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CORROSION
and its Types
CORROSION AND ITS
CONTROL
DEFINITION
Corrosion is defined as the gradual
destruction or deterioration of
metals or alloys by the chemical or
electrochemical reaction with its
environment.
Corrosion is a surface
phenomenon.
CONSEQUENCES OF CORROSION
6
Oxygen changes to ionic form (O2-) due to
the transfer of electron from metal, which
occurs at the oxide film / environment
interface.
½ O2 + 2e- → O2-
R = Md/nmD
Thus the metal ions (from anodic part) and non-metallic ions
(from cathodic part ) diffuse towards each other through
conduction medium and form a corrosion product between
anode and cathode.
a) Hydrogen evolution type corrosion
Metals have negative reduction potential
i.e., below hydrogen reduction potential
value in the electrochemical series get
dissolved in acidic solution with
simultaneous liberation of “hydrogen gas”.
Example: Iron metal in contact with non-
oxidizing acid like HCl results in H2
evolution
At anode: Iron (Fe) undergoes dissolution to
Fe2+ with the liberation of electrons.
At cathode: The liberated electrons follow
from anode to cathode, where H+ ions get
reduced to H2.
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b) Absorption of oxygen or formation of hydroxide
ion type corrosion
Fe surface usually contains a coating of Iron oxide and if
this oxide layer develops, cracking happens.
As a result anodic areas are created on the surface and
remaining area acts as cathode.
Example: Iron metal in contact with a neutral solution of
electrolyte in the presence of O2, OH- ions are formed.
At anode: Iron (Fe) undergoes dissolution to Fe2+ with the
liberation of electrons.
At cathode: The liberated electrons follow from anode to
cathode, where dissolved O2 is consumed to form OH-
ions.
1/2O2 + H2O + 2e- 2OH-
Fe2+ + 2OH- Fe(OH)2
Fe(OH)2 + 2H2O + O2 4Fe(OH)3 (rust)
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Chemical Corrosion Electrochemical Corrosion
It occurs only in dry condition It occurs in the presence of
moisture or electrolyte
It is due to the direct chemical It is due to the set up of a
attack of the metal by the large number of cathodic and
environment anodic areas
Even a homogeneous metal Hetergeneous surface or
surface gets corroded bimetallic contact is required
for corrosion
Corrosion products Corrosion occurs at the anode,
accumulate in the same place, while products formed
where corrosion occurs. elsewhere
Chemical corrosion is self- It is continuous process
controlled
It follows adsorption It follows electrochemical
mechanism reaction
Eg. Formation of mild scale on Eg. Rusting of iron in moist
iron surface atmosphere 20