0.

01M EDTA

2014-03-24 Department of Chemistry, Yonsei Univ. 1



1.
2.
3.
4.
5.
6.

2014-03-24 Department of Chemistry, Yonsei Univ. 2



factor

2014-03-24 Department of Chemistry, Yonsei Univ. 3



2014-03-24 Department of Chemistry, Yonsei Univ. 4

 EDTA(ethylendiamine tetraacetic acid)

1. Chelate effect

2. Stoichiometry
with metal

EDTA

2014-03-24 Department of Chemistry, Yonsei Univ. 5


2+
Hg + EDTA(excess) Hg-EDTA
2+
EDTA(remain)+Mg Mg-EDTA

1.

2. pH

3.

2014-03-24 Department of Chemistry, Yonsei Univ. 6


n+ 2- n-4 2+
M +MgY MY + Mg

n-4 2-
MY MgY

n+
, M
.

2014-03-24 Department of Chemistry, Yonsei Univ. 7


4- n+ n-4
Y +M MY

Conditional Formation Constant

n4
[MY
Kf = M
n+
[Y
4
]
]
n4
[MY
Kf = Y4Kf = M
n+
[Y
4
]
]

2014-03-24 Department of Chemistry, Yonsei Univ. 8

 <pH EDTA >

2014-03-24 Department of Chemistry, Yonsei Univ. 9


-
.

-
.

- EDTA
.

Figure 11.15 Guide to EDTA

titrations of common metals.

2014-03-24 Department of Chemistry, Yonsei Univ. 10

 EBT N.N.

pH 10 Ca2+, Mg2+ pH 12~13 Ca2+

EDTA
-
() EDTA- +
()

2014-03-24 Department of Chemistry, Yonsei Univ. 11


2+ 2+
(Mg , Ca )
. CaCO3 ppm .

CaCO3 ?
CaCO3 100

2014-03-24 Department of Chemistry, Yonsei Univ. 12



2014-03-24 Department of Chemistry, Yonsei Univ. 13


500ml 2, 100ml 2, 100ml
3, 25ml , , pH paper, ,
,

2014-03-24 Department of Chemistry, Yonsei Univ. 14

 -
1) EBT(Eriochrom Black T)

EBT triethanolamine
ethanol .

Q. triethanolamine ?

A. Masking agent
EDTA
.

2014-03-24 Department of Chemistry, Yonsei Univ. 15

 -
2) (pH 10)

NH4Cl .

Q. ?

A. pH
pH
.

2014-03-24 Department of Chemistry, Yonsei Univ. 16

 -
3) 0.01M CaCl2

CaCl2
.

Q. CaCO3 CaCl2 ?

A. CaCl2
.
cf. CaCO3 : 0.0013g/100ml (25)
CaCl2 : 74.5/100ml (20)

2014-03-24 Department of Chemistry, Yonsei Univ. 17

 -
4) 0.01M EDTA

EDTA2Na

.

2014-03-24 Department of Chemistry, Yonsei Univ. 18

 -
5) 6N-NaOH

NaOH

.

2014-03-24 Department of Chemistry, Yonsei Univ. 19


1 : 0.01M EDTA
CaCl2
EBT 3
.

EDTA

.

2014-03-24 Department of Chemistry, Yonsei Univ. 20


2 :

EBT
.

EDTA


.

2014-03-24 Department of Chemistry, Yonsei Univ. 21


3 : Ca
6N-NaOH pH 12-13
. N.N. .
EDTA
.

Q) NaOH ?

A) Mg2+
Ca2+

2014-03-24 Department of Chemistry, Yonsei Univ. 22


2014-03-24 Department of Chemistry, Yonsei Univ. 23


1 0.01M EDTA

1 2 3
(mL) 20.21 19.34 20.05 19.87

2014-03-24 Department of Chemistry, Yonsei Univ. 24

 1

Factor = /

2+
EDTA Ca 1:1
Ca = EDTA
MV = MV
[Ca2+] 0.020L = [EDTA] X 0.01987L
0.010M X 0.020L = [EDTA] X 0.01987L
[EDTA] = 0.01006M 0.010M
Factor = 0.01006M/0.010M 1.0

2014-03-24 Department of Chemistry, Yonsei Univ. 25


2

1 2 3
(mL) 3.64 3.35 3.82 3.60

2014-03-24 Department of Chemistry, Yonsei Univ. 26

 2

(ppm = mg/L)
= CaCO3 (mg)/ (L)

CaCO3 = [EDTA] X EDTA X factor

0.010M X 0.00360L X 1.0 = 0.000036 mol

3 3
100.09 1000
0.000036
= 1

() 0.050

= 72mg/L = 72ppm

2014-03-24 Department of Chemistry, Yonsei Univ. 27


2+
3 Ca
1 2 3
(ml) 2.36 2.45 2.31 2.37

2014-03-24 Department of Chemistry, Yonsei Univ. 28

 3
2+
Ca : EDTA
.

0.01 2.37 1.0 100.09/

= 0.047g/L
1000 0.050
= 47ppm

Mg2+ : Ca2+

72ppm 47ppm = 25ppm

2014-03-24 Department of Chemistry, Yonsei Univ. 29


http://upload.wikimedia.org/wikipedia/co
mmons/5/57/Metal-EDTA.png (EDTA
) 2014.03.19
Daniel C. Harris, Quantitative Chemical
Analysis, 8th edition, 237p (chelate effect)
Daniel C. Harris, Quantitative Chemical
Analysis, 8th edition, 240~242p
(Conditional Formation Constant)
http://en.wikipedia.org/wiki/File:Erio_T.svg
(EBT ) 2014.03.17
http://www.tcichemicals.com/eshop/en/u
s/commodity/H0250/ (N.N.
) 2014.03.17

2014-03-24 Department of Chemistry, Yonsei Univ. 30


Daniel C. Harris, Quantitative Chemical
Analysis, 8th edition, 251p (Figure 11-15)
http://www.mpbio.com/product.php?pid=
02157451&country=113 (2014.03.17)
Daniel C. Harris, Quantitative Chemical
Analysis, 8th edition, 253p (Box 11-3)
http://en.wikipedia.org/wiki/Calcium_chlo
ride
http://en.wikipedia.org/wiki/CaCO3

2014-03-24 Department of Chemistry, Yonsei Univ. 31