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Chapter 7 Lecture
Chapter 7 Lecture
Chapter 7
ENTROPY
Mehmet Kanoglu
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
ENTROPY
The second law of thermodynamics often leads to expressions that involve inequalities
An irreversible (i.e., actual) heat engine, for example, is less efficient than a reversible one
operating between the same two thermal energy reservoirs.
Likewise, an irreversible refrigerator or a heat pump has a lower coefficient of performance
(COP) than a reversible one operating between the same temperature limits.
Another important inequality that has major consequences in thermodynamics is the Clausius
inequality.
It was first stated by the German physicist R. J. E. Clausius (1822–1888), one of the founders
of thermodynamics, and is expressed in 1865 as
Clasius
inequality
Formal
definition
of entropy
Note that entropy is a property, and like all other properties, it has fixed values at fixed states.
Therefore, the entropy change DS between two specified states is the same no matter what path, reversible
or irreversible, is followed during a process
A quantity whose cyclic
integral is zero (i.e., a
property like volume)
Entropy is an extensive
property of a system.
A cycle composed of a
reversible and an
irreversible process.
The increase of
entropy
principle
8
Some Remarks about Entropy
1. Processes can occur in a certain direction
only, not in any direction. A process must
proceed in the direction that complies with
the increase of entropy principle, that is, Sgen
≥ 0. A process that violates this principle is
impossible.
2. Entropy is a nonconserved property, and
there is no such thing as the conservation of
entropy principle. Entropy is conserved
during the idealized reversible processes
only and increases during all actual
processes.
3. The performance of engineering systems is
degraded by the presence of irreversibilities,
The entropy change of a and entropy generation is a measure of the
system can be negative, magnitudes of the irreversibilities during that
but the entropy generation process. It is also used to establish criteria
cannot. for the performance of engineering devices.
9
ENTROPY CHANGE OF PURE SUBSTANCES
Entropy is a property, and thus the
value of entropy of a system is fixed
once the state of the system is fixed.
During an internally
reversible, adiabatic
The isentropic process appears as a
(isentropic) process, the
vertical line segment on a T-s diagram.
entropy remains constant.
11
PROPERTY DIAGRAMS INVOLVING ENTROPY
On a T-S
diagram, the
area under the
process curve
represents the
heat transfer for
internally
reversible
processes.
For adiabatic steady-flow
devices, the vertical distance
∆h on an h-s diagram is a
measure of work, and the
horizontal distance ∆s is a
measure of irreversibilities.
12
WHAT IS ENTROPY?
Boltzmann
relation
13
The paddle-wheel work done on a gas increases the
level of disorder (entropy) of the gas, and thus energy
is degraded during this process.
15
ENTROPY CHANGE OF LIQUIDS AND SOLIDS
Liquids and solids can be
approximated as
incompressible substances
Since for liquids and solids since their specific volumes
remain nearly constant
during a process.
16
THE ENTROPY CHANGE OF IDEAL GASES
From the first T ds relation From the second T ds relation
A broadcast
from channel IG.
17
Constant Specific Heats (Approximate Analysis)
19
Isentropic Processes of Ideal Gases
Constant Specific Heats (Approximate Analysis)
20
Isentropic Processes of Ideal Gases
Variable Specific Heats (Exact Analysis)
Isentropic
Efficiency
of
Turbines
A substance leaves
actual nozzles at a
higher temperature
(thus a lower velocity)
as a result of friction.
28
ENTROPY BALANCE
Entropy Change of a
System, ∆Ssystem
31
Entropy Generation, Sgen Entropy generation
outside system
boundaries can be
accounted for by
writing an entropy
balance on an
extended system that
includes the system
and its immediate
surroundings.
33
Control Volumes
The entropy of a
substance always
increases (or
remains constant in The entropy of a control
the case of a volume changes as a
reversible process) result of mass flow as well
as it flows through a as heat transfer.
single-stream,
adiabatic, steady-
flow device. 34
EXAMPLES
Entropy balance for heat
transfer through a wall
35
Entropy generation associated
with a heat transfer process