750 24.0423817453
775 26.4221432228
800 28.9445992638
825 31.6246263593
850 34.4777086498
875 37.5199192404
900 40.7679058281
925 44.2388796639
950 47.9506071023
975 51.9214031668
1000 56.1701266872
1025 60.7161766681
1050 65.5794896207
1075 70.7805376487
1100 76.3403271263
1125 82.2803978387
1150 88.6228224833
1175 95.3902064516
1200 102.6056878288
1225 110.2929375601
1250 118.4761597431
1275 127.1800920159
1300 136.430006015
1325 146.2517078819
1350 156.671538805
1375 167.7163755817
1400 179.4136311925
1425 191.791255379
1450 204.8777352194
1475 218.7020956973
1500 233.2939002603
 0.000019115

8.314
298

25453

13911.92

Keq(2)
2.582404E+60
3.412893E+26 Lnk0T0= -5.61514
1.144903E+12 k0T0= 0.003642
65518.318993
8.4981575382
0.0648319833
0.0051078603
0.0016587014
0.0013173015
0.0018705903
0.0039055485
0.0105714815
0.0341571874
0.1247286806
0.4964548296
2.1038572873
9.3547549704
43.287507827
207.72379567
1033.7683316
5350.3258111
28940.082564
164694.58042
994121.89589
6424332.0551
44910312.502
343475997.99
2908985627.6
27635907081
298532076456
3.719459E+12
5.425012E+13
9.407595E+14
1.971033E+16
5.073136E+17
1.631929E+19
6.678579E+20
3.541432E+22
2.479568E+24
2.337225E+26
3.025593E+28
5.490311E+30
1.426208E+33
5.419045E+35
3.078951E+38
2.675718E+41
3.639855E+44
7.936229E+47
2.841466E+51
1.712427E+55
1.781553E+59
3.283293E+63
1.100487E+68
6.891225E+72
8.286097E+77
1.96736E+83
9.49008E+88
9.574439E+94
2.08091E+101
 Cálculo da constante de equilíbrio para a reação 3
A B C
Cp(NH2CONH2; J/molK)= 35.19258 0.079627 0.000473
Cp(NH2CONHCONH2; J/molK)= 27.56 0.3378 -1.83E-04
Cp(NH3)(L); J/molK)= 0.03515 0.00002954 4.42E-09

Cálculo da variação dos coeficientes de Cp

alfa(0)= -42.79001 alfa(1)= 0.17857554

alfa(3)= 0.000002447 alfa(4)= -2.52E-09

Cálculo do delta H padrão da reação na temperatura T0

Delta H0 kJ/mol (NH3)= 45.85664 Delta H0 da reação(J/mol

Delta H0 kJ/mol (NH2CONHCONH2)= -561.6
Delta H0 kJ/mol (NH2CONH2)= -333.6

Delta G0 kJ/mol (NH3)= -16.401 Delta G0 da reação(J/mol

Delta G0 kJ/mol (NH2CONHCONH2)= -69.59
Delta G0 kJ/mol (NH2CONH2)= -197.15
Temp (K)
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 650
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uilíbrio para a reação 3
D E
-1.21E-06 1.26E-09
2.70E-08 0
-6.69E-12 0

alfa(2)= -0.001129

R(J/mol*K)= 8.314
T0(K) 298

Delta H0 da reação(J/mol) 151456.64

Delta G0 da reação(J/mol) 308309.16

lnk(3) Keq(3)
-546.9907170123 2.7858E-238
-185.1525086346 3.884071E-81
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-125.1481235906 4.455131E-55
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-33.7810140614 2.133497E-15
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