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Chapter B2: Sedimentation and Flotation: Frik Schutte
Chapter B2: Sedimentation and Flotation: Frik Schutte
Frik Schutte
INTRODUCTION
The terms sedimentation and settling are used interchangeably. A sedimentation tank
may also be referred to as a sedimentation basin or settling tank. Sedimentation tanks
may be of different shapes and can be functioning as settling tank only, or it can also
incorporate flocculation and sludge compression. Different proprietary designs are
available, but the basic functioning of all types is similar.
PROCESS DESCRIPTION
Sedimentation or settling is the simple process in which particles that are heavier than
water settle to the bottom of a container in which the suspension is held, or through
which the suspension flows. On the basis of the concentration of particles and the
tendency of particles to interact, four types of settling behaviour can be distinguished:
discrete particle settling, flocculent settling, hindered (also called zone settling) and
compression settling. These types of settling phenomena are described in Table B2.1.
Often more than one type of settling occur at the same time during the settling process
and it is not uncommon to have all four occurring simultaneously as shown
schematically in Figure 1.
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Hindered, also called Refers to suspensions of intermediate concentration of chemical
Zone settling floc, in which inter-particle forces are sufficient to hinder the
(Type 3) settling of neighbouring particles. The particles tend to remain in
fixed position with respect to each other and the mass of particles
settles as a unit. A solid-liquid interface develops at the top of the
settling mass.
Compression Refers to the settling in which the particles are of such
(Type 4) concentration that a structure is formed and further settling can
occur only by compression of the structure. Compression takes
place from the weight of the particles, which are constantly being
added to the structure by sedimentation from the supernatant
liquid.
Effective sedimentation and removal of particles from water depends mainly on the
effectiveness of the coagulation-flocculation process and on the proper design of the
sedimentation tank. If coagulation (charge neutralisation and destabilisation) is not
effective, the forces that keep particles apart will persist. If flocculation is not
effective, the opportunity for collision between particles and floc growth will not be
optimal and large floc aggregates that settle readily will not be formed. If coagulation-
flocculation is effective but the design of the sedimentation tank is such that flocs
deteriorate due to poor inlet design, or flocs cannot settle due to too high up-flow
velocity or short-circuiting, the effluent water will still have a high turbidity.
EQUIPMENT
Different designs exist for sedimentation tanks. The most common designs are
rectangular horizontal flow tanks in which the water enters one side and leaves at the
other end, and circular tanks with flat or cone-shaped bottoms with water entering the
tank at a central distribution section and leaving at collection troughs at the
circumference of the tank.
All sedimentation tanks can be divided into four zones, each with a specific function.
These are the inlet zone, settling zone, outlet zone, and the zone for sludge storage. A
schematic diagram of the zones is given in Figure B2.1.
The purpose of the inlet zone is to distribute the flow and suspended floc particles
evenly across the cross section of the settling zone. It normally consists of a series of
pipes and baffles through which the flow is distributed into the settling zone. The
water velocity is reduced as it enters the settling zone. Proper inlet zone design is
important to prevent deterioration in floc structure and to achieve good solids removal
efficiency. The settling zone is the largest part of the sedimentation tank and settling
takes place as the water flows at reduced velocity through a large flow area (width
times depth). The low velocity allows floc particles to settle into the sludge zone and
be removed from the water leaving the tank.
The settling velocity and overflow rate are two important parameters that determine
solids removal efficiency in the settling zone. The rate at which a particle settles is the
particle settling velocity, while the velocity of the water rising in the settling zone is
the overflow rate. Obviously if a particle is to be removed in the settling zone the
settling velocity must be higher than the water rise velocity or the overflow rate. The
overflow rate (up-flow rate) or surface-loading rate is an important design parameter
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and has the units of m3/m2.d or m/d (flow of water m3/d being applied per mof 2
3 2 3
surface area), or m /m .h if flow is in m /h. The overflow rate is relatively low for
horizontal flow tanks, in the range of 1-2 m/h and higher for vertical tanks, in the
range of 3-5 m/h. Much higher rates of 15 m/h and higher have been mentioned in the
literature.
Depth ........
Hindered settling (3) ........
........
…....
........
……
...…
…....
........
........
Time
The outlet zone provides a large area for the water to leave the sedimentation tank
before flowing into a pipe or canal to transport the water to the sand filters. The outlet
zone is designed so that settled water can be removed from the tank without
entraining any floc particles that have settled. The objective of the large area is to
minimise the flow velocity and thereby prevent scouring or lifting of the settled floc.
The large outlet area is obtained by means of a series of weirs or troughs into which
the water decants or overflows.
The configuration and depth of the sludge storage zone depends on the quantity of
sludge removed from the water and the method and frequency of cleaning.
Mechanically cleaned settling tanks normally have a bottom scraper that scrapes the
sludge continuously to a hopper from where the sludge is pumped out. Figure B2.2
portrays the different zones in horizontal sedimentation tank.
A specific design of sedimentation tank that allows flocculation to take place in the
unit is the so-called sludge blanket (or floc blanket clarifier). A typical unit consists of
a cylindrical upper section with a concentric inlet and flat or hopper-shaped base.
Water that has been coagulated is fed downward through the inlet into the base of the
tank. The upward flow through the settling section facilitates contact with particles in
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that zone and allows flocculation to occur so that large floc particles remain in
suspension in the tank. Particles in suspension accumulate slowly at first but increase
because of enhanced flocculation. This continues to a maximum accumulation rate
limited by the upflow velocity of the water and particle characteristics. At this rate a
floc blanket has been established in the tank.
Inlet
baffle Effluent weir
Settling zone
Inlet
zone
Outlet zone
Sludge zone
The floc-blanket surface level is controlled by removing solids from the blanket so as
to keep a zone of clear water between the surface of the floc blanket and the troughs
through which the clear water leaves the clarifier.
OPERATIONAL ASPECTS
A number of factors affect the performance of sedimentation tanks. These factors fall
in two categories, i.e. hydraulic factors and particle characteristics. Hydraulic aspects
include the flow-through rate, residence time in the tank, the size and shape of the
tank, the inlet and outlet flow arrangements, possible short-circuiting, sludge removal
mechanism and removal frequency. Floc particle characteristics include size, nature,
density and strength of the floc.
Sedimentation is suitable for removal of flocs such as silt and clay particles that are
relatively heavy and settle readily. However, flocs formed by flocculation of algae or
organic matter are relatively light and do not settle readily. Flotation is a much more
effective process for removal of such light flocs. Sedimentation and flotation perform
the same function, with sedimentation being used normally when the raw water
contains mainly silt or clay particles, while flotation is used when the raw water
contains algae or other types of organic material.
Settling velocities
The function of a settling tank is to remove by gravity particles that are denser than
water. The rate at which a particle will settle (vp) under quiescent conditions depends
on:
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š The concentration of particles
š The size and shape of the particles. Large particles settle faster than small particles
and smooth spherical particles faster than flaky ones such as agglomerates.
š The density of the particle relative to the density of water.
š The viscosity of the liquid. The higher the viscosity, the lower the settling rate.
As the viscosity of a liquid is also a function of temperature, the cooler the liquid,
the higher the viscosity and thus the lower the settling rate.
One of the main criteria for the design and operation of a settling tank is the surface
overflow rate. The surface overflow rate gives the upflow velocity of the water for a
given flow of water (Q) and water surface area (A) of the settling tank and can be
presented mathematically:
Vs = Q/A
All particles with a settling rate (Vp) > surface overflow rate (Vs), will settle and be
removed from the influent stream.
The hydraulic residence time indicates how much time the water spends in the tank.
The hydraulic residence time is calculated as follows:
W =
V/Q
Where:W = hydraulic residence time, h
V = volume of settling tank, m3
Q = inflow rate, m3/h
Although the hydraulic residence time theoretically does not play a role in the
efficiency of the settling tank, larger settling tanks with longer hydraulic residence
times have more storage space for sludge and generally give a higher sludge
concentration.
With rectangular horizontal-flow tanks the water enters the tank at the inlet section
and the settled water leaves the tank through outlet troughs at the outlet end. The inlet
flow arrangement must provide a flow distribution that maximises the opportunity for
particles to settle. If flocculation has been carried out to maximise floc particle size,
then the flow at the inlet should not disrupt or break up the flocs. This requires
minimising the head loss between the distribution channel and the main body of the
tank. However, a certain amount of head loss is necessary to achieve flow
distribution.
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The principal differences between tanks relate to inlet and outlet arrangements;
length, width and depth ratios and the method of sludge removal. For horizontal-flow
tanks with a small length-width ratio the end effects dominate efficiency. Poor flow
distribution may produce currents or high flow velocities near the bottom of a tank.
This may cause scour, or re-suspension of particles from the layer of settled sludge.
Scour may cause transportation of solids along the bottom of the tank to the outlet
end. An adequate tank depth of not less than 2,5m limits scour.
The frequency of sludge removal depends upon the rate of sludge accumulation. This
is estimated by mass balance calculations to determine the removal frequency.
Sometimes, the decomposition of organic matter in the sludge necessitates more
frequent sludge removal. Decomposition may produce gas bubbles that disturb the
settled sludge and cause deterioration in settled water turbidity.
Frequent sludge removal is best carried out with mechanical sludge scrapers that
sweep the sludge to a hopper at the inlet end of the tank. Frequent removal results in
easy maintenance of tank volumetric efficiency, and better output efficiency with
continuous operation. In larger tanks sludge may be removed continuously by means
of sludge pumps located on a travelling bridge.
Figure B2.3 shows a large horizontal sedimentation tank at the Vereniging works of
Rand Water.
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Factors influencing sedimentation efficiency
For all types of settlers, flow velocities in approach channels or pipe work that are low
enough to allow premature settlement must be avoided. Conversely, flows high
enough to disrupt and break up floc aggregates must be avoided.
Baffles are useful in horizontal-flow tanks at the inlet and outlet to assist flow
distribution, longitudinally to increase length-width ratio, and as vanes to assist
changes in horizontal-flow direction.
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Wind and density currents
Wind can induce undesirable circulation in horizontal-flow tanks. Wind effects should
be minimised by constructing tanks to align with prevailing winds. Strong winds can
disrupt floc-blanket stability. This can be counteracted by covering tanks with roofs,
constructing windbreaks around tanks, or installing fully submerged baffles in the
supernatant water.
High solar radiation can cause diurnal changes in water temperature and density.
Rapid density changes because of temperature, solids concentration, or salinity can
induce density currents that can cause short-circuiting and reduced efficiency in
horizontal tanks.
Wastes produced
The sludge removed from sedimentation tanks is the major waste produced at a water
treatment plant. The sludge consists of the suspended and colloidal material removed
from the water together with the precipitate formed by the coagulant and flocculant.
The nature of the sludge is largely determined by the coagulant used, for example the
nature of lime sludge differs largely from the nature of sludge produced from ferric
chloride as coagulant.
The sludge is withdrawn from the sedimentation tank and may then be thickened
before disposal or may be disposed of directly. The concentration of sludge produced
determines the actual volume to be disposed of. Alum sludge normally has a low
solids concentration of less than 1% m/v while lime sludge can have a solids
concentration of up to 4 or 5% m/v.
Sludge can be thickened to reduce the volume to be disposed of. This is normally
done in circular thickening tanks that produce thickened alum sludge of about 3% m/v
solids concentration and lime sludge of 20-22 % m/v solids in the under flow.
Operational considerations
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š Ensuring an even inflow and distribution of flocculated water into the tank. The
distribution of flocculated water in the sedimentation tank is mainly determined by
design. The operator must therefore observe flows and the nature of flocs. If it is
evident that flow distribution problems exist, the operator must investigate possible
problems such as blockages in channels or inlet pipes and clean if necessary.
š Ensure that the scraping mechanisms and moving bridge function properly.
Maintenance must be carried out according to schedule to ensure proper
functioning. Regular visual inspections are also necessary to detect possible
mechanical problems. If mechanical problems occur, the equipment must be
stopped and maintenance staff called in.
š Sludge must be pumped regularly from the tank according to operating
instructions. If sludge is left too long in the tank, it may become too thick and
cause pump problems. Alternatively settled sludge may be entrained and cause a
deterioration in settled water quality. If sludge is pumped too frequently, the sludge
may become very thin, resulting in high water losses and rapidly filling of sludge
dams or lagoons.
š The sides and overflow weirs of the sedimentation tanks must be kept free from
algal and other growths by regular brushing and cleaning. Algal growths may cause
taste and odour problems and also create a poor impression of the operation and
control.
š The turbidity of the overflow from each tank must be determined on a regular
basis. If the turbidity exceeds set values, the cause for poor performance must be
determined and corrective action taken. Possible causes include an increase in
inflow to the sedimentation tank as a result of increased production or due to
problems with flow distribution between tanks. Other possible causes include too
low pumping frequency of sludge or wind or density currents.
š In case of poor performance, check inflow volume, calculate upflow velocity,
check inflow distribution, check coagulation, check flocculation and correct where
necessary
FLOTATION
Flotation involves the formation of small air bubbles in water that has been
coagulated. The bubbles attach to the flocs causing them to rise to the surface where
they are collected as a froth that is removed from the top of the flotation unit.
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Both sedimentation and flotation remove the bulk of the flocs from the water.
However, most of the time a small amount of (broken) flocs or non-flocculated
colloidal material remains in the water. This material has to be removed to ensure a
low enough turbidity in the water. A sufficiently low turbidity level is required for
effective disinfection of the water and to remove all traces of murkiness from the
water. Removal of turbidity to low levels is achieved by means of sand filtration.
In dissolved air flotation systems, air is dissolved in the water under a pressure of
several atmospheres, followed by release of the pressure to the atmospheric level. In
small pressure systems, the entire flow may be pressurised by means of a pump to 275
to 350 kPa. The entire flow is held in a retention tank under pressure for several
minutes to allow time for the air to dissolve. It is then admitted through a pressure-
reducing valve to the flotation tank where air comes out of solution in minute bubbles
throughout the entire volume of water.
In larger units a portion of the water (7-15%) is recycled, pressurised and saturated
with air. The recycled flow is mixed with the un-pressurised main stream just before
admission to the flotation tanks.
The combination of flotation and filtration in one unit has developed over the last
number of years. The main advantage of this arrangement is a very compact
treatment plant that is very useful in package treatment plants. A rapid gravity sand
filter is incorporated in the bottom section of the flotation unit. Limitations of this
type of plant include the fact that the flotation rate is limited by the filtration rate, and
furthermore the flotation unit has to be stopped occasionally to allow backwashing of
the filter.
Flotation elements
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clarified water is recycled into the air saturation system. The water is pumped
through an injection device such as an eductor that introduces high-pressure air into
the system. Saturated water flows to the dispersion system where the pressure is
released and the micro bubbles formed.
š Bubble size is very important. Too large bubbles will rise rapidly and result in poor
performance. Too small bubble will add to size and cost of flotation tank. Bubbles
should be in around 50 μm, in the range of 10 – 100 μm.
š Flocculated water must be introduced uniformly across the end of the tank near the
bottom into the dispersion zone.
š The float of bubbles and floc collects at the surface of the tank where it forms a
stable and continuously thickening float. The float must be removed regularly
either by mechanical skimming or hydraulic removal.
Combined flotation/filtration
For potable water treatment purposes, whether flotation or sedimentation is used, the
water is inevitably filtered as a final polishing step. For clarification purposes, the
flotation and filter functions are sometimes combined into a single process unit, with
flotation carried out on top of the filter bed. The process is commonly known in
South Africa as the DAFF process (dissolved air flotation filtration) and as Flofilter in
Europe and as Sandfloat in the USA. There is no difference between settled and
floated water as far as its effect on the subsequent filtration step is concerned.
Operational considerations
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