TRUNG TM NHIT I VIT-NGA

VIN BN NHIT I

BO CO NHIM V
Tn nhim v: Nghin cu ch to sn lt VL-02.VN
thay th cho sn c sn xut ti Lin bang Nga s
dng trong ch to tn la IGLA

Ch nhim: Nguyn Th Yn
H Ni - 2016

NI DUNG BO CO
1. MC TIU
2. GII THIU CHUNG V SN VL-02
3. YU CU K THUT SN VL-02
4. QUY TRNH CH TO SN VL-02
5. CC THNH PHN CH TO SN VL-02 V PHNG
N THAY TH
6. PHNG N THC HIN NHIM V

1. MC TIU

Xy dng qui trnh ch to sn lt VL-02.VN c

tnh nng k thut tng ng vi sn lt -02 ca
Lin Bang Nga
Tm ngun nguyn liu sn c trong nc phc v
cho vic ch to sn lt VL-02.VN

2. GII THIU CHUNG V SN VL-02

Sn lt -02 c mu vng xanh c s dng lm sn lt
bo v thay th cho vic photphat ha b mt
Sn lt -02 gm hai thnh phn chnh:
Sn bn thnh phm -02
Cht pha long axit
Theo nghin cu thnh phn ch tao sn lt -02 bao gm:
Cht to mng PVB
Cht to mu (pigment)
Bt n
Dung mi ha tan
Cht pha long

3. YU CU K THUT SN VL-02 V CC THNH PHN

3.1. Sn lt VL-02 theo GOST 12707-77
TT
1

2
3
4
5
6
7
8
9

Tn ch tiu
Dng ngoi mng sn sau khi kh

nht theo BZ-246 ng knh 4 mm (202) oC,

giy
n nh ca nht sau khi ch to 6 gi thay i,
khng ln hn, %
Thi gian kh t cp 5 (202) oC, pht, khng ln
hn
bn un ca mng, mm, khng ln hn
bn va p ca mng trn thit b U-1, cm, khng
nh hn
bm dnh, im, khng ln hn
mn, m, khng ln hn
Khi lng ring (202) oC, g/cm3, trong khong

Mc
Mn ng nht, m hoc hi
bng, c mu vng xanh
2035
20
15
1
50
1
30
0,890,95

3.2. Sn bn thnh phm -02 theo GOST 12707-77

TT
1
2
3

Tn ch tiu

Mc

Hm lng cc cht khng bay hi, %, trong khong

mn, micromet, khng ln hn
Khi lng ring (202) oC, g/cm3, trong khong

2022
30
0,890,95

3.3. Cht pha long sn -02 theo GOST 12707-77

Tn ch tiu
TT
1 Dng ngoi
2

Hm lng axit orthophosphoric, %, trong khong

Khi lng ring (202)

o
C, g/cm3, trong khong

Mc
Cht lng trong sut, khng mu, khng c
tp cht v khng b tch lp khi bo qun
15,015,5
0,9080,918

4. QUY TRNH CH TO SN VL-02

Theo nghin cu ti liu ch to sn VL-02 cn:

Dng c: My trn
Phng php: Cho tt c cc thnh phn theo cng thc vo
trong my nghin (vi bi nghin bng s hnh cu).
Thi gian nghin 72 gi, cho n khi t tn nh thch hp

5. CC THNH PHN CH TO SN VL-02 V

PHNG N THAY TH
5.1. Cht to mng
Sn lt VL-02 s dng cht to mng PVB.
PVB thu c do tng hp theo s :

Mua nha PVB c bn sn trn th trng

Theo GOST 9439-85 sn xut sn lt VL-02 ta s dng mc PVB
mc LA v LB c yu cu k thut nh sau:
TT
1
2
3
4
5
6

Tn ch tiu

Mc cho
LA cao

Mc cho
LB cao

Thnh phn khi lng nc, %, khng ln hn

Thnh phn khi lng nhm axetat chuyn i
trong dng kh, %, khng ln hn
Thnh phn khi lng nhm butyral chuyn
i trong dng kh, %, khng ln hn
Thnh phn khi lng ion Cl, , %, khng ln hn
pH, s mg KOH trn 1 g sn phm kh, khng ln
hn
nht tng i 20 oC, c

2,0

2,0

2,0

2,0

45-48

45-48

0,002

0,002

0,10

0,10

8-18

19-30

 Sn phm thng mi ph hp c trn th trng:

Mowital B 30H, v Mowital B 30HH ca Tp on Kuraray
Butvar Resins (Loi B-76 v B-79) ca Eastman Chemical
S-LEC B, K (Loi BL-1H, BL-S, KS-10) ca Cng ty Sekisui
chemical Co., Ltd
Nh cung cp ti Vit Nam
Cng ty Sn Anh c a ch ti P 608, ta nh 142 L Dun,
Qun ng a, HN
Cng ty TNHH Ha cht Thin Vit 355 Quang Trung, P.10, Q.
G Vp.

5.2. Cht to mu (pigment)

Sn VL-02 s dng cht to mu cromat km C.I.Pigment Yellow 36.
Vi yu cu k thut theo GOST16763-79 nh sau:
Tn ch tiu
1. Mu sc
2. Thnh phn khi lng cht khng bay hi, %, khng ln hn
3. Thnh phn khi lng lin kt km chuyn i thnh ZnO,%
4. Thnh phn khi lng lin kt crom chuyn i thnh CrO3, %, khng
nh hn
5. Thnh phn khi lng cht khng tan trong dung dch amoniax NH4Cl,
%, khng ln hn
6. Thnh phn khi lng ca cc cromat tan trong nc chuyn i thnh
CrO3, %, khng ln hn
7. Thnh phn khi lng ca sunfat tan trong nc chuyn i thnh SO 3,
%, khng ln hn
8. Thnh phn khi lng ca clorid tan trong nc chuyn i thnh Cl, %,
khng ln hn
9. Phn d sau khi sng t qua sng vi mt sng s 0063, %, khng ln
hn

nh mc
Khng nh
mc
1,5
61-65
19-23
1,0
1,7
1,0
0,1
0,5

Cc nh cung cp:
c cung cp bi Chemical Land21 (Hn Quc) v AlliansYug (Trung Quc) c s CAS l 37300-23-5
Sn phm Lemon Chrome yellow ca nh sn xut Guangxi
Dongfa Trade Co,. Ltd (Trung Quc) c cung cp bi cng ty
TNHH Ha cht Thun Nam .

5.3. Bt n
Theo cc ti liu ca Nga, sn lt -02 s dng bt n
Mg3Si4O10(OH)2 hay cn gi l cht TALC [13]
Nh cung cp bt n Mg3Si4O10(OH)2 c trn th trng Vit
Nam:
Cng Ty TNHH Sn xut, dch v, thng mi B.B.T ti
873A/1 u C Qun Tn Ph Tp. H Ch Minh
Cng Ty TNHH u T V Pht Trin Lai n - 40/24 H
Vn Long, Phng Bnh Hng Ha B, Qun Bnh Tn, TP H
Ch Minh
Cng Ty TNHH Ha Cht Cng Nghip Tun Minh - 163/35
Khng H, Phng Khng nh, Qun Thanh Xun, TP H
Ni.

5.4. Dung mi ha tan

Theo GOST 12707-77 dung mi ha tan c khuyn co s dng
dung mi RFG l hn hp C2H5OH hoc CH3CH(OH)CH3 v
CH3(CH2)3OH hoc (CH3)2CHCH2OH theo t l 3:1 v khi lng
5.5. Cht pha long
L hn hp ca axit ortho - Phosphoric trong ru C2H5OH

5. PHNG N THC HIN

XIN CHN THNH CM N!