45. 46. 41, 48. 49. 50. Sis 82 The number of unpaired electrons calculated in [Co(NH,),P” and [Co(k,)|*are (Aja and 4 (B) 0 and 2 (©) 2and 4 (D) Oana 4 In the grignard reaction, which metal forms an organometallic bond ? (A) Sodium (B) Titanium (©) Magnesium (D) Palladium The — bonded organometallic compound which has ethane as one of its component is (A)Zeise’s salt (B) Ferrocene (C) Dibenzene chromium (D) Tetraethyl tin Which one of the following complex isan outer orbital complex (At no, Mn=25, Fe=24, Co=27, Ni=28) (A) [Fe(CN) J (B) [Mn(CN) J’ (C) [CoNHy,) (D) [NH ‘The magnetic moment of [Co(NH,),ICI, s (A173 (B) 2.83 (€) 66 (D) Zero In Fe(CO), the Fe -C bond possesses (A) 2—charcter only (Byboth Gand 7 — character (C)ionic character (D) o character only According to wemer’s theory : (A)Primary Valeocy can be ionized (B) Secondary valency can be ionized (C)Primary and secondary vakencies cannot be ionized (D) Only primary valency cannot be ionized Ligand in acomplex salt are : (A)Anions linked by coordinate bonds to a central metal atom or ion (B) Cation linked by coordinate bonds to a central metalatom or ion (C)Moleculer linked by coontinate bonds to. central metal atom or ion (D)lons or mokeules linked by coordinate bonds toa central metal atom orion58. 59. 60, According to Lewis the ligand are (A) Acidic in nature (B) Basie in nature (©)Neither acidic nore basic (D) some are acidic and other are basic Which of the following acts as.a bidentate ligand in complex formation ? (A) Acetate (B) oxalate (©) Thiveyanate (D) EDTA ‘The coordination number of cobalt in the complex [Co(en),Br,]el,, (a2 (B)6 @s (4 Which is the example of hexadentate ligand ? (A)2,2-dipyridy! (B) Dimethyl glyoxime (© Aminodiacetate ion (D) Ethylene diammine tetra actate ion (ayPn (By Ptn (©) PO; (D)A and B both ‘The primary valeney of the metal ion in the eoordinateion compound K,{Ni(CN),]is. (A) Four (B) Zero (C) Two (0) Six ‘The metal which forms polynuclear earbonylis? (A)Ma (B) Co (yer () Fe Potassium ferrocyanide is a. (A) Nonmal salt (B) Mixed salt (©) Double salt (D) Complex salt6. 02 63 6s. 66, 67 68 68, Given the molecular formula of the hexa coordinated complexes. (A)Co C1, 6NH, (B) Co Cl, SNH, (©)CoCl4NH, [Ifthe number of coordinated NH, molecudes in A.B and C respectively are 6,5 and 4 the primary valency (A), (B) and (C) ae. (A054 (8) 324 01.2 338 Inthe compound fihium teshydroskuminat the ligand is wn en on (O)None ofthese Which ofthe folowing isthe od one out (4) Potassium ferocyanide @ Ferous ammonium suiphate (C) Potassium ferricyanide (D) Tetrammine copper (Il) sulphate Ligand in complex compounds (A) Accept pair ) Donate &~ pair (©) Neither accept e-= pair nor donate O)Allorthese Which ofthe following sa common donor stom in ligands ? ()Ansenic (8) Nitrogen (Oxygen (©) Both Band C Finely divide combines with CO to give (FEC), (8) Fe{CO), (©) FeCO,, (©) FeO), Zeighr-Nava catalysts used for which ype of reaction, (A)Hydrogenation —(B) Polymersation —_(C) Oxidation (D)Redustion ‘An aqueous solution of potash Alum gives. (A) Tro types of ons (Only one ype of on (©)Four ype ofions (Oy Thece types of ins CCamalitin solution in HO shows the propetios of (A) K'Mg2ct (8) K.CrSO? Be (CK Mg*.cO,* (0) Kg", C, Broo. 70. nm. 72. 74, 15. Camalite in solution in HO shows the properties of. (A) K’.Mg™ (B) K’,CI,SO?> Br- (C) KMg2,CO, (D) K Mg In a complex, the highest possible coordination number is (Ay6 (2 «a4 8 Number of ions present in aqueous solution of Fe, [Fe(CN),], is ws (B)2 7 (6 How many ions are produced in aqueous solution of (CoH,0),} Cl, ? (A)2 (B)3 4 (6 Compound Oxidation state (A) [Co(NH),CIICI, 0 (B) NH,OH -l (C) (NHY,SO, 2 (D) Mg.N, 3 ‘The formula of dichlorido bis (urea) copper (II) is ? (A) [Cu O=C(NH,)JCLI (B) [Cucl(O=C(NH),),] (C) [Cu (O=C(NH,))CLICL (D) [(CuCl(O=C(NH,),H,] Correct formula of diammine silver (I) chloride is? (A) Ag(NH,)C1 (B) Ag(NH,)C1 (C) [Ag(NH)),JC1 (D) [Ag(NH,),]C176. 77. 28. 79. 80. 81. 83. ‘The formula of sodium nitroprusside ? (A) Na,[Fe(CN).NOS] (B) Na,{Fe(CN),NO] (C) NaFe[Fe(CN),] (D) Na,[Fe(CN),NO,] ‘The IUPAC name of [Co (NH,),(NO,),) is ? (A) Trinitrotriammine cobalt (IM) (B) Trinitrotriammine cobak (11) (C) Trinitrotriammine cobalt (III) ion (D) Trinitrotriammine cobaltate (II) The oxidation numbers of chromium in Na{CrF 0] complex is ? (Ay @)yIV (vi (i The correct IUPAC name of Fe,{Fe(CN),],is ? (A) Ferroso - Ferric cyanide (B) Ferric - Ferrous hexacyanide (C) Iron (11) hexacyano ferrate (II) (D) Hexacyano ferrate (III-II) In which of the following complex the oxidation number of method is zero ? (A)EPKNH),CL] (BY [Cr (CO), (C)[CrNH,),Cl, — (D) [ Cren), CL] In the complex compound K,[Ni(CN),] oxidation state of nickel is ? (A)-1 (B)O (C)+1 (D) +2 ‘The pair of the compounds in which both the metals are in the highest possible oxidation state is ? (A) [Fe(CN),J, [Co(CN),]* (B) CrO,Cl,, MnO, (C) TiO, Mn, (D) [Co(CN),}*, MnO, The number of unpaired electrons in the complex ion [CoF,]° is (Atomic no of Co=27) (A) zero. (B)2 (C)3 (D)484, 85. 87. 88. 89, 90 Which one of the following will not show geometrical isomerism ? (A) CrNHY, CLICI (B) [Co(en),C1 JCI (C) [Co(NH,),NO,}CI, (D) [PUNH)),CL] Which would exhibit co-ordination isomerism. (A). CHINH,) JICO(CN)g] (B) [Co(en),CL] (C) [Cr (NH) JCI, (D) [Cx(en),CL] (A) Geometrical isomer (B) Optical isomer (C) Linkage isomer (D) Co-ordination isomer [Co(NH,),Br] SO, and [Co(NH,),SO]Br ase examples of which type of isomerism ? (A) Linkage (B) Geometrical (C) lonisation (D) Optical Which would exhibit ionisation isomerism. ? (A)[ Cr (NH) JCI, (B) (Co(NH,), Br]SO, (C) [Cr(en),Ch] () [Cx(en),Cl,] Among the following ions which one has the highest paramagnetisin ? (A) [Cr (H,0),)? (B) [Fe(H,0),]* (C)[ Cu (H,0),° (D) [Zn (H,0),P* The type of isomerism present in nitro pentamine chromium (III) Chloride is ? (A) Optical (B) Linkage (C) lonisation (D) Polymerisationm1. 92. 93. 94. 95. 96. 97. 98. Pick out from the following complex compounds,a poor electrolytic conductor in solution ? (A) KPrc,] (B) [Co(NH,), (NO,),] (C) K,[Fe(CN),] (D) [Cu(NH,),] SO, ‘The oritical Magnetic moment of (Cu(NH),}* ion is ? (A) Lata (B) 1.73 (©)2.23 (D) 238 Which of the following is paramagnetic ? (A) [Ni(CO),F> (B) (Co(NH,),P* (C) INi(CN),P (D) Niel, ‘The numbers of unpairelectrone in Ni(CO),is ? (A) zero (B) One (C) Three (0) Five Which of the following has highest paramagnetismm ? (A) Ni(CO), (B) [Ni (NH),JCI, (C) [Ni(NH,)JCL, () [Cu (NH) JCI, Which of the following does not have optical isomer? (A) [Co(NH,), Ch] (B) (Co (en),JCl, (©) [Co (en),Cl JC} (D) [Co (en)(NH),CLICI ‘The colour of tetrammine copper (Il) sulphate is ? (A) Blue (B) Red (CWiolet (D)Green Cuprammonium ion [Cu(NH),° & ? (A) Tetrahedral (B) Square planar (©) Triangularbipyramidal (D) Octrahydra99. 101. 102. 103. 104. 105. 106. ‘The type of hybridisation involved in the metal ion of [Ni(H,O),* complex is ? (A) d’sp? (B) sp'd? (C)sp> (D) dsp? water.one mole of the same complex react with two moles of AgNO, solution to yeild two moles of AgCl., the structure of the complex is... (A) [Co(NH,), CCI, (B) [Co(NH,),C1,]Z NH, (C) [Co(NH,), CLJCLNH, (D) [Co(NH,), CICL.NH, Which one of the following has squar planar geometry? (A) [Ag(NH)),]° (B) [Cu(en),* (© Mn cL? (D) [Ni(CO),] The complex ion which has no ‘d’ electrons in the central metal atom is (A) [Ma O,]- (B) [CoH (C) [Fe(CN), (D) (Cx(H,0),)" The strongest ligand in the following is (AYCN- (B)Br (CHO (DF The most stable ion is (A) [Fe(OX),]* (B) [Fe(C),] (C) [Fe(CN),P (D) [Fe(H,0),P* Wilkinson's catalyst is used in (A)Polymerisation __(B) Condensation (C)Halogenation _(D) Dehydrogenation Mixture X=0.02 mole of [Co(NH,),SO, ]Br and 0.02 mole of [Co(NH,),Br]SO, was prepared in 2 litre of solution. 1 Litre of mixture X + excess AgNO, > Y 1 Liter of mixture X+ excess BaCl,>Z Number of moles of Y and Z are respectivly (A) 0.01, 0.01 (B) 0.02, 0.01 (C) 0.01, 0.02 (D) 0.02, 0.02107. In [Ni(NH,),]SO, the valency and coordinate number of ill be respectivly ? (A)3 and 6 (B) 2 nad 4 (C)4and 2 (D)4and 4 108. Which of the following compunds shows optical isomerism? (A) [Cu(NH),P (B) [Zn (€) [CXC,0,),P (D) [Co(CN),P o% 109. In the process of extraction of gold, Roasted gold ore +CN- + H,0 > X+OH- [X]+Zn — Y+Au Wentify the complexes [X] and [Y] (A)X=[AU(CN) J Y= [2n(CN),P (B) X= [AuCN),* Y= [2n(CN), (C)X=[AWCN), Y= [2n(CN)+ (D)X=[Au(CN)- Y= [Za(CN) 2 110. Which of the following statement is incorrect ? (A) In K[Fe(CN),) the ligand has satisfied both primary and secondary vakrcies of ferric ion (B) In K {Fe(CN),}, the ligand has satisfied both primary and secondary valencies of ferrous ion (C) In K[Fe(CN),], the ligand has satisfied only secondary valencies of ferric ion (D) K{Fe(CN),] is diamegenctic while K,[Fe(CN),] is paramagneticRead theassertion and reason carefully to mark the correct option out of the option given below = (A) If both assertion and reason are true and the reason is the correct explanation of the assertion. assertion. (C) _Ifassertion is true but reason is false. (D) Ifthe assertion and reason both are false. (F) Ifthe accortinn is falco hut mason ie tae (111) Assertion —: Potassium ferocyanide and potassium ferricyanide both are diamagnetic, Reason: Both have unpaired election. (112) Assertion: The [Ni(en),]CI, has lower stability than (Ni(NH,),JC1, Reason = In [Ni(en),]Cl, the geometry of Ni is trigonal bipyramidal, (113) Assertion Geometrical isomerism is also called cis -trans isomerism. Reason = tetrahedral complexes show geometrical isomerism. (114) Assertion; HN - NH, is a chelating ligand. Reason _: A chelating ligand must possess two or more lone pair atsuch distance that it may form suitable strain free ring at the metal ion. (115) Assertion: [Ti(H,0),]"3 is coloured while [Se(H,0),]* is Colourless Reason _: d-d transition is not possible in [Se(H,O),]* (116) Asserion —_; Allthe octahedral complexes of Ni? must be outer orbital complexes. Reason Outer orbital octahedral complexes are given by weak ligand.SWER KEY AN! o| 8) 3] 3] a] 3] 3] 4) 5] 8] a/R) A] A] aya] a