TRNG I HC KHOA HC T NHIN - HQGHN

KHOA HA HC- B MN HA PHN TCH

BO CO CH

PHN TCH HIN TRNG NG THI BENZENE, TOLUEN, ETHYLBENZEN V XYLENE

TRONG NC BNG PHNG PHP SC K KH CM TAY - U D ION HO NGN LA,
KT HP VI VI CHIT PHA RN

Ging vin: TS. NGUYN TH NH HNG

Hc vin: NG TH TUYN YN
 NI DUNG

I. Mc tiu, i tng nghin cu

II. Phng php sc k kh

III. Cu to, u nhc im h sc k phng th

nghim v hin trng

IV. ng dng

V. Kt lun
phng php phn tch benzen, toluene, Cc phng php phn tch benzen, toluene, ethylbenzene, xylene
ethylbenzene, xylene
I. MC TIU
I. BENZEN, TOLUENE, ETHYLBENZENE, XYLENE
 II. PHNG PHP SC K KH
Nguyn tc ca phng php

Sc k kh l phng php tch cc cht da trn

c s cc hp cht dng kh cn phn tch s
tng tc vi thnh ct c ph bi pha tnh,
dn n tng hp cht c tch ra ti nhng thi
im khc nhau. Khi cc cht ha hc i ra cui
ct, s c pht hin v xc nh bng in t.
III. CU TO H SC K KH
 III. CU TO H SC K KH
GC phng th nghim

- C kch thc: 440(H) x 515(W) x 530(D) mm,

- Trng lng: khong 30 kg, in p yu cu: 1800VA
- Th tch bn trong l : 13.7 lt
- Ct phn tch mao qun SH-Rxi-5Sil.
kch thc: 30m x 0.25mm x 0.25m
- Gii hn pht hin: < 1.5pg C/s
- Khong ng hc tuyn tnh: > 10-7
- Khong nhit vn hnh: T trn nhit phng + 4oC n 450oC khi
chy iu kin thng.
 III. CU TO H SC K KH
GC phng th nghim

u im:

- Phng php c nhy v kh nng nh lng tt, ph hp xc

nh nhiu i tng khc nhau nh hp cht d v kh bay hi, cht phn
cc v km phn cc
-ng dng phn tch ha cht, du m, dc phm, v sinh dch t,
VSATTP, an ninh

Nhc im:

- Thit b cng knh

 CC BC THC HIN TRONG PHNG TH NGHIM

L thy tinh Thm

Ly mu(10ml) 14ml, nt Na2SO4
kn

Vi chit pha rn Khuy

GC-FID
(10 pht)
 III. CU TO H SC K KH
THIT B HIN TRNG

L tng cho quan trc VOCs trong mi trng

Kt ni my tnh qua cng RS 232
Kch thc(HxWxD)(cm): 39 x 27 x 15
iu kin hot ng: Nhit : 0 - 40C , m tng i: 5 95% ( khng
ngng t )
Kh mang: kh nito UHP
Di o: 0.005 9999 ppm
Chng trnh o: Ring bit hoc tng VOCs
 III. CU TO H SC K KH

MT S LOI SC K KH CM TAY

H thng sc k kh lin tc CMS5000

My sc k kh Micro GC Fusion

My sc k kh 3000 Micro GC

Mt s ci tin h sc k
Kh mang c th ly trc tip t khng kh

Thi gian chit ngn

L ct c dng hnh trn, Ct sc k c khc vo tm wafer silicon

Chng trnh tng nhit cc nhanh v lm mt nhanh chng.

 III. CU TO H SC K KH
THIT B HIN TRNG

Nit

hidro

1. Kh Nito 7. Vial
2. Van iu chnh 8. B lc m
3. Van Solenoid 3 cng 9. Van Solenoid 2 cng
4. Bm mng 10. u ni ch Y
5. SPME 11. Ct sc k
6. Kim van 12. u d FID
III. CU TO H SC K KH
THIT B HIN TRNG

Ct wafer Silic
 III. CU TO H SC K KH
THIT B HIN TRNG

(1) my tnh xch tay; (2) GC190; (3) Cp in GC190 v cung cp kh t; (4) bng iu
khin cho mch vi x l; (5) mch gim st kh; (6) iu khin kh nn; (7) nm iu
chnh lung khng kh; (8) cng tim; (9) u vo chia / tch mao mch; (10) in p cao;
(11) mao mch; (12) my d FID; (13) B khuych i vi m FID

Jie Ji, Chunhui Deng, Talanta 69(2006)894-899

 III. CU TO H SC K KH
THIT B HIN TRNG

u im:
- Thit b kh nh, thun tin khi mang ra hin trng
- Loi tr nh hng ca qu trnh vn chuyn, ly mu, phn hy
mu
- Xc nh nhanh chng ca nhiu hp cht hu c
- Qu trnh phn tch nhanh
- nhy v chn lc tng i cao
Nhc im:
- chnh xc khng cao bng GC phng th nghim
- Mu khng ng u, s lng mu phn tch phi ln hn.
 IV. NG DNG
XY DNG NG CHUN

Di tuyn tnh i vi Benzene 10-1000 g / l v i vi toluene, ethylbenzene v

xylene: 10-2000 g / l

Sc k GC-FID ca BTEX thu c bng si PDMS / DVB 65 m cho 50 g / l BTEX.

Cc nh: benzen (1), toluene (2), ethylbenzene (3), m- v p-xylene (4), v o-xylene (5)
 KT QU PHN TCH MU THC
BENZEN, TOLUENE, ETHYLBENZENE, XYLENE
TRONG NC

A: Thng Hi, B: trung quc. Nng benzen, toluen, ethylbenzen v xylene trong
mu nc thi l 21, 14, 18 v 26 g / l (mu A), v 32, 37, 14 v 12 g / l (mu B)
 SO SNH KT QU
PHNG PHP HIN TRNG V PHNG TH NGHIM
 KT QU TH NGHIM
PHNG PHP SC K HIN TRNG
Thi gian phn tch l khong 3 pht (1 pht
bng k thut SPME. Thi gian phn tch ca
BTEX bng my GC cm tay nh hn 2 pht)

GC-FID cm tay kt hp vi HS-SPME l

phng php phn tch nhanh BTEX trong cc
mu nc v l mt cng c tim nng v
mnh m cho vic theo di mi trng.
 V. KT LUN

1. nh lng Btex trong mu nc l vic lm cn thit

nh gi mc nhim trong nc.

2. Phng php GC -FID cm tay kt hp vi HS-

SPME c pht trin thnh cng phn tch BTEX
trong mu nc. Thit b phn tch nh gn, kh nng
phn tch nhanh chng, hiu qu.

3. p ng nhu cu quan trc, ng dng mnh m cho

vic theo di mi trng.
.
XIN TRN TRNG CM N!