India, considered one of the world’s worst industrial catastrophes.
It occurred on the night of December
2-3,1984 at the Union Carbide India Limited, a pesticide plant in Bhopal , Madhya Pradesh , India.
A leak of methyl isocyanate gas and other
chemicals from the plant resulted in the exposure of hundreds and thousands of people. UCIL was the Indian subsidiary of Union Carbide Corporation (UCC), with Indian Government controlled banks and the Indian public holding a 49.1 percent stake.
It started in 1969 at the northern state
of India.
Phosgene, Monomethlyamine, Methyl
Isocyanate (MIC) and the pesticide Carbaryl, also known as Sevin were manufactured here. UCC produced carbaryl using MIC as an intermediate.
After the Bhopal plant was built,
other manufacturers including Bayer produced carbaryl without MIC, though at a greater manufacturing cost.
However, Bayer also uses the UCC
process at the chemical plant once owned by UCC at Institute, West Virginia, USA and many other states. Methylamine (1) reacts with phosgene (2) producing methyl isocyanate (3) which reacts with 1-naphthol (4) to yield carbaryl (5) According to one theory: Water leaked into tank from valves while workers were cleaning the clogged pipe which is 400 feet above it. According to theory of UCC: Water was directly introduced into tank intentionally by a worker via a missing pressure gauge . It resulted in exothermic reaction and finally to a explosion. Cause Of Bhopal Disaster Use of a more dangerous pesticide manufacturing method for decreasing generation cost. Plant location close to a densely populated area. Plant management deficiencies like : Lack of skilled operators, Reduction of safety management. Insufficient maintenance and inadequate emergency action plans. UCIL didn’t maintained safety rules....... • A pipe leaked? Don't replace it. • MIC workers needed more training. They could do with less. • The MIC tank alarms had not worked for four years. • The flare tower and the vent gas scrubber had been out of service for five months before the disaster. • To reduce energy costs, the refrigeration system was idle. The MIC was kept at 20 degrees Celsius, not the 4.5 degrees advised by the manual. • The steam boiler, intended to clean the pipes, was out of action for unknown reasons.
• Carbon steel valves were used at the factory, even though
they corrode when exposed to acid.
• According to the operators the MIC tank pressure gauge
had been malfunctioning for roughly a week
• UCC admitted in their own investigation report that most
of the safety systems were not functioning on the night of December 3, 1984. Medical staff were unprepared for the thousands of casualties.
Doctors and hospitals were not informed of proper
treatment methods for MIC gas inhalation. They were told to simply give cough medicine and eye drops to their patients.
The gases immediately caused visible damage to
the trees. Within a few days, all the leaves fell off.
2,000 bloated animal carcasses had to be disposed
of.
"Operation Faith": On December 16, the tanks 611
and 619 were emptied of the remaining MIC. This led to a second mass evacuation from Bhopal.