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Method: using field kits (used for water) to measure arsenic in soils and
digital image analysis for quantification.
Total Arsenic 40 40
Total Cadmium 80 30
Total Mercury 10 10
Areas of Concern:
• Arsenic in soil is mobile into water and plant sources.
• Is there bioaccumulation in rice?
• What are the average concentrations in soil and rice?
• Why is it more important to measure arsenic in soil than water?
Quandt, S. A.; Jones, B.T.; Talton, J. W.; Whalley, L.E.; Galvan, L.; Vallejos, Q.M.;
Grzywacz, J. G.; Chen, H.; Pharr, K.E.; Isom, S.; Arcury, T.A.
Heavy metals exposures among Mexican farm workers in eastern North Carolina,
Envir. Res. 2010 110, 83-88
Rahman, A.M.; Hasegawa, H.; Rahman, M. M.; Rahman, A. M.; Miah, M.M.; and Miah, M.A.M.
Arsenic accumulation in rice (Oryza sativa L.): Human exposure through food chain.
Eco. and Enviro. Safety, 2008, 69, 317-342
Chen, M., Ma, L.Q., Harris, W.G. Arsenic concentrations in Florida surface soils: Influence of soil type
properties, Soil Sci. Soc. of Amer. J., 2002, 66, 632-640
• Cost: $25,000
Blue pixel count versus concentration of arsenic in mg kg -1 for five mass values at 1-20 reacted 20 minutes, 0.1 g (diamond),
0.5 g (square), 1 g (triangle), 5 g (x with a line), 10 g (x).
Plot of concentration of blue pixel value versus arsenic for 0.1 grams mass soil at 1-1000
mg kg-1 for four time periods; 1 hour(diamond), 45 min. (square), 30 min. (triangle), 20 min.(x).
Plot of concentration of arsenic in mg kg-1 versus average blue values for 0.05 g mass soil at 1 to 1000 mg kg -1for four
time periods, 20 min.(x), 30 min. (triangle), 45 min. (square), 1 hour (diamond)
Plot of concentration of arsenic in mg kg-1 versus average blue values for 0.1 g mass soil at 20 to 1000
mg kg-1for three extracting solvents, sulfamic acid 1 M (blue diamond), phosphoric acid 1 M (red
square), phosphoric acid 1 M at 24 hours (green triangles).
Time: continue to investigate the relationship between time of exposure and ability to
extract the metals from the soil matrix.