RATE OF REACTION

CLASS XII SEMESTER 1

Standard competency
Identifies factors which influences rate of reaction
Based competency
Determines rate of reaction and order reaction
Explains factors which influences rate of reaction
Leaning Objective
co-signature and comprehends definition of rate of
reaction and determines change of concentration of per
set of time in form of rate equation of reaction.
co-signature and comprehends principles reaction of in
rate law.
co-signature factors influencing speed reaction, that is:
concentration, reacting matter character, temperature
and catalyst.
co-signature and comprehends theory and event of
hammering, and principal and influencing factories
hammering.
co-signature and comprehends definition of order
reaction and order expression reaction of at rate
equation of reaction, and way of determining reaction
order.
RATE OF REACTION
Level of change of concentration of reactant or
product in one set of time

Rate of reaction = concentration change

time change

Example:
Rate of reaction =
Factors influencing rate of reaction;
Concentration of reactant
Ever greater concentration of reactant hence rate of
reaction would be quicker taken place
Character reactant
Reaction of between ionic compounds generally takes
place quickly, while reacting between covalent
compounds to take place is slow
Temperature
If temperature is boosted up [by] hence reaction will
take place is quicker
Catalyst
Catalyst is matter added into a having a purpose
reaction enlarges reaction speed, catalyst will react but
end reaction will be formed again in the form and
number of the same like before reactions
FUNCTION OF CATALYST
 Function of catalyst is enlarge speed of its the reaction (quickens
reaction) by way of minimizing activation energy a reaction and
formed [by] it new reaction phases. With lowering of activation energy
hence at the same temperature reacted can take place quicker.
REACTION ORDER
Order a reaction is number of all exponents ( from
concentration of in rate equation). Order reaction of
also express level of influence concentration of
(reactant) to rate of reaction
Reacted first order if Rate=k[A]
Reacted second order if Rate=k[A][B]
Reaction of third order,
Rate=k [ A][B]2
DETERMINES REACTION ORDER
Reaction 4HBr + O2  2H2O + 2Br2 takes place in step;
Step 1; HBr + O2  HOOBr (slow)
Step 2; HBr + HOOBr  2HOBr (fast)
Step 3; 2HBr + 2HBrO  2H2O + 2Br2 (fast)
Hence order reaction of determined by reaction ( 1).
Rate equation of Reaction: V=[HBr][O2]
Order reaction of total ( sees reaction coefficient) = 1 + 1
= 2.
EXAMPLE OF PROBLEM
Reaction; P + Q + R  X + Y, obtained attempt data as
follows :
Number [P] [Q] [R] Times
1 0,1 0,1 0,2 6 minute
2 0,1 0,1 0,3 6 minute
3 0,2 0,1 0,2 3 minute
4 0,1 0,2 0,2 3 minute
5 0,1 0,3 0,2 2 minute

 Order reaction of to P, searched by seeing concentration [Q] and [ R] which

permanent. From data ( 1) and ( 3), known concentration [ Q] and [ R]
permanent, [ P] boosted up twice. So reaction of taking place 2 quicker times.
PROBLEM SOLVING

 Order reaction of to Q, searched by seeing concentration [ P] and [ R]

which is permanent namely as follows.
 Data ( 4) and ( 5)  1,5 quicker times
 Data ( 1) and ( 4)  2 quicker times
 Data ( 1) and ( 5)  3 quicker times
 Remembers : order reaction of determined by slowest reaction phase
Order reaction of to R, hence view data ( 1) and ( 2) where
concentration [ P] and [ Q] permanent. Concentration Of r
is boosted up [by] 1,5 times, simply reaction of taking place
is same quickly.

Hence rate equation of its(the reaction is as follows:

V = k [ P] [ Q]
Thanks