• 1. A 5.

1 g piece of gold jewelry at a temperature

of 100.0oC is placed in a coffee cup calorimeter
containing 16.9 g of water at 22.5oC. The
equilibrium temperature of the system is
23.2oC. The calorimeter constant is known to be
1.54 J/oC.
•  
• What is the specific heat of the gold? For pure
gold s = 0.129 J/(goC). Is the jewelry pure gold?
• 2. From the following enthalpies of reaction,
•  
• 4 HCl(g) + O2(g)  2 H2O (l) + 2 Cl2(g) DH = -202.4 kJ/mol
•  
• ½ H2(g) + ½ F2(g)  HF(l) DH = -600.0 kJ/mol
•  
• H2(g) + ½ O2(g)  H2O(l) DH = -285.8 kJ/mol
•  
•  
• Calculate DHorxn for
•  
• 2 HCl(g) + F2(g)  2 HF(l) + Cl2(g)