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Even Even 0 12
C, 16O, 32S
Odd Even ½ 1
H, 19F, 31P
3/2 11
B, 35Cl, 79Br
Even Odd ½ 13
C
3/2 127
I
5/2 17
O
Odd Odd 1 2
H, 14N
Role of Spin Quantum Number in NMR
Spin Number “I” determines whether the Atomic Nuclei is
NMR active or inactive.
For e.g. 12C, 16O, 32S these Atomic Nuclei have Spin
Number zero. Therefore, these nuclei are NMR inactive.
The Spin Number determines the number of orientation a
nucleus may assume in an external uniform magnetic
field in accordance with the formula 2I+1.
Principle of NMR
Shielded Protons
- A Proton is Shielded when it is surrounded by electrons whose Induced
Magnetic Field opposes the externally applied magnetic field and shields the
proton from its influence.
Deshielded Protons
- A Proton is Deshielded when bonded to a group which withdraws part of the
shielding electron density from around the proton.
These shifts in the position of NMR signals which arise from the shielding or
deshielding of electrons are generally called Chemical Shifts.
Chemical Shift ( δ, in ppm) is the position of an peak relative to that of a
Reference Substance such as TMS ( Tetra methyl Silane).
Factors Influencing Chemical Shift