PROBLEM 2

UV-VIS SPECTROSCOPY
PELARUT : METHANOL (POLAR)
maks : 224 nm (log10 3.4)

KROMOFOR AUKSOKROM

C=C -OH

C=O -OR

N=N -NHR
INFRA RED SPECTROSCOPY
BILANGAN GELOMBANG (CM-1) GUGUS FUNGSI

2500-3200 -OH

1580-1615 C=C (Aromatik)

1680-1750 C=O

1050-1300 C-O

835-879 C-C

675-870 C-H
MASS SPECTROSCOPY
M/Z FORMULA M/Z LOST GROUP LOST

152 C8H8O3 - -

135 C8H7O2 17 -OH

107 C7H7O 45 CHO2

81 C5H5O 71 C3H3O2

65 C5H5 87 C3H3O3

43 C2H3O 109 C6H5O2

C-NMR
GUGUS FUNGSI PERGESERAN KIMIA (PPM) INTERFERENCE

O-CH3 40-60 UPFIELD

C=C 90-130 DOWNFIELD

C6H5 100-140 DOWNFIELD

H-NMR
GUGUS FUNGSI PERGESERAN KIMIA (PPM) INTERFERENCE

AR-H 6.5-8 DOWNFIELD

-CO=OH 10-12 DOWNFIELD

O-CH3 3.5-4 UPFIELD

STRUKTUR
VANILLIN