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14 Gas Dehydration
14 Gas Dehydration
• Introduction
When the gas is at reservoir temperature and pressure, it is
generally saturated with water.
• Purpose:
• Definition:
Crystal structures with a set geometry that require the presence of
water and components present in hydrocarbons, for their formation.
• Why is it a problem?
Hydrate formation leads to:
– blocking of the pipes and equipment
– production shutdown
– risks of overpressure in the installations.
water deposition due to condensation in the pipes or free water
from the reservoir may cause large pressure drops with risks of:
– "water hammer" effects due to the liquid slugs
– erosion
Water is responsible for most types of corrosion when it is
associated with
– acid gases (H2S and CO2)
– or salts (calcium carbonates).
• Why is it a problem ?
• Commercial gas
H2S content: 1.5 to 4 ppm
Total sulphur and contaminants: 50 to 150 mg/Sm3
CO2 content: 2 to 3% molar mass
Water dew point: - 15°C at 70 bar
Hydrocarbon dew point: - 2°C at 70 bar
Composition (% volume)
N2 1.50
H2O 1.00
H2S 15.30
CO2 9.30
C1 68.00
C2 3.00
C3 0.90
C4 0.50
C5 0.20
C6+ 0.30
Condenseur
– Regeneration section de tête
- water-laden glycol is
Still column
Rebouilleur
urni - series of filters
Filtre
- glycol flows down Colonne
Stripping
Fuel gas
de
through the column stripping
Gaz
sec
Stockage
- exits the column towards
the reboiler for regeneration
- the water vapour exits Gaz
de flash
the distillation column in
the reverse direction
Glycol sec Gazoline
Glycol
- the concentrated glycol
exits the reboiler via Pompe à glycol
Séparateur gazoline
a weir glycol
• dehydration by adsorption
property of certain solids (= desiccants) to fix certain molecules on
their surface.
• dehydration by adsorption
• dehydration by adsorption
Differences between the main desiccants:
• REPRESENTATION
PFD (Process Flow Diagram):
this document, which is issued during the project phase, shows
the main process lines and tanks and their main operating
parameters
• Representation
P&ID (Piping & Instrumentation Diagram)
This document, which is issued during the project phase, shows
all the process lines and tanks and their main operating
parameters in a much more complex format than the PFD.
• Location
• Criticality
• Absorption section
Parameters governing absorption
– Concentration of the regenerated glycol
The glycol's purity level depends on:
- The bath temperature in the reboiler.
The higher the temperature, the more water is released by the
TEG.
The limit is set at 204°C because the TEG deteriorates above
215 C.
- The operating pressure of the distillation column
Operating below atmospheric pressure generates higher
concentrations at equivalent temperatures.
- The use of a dry gas stripping column.
With the stripping column, a level of 99.9% can be reached
(<98.7%).
• Absorption section
Parameters governing absorption
– Gas temperature in the absorber
The dew point at the top of the absorber depends on the
temperature there. A reduction in the gas temperature at the inlet
to the unit reduces the dew point at the outlet.
– Glycol circulation rate
- The minimum glycol circulation rate for a good glycol-gas
contact is approximately 15 litres per kg of water to be
removed from the gas.
- Average flow rate of 25 l/kg of water to be removed, for a
conventional installation..
• Absorption section
Normal operation
Downgraded operation
– Dehydration column by
passed
– MeOh pump operating
• Regeneration section
Thermal breakdown
– An excessive temperature in the reboiler can break down the
glycol and form corrosive products (the TEG decomposition
temperature is 215°C).
– Local overheating may be caused by salt or bitumen deposits on
the fire tubes or heating tubes.
Deposits
– Good filtration and activated charcoal treatment prevents the solid
particles and bituminous hydrocarbons from being deposited.
Presence of condensates
– The liquid hydrocarbons cause the glycol to foam.
– They can be eliminated in the flash drum and in the activated
charcoal filters.